US3547193A - Method and apparatus for recovery of minerals from sub-surface formations using electricity - Google Patents

Method and apparatus for recovery of minerals from sub-surface formations using electricity Download PDF

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US3547193A
US3547193A US868277A US3547193DA US3547193A US 3547193 A US3547193 A US 3547193A US 868277 A US868277 A US 868277A US 3547193D A US3547193D A US 3547193DA US 3547193 A US3547193 A US 3547193A
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casing
formation
conductive
electrode
insulating
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William G Gill
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Electrothermic Co
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Electrothermic Co
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
    • E21B43/2401Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection by means of electricity

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  • Murphy ABSTRACT There is disclosed a method and apparatus in which electrical current is caused to flow through water in a mineral bearing, subsurface formation to produce heating of the mineral and promote the recovery thereof.
  • An electrode is established in the formation which extends into the formation from the bore hole, and which has a greater effective diameter than the diameter of the bore hold. Electrical current is caused to flow from the electrode through the formation to heat the mineral to be recovered.
  • One specific electrode disclosed is formed of shot or pellets packed into the formation and another electrode disclosed is a collapsible member which extends into the formation.
  • the method and apparatus of the present invention are especially adapted to the secondary recovery of oil, but also has application to production of other minerals, particularly sulphur.
  • the present invention renders it feasible to provide an electrode of any desired diameter in mineral-bearing formation, such that any desired area can be heated. For example, if an electrode is installed in the mineral-bearing formation and the effective diameter of the electrode is 25 feet, and assuming favorable boundary conditions, an area of approximately 225 feet in diameter would be heated with approximately 50 percent of the heat being produced in an area 75 feet in diameter. Accordingly, it is feasible to introduce into the formation a much greater amount of heat in a much shorter period oftime.
  • a method and apparatus for producing minerals from a subsurface formation through a bore hole extending from the surface into the formation wherein an electrode is established in the formation which extends into the formation from the bore hole and thereafter electrical current is caused to flow from the electrode through the formation to heat the mineral to be recovered.
  • the electrode comprises conductive shot or pellets which extend into the formation and which is electrically connected to a source of supply voltage.
  • a collapsible member is utilized as the electrode, such that when the electrode is properly positioned in the bore hole it can be collapsible, causing portions thereof to be extended into the formation providing an electrode of increased diameter.
  • HO. 1 is a view diagrammatically illustrating a well bore penetrating a mineral-bearing formation in accordance with one embodiment of the invention
  • FIG. 2 is a side elevation view of a tool for providing an electrode in accordance with a second embodiment of the invention
  • FIG. 3 is a view diagrammatically illustrating a second embodiment of the invention in which the tool of FIG. 2 is used, the tool being shown in the operative position;
  • FIG. 4 is a view diagrammatically illustrating a typical oil field layout
  • FIG. 5 is a view diagrammatically illustrating a third embodiment of the invention.
  • FIG. 6 is a view diagrammatically illustrating a fourth embodiment of the invention.
  • FIG. 7 is a view diagrammatically illustrating a fifth embodiment of the invention.
  • FIG. 1 of the drawings there is shown a well bore 10 which penetrates the surface of the earth into a mineral bearing formation l2.
  • the present invention is especially adapted for the secondary recovery of oil and the preferred embodiments thereof will be described with reference to the secondary recovery of oil, but also can find great utility in production of sulphur and other liquifiable minerals.
  • Apparatus in accordance with one specific example of the invention especially useful in the recovery of oil includes a string of casing 14- which extends from the surface into the formation 12.
  • the string of casing l4 includes an upper conductive portion 18 suitably of conventional steel casing material, an insulating portion 20, and a screen 22 which can be considered as part of the casing string.
  • the insulating portion 20 is suitably of fiberglass material although in some instances ceramic material is preferred.
  • the lower end 24 of the insulating portion 20 extends to the top of the mineral bearing formation l2 and the screen 22 extends from the bottom of the bore hole into the insulating portion 20.
  • a thermal packer 28 suitably of the type made of asbestos, is positioned at the top of the screen 22 for holding the screen 22 in place and closing the annular space 27 between the screen and the insulating portion 20 of the casing.
  • the screen 22 is suitably of conventional type and comprises a length of pipe having longitudinal slots cut therein. I-ieavy wire is wrapped around the length of pipe and in conjunction with the slots cut in the length of pipe provides aperatures through which oil can flow into the easing.
