US3652419A - Antistatic fiber lubricant - Google Patents

Antistatic fiber lubricant Download PDF

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Publication number
US3652419A
US3652419A US710761A US3652419DA US3652419A US 3652419 A US3652419 A US 3652419A US 710761 A US710761 A US 710761A US 3652419D A US3652419D A US 3652419DA US 3652419 A US3652419 A US 3652419A
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parts
alcohol
fiber
weight
emulsion
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Expired - Lifetime
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US710761A
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Gerhart Karg
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Witco Corp
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Witco Chemical Corp
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C10M2215/082—Amides [having hydrocarbon substituents containing less than thirty carbon atoms] containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/46—Textile oils
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

  • ABSTRACT An emulsifiable antistatic fiber lubricant composition, which exhibits excellent long term emulsion stability, comprising a mixture of a mineral oil, a methyl ester of a long chain fatty acid, a neutralized phosphoric acid ester of an ethoxylated alkyl phenol or alkyl alcohol, a polyoxyethylene sorbitan tristearate and fatty alkanolamide.
  • compositions applied to textile fibers must also have antistatic properties.
  • the problem of preventing the accumulation of static changes on textiles has troubled the industry for a number of years. This property of retaining static electrical charges is most often encountered in the processing of synthetic fibers such as are manufactured from polyesters and polyamides, polyvinyl chloride, polyvinyl acetate and other vinyl polymerization products as well as polymers of acrylic acid derivatives.
  • a novel emulsifiable antistatic fiber lubricant which comprises in combination one or more of each of the following materials in the stated parts by weight:
  • a polyoxyethylene sorbitan tristearate from about eight to 10 parts;
  • An alkanolamide of a C to C normally liquid fatty acid from about 3 to 4 parts.
  • the phosphoric acid esters which, as prepared, are generally mixtures of monoand di-esters, are preferably made by reacting 1 mol of P with from 2 to 4.5 mols of the ethylene oxide adducts of the linear alkyl alcohol or the alkyl phenol, as the case may be, at a temperature in the range up about 100 C, in the presence or in the absence of an inert organic liquid diluent, most advantageously in the range of about 50 to 65 C.
  • Such phosphating procedures are disclosed, for instance, in US. Pat. Nos. 2,441,295; 2,676,975; 2,701,258 and 3,004,056; Chemical Industries, Oct. 1942, pp. 516-521 and 557; and Organo Phosphorous Compounds, John Wiley & Sons, New York, 1950, pp. 220-223.
  • Illustrative alcohols and alkyl phenols from which the aforesaid ethylene oxide-adducts are made and which are reacted, for example, with P 0 to produce said phosphoric acid esters are n-octyl alcohol, n-nonyl alcohol, n-decyl alcohol, n-dodecyl alcohol, n-tridecyl alcohol, n-tetradecyl alcohol, n-pentadecyl alcohol, n-hexadecyl alcohol, oleyl alcohol, n-stearyl alcohol; Oxo alcohols containing from to 20 carbon exemplified by Oxo tridecyl alcohol, 0x0 hexadecyl alcohol, and Oxopentadecyl alcohol (and others as shown in U.S.
  • dodecyl phenol and didodecyl phenol are the phosphoric acid esters of the 2 to 8 mol ethylene oxide adducts of C to C linear alkyl alcohols (decyl undecyl, dodecyl, tridecyl and tetradecyl alcohols) and mixtures of two or more of said alcohols.
  • the phosphoric acid ester may be neutralized with an alkali (e.g. hydroxide of an alkali metal such as sodium, potassium, lithium or ammonium) in situ during the preparation of the lubricant composition or it may be added in the neutralized form.
  • an alkali e.g. hydroxide of an alkali metal such as sodium, potassium, lithium or ammonium
  • potassium hydroxide is used as the neutralizing agent because of its better solubility, and it is conveniently added as a 45 percent solution.
  • the exact quantity of base added is dependent upon stoichiometric considerations. Generally, a slight excess over the stoichiometric amount is used since the desired pH range of the ultimate emulsion composition is in the range of 7.5-8.5. This final pH has been found particularly suitable because of emulsion stability demands and, also, to prevent or inhibit corrosion when the composition is contacted with textile fibers and machincry.
