US3482259A - Process of producing ledeburitic tool steel - Google Patents
Process of producing ledeburitic tool steel Download PDFInfo
- Publication number
- US3482259A US3482259A US601601A US3482259DA US3482259A US 3482259 A US3482259 A US 3482259A US 601601 A US601601 A US 601601A US 3482259D A US3482259D A US 3482259DA US 3482259 A US3482259 A US 3482259A
- Authority
- US
- United States
- Prior art keywords
- tube
- tool steel
- producing
- ledeburitic
- steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 25
- 229910001315 Tool steel Inorganic materials 0.000 title description 9
- 239000000463 material Substances 0.000 description 16
- 238000007670 refining Methods 0.000 description 9
- 229910000831 Steel Inorganic materials 0.000 description 8
- 238000005266 casting Methods 0.000 description 8
- 239000010959 steel Substances 0.000 description 8
- 229910000997 High-speed steel Inorganic materials 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 150000001247 metal acetylides Chemical class 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- 238000010891 electric arc Methods 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 210000001787 dendrite Anatomy 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/16—Remelting metals
- C22B9/18—Electroslag remelting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/06—Casting in, on, or around objects which form part of the product for manufacturing or repairing tools
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
Definitions
- This structure and particularly the coarse carbide network can adversely affect the quality of ledeburitic tool steels and particularly of high-speed steels.
- zone refining method which is used, e.g., in the electric slag refining process.
- an electrode consisting of the desired tool steel or high-speed steel is remelted in a layer of liquid slag.
- the molten metal from the electrode trickles in droplets through the slag into a water-cooled mold, where the ingot is progressively built up.
- Other processes in which zone refining can be practiced are electric arc remelting processes carried out in a vacuum or in a shielding gas and electron beam remelting processes.
- zone refining results in different crystallization conditions so that there is no formation of a fine-grained skin nor of a coarsegrained core or intermediate zone.
- Ingots made in such a remelting process have an approximately uniform structure and medium grain sizes at the center and at the surface.
- the present invention is based on the idea to combine the advantages of the usual ingot casting process with those of the zone refining process and to avoid the disadvantages of both kinds of processes.
- the molten metal may consist of the same alloy as the tube or, e.g., in the making of composite tools, of a different alloy.
- a material which has the same temperature expansion and phase transformation characteristics as the tube material will be referred to hereinafter as an akin material.
- the invention provides a process of producing a ledeburitic tool steel having carbides only in finegrained form, particularly a high-speed steel, which steel is suitable for the manufacture of tools, and the invention resides in that the hollow interior of a tube of the desired steel is filled by zone refining with an akin material.
- the tube may be cast, for instance. In this case the casting must be cooled so rapidly that a fine-globular solidification results.
- the melting rate of the electrode material must be selected so that a perfect fusion'bond to the tube results, on the one hand, and that sufficient tube material is not affected in its crystal structure by this fusion bonding. To this end, it has been found satisfactory to spray cooling water from nozzles onto the outside surface of that tube portion which is below the level of molten metal in the tube. Without such cooling, the buckling strength of the tube may not be satisfactory.
- the tube may be preheated before molten metal is poured into the tube.
- a tube consisting of a previously worked material may be employed. This will be desirable if a specific distribution and size of carbides is desired in the skin of the material to be made according to the invention.
- the tube may also be obtained by forming a bore in a casting. This will be desirable where castings having a fine-grained skin are available.
- the drawing shows a tube 1, an electrode 2 of akin material, molten slag 3, a pool 4 of molten metal and solidified metal 5.
- the material according to the invention may be used in the manufacture of tools Without Working. In this case the material must be process-annealed before it is machined. Alternatively, the material may be hotworked, e.g., by rolling or forging, and be used in a deformed state and after the required process-annealing may be used as a starting material in the manufacture of tools.
- the present invention eliminates a ditficulty which previously prevented a manufacture of high-grade tools, particularly of large-size tools, from ledeburitic steels, which can be metallurgically controlled only With difficulty.
- EXAMPLE 1 A tube consisting of a high-speed steel containing 0.80% carbon, 4% chromium, 2% vanadium, 6% tungsten, 5% molybdenum, balance iron and inevitable impurities had in an as-cast condition an outside diameter of 250 mm. and a wall thickness of 42 mm. and was forged to a diameter of 200 mm. and a wall thickness of 37 mm. The hollow interior of the tube was filled with the same material in an electric arc zone remelting process carried out in a vacuum.
