US3567356A - Reactive and disperse dyes fixed on cellulose blended fabrics travelling on drum radially passing hot gas - Google Patents

Reactive and disperse dyes fixed on cellulose blended fabrics travelling on drum radially passing hot gas Download PDF

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Publication number
US3567356A
US3567356A US637457A US3567356DA US3567356A US 3567356 A US3567356 A US 3567356A US 637457 A US637457 A US 637457A US 3567356D A US3567356D A US 3567356DA US 3567356 A US3567356 A US 3567356A
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Prior art keywords
fabric
reactive
dyestuffs
disperse
travelling
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Expired - Lifetime
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US637457A
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English (en)
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Hans-Ulrich Von Der Eltz
Richard Gross
Kurt Petersen
Jurgen Schafer
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Hoechst AG
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Hoechst AG
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
    • D06P3/8238—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye
    • D06P3/8252—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye using dispersed and reactive dyes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S68/00—Textiles: fluid treating apparatus
    • Y10S68/903—Perforated drum and continuous textile feed and discharge

Definitions

  • mixed fabrics made of cellulose and synthetic fibers preferably of high molecular weight linear polyesters, can be simultaneously dyed or printed with reactive and disperse dyestuffs according to the thermosol process.
  • the mixed fabric is padded with an aqueous preparation containing, besides disperse and reactived dyestuffs, alkalies and, if necessary, further auxiliaries, such as for example wetting substances and thickeners.
  • the fabric is subsequently dried and then subjected, for 30 to 60 seconds, to a thermal treatment at temperature of about 185 to 230 C.
  • a thermal treatment at temperature of about 185 to 230 C.
  • the polyester portion of the mixed fabric is fixed in order to provide its optimal technological properties.
  • the fixation of the disperse dyestuffs in the polyester fiber and that of the reactive dyestuffs in the cellulose fiber takes place.
  • the high temperatures and the long fixation periods are necessary to obtain, besides the fixation of the fabric, a maximum fixation of the disperse dyestuffs.
  • the long fixation periods and the high fixation temperatures which are required cause a partly high loss in yield of the dyestuff being fixed, sometimes accompanied by a marked change of the tint.
  • the fixation yield of the reactive dyestuffs could be increased, though this would reduce the yield of the disperse dyestuffs being fixed.
  • the yield of the reactive dyestuffs being fixed could be increased likewise, though this would reduce the yield of the disperse dyestuffs and, above all, impair the textile-technological properties of the polyester fibers.
  • the mixed fabric is generally transported horizontally through a so-called stretching frame, whereby heated gas, mostly heated air, sometimes also overheated steam or a mixture of air and overheated steam, is blown from both sides onto the fabric.
  • heated gas mostly heated air, sometimes also overheated steam or a mixture of air and overheated steam, is blown from both sides onto the fabric.
  • the fabric is carried on through the stretching frame by means of pins and clips, so-called clamps, which fasten the material at the selvedges and adjust the breadth of the material as desired.
  • the heating time required for this process is usually about 30-60 seconds.
  • the process of the invention not only has the advantage of permitting better yield of the reactive dyestuif being fixed but it also permits a considerably higher production rate, since the fixing period can be essentially reduced, so that, depending on dyestuff and type of fabric, complete fixation of the synthetic fiber and of the dispersion dyestuff is obtained after a period of about 1-20 seconds; whereas the usual fixation on the stretching frame is obtained at the same temperature only after about 30-60 seconds. It is very surprising that by blowing heated gas through the textile materials from one side the fixing period is shorter than when the heated gas is blown over the material from both sides.
  • the textile material is passed over sieves, preferably, cylindrical sieves 5' which serve as carrying and transporting elements for this material.
  • sieves preferably, cylindrical sieves 5' which serve as carrying and transporting elements for this material.
  • Rotating perforated cylinders cylindrical sieves
  • the textile material is passed over the cylinders and is pressed and kept on the sieves by the heated gas which is forced through it, so that the textile material need generally not be transported by an additional means.
  • the textile materials may additionally be fastened at both sides by means of appropriate devices, for example, pins, dents or clips.
  • the heated gas is sucked or pressed through the textile material into the cylinders and is expelled from the cylinder through the front side with the aid of ventilators 3.
  • the gas is then passed over a heating device 4 and once more conducted towards the surface of the cylindrical sieves.
  • the continuous circulation of the gas assures a constant temperature and thus a uniform and quick conveying of heat to the textile material.
  • the perforation design may be finely shaped. It is, however, also possible and in many cases advantageous, to cover the perforated cylindermantle with a preferably seamless fine-meshed sieve 6 on which the textile material then lies. It is also possible to use several layers of sieve-fabric. It is suitable and advantageous that the sieve-fabric which comes in contact with the textile material, has the finest possible meshes, the distance between the wires of the sieve-fabric being advantageously less than 1 mm., preferably less than 0.3 mm.
