US3639235A - Antistatic carding lubricant - Google Patents

Antistatic carding lubricant Download PDF

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Publication number
US3639235A
US3639235A US710759A US3639235DA US3639235A US 3639235 A US3639235 A US 3639235A US 710759 A US710759 A US 710759A US 3639235D A US3639235D A US 3639235DA US 3639235 A US3639235 A US 3639235A
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parts
ingredient
composition according
alcohol
ethylene oxide
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US710759A
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Gerhart Karg
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Witco Corp
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Witco Chemical Corp
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D06M13/295—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing polyglycol moieties; containing neopentyl moieties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C10M2215/082—Amides [having hydrocarbon substituents containing less than thirty carbon atoms] containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/46—Textile oils

Definitions

  • a familiar problem in textile processing is the tendency of fibers to accumulate and retain static electrical charges, which result from both fiber-to-fiber and fiber-to-metal friction.
  • a great number of both natural and synthetic fibers are poor electrical conductors and the elimination of the tendency of said fibers to accumulate and retain static electrical charges is a critical factor for efficient textile processing.
  • Carding is one segment of overall textile processing whose particular purpose is to produce a continuous strand or sliver of fabric.
  • the carding technique was developed as part of the cotton system of processing, but it is used today in the manufacture of both natural and manmade fibers.
  • a revolving flat card is used to convert the fiber sheets or laps from the picking operation into a continuous sliver.
  • subsequent operations include such procedures as combing and drawing to clean and parallelize the fibers, and roving, spinning, winding and twisting to further finish the fibers.
  • a sulfonated sperm oil from about 10 to 12 parts;
  • the phosphoric acid esters which, as prepared, are generally mixtures of monoand diesters, are preferably made by reacting 1 mol of P with from 2 to 4.5 mols of the linear aliphatic alcohol or the branched chain aliphatic alcohol or the alkyl phenol, as the case may be, at a temperature in the range up about 100 C., in the presence or in the absence of an inert organic liquid diluent, most advantageously in the range of about 50 to 65 C.
  • Such phosphating procedures are dis closed, for instance, in US. Pat. Nos. 2,441,295; 2,676,975;
  • Illustrative alcohols and alkyl phenols from which the aforesaid ethylene oxide-adducts are made and which are reacted, for example, with P 0 to produce said phosphoric acid esters are n-octyl alcohol, n-nonyl alcohol, n-decyl alcohol, n-dodecyl alcohol, n-tridecyl alcohol, n-tetradecyl alcohol, n-pentadecyl alcohol, n-hexadecyl alcohol, oleyl a1- cohol, n-stearyl alcohol; Oxo alcohols containing from 10 to 20 carbon exemplified by Oxo tridecyl alcohol, Oxo hexadecyl alcohol, and 0x0 pentadecyl alcohol (and others as shown in US.
  • phosphoric acid esters of the 2 to 8 mol ethylene oxide adducts of C to C linear aliphatic alcohols decyl, undecyl, dodecyl, tridecyl and tetradecyl alcohols
  • mixtures of two or more of said alcohols decyl, undecyl, dodecyl, tridecyl and tetradecyl alcohols
  • the alkanolamines which are especially useful in the compositions of the present invention are monoethanolamine, diethanolamine and triethanolamine, and mixtures of two or more thereof, and, particularly, diethanolamine.
  • Other alkanolamines particularly those which contain from two to nine carbon atoms, can however, be used as, for instance, propanolamines, isopropanolamines, butanolamines, hexanolamines, ethyl ethanolamine, arninoethyl ethanolamine and glycerolamines.
  • the alkanolamines react with the aforementioned phosphoric acid esters and with the long chain fatty acids to neutralize the same. While small proportions of inorganic alkalies, such as sodium hydroxide or potassium hydroxide, may be used in conjunction with the alkanolamines, it is preferred not to do so.
  • the long chain fatty acids containing predominately from 14 and, particularly, from 16 to 18 carbon atoms include the saturated and unsaturated fatty acids, for instance, myristic acid, palmitic acid, stearic acid, oleic acid, palmitoleic acid and, especially, tall oil fatty acids.
  • the rosin content of the tall oil fatty acids does not adversely affect the utility of the tall oil fatty acids for the purposes of the present invention.
  • the sulfonated sperm oil is conventionally made by reacting sperm oil with sodium bisulfite, a true sulfonate, i.e., a carbon to sulfur linkage resulting.
  • Sperm oil is composed mainly of fatty alcohol esters of fatty acids in the C to C range, the fatty acid portion of the molecule generally comprising -90 percent unsaturated fatty acids and l020 percent saturated fatty acids.
  • the sulfonated sperm oil sold under the trade designation "Eureka 400 (Atlas Refinery, Inc.) is illustrative of sulfonated sperm oils which are very satisfactory for use in the compositions of the present invention.
  • branchedchain aliphatic alcohols or of the alkyl phenols which are particularly useful in the compositions of the present invention are normally liquids at ambient temperatures. Most desirable are the approximately 3 mol ethylene oxide adducts of the C to C linear aliphatic alcohols, namely, dodecyl alcohol, tridecyl alcohol, tetradecyl alcohol and pentadecyl alcohol.