  • the methyl esters of fatty acids useful in the compositions of the present invention comprise the methyl esters of C to C saturated and unsaturated fatty acids, illustrative examples of said acids being lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, palmitoleic acid, tall oil fatty acids, and commercial and other mixtures of said acids such as coconut oil mixed fatty acids and various narrower fractions of mixed fatty acids.
  • a particularly desirable commercial mixture of fatty acid methyl esters is that sold under the designation CE-l8 by The Procter & Gamble Company and consisting of about percent oleate, linoleate and stearate, 25 percent palmitate and the remainder varying amounts of laurate and myristate methyl esters.
  • the polyoxyethylene sorbitan tristearate is generally produced by condensing sorbitan tristearate with ethylene oxide.
  • this compound should have an HLB value of from about 8 to 15, or 40 to weight percent ethylene oxide.
  • a polyoxyethylene sorbitan tristearate containing about 52 weight percent ethylene oxide is particularly suitable.
  • alkanolamides of the C to C normally liquid fatty acids which constitute one of the ingredients of the compositions of the present invention include, by way of illustration, oleic diethanolamide, tall oil fatty acid diethanolamide, linole ic acid diethanolamide and the corresponding fatty acid amides of glycerol monoand di-amines, dipropanolamine, diisopropanolamine, aminoethyl ethanolamine, dibutanolamine and diisobutanolamine.
  • Oleic diethanolamide is especially satisfactory and it may be made, for instance, by condensing equal mols of diethanolamine and oleic acid, or by condensing about 1.5 to 2 mols of diethanolamine with 1 mol of oleic acid, at temperatures of 150 to 165 C. for several hours, or by condensing the oleic acid, in the form of an ester thereof, such as the triglyceride ester, with diethanolamine, or by condensing methyl oleate with diethanolamine in the presence of sodium methylate as a catalyst, or by oxyethylating the amide of oleic acid.
  • the order of mixing the ingredients in preparing the emulsifiable lubricant compositions of the present invention is not critical but it is usually more convenient to add the several ingredients, with mixing, to the mineral oil.
  • emulsification occurs readily at temperatures above as well as below room temperatures in water, including tap water, by simply mixing the lubricant composition with the water.
  • an emulsion containing 10 percent by weight of the lubricant composition may be prepared quite readily at 10 C. with no separation observable over a 24 hour period.
  • the preferred oil-in-water emulsions consist of 10 weight parts of the lubricating composition and weight parts of water. However, this range may be varied considerably as, for example, 5 to 20 parts of the lubricating composition and to 80 parts of water. Generally, it is not desirable to exceed about 30 percent by weight of the lubricating composition since the emulsion tends to thicken at these higher levels and stability tends to become marginal. Hence, generally speaking, said emulsions will comprise 70 to 99 parts of water and 30 to l parts of the lubricant composition.
  • compositions of the present invention achieve highly satisfactory fiber to fiber and fiber to metal frictional properties. An accumulation of electrostatic charges on treated fibers is largely or substantially eliminated.
  • Application to the fibers may be by any conventional means such as by immersion, spraying or roll application.
  • a liquid emulsifiable antistatic fiber lubricant was prepared by combining the following components:
  • a 10 percent emulsion was prepared using each of the compositions of examples ll-V and stored at room temperature for visual observations of the stability of the emulsion. After 24 hours, little or no evidence of creaming, oiling or ring formation was perceived.
  • EXAMPLE VII The following results demonstrate the friction characteristics of fibers which were treated with emulsions prepared using compositions of the present invention. The tests were conducted using a Rothschild tension analyzer, which furnishes a continuous recording of tension in grams as the fibers are tested.
  • An oil-in-water fiber lubricant emulsion consisting essentially of 70-99 parts by weight of water and 30-1 parts by weight of a mineral oil composition consisting essentially of, by weight,
  • An aqueous emulsion comprising, by weight, about parts of water and about 10 parts of the composition of claim 1.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US710761A 1968-03-06 1968-03-06 Antistatic fiber lubricant Expired - Lifetime US3652419A (en)

Applications Claiming Priority (1)

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US71076168A 1968-03-06 1968-03-06