  • Screen 2.2 is preferably formed of stainless steel material. preferably formed of stainless steel material.
  • a string of conventional tubing 16 which is of steel or other conductive material such as aluminum.
  • Tubing 16 extends below the lower end 24 of the insulating casing 29, preferably to a point near the bottom of the bore hole.
  • a string of insulating tubing 29 which extends between the tubing 16 and the conductive portion 18 of casing M.
  • the tubing 29 is preferably formed of fiberglass material as it has been found to provide excellent results at reasonable cost in most application.
  • Other types of insulating tubing can be used, such as epoxy-coated tubing of the regular type.
  • the string of tubing 16 is electrically connected to the screen 22 by a centralizer 3% or by a decentralizer, both of which are well known in the art.
  • a preferred form of centralizer may include longitudinal bands or springs 31 mounted in a manner to be forcibly bowed outwardly from the tubing 16 into engagement with the internal cylindrical surface of the screen 22, with the bands being coated with carbon in the area of engagement with the screen surface.
  • the inner surface of the screen which is engaged by the centralizer may also be coated ing 16 by conductor 34 and connected by conductor 36 to the conductive portion 18 of the string of casing. Electrodes 40 extend from the screen 22 into the formation from the bore hole 10.
  • the effective diameter of the electrodes 40 can be substantially greater than the diameter of the screen 22.
  • the flow of electrical current will be from the electrodes 40 through the conductive portion lb of the casing 14 to the source of alternating current supply voltage and through the tubing 16, the centralizer 3b and the screen 22 to the electrode.
  • electrodes an comprise a mass of conductive particles which are packed into cavities which extend into the formation from the bore hole but which remain porous and permeable to the flow of fluid.
  • the conductive particles preferably consist of conductive metal shot, or pellets coated with carbon, but may consist of uncoated metallic pellets or carbon pellets or granules. These particles preferably directly engage the exterior cylindrical surface of the screen 22; and
  • this surface may be carbon coated for the purpose of providing good electrical contact with the conductive particles.
  • the present invention also provides a method for establish- .ing the apparatus shown in FIG. 1 of the drawings.
  • conventional drilling methods are used to drill a bore hole which exrtends from the surface into the formation 12.
  • the portion of the bore hole within the formation can also be formed by conrventional drilling methods, but it is preferred that the portion of the well bore extending into the formation be cored in order that information can be obtained as to the character of the mineral-bearing formation.
  • the casing is then set in the 'bore hole with the lower insulating portion preferably extending a short distance into the formation.
  • the casing 14 is set in place by pumping concrete under pressure into the earth surrounding the lowermost portion of the casing to fill the annulus between the casing and the well bore.
  • a cement basket (not shown) of the type well known in the art can be used to prevent the cement used to set the casing from flowing down into the portion of the well bore that extends into the mineralbearing formation. 112.
  • cavities 42 are formed in the formation 12 with the cavities 42 extending outwardly into the formation 12 from the well bore litl. Cavities 42 can be formed at one or more elevations depending upon the thickness of the mineral-bearing formation.
  • the notches or cavities 4 2 are preferably formed by using an abrasive jet or hydrojet of the type well known in the oil industry.
  • a stream of sand or other abrasive material carried in either water or light oil is pumped through a nozzle at high pressure against the face of the producing formation with the jet nozzle rotating in a circular path to cut a disc from the formation to any desired depth.
  • the vertical dimension of the notch or cavity can be controlled by raising or lowering the jet nozzle.
  • the formation can be treated with a suitabe acid of the type well known in the art if the reservoir or formation is oflimestone or other calcareous structure, such that the chemical reaction would be helpful.
  • a suitabe acid of the type well known in the art if the reservoir or formation is oflimestone or other calcareous structure, such that the chemical reaction would be helpful.
  • the notch or cavity can be formed with a mechanical underreamer or, if the formation is of a character permitting such, by a treatment with acid alone.
  • the portion of the bore hole extending into the formation and the cavity or notches 26 formed as described above are then filled with conductive particles such as metallic shot or carbon granules.
  • conductive particles such as metallic shot or carbon granules.
  • This is suitably accomplished by pumping the particles into the bore hole with the particles being carried in suspension in a liquid such as saltwater or diesel oil to which a jell-forming organic material has been added.
  • Conventional drilling mud can be used, but in general the salt water jell or diesel oil jell is preferred as there is greater tendency for the shot to fall out of suspension in the bottom of the bore hole and there is less chance of formation damage.