  • alkanolamides of the C to C normally liquid fatty acids which constitute one of the ingredients of the compositions of the present invention include, by way of illustration, oleic diethanolamide, tall oil fatty acid diethanolamide, linoleic acid diethanolamide and the corresponding fatty acid amides of glycerol monoand diamines, dipropanolamine, diisopropanolamine, aminoethyl ethanolamine, dibutanolamine and diisobutanolamine.
  • Oleic diethanolamide is especially satisfactory and it may be made, for instance, by condensing equal mols 0f diethanolamine and oleic acid, or by condensing about 1.5 to 2 mols of diethanolamine with 1 mol of oleic acid, at temperatures of to C. for several hours, or by condensing the oleic acid, in the form of an ester thereof, such as the methyl ester or the triglyceride ester, with diethanolamine.
  • the lubricant compositions of the present invention are most advantageously applied to the fiber as an oil-in-water emulsion.
  • the emulsions are readily made at room temperature using conventional emulsification techniques.
  • the oil-in-water emulsions will comprise, by weight, from about 5 to 20 parts lubricant composition to about 95 to 80 parts water.
  • the carding lubricant emulsions of the present invention may be applied to the fiber by any conventional method. Preferably, they are sprayed onto the fabric during the picking operation just prior to carding.
  • the carding lubricant compositions are not limited in their ultimate application to any particular fibers or class of fibers. They can be utilized with any fiber requiring lubrication during carding. They have been found especially suitable in treating acrylic, polyamide, polyolefin and polyester fibers and blends of these fibers with each other and with natural fibers such as polyester-wool and polyester-cotton blends.
  • the product was a clear liquid with a cloud point and a pour point ofless than C.
  • a 5 percent oil-in-water emulsion was prepared from the composition of part (i) hereof and applied by spraying onto nylon fiber prior to carding.
  • the lubricated fiber processed satisfactorily with excellent static control. No card loading was observed.
  • EXAMPLE II A composition was prepared as described in part (i) of Example l except that 62.0 parts of the mineral oil and 8.0 parts of diethanolamine were used.
  • EXAMPLE iii A composition was prepared as described in part (i) of Example except that 61.9 parts of the mineral oil, 6.3 parts of diethanolamine and 1.7 parts of potassium hydroxide were used.
  • EXAMPLE IV The compositions of Examples II and ill were clear liquid products. When 5 percent emulsions in water of each of the compositions of Examples ii and III were prepared, they were translucent and exhibited excellent long term stability with no creaming or other instability evident.
  • EXAMPLE V The following test data on polyester fiber indicates the superior antistatic qualities of the compositions of the present invention. A 5 percent emulsion of the lubricant described in Example I was employed. The static inhibition was tested by the resistivity method using Rothschild testing equipment. Excellent antistatic half life reproducibility is demonstrated.
  • An emulsifiable carding lubricant composition consisting essentially of, by weight,
  • alkanolamide of a C to C normally liquid fatty acid
  • said alkanolamide being derived from an alkanolamine selected from the group consisting of diethanolamine, glycerol monoand diamines, dipropanolamine, diisopropanolamine, aminoethyl ethanolamine, dibutanolamine and diisobutanolamine.
  • composition according to claim 1 wherein the (b) ingredient is a phosphoric acid ester of a 2 to 8 mol ethylene oxide adduct ofa C to C linear alkyl alcohol.
  • composition according to claim 1 wherein the (c) ingredient is at least one member selected from the group consisting of monoethanolamine, diethanolamine and triethanolamine.
  • composition according to claim 1 wherein the (d) ingredient is at least one member selected from the group consisting of oleic acid and tall oil fatty acids.
  • composition according to claim 1 wherein the (f) ingredient is an approximately 3 mol ethylene oxide adduct of a C to C linear alkyl alcohol.
  • composition according to claim 1 wherein the (g) ingredient is a diethanolamide of a fatty acid selected from the group consisting of oleic acid and tall oil fatty acids.
  • composition according to claim 2 wherein the (c) ingredient is at least one member selected from the group consisting of monoethanolamine, diethanolamine and triethanolamine.
  • composition according to claim 7, wherein the (d) ingredient is at least one member selected from the group consisting of oleic acid and tall oil fatty acids.
  • composition according to claim 8 wherein the (f) ingredient is an approximately 3 mol ethylene oxide adduct ofa C to C linear alkyl alcohol.
  • composition according to claim 9 wherein the (g) ingredient is a diethanolamide of a fatty acid selected from the group consisting ofoleic acid and tall oil fatty acids.
  • An aqueous emulsion consisting essentially of, by weight, from about to parts of water and from about 20 to 5 pans of the composition of claim 1.
  • An aqueous emulsion consisting essentially of, by weight, from about 80 to 95 parts of water and from about 20 to 5 parts ofthe composition ofclaim 2.
  • An aqueous emulsion consisting essentially of. by weight, from about 80 to 95 parts of water and from about 20 to 5 parts of the composition of claim 3.
  • An aqueous emulsion consisting essentially of, by weight, from about 80 to 95 parts of water and from about 20 to 5 parts of the composition of claim I10.
  • An aqueous emulsion consisting essentially of, by weight, from about 80 to 95 parts of water and from about 20 to 5 parts of the composition of claim lll.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Lubricants (AREA)
US710759A 1968-03-06 1968-03-06 Antistatic carding lubricant Expired - Lifetime US3639235A (en)