  • the textile material is passed over the cylinders in such a manner as to cover about /3 to /2, advantageously, not more than of the cylinder mantle, or inversely, the cover generally screens about A to /3 of the cylinder mantle against the access of gas.
  • the diameter of the cylinder may be adapted to each individual case and to the industrial requirements.
  • the cylinders chosen generally have a diameter within the range of from 50 to 350 cm., but cylinders of a greater size may also be used, for example, those having a diameter of about 10 m.
  • the width of the cylindrical sieves depends on the textile material to be treated. In most cases, it is within the range of from 90 to 200 cm., but it may, however, be even greater or smaller if required. It is not an inconvenience if a part of the perforated cylinder mantle is not covered with the material. In extreme cases, i.e., a broad cylinder and a narrow width of the material, the margin of the mantle surface which is not covered with the material, may be covered with a correspondingly adjusted cuff.
  • thermosetting apparatus with cylindrical sieves is shown in the accompanying drawing (FIGS. 1 and 2).
  • the number of revolutions of the cylinders is advantageously adapted to each individual case, and depends on, for example, the diameter of the cylinder, the number of cylinders used and the fixing period required. It is also possible to vary the number of revolutions of the cylinders arranged in series so that each cylinder rotates a little slower than the preceding one, whereby an' overfeeding of the material is achieved and thus the material can shrink in its warps without tension as a result of the action of heat. Another possibility of achieving an overfeeding of the material is obtained by passing the material to the cylindrical sieves over a feeding arrangement 8, for example, a pair of rollers, at a speed which is greater than that of the first cylinder.
  • Another decisive influence on the fixing period required and, thus, on the production rate is determined by the speed at which the heated gas is passed through the material.
  • This speed can be regulated by adjusting the number of revolutions of the ventilators as required.
  • This speed is furthermore determined by the thickness of the textile material lying on the cylinder, it is generally adjusted to 0.5-5 metres/second. It is advantageous to maintain the gas flow at a velocity of more than 2 metres/ second.
  • the period of heat transfer to the textile material and of the fixing process may be shortened by further appropriate means.
  • the material may be preheated before being introduced into the thermosetting apparatus, by passing it over heated rolls, by infrared irradiation or similar arrangements. It is also possible to additionally heat the cylindrical sieves by appropriate devices, for example, by infrared irradiators or by electric heaters.
  • thethermosetting apparatus has a sufiicient output, it is also possible to dispense with the preheating of the padded or printed textile material and to heat and fix the material within the apparatus.
  • the textile material may be passed for that purpose, for example, over one or several cooling rolls or cold air may be blown on or passed through the material after its leaving the thermosetting apparatus.
  • gases serving as heat transferring agents according to the process of the present invention there may be used all inert, noninflammable gases or mixtures of gases. Suitable gases are, for example, nitrogen or carbon dioxide, preferably air. There may furthermore be used steam per se or steam in mixture with the gases mentioned, advantageously, with air.
  • the fixing temperatures to be applied in the process of the present invention are to be adapted to the conditions of each individual case. In general, they are in the range of from about to about 230 C.
  • the fixing period which depends above all on the dispersion dyestuffs to be fixed and, if required, on the fibrous materials to be fixed, is in the new method of the invention considerably shorter than that required in the known thermosetting process on stretching frames. In general, a fixing period in the range of about 1 to about 20 seconds is sufficient. In most cases fixing periods of about 3-15 seconds or preferably 5-10 seconds will be suflicient for obtaining complete fixation.
  • organic dyestuffs can be used which contain at least one group capable of reacting with the cellulose fiber or a group capable of being converted into such a group or a substituent capable of reacting with the cellulose fiber.
  • organic dyestuffs those of the anthraquinone, azo and phthalocyanine dyestuff series are especially appropriate. Those of the azo and phthalocyanine series may be metal-free or may contain metal.
  • groups capable of reacting or groups capable of forming such groups in an alkaline medium the following may be mentioned as examples: the epoxy group, the ethyleneimide group, the vinyl radical in a vinyl sulfonic group or in an acrylic acid group and the B-sulfatoethylsulfonyl group.
  • dyestuffs the reactive group of which, for example the vinyl group, have been converted into the hydroxy group under the action of alkalies.
  • substituents capable of reacting may be considered those which are capable of being easily split Off and which form a residual electrophilic radical, for example halogen atoms in the following ring systems: quinoxaline, triazine, pyrimidine, phthalazine and pyridazme.
  • the disperse dyestuffs which can be used are those generally known for dyeing synthetic fibers, especially fibrous materials of linear polyesters, for example, those of the azo or anthraquinone dyestuff series.