  • the size of the electrode can be increased further by applying pressure to the bore hole in a manner conventional in the art to produce fracturing of the formation and further increase the extent to which the electrode extends into the formation away from the bore hole.
  • the screen 22 is washed into position using conventional techniques.
  • the packer 28 is set to mechanically connect the screen 22 into the string M of casing. It will be noted that not only does the packer hold the screen in place but it also seals the joint therebetween holding the conductive particles forming the electrode in place but permitting the conductive shot which remains within the screen to be washed out of the string of casing providing a space into which mineral to be produced can flow. it will also be noted in this regard that in the event the electrode should become dissipated, it can be replaced by removing the packer and washing additional conductive material into place in the formation.
  • the conductive path not be provided between the string of tubing 15 and the conductive portion 18 of the string of casing l4, except through the formation. Accordingly, depending upon the characteristics of the well, the amount of water present, and other factors, it may be desirable to set an additional packer 46 in the space between the tubing 28 and the insulating portion 20 the string of casing 14 to prevent liquid rising in the annulus 48 therebetween. If desired, the annulus can be filled with oil or nitrogen gas to further restrict the possibility of flow of current directly between the tubing 15 and the casing 18 and also to serve as heat insulation. However, the packer 46 will not be required in all installations.
  • the large area which is heated provides a substantial volume in which the mineral to be recovered has high mobility, and if the mineral is oil, even though the oil outside the heated area remains very viscous, the area surrounding the volume which is heated to the extent that the oil has a high mobility due to its reduced viscosity is very large. Accordingly, even though oil outside the heated area is very viscous, a very large effective area is provided into which the oil can flow and, assuming adequate drive is present in the field, substantial quantities of oil can be recovered as a result of the flow of the oil into the area of heat. Further, it is important to note that the heating process is continuous and is not in any way effected by the flow of oil into the screen, assuming that sufficient connate water is present to maintain the electrical circuit. in virtually all formations, this amount of connatc water will be present.
  • the screen is formed to have a center section as shown in FIG. 2 of the drawing with the remainder of the installations as respect to the tubing and easing, suitably being as shown in FIG. l.
  • the screen in accordance with this second embodiment of the invention, includes an upper portion 60 and a lower portion 62, each of which has apertures formed therein as described previously with respect to screen 22 of FIG. l of the drawings.
  • Upper portion 64 includes a cylindrical portion 64 of reduced diameter which is adapted to slide within the upper end 66 of the lower portion 62.
  • the portions 64 and 66 are suitably connected by a pin 68.
  • a collapsing metal basket '70 Positioned on and carried by the screen is a collapsing metal basket '70 which is connected at one end '72 to the upper portion 6t) and a lower end '74 to the lower portion 62.
  • the basket diameter is very little more than the diameter of the screen, accordingly the assembly can be moved up and down through the casing 14.
  • the pin will be sheared permitting cylindrical portion 64 to slide further into the lower portion 62 into a position as shown in FIG. 3 of the drawings.
  • the metal basket When in such position, the metal basket will be expanded outwardly such that the circumference of the electrode provided by the metal basket is substantially greater than the circumference of the bore hole.
  • the formation from which the mineral is to be produced is of soft material it may be possible for the basket to punch into the formation as it expands.
  • the formation is of hard material, it is preferable to form notches or cavities as described with reference to H6. i into which the basket will protrude as it is expanded.
  • H6. 3 also illustrates an alternative means for insulating the tubing 56 from the string of casing 14. It will be noted that in the embodiment of the invention shown in FIG. 3 of the drawings, a string of insulating tubing is not provided. Rather insulating packer 78 is set between the tubing 16 and the insulating portion 20 of the string of easing. Positioned along the length of tubing above the tubing is a plurality of insulating spacers 8b which are formed of an insulating material. The insulating spacers are preferably of a spider configuration and formed of Teflon or other insulating material which can withstand the temperature present in the well bore.
  • the insulating spacers maintain the tubing 16 centrally positioned within the bore of the casing, preventing electrical or mechanical contact between the tubing l6 and the conductive portion of the casing 14-.
  • the annulus between the tubing 16 and the casing 14 is preferably filled with insulating fluid 79, which suitably can be a heavy crude oil.
  • insulating fluid 79 which suitably can be a heavy crude oil.
  • FIG. 4 of the drawing there is shown diagrammatically a typical oil field comprising a plurality of oil wells.