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US71075968A 1968-03-06 1968-03-06

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US (1) US3639235A (fr)
BE (1) BE750237A (fr)
FR (1) FR2088063B1 (fr)
GB (1) GB1312068A (fr)
NL (1) NL7006846A (fr)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855776A (en) * 1971-06-22 1974-12-24 Asahi Chemical Ind Synthetic thermoplastic multifilament yarns
US3997450A (en) * 1972-04-10 1976-12-14 Fiber Industries, Inc. Synthetic fibers of enhanced processability
US4051299A (en) * 1974-03-15 1977-09-27 Fiber Industries Inc. Synthetic fibers of enhanced processability
US4072617A (en) * 1976-04-12 1978-02-07 Dow Badische Company Finish for acrylic fiber
US4080301A (en) * 1975-06-27 1978-03-21 Hoechst Aktiengesellschaft Conditioning agents for the texturizing of polyester fibers
US4292182A (en) * 1978-10-30 1981-09-29 Badische Corporation Imparting anti-soiling properties to fibers
US4624793A (en) * 1984-06-20 1986-11-25 National Distillers And Chemical Corporation Fiber finishes
US5190676A (en) * 1989-11-30 1993-03-02 Kao Corporation High-speed spinning oil composition containing an organophosphoric ester salt and an oxyalkylene polymer
US5980772A (en) * 1997-02-25 1999-11-09 Takemoto Yushi Kabushiki Kaisha Lubricants for and methods of processing synthetic fibers
WO1999064658A1 (fr) * 1998-06-11 1999-12-16 Cognis Corporation Agents antistatiques utilises en texturation dans un appareil chauffant, pour contact bref, a haute temperature
US6139764A (en) * 1998-02-09 2000-10-31 Bayer Aktiengesellschaft Biodegradable coating compositions
US20050020458A1 (en) * 1998-10-15 2005-01-27 Wolfgang Becker Lubricants for spinning combed wool slivers and methods of using the same
US20060038157A1 (en) * 2002-02-06 2006-02-23 Wolfgang Becker Use of ethoxylated fatty acids as smoothing agents for synthetic and natural fibres
US20100022421A1 (en) * 2008-07-25 2010-01-28 Intevep, S.A. Process for preparing thermally stable oil-in-water and water-in-oil emulsions
CN103966846A (zh) * 2014-04-21 2014-08-06 江苏新凯盛企业发展有限公司 防水涤纶起绒布及其生产工艺

Citations (7)