  • the alkaline substances to be added to the preparations can be applied in the quantities usual in the dyeing with reactive dyestuffs, i.e., in quantities of about 5-25 g./kg. of printing paste or padding liquor.
  • inorganic compounds such as sodium carbonate, sodium bicarbonate, trisodium phosphate, sodium hydroxide, sodium silicate, the corresponding potassium compounds or mixtures of these alkaline substances.
  • sodium hydroxide, sodium carbonate or sodium bicarbonate is used.
  • the process of the present invention is preferably applied in the dyeing of mixtures of fibers of native or regenerated cellulose and fibrous materials of high molecular weight linear polyesters. It may also be used for the printing or dyeing of mixtures of cellulosic fibers with synthetic fibers, for example polyamide fibers.
  • the process of the invention can be used for the thermosetting of pad dyeings or prints on fabrics or on textile materials of any other form, for example, knit fabric or fiber fleeces.
  • EXAMPLE 1 A mixed fabric of polyethylene terephthalate fibers and cotton in a mixing proportion of 67:33 was padded on the foulard, with a squeezing effect of 55% by weight, with a bath containing, per liter of water, 30 grams of the orange reactive dyestuff of the formula NHz I I n N no- T HOsS- N02 Ho.s J01 co-complex having the form and composition usual in commerce, 30 grams of the disperse dyestufr of the formula (Synthesis of which is shown in U.S. Pat. No. 1,618,413) identified as C.I. Disperse Orange 13, Color Index No. 26080.
  • the padded fabric was dried for 40 seconds at 120 C. and then subjected for 10 seconds to a heat treatment at 220 C. in the thermosetting apparatus described hereafter.
  • the apparatus consisted of 4 rotating cylindrical sieves of a diameter of 140 cm. (diameter of the sieve perforation: 8 mm.) which had been covered with a finely porous seamless sieve-fabric (distance of the sieve-filaments: 0.12 mm).
  • the cylinders were arranged in series in a horizontal position in a closed casing.
  • the interior of the cylinders was under suction draft which sucked the air heated to 220 C. from outside through the textile material, the sieve-fabric and the perforation, into the interior of the cylinders.
  • the halves of the cylinder mantles which were not covered with the textile material, were screened against the draft by cover sheets which had been installed in fixed position in the interior of the cylinders.
  • the fabric was rinsed in the usual manner, acidified with a solution containing, per liter, 2 cc. of acetic acid having a strength of about 50%, rinsed again and soaped for minutes at 95 C. with a bath containing, per liter, 2 grams of a nonionic surface-active agent.
  • EXAMPLE 2 A mixed fabric of polyester and cotton in a mixing proportion of 67:33 was padded on the foulard, with a squeezing effect of 55 by weight, with a bath, containing per liter 30 g. of the reaction dyestuif of the following formula IIIH-COCH;
  • CHzCH-OzS O-S 03H identified as CsI. Reactive Red 21, cf. U.S. Pat. 3,008,950
  • the padded fabric was dried for 40 seconds at 120 C. and then subjected, as described in Example 1, for 10 seconds at 220 C. to a heat treatment consisting of conducting hot air through it.
  • the fabric was rinsed in the usual manner, acidified with a bath containing, per liter, 2 cc. of acetic acid having a strength of 50%, rinsed again and soaped for 3 minutes at C. with a bath containing, per liter of water, 2 g. of a nonionic surface-active agent, whereafter the fabric was rinsed again. Prints having deep red shades on both kinds of the fibrous material were obtained.
  • thermofixation was effected in usual manner on a stretching frame and likewise at 220 C., 40 seconds were necessary to dye the polyester portion the same deep shade as that obtained by the fixation described above.
  • the cotton portion however, showed a considerably lighter shade.
  • EXAMPLE 3 A mixed fabric of polyethylene terephthalate and cotton in a mixing proportion of 67:33 was padded on the foulard with a squeezing effect of 55% by weight, with a bath containing, per liter g. of the reactive dyestuff of the formula N:NCHICCHa SOsI-I the preparation of which is shown in German Pat. 1,239,420 in Formula XVL having the form and composition usual in commerce and 30 g. of the disperse dyestuff of the formula and identified as C.I. Disperse Yellow 64, cf. U.S. Pat. 3,036,876
  • the padded fabric was dried for seconds at 120 C. Subsequently, air which had been heated to 200 C. was passed through it for 10 seconds in the apparatus described in Example 1.
  • the fabric was rinsed in the usual manner, acidified with a solution containing, per liter, 2 cc. of acetic acid having a strength of rinsed again and soaped for 3 minutes at C. with a bath containing, per liter of water, 2 g. of a nonionic surface-active agent, whereafter the fabric was rinsed again. Prints having yellow shades of medium depth on both kinds of the fibrous material were obtained.
  • thermofixation was effected in usual manner on a stretching frame and likewise at 220 C., 40 seconds were necessary to dye the polyester portion the same deep shade as that obtained by the thermosetting process of the present invention described above.
  • the cotton portion however, showed a considerably lighter shade.
  • a process for the simultaneous fixation of disperse and reactive dyestuffs on mixed fabric made of fibrous materials of high-molecular weight linear polyesters and fibers of native or regenerated cellulose, or made of cellulosic fibers and linear polyamide fibers which comprises: passing an inert gas heated to temperature between about C. and 230 C. through said fibrous materials spread on a perforated drum, covered with a fine mesh, sieve like material having a mesh size of less than 1 mm.