  • a source of supply voltage 84 is connected between the tubing of wells 86 and 38 which extend into mineral bearing formations.
  • the source of supply voltage 84 is connected between the tubing of well 86 and the tubing of a well 88 such that the flow of electrical current will be down one length of tubing, through the electrode associated with it thence through the formation to the electrode of the second well with the return path for the flow of current being through the tubing of the second well.
  • the amount of voltage required will be approximately twice that required in an installation such as that shown in H6. 2 if an equivalent amount of heating is to be produced at each well.
  • the principal advantage of installation such as that shown in FlG. 3 is that the insulation requirements between the tubing to and the casing are not as stringent as the purpose of insulation is to insure that the electrical current flows from the electrode in the formation rather than a portion of the casing positioned in the overlying strata acting as an electrode.
  • H68. 5 and 6 illustrate embodiments of the invention which are particularly suitable for the recovery of minerals from producing formations which are relatively thin.
  • a bore hole which has been drilled from the surface downward through a producing formation 1E2
  • a string of casing has been set in the bore hole extending to the lower surface of the formation 12; the casing including a lower insulating portion hi3 which extends from the lower surface of the formation to a point somewhat above the surface of the formation, and an upper insulating portion 114 extending from this insulating portion to the surface.
  • the casing is suitably cemented within the bore hole; and a cement bottom plug MS may be provided to define the bottom of the bore hole and prevent direct electrical contact with the underlying strata which may be a low resistivity material such as shale.
  • An electrode 118 similar to that described in connection with FIG. 1, is provided; however, in this embodiment a portion of the insulating casing 113 is cut away along with a portion of the encasing cement to define an annular slot ii) in the casing wall communicating with the formation Hi2.
  • This slot is provided by techniques which are well known in the art.
  • An adjacent cavity or notch 12% is then provided in the formation M2, again using conventional techniques as described in connection with the embodiment of the FIG. l.
  • the lower portion of the bore hole including the cavity is filled with conductive particles, of the type described heretofore, to define the expanded electrode lib; and these particles are retained in place by a conductive screen R21 set within the insulated casing 113 and extending from the bottom of the bore hole to a point above the top of the formation 112 but within the insulating portion 113 of the casing,
  • the upper end of the screen is sealed relative to the casing ass by means ofa packer 122 to retain the conductive electrode particles in the cavity R26 and within the annulus defined by the screen and the casing.
  • a string of conventional tubing R24 fabricated of steel, aluminum or other conductive material, is supported from the surface and extends downwardly into the screen $21 and is electrically connected to the screen by a centralizer E25.
  • This tubing defines a conductor for the flow of current from the surface to the electrode 118, and is insulated from the conductive casing M4 by a string of insulating tubing 126, as in the embodiment of HO. 2.
  • This insulating tubing 126 extends in the bore hole to a depth sufficient to overlap the upper end of the insulating tubing 126 with the upper end of the insulating casing M3 to prevent a short-circuiting flow ofcurrent, within the casing, from the conductive tubing i134 to the conductive casing lid.
  • the described electrode is porous and permeable to the flow of fluid, which flows into the well through the electrode.
  • FIG. 6 illustrates an alternative embodiment of the invention for use in a shallow producing formation Hi2, where the formation is heated by alternating current flowing through the formation between two wells, as discussed in respect to FIG. 4.
  • the structure of the well in FIG. 6 is quite similar to that of FIG. with a principal exception that the entire string of casing 135 is fabricated of an insulating material, such as fiberglass or ceramic and the string of insulating tubing 126 is omitted.
  • the structure of the well, in the area of the formation R12, is the same as that of FIG. 5, the electrode E18 being formed from conductive particles packed into a formation cavity 1% and the annular space defined between the conductive screen 121 and the lower end of the insulating casing 135,
  • a second packer 136 may be provided if it is desired to seal the tubing 124 to the casing 135 above the screen 121.
  • a string of conductive tubing 124% extends from the surface to the screen R21 and is electrically connected thereto by the centralizer 125.
  • the insulating casing 335 insulates the tubing 124 from the bore hole throughout the entire depth of the bore hole except in the area of the electrode lib.
  • a source of alternating current supply voltage 140 is connected by means of one conductor Hill to the conductive tubing I24; and a conductor 142 may connect the voltage source 140 to the corresponding conductive tubing of an adjacent bore hole to define a second electrode 113 within the formation.
  • the second conductor 142 may be connected to the conductive casing of an adjacent well, or to an auxiliary electrode or pipe serving as a return for current flowing through the formation.