- EXAMPLE 3 A cylindrical ingot consisting of 1.10% carbon, 3.75% chromium, 1.15% vanadium, 1.50% tungsten, 9.50% molybdenum, 8% cobalt, balance iron and inevitable impurities, and having a diameter of 430 mm. was bored to form a tube having a wall thickness of 50 mm. The hollow interior of the tube was filled with the same material in an electric arc zone remelting process under argon as a shielding gas.
- a process of producing a material which consists of lede'buritic tool steel and contains carbides only in a fine-grained form comprising providing a tube consisting of lcdeburitic tool steel which contains carbides only in fine-grained form, and producing in situ in said tube a core of ledeburitic tool steel having the same thermal expansion and phase transformation characteristics as said ledeburitic tool steel of said tube by a zone-refining process, said core being simultaneously fusion-bonded to said tube.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Heat Treatment Of Articles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT1122265A AT269933B (de) | 1965-12-14 | 1965-12-14 | Verfahren zur Erzeugung eines feinkarbidischen Vormaterials aus ledeburitischen Werkzeugstählen, insbesondere Schnellarbeitsstählen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3482259A true US3482259A (en) | 1969-12-02 |
Family
ID=3627513
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US601601A Expired - Lifetime US3482259A (en) | 1965-12-14 | 1966-12-14 | Process of producing ledeburitic tool steel |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3482259A (de) |
| AT (1) | AT269933B (de) |
| CH (1) | CH488508A (de) |
| DE (1) | DE1508127B2 (de) |
| FR (1) | FR1504348A (de) |
| GB (1) | GB1153798A (de) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3603374A (en) * | 1969-02-10 | 1971-09-07 | Heppenstall Co | Methods of producing large steel ingots |
| US3743005A (en) * | 1970-09-22 | 1973-07-03 | Voest Ag | Process for producing hot rolled three layer steel products from continuously cast hollow tubes |
| US3779299A (en) * | 1970-05-15 | 1973-12-18 | Permanence Corp | Tire stud |
| US4544019A (en) * | 1982-05-14 | 1985-10-01 | Hitachi, Ltd. | Method and apparatus for manufacturing composite steel ingot |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2137265A1 (en) * | 1971-05-17 | 1972-12-29 | Heppenstall Co | Pipe-free steel ingot prodn |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3067473A (en) * | 1960-03-29 | 1962-12-11 | Firth Sterling Inc | Producing superior quality ingot metal |
| US3139654A (en) * | 1959-05-28 | 1964-07-07 | Titanium Metals Corp | Mold assembly |
| US3287769A (en) * | 1963-02-11 | 1966-11-29 | Euratom | Vacuum melting and casting apparatus |
-
1965
- 1965-12-14 AT AT1122265A patent/AT269933B/de active
-
1966
- 1966-12-09 CH CH1777866A patent/CH488508A/de not_active IP Right Cessation
- 1966-12-12 DE DE1508127A patent/DE1508127B2/de not_active Ceased
- 1966-12-13 FR FR87166A patent/FR1504348A/fr not_active Expired
- 1966-12-14 GB GB55975/66A patent/GB1153798A/en not_active Expired
- 1966-12-14 US US601601A patent/US3482259A/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3139654A (en) * | 1959-05-28 | 1964-07-07 | Titanium Metals Corp | Mold assembly |
| US3067473A (en) * | 1960-03-29 | 1962-12-11 | Firth Sterling Inc | Producing superior quality ingot metal |
| US3287769A (en) * | 1963-02-11 | 1966-11-29 | Euratom | Vacuum melting and casting apparatus |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3603374A (en) * | 1969-02-10 | 1971-09-07 | Heppenstall Co | Methods of producing large steel ingots |
| US3779299A (en) * | 1970-05-15 | 1973-12-18 | Permanence Corp | Tire stud |
| US3743005A (en) * | 1970-09-22 | 1973-07-03 | Voest Ag | Process for producing hot rolled three layer steel products from continuously cast hollow tubes |
| US4544019A (en) * | 1982-05-14 | 1985-10-01 | Hitachi, Ltd. | Method and apparatus for manufacturing composite steel ingot |
Also Published As
| Publication number | Publication date |
|---|---|
| CH488508A (de) | 1970-04-15 |
| DE1508127A1 (de) | 1970-03-12 |
| GB1153798A (en) | 1969-05-29 |
| FR1504348A (fr) | 1967-12-01 |
| AT269933B (de) | 1969-04-10 |
| DE1508127B2 (de) | 1974-02-21 |
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