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  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Woven Fabrics (AREA)
US637457A 1966-05-11 1967-05-10 Reactive and disperse dyes fixed on cellulose blended fabrics travelling on drum radially passing hot gas Expired - Lifetime US3567356A (en)

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Application Number Priority Date Filing Date Title
DEF0049172 1966-05-11

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US3567356A true US3567356A (en) 1971-03-02

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US (1) US3567356A (de)
JP (1) JPS5114627B1 (de)
BE (1) BE698344A (de)
CH (2) CH646767A4 (de)
DE (1) DE1610948C3 (de)
ES (1) ES340260A1 (de)
GB (1) GB1167064A (de)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3795479A (en) * 1970-10-15 1974-03-05 Hoechst Ag Fixing prints of stabilized azoic and reactive dyes on cellulose and cellulose/polyester
US3949574A (en) * 1973-07-20 1976-04-13 Richard Donovan Glover Sublimatic printing machine
US4025305A (en) * 1966-10-20 1977-05-24 Vepa Ag Process for the heat-setting of padded or printed continuous synthetic filament groups
US4448582A (en) * 1982-02-01 1984-05-15 American Artos Corporation Process for continuous thermosol dyeing of textile fabrics
WO2015154155A1 (pt) * 2014-04-09 2015-10-15 Akmey Brasil Indústria E Comércio De Produtos Químicos Ltda Epp Processo e equipamento para tingimento de fibres celulcósicas em meio gasoso

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4025305A (en) * 1966-10-20 1977-05-24 Vepa Ag Process for the heat-setting of padded or printed continuous synthetic filament groups
US3795479A (en) * 1970-10-15 1974-03-05 Hoechst Ag Fixing prints of stabilized azoic and reactive dyes on cellulose and cellulose/polyester
US3949574A (en) * 1973-07-20 1976-04-13 Richard Donovan Glover Sublimatic printing machine
US4448582A (en) * 1982-02-01 1984-05-15 American Artos Corporation Process for continuous thermosol dyeing of textile fabrics
WO2015154155A1 (pt) * 2014-04-09 2015-10-15 Akmey Brasil Indústria E Comércio De Produtos Químicos Ltda Epp Processo e equipamento para tingimento de fibres celulcósicas em meio gasoso

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Publication number Publication date
CH646767A4 (de) 1970-11-13
JPS5114627B1 (de) 1976-05-11
DE1610948B2 (de) 1974-10-10
CH503836A (de) 1970-11-13
BE698344A (de) 1967-11-13
DE1610948C3 (de) 1975-07-31
ES340260A1 (es) 1968-06-01
GB1167064A (en) 1969-10-15
DE1610948A1 (de) 1972-02-24

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