  • FIG. 7 illustrates still another alternative embodiment of the invention which is particularly advantageous for use in deeper wells.
  • the structure of the well of FIG. '7 is quite similar to that of FIG. 6 with the well being provided with a string of insulating casing 145 which extends from the surface to the bottom of the well bore defined by the cement bottom plug M5, which is preferably in insulating cement.
  • the insulating casing 145 is not, however, fabricated from an insulating material as is the casing of FIG. 6. Rather, the casing is made up ofa string of conductive metal casing 146 which has been fabricated with a coating or layer M7 of insulating material, such as fiberglass or epoxy.
  • additional insulating material may be applied at the joints and cured by known techniques, to assure continuity of the insulating coating along the string.
  • One of the advantages of this form of casing is that of providing an insulating barrier adjacent to the walls of the bore hole while, at the same time, enabling the use ofa higher strength casing which may be required in deeper wells.
  • An additional advantage is that the casing, while providing the above-mentioned insulating function, may provide an additional low-resistance conductive path from the surface to the bottom of the hole; as illustrated in FIG. 7.
  • the electrode IE8 is formed in a manner similar to that of FIGS. 5 and 6, being formed of conductive particles packed into a formation cavity 126) at the casing slot ill), and also into the annular space defined between the conductive screen 122 and the lower end of the casing M5, the. screen again being sealed to the casing by means of a packer R22 to retain the conductive particles. in this annular space, the electrode particles conveniently contact the inner wall of the conductive portion 146 ofthe casing to provide the desired electrical connection between the casing and the electrode particles.
  • a string of conductive tubing 124 which is the production tubing for the well, extends from the surface to the screen Hi.
  • the electrical connection between the tubing llZd and the screen lZll is provided by a plurality of metallic springs or brushes E48 which are mounted in the interior wall of the screen 12.. and extend inwardly to engage the tubing 124.
  • These contact springs M8 are fixed to the interior walls and screen in any suitable manner, such as by welding or riveting, with the lower ends of the springs formed to be urged inwardly.
  • One terminal of a source of alternating current supply voltage lfi'ili is connected by means of conductors l5l and 152 to the tubing 124 and the casing M5, respectively.
  • Another terminal of the source of supply voltage is connected by means of conductor 153 to another conductive path to the formation which may be defined by conductive pipe in an adjacent bore hole, or other electrode or pipe serving as a return for current flowing through the formation.
  • the electrode in accordance with the present invention can be used advantageously in installations other than those described as preferred, specific example of the invention when the mineral to be produced is oil.
  • the installation will, of course, be substantially different if minerals other than oil, such as sulphur are to be produced.
  • the shot and the formation form an underground cracking unit whose efficiency is a function of the surface area of the shot forming the electrode.
  • the sand in formation further contributes to the surface area. It will be noted, in this connection, that if the field is one having mobility that pressure will be maintained at the bottom of the hole and this, in conjunction with the surface area of the shot in the sand and the heat provided as a result of a flow of electrical current, produces a cracking effect in the formation. it is also theorized that the steel shot may act as a catalyst to some extent.
  • a method for producing minerals from a subsurface formation through a bore hole extending from a surface into the formation comprising the steps:
  • a method as set forth in claim 1 wherein said electrode is established by collapsing a collapsible member within said bore hole, to cause portions of said collapsible member to extend laterally into said cavity from said bore hole.
  • a method as set forth in claim l including positioning a conductive screen in said bore hole in electrical contact with said electrode.
  • a method as set forth in claim 5 including establishing electrical contact between said pipe and said screen by means of a centralizer fixed to said pipe and having carbon-coated members contracting said screen.
  • a method as set forth in claim l including positioning a conductive screen in said bore hole in electrical contact with said electrode and spaced apart from said conductive casing a substantial distance.
  • a method as set forth in claim 1. including providing a string of insulating casing extending from the surface to said formation, to insulate said conductive pipe from the walls of said bore hole.
  • Apparatus for producing minerals from a subsurface formation through a bore hole extending from the surface into the formation comprising:
  • a string of conductive pipe extending from the surface to said electrode; means electrically connecting said conductive pipe to said electrode; said electrode, said connecting means and said conductive pipe defining a first relatively low-resistance electrically conductive path to said formation;
  • insulating means for insulating said conductive pipe from walls of said bore hole above said electrode
  • lltll means defining a second relatively low-resistance conductive path from the surface to said formation
  • a source of supply voltage connected at the surface to said conductive pipe and to said second conductive path means to produce a flow of electric current through said formation to heat the mineral to be produced.