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US (1) US3652419A (fr)
BE (1) BE749964A (fr)
DE (1) DE2022888A1 (fr)
FR (1) FR2088014B1 (fr)
GB (1) GB1285391A (fr)
NL (1) NL7006309A (fr)

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3888775A (en) * 1972-01-29 1975-06-10 Teijin Ltd Oil composition for synthetic staple fibers
US3898166A (en) * 1973-01-16 1975-08-05 Gaf Corp Organic antistatic composition
FR2292068A1 (fr) * 1973-11-22 1976-06-18 Ici Ltd Ensimage pour textiles et applications
US3977979A (en) * 1973-09-14 1976-08-31 George A. Goulston Company, Inc. Yarn finish formulations
US3997450A (en) * 1972-04-10 1976-12-14 Fiber Industries, Inc. Synthetic fibers of enhanced processability
US4051299A (en) * 1974-03-15 1977-09-27 Fiber Industries Inc. Synthetic fibers of enhanced processability
US4052321A (en) * 1976-03-17 1977-10-04 Dixie Yarns, Inc. Flame-retardant yarn or thread containing brominated ester of oleic or linoleic acid
US4080301A (en) * 1975-06-27 1978-03-21 Hoechst Aktiengesellschaft Conditioning agents for the texturizing of polyester fibers
US4085052A (en) * 1974-04-16 1978-04-18 The Procter & Gamble Company Fabric treatment compositions
US4446034A (en) * 1981-09-25 1984-05-01 Bayer Aktiengesellschaft Textile-treatment agents, and their use for finishing textile materials
US5190676A (en) * 1989-11-30 1993-03-02 Kao Corporation High-speed spinning oil composition containing an organophosphoric ester salt and an oxyalkylene polymer
US5288416A (en) * 1992-01-27 1994-02-22 Milliken Research Corporation Finish for textile fibers containing silahydrocarbon lubricants and nonionic emulsifiers having a plurality of hydrocarbon chains
USRE35621E (en) * 1989-05-30 1997-10-07 Hercules Incorporated Cardable hydrophobic polypropylene fiber, material and method for preparation thereof
US5721048A (en) * 1990-11-15 1998-02-24 Fiberco, Inc. Cardable hydrophobic polyolefin fiber, material and method for preparation thereof
US5733863A (en) * 1997-01-17 1998-03-31 The Procter & Gamble Company Process for making a free-flowing particule detergent admix containing nonionic surfactant
US5739094A (en) * 1997-01-17 1998-04-14 The Procter & Gamble Company Free-flowing particulate detergent admix composition containing nonionic surfactant
US5830240A (en) * 1996-10-23 1998-11-03 Solutia Inc. Fibers and textile materials having enhanced dyeability and finish compositions used thereon
US5944852A (en) * 1996-10-23 1999-08-31 Solutia Inc. Dyeing process
US5980772A (en) * 1997-02-25 1999-11-09 Takemoto Yushi Kabushiki Kaisha Lubricants for and methods of processing synthetic fibers
US6139764A (en) * 1998-02-09 2000-10-31 Bayer Aktiengesellschaft Biodegradable coating compositions
US20040007687A1 (en) * 2002-07-11 2004-01-15 Hubert Dobbelstein Formulation of a highly viscous mineral oil for the production of filters for tobacco products
US20040131790A1 (en) * 2003-01-07 2004-07-08 Voegtli Leo Paul Method for using an ethoxylated alkyl phosphate ester additive as plugmaker processing aid
US20050202993A1 (en) * 2003-01-07 2005-09-15 Voegtli Leo P. Method for using an ethoxylated alkyl phosphate ester additive as a plugmaker processing aid
BE1023475B1 (nl) * 2016-06-09 2017-04-03 Vertexco Nv Werkwijze voor het vervaardigen van een spinolie

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6269881A (ja) * 1985-09-17 1987-03-31 花王株式会社 合成繊維処理用油剤
JP4097266B2 (ja) * 2003-08-07 2008-06-11 竹本油脂株式会社 合成繊維処理剤の低濃度水性液の調製方法、合成繊維処理剤の低濃度水性液及び合成繊維の処理方法