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Publication number Priority date Publication date Assignee Title
US2268141A (en) * 1938-05-04 1941-12-30 Nat Oil Prod Co Composition and process for treating fibrous materials
US2730498A (en) * 1952-01-09 1956-01-10 Celanese Corp Textile lubricants
US2806804A (en) * 1952-12-29 1957-09-17 Drew & Co Inc E F Method of treating wool
US2810694A (en) * 1949-11-25 1957-10-22 Exxon Research Engineering Co Textile oil
US2956949A (en) * 1955-10-19 1960-10-18 Eastman Kodak Co Fiber treating compositions
US3056744A (en) * 1957-09-18 1962-10-02 Gen Aniline & Film Corp Textile assistant
US3170877A (en) * 1961-12-21 1965-02-23 Gen Aniline & Film Corp Antistatic treating solution for polyacrylonitrile fibers and method

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE634541A (fr) * 1954-03-30
US3357919A (en) * 1964-09-18 1967-12-12 Celanese Corp Finish compositions for textile materials

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2268141A (en) * 1938-05-04 1941-12-30 Nat Oil Prod Co Composition and process for treating fibrous materials
US2810694A (en) * 1949-11-25 1957-10-22 Exxon Research Engineering Co Textile oil
US2730498A (en) * 1952-01-09 1956-01-10 Celanese Corp Textile lubricants
US2806804A (en) * 1952-12-29 1957-09-17 Drew & Co Inc E F Method of treating wool
US2956949A (en) * 1955-10-19 1960-10-18 Eastman Kodak Co Fiber treating compositions
US3056744A (en) * 1957-09-18 1962-10-02 Gen Aniline & Film Corp Textile assistant
US3170877A (en) * 1961-12-21 1965-02-23 Gen Aniline & Film Corp Antistatic treating solution for polyacrylonitrile fibers and method

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855776A (en) * 1971-06-22 1974-12-24 Asahi Chemical Ind Synthetic thermoplastic multifilament yarns
US3997450A (en) * 1972-04-10 1976-12-14 Fiber Industries, Inc. Synthetic fibers of enhanced processability
US4051299A (en) * 1974-03-15 1977-09-27 Fiber Industries Inc. Synthetic fibers of enhanced processability
US4080301A (en) * 1975-06-27 1978-03-21 Hoechst Aktiengesellschaft Conditioning agents for the texturizing of polyester fibers
US4072617A (en) * 1976-04-12 1978-02-07 Dow Badische Company Finish for acrylic fiber
US4292182A (en) * 1978-10-30 1981-09-29 Badische Corporation Imparting anti-soiling properties to fibers
US4624793A (en) * 1984-06-20 1986-11-25 National Distillers And Chemical Corporation Fiber finishes
US5190676A (en) * 1989-11-30 1993-03-02 Kao Corporation High-speed spinning oil composition containing an organophosphoric ester salt and an oxyalkylene polymer
US5980772A (en) * 1997-02-25 1999-11-09 Takemoto Yushi Kabushiki Kaisha Lubricants for and methods of processing synthetic fibers
US6139764A (en) * 1998-02-09 2000-10-31 Bayer Aktiengesellschaft Biodegradable coating compositions
WO1999064658A1 (fr) * 1998-06-11 1999-12-16 Cognis Corporation Agents antistatiques utilises en texturation dans un appareil chauffant, pour contact bref, a haute temperature
US20050020458A1 (en) * 1998-10-15 2005-01-27 Wolfgang Becker Lubricants for spinning combed wool slivers and methods of using the same
US20060038157A1 (en) * 2002-02-06 2006-02-23 Wolfgang Becker Use of ethoxylated fatty acids as smoothing agents for synthetic and natural fibres
US20100022421A1 (en) * 2008-07-25 2010-01-28 Intevep, S.A. Process for preparing thermally stable oil-in-water and water-in-oil emulsions
US9109151B2 (en) * 2008-07-25 2015-08-18 Intevep, S.A. Process for preparing thermally stable oil-in-water and water-in-oil emulsions
CN103966846A (zh) * 2014-04-21 2014-08-06 江苏新凯盛企业发展有限公司 防水涤纶起绒布及其生产工艺

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FR2088063B1 (fr) 1974-07-12
FR2088063A1 (fr) 1972-01-07
GB1312068A (en) 1973-04-04
BE750237A (fr) 1970-10-16
NL7006846A (fr) 1971-11-16

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