  • Apparatus as set forth in claim l3 including a length of conductive casing in said formation contacting said conductive particles; and connecting means electrically connecting said conductive pipe and said length of conductive casing.
  • connecting means comprise contact members coated with carbon.
  • Apparatus as set forth in claim l6 including a string of conductive casing in said bore hole extending from the surface to a point above said electrode, defining said second conductive path; and means insulating said string of conductive casing from said length of conductive casing in said formation to effect the flow of current through a path of substantial length in said formation between said electrode and said conductive casing.
  • Apparatus as set forth in claim 16 including a string of casing in the bore hole extending from the surface to said formation; said string of casing including an upper conductive portion extending from the surface to a point above said electrode defining said second conductive path, and a lower insulating portion of substantial length extending between said upper conductive portion and said length of conductive casing in said formation to effect a flow of current through a path of substantial length in said formation between said electrode and said conductive portion.
  • Electrode comprises a collapsible member received in said bore hole, and collapsible to urge portions thereof into a cavity extending laterally from the bore hole.
  • said collapsible member includes a first tubular member having an end portion of reduced diameter, a second tubular member having an end portion adapted to slidably receive the end portion of reduced diameter, means releasably connecting said first and second tubular members in extending relation. and a collapsible basket member connected between said first and second tubular members and adapted to extend. laterally outward in response to movement of said first portion into said second portion from said extended position.
  • Apparatus as set forth in claim if. wherein said means defining a second conductive path comprises a string of conductive pipe positioned in a second bore hole spaced apart from the first mentioned bore hole.
  • Apparatus as set forth in claim 12 including a string of casing in said bore hole extending from the surface to said formation.
  • said casing includes an upper conductive portion extending from the surface to a point above said electrode; said portion said second conductive path; and
  • said casing including a lower insulating portion of substantial length, insulating said conductive portion from said electrode, to effect the flow of current through a path of substantial length in said formation between said electrode and said conductive casing.
  • Apparatus as set forth in claim 2? including means for insulating said conductive pipe from said upper conductive portion of said casing.
  • said insulating means comprises a string of insulating tubing disposed in the annulus between said pipe and said casing.
  • insulating means comprises a plurality of insulating spacers disposed between said pipe and said casing.
  • said insulating means comprises an insulating fluid filling the space between said pipe and said casing.
  • said casing includes a lower insulating portion extending into said formation
  • Apparatus as set forth in claim 35 including means electrically connecting said string of casing between said electrode and said supply source to define a portion of said first relatively low-resistance electrically conductive path.

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Cited By (146)

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US3857776A (en) * 1973-06-14 1974-12-31 Electro Petroleum Deep submersible power electrode assembly for ground conduction of electricity
US3946809A (en) * 1974-12-19 1976-03-30 Exxon Production Research Company Oil recovery by combination steam stimulation and electrical heating
US3958636A (en) * 1975-01-23 1976-05-25 Atlantic Richfield Company Production of bitumen from a tar sand formation
US4037655A (en) * 1974-04-19 1977-07-26 Electroflood Company Method for secondary recovery of oil
US4084637A (en) * 1976-12-16 1978-04-18 Petro Canada Exploration Inc. Method of producing viscous materials from subterranean formations
US4199025A (en) * 1974-04-19 1980-04-22 Electroflood Company Method and apparatus for tertiary recovery of oil
US4303128A (en) * 1979-12-04 1981-12-01 Marr Jr Andrew W Injection well with high-pressure, high-temperature in situ down-hole steam formation
US4463805A (en) * 1982-09-28 1984-08-07 Clark Bingham Method for tertiary recovery of oil
US4484627A (en) * 1983-06-30 1984-11-27 Atlantic Richfield Company Well completion for electrical power transmission
US4495990A (en) * 1982-09-29 1985-01-29 Electro-Petroleum, Inc. Apparatus for passing electrical current through an underground formation
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US4545435A (en) * 1983-04-29 1985-10-08 Iit Research Institute Conduction heating of hydrocarbonaceous formations
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US4645004A (en) * 1983-04-29 1987-02-24 Iit Research Institute Electro-osmotic production of hydrocarbons utilizing conduction heating of hydrocarbonaceous formations
US4651825A (en) * 1986-05-09 1987-03-24 Atlantic Richfield Company Enhanced well production
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