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US2496631A (en) * 1946-07-08 1950-02-07 Nopco Chem Co Wool treatment
US2690426A (en) * 1950-03-07 1954-09-28 Atlas Powder Co Lubricating compositions
US2730498A (en) * 1952-01-09 1956-01-10 Celanese Corp Textile lubricants
US3056744A (en) * 1957-09-18 1962-10-02 Gen Aniline & Film Corp Textile assistant
US3170877A (en) * 1961-12-21 1965-02-23 Gen Aniline & Film Corp Antistatic treating solution for polyacrylonitrile fibers and method
US3336222A (en) * 1965-01-19 1967-08-15 Nopco Chem Co Cotton treating compositions
US3428560A (en) * 1967-02-27 1969-02-18 Du Pont Yarn-lubricating composition

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2496631A (en) * 1946-07-08 1950-02-07 Nopco Chem Co Wool treatment
US2690426A (en) * 1950-03-07 1954-09-28 Atlas Powder Co Lubricating compositions
US2730498A (en) * 1952-01-09 1956-01-10 Celanese Corp Textile lubricants
US3056744A (en) * 1957-09-18 1962-10-02 Gen Aniline & Film Corp Textile assistant
US3170877A (en) * 1961-12-21 1965-02-23 Gen Aniline & Film Corp Antistatic treating solution for polyacrylonitrile fibers and method
US3336222A (en) * 1965-01-19 1967-08-15 Nopco Chem Co Cotton treating compositions
US3428560A (en) * 1967-02-27 1969-02-18 Du Pont Yarn-lubricating composition

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3888775A (en) * 1972-01-29 1975-06-10 Teijin Ltd Oil composition for synthetic staple fibers
US3997450A (en) * 1972-04-10 1976-12-14 Fiber Industries, Inc. Synthetic fibers of enhanced processability
US3898166A (en) * 1973-01-16 1975-08-05 Gaf Corp Organic antistatic composition
US3977979A (en) * 1973-09-14 1976-08-31 George A. Goulston Company, Inc. Yarn finish formulations
US4098703A (en) * 1973-09-14 1978-07-04 George A. Goulston Company, Inc. Yarn finish formulations
FR2292068A1 (fr) * 1973-11-22 1976-06-18 Ici Ltd Ensimage pour textiles et applications
US4051299A (en) * 1974-03-15 1977-09-27 Fiber Industries Inc. Synthetic fibers of enhanced processability
US4085052A (en) * 1974-04-16 1978-04-18 The Procter & Gamble Company Fabric treatment compositions
US4080301A (en) * 1975-06-27 1978-03-21 Hoechst Aktiengesellschaft Conditioning agents for the texturizing of polyester fibers
US4052321A (en) * 1976-03-17 1977-10-04 Dixie Yarns, Inc. Flame-retardant yarn or thread containing brominated ester of oleic or linoleic acid
US4446034A (en) * 1981-09-25 1984-05-01 Bayer Aktiengesellschaft Textile-treatment agents, and their use for finishing textile materials
EP0075770A3 (en) * 1981-09-25 1985-01-16 Bayer Ag Textile treating composition and its use in finishing textile materials
USRE35621E (en) * 1989-05-30 1997-10-07 Hercules Incorporated Cardable hydrophobic polypropylene fiber, material and method for preparation thereof
US5190676A (en) * 1989-11-30 1993-03-02 Kao Corporation High-speed spinning oil composition containing an organophosphoric ester salt and an oxyalkylene polymer
US5721048A (en) * 1990-11-15 1998-02-24 Fiberco, Inc. Cardable hydrophobic polyolefin fiber, material and method for preparation thereof
US5288416A (en) * 1992-01-27 1994-02-22 Milliken Research Corporation Finish for textile fibers containing silahydrocarbon lubricants and nonionic emulsifiers having a plurality of hydrocarbon chains
US5830240A (en) * 1996-10-23 1998-11-03 Solutia Inc. Fibers and textile materials having enhanced dyeability and finish compositions used thereon
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NL7006309A (fr) 1971-11-02
BE749964A (fr) 1970-10-16
DE2022888A1 (de) 1971-11-25
FR2088014B1 (fr) 1974-09-20
GB1285391A (en) 1972-08-16
FR2088014A1 (fr) 1972-01-07

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