US3704716A - Method for continuous preparation of tobacco - Google Patents
Method for continuous preparation of tobacco Download PDFInfo
- Publication number
- US3704716A US3704716A US884850A US3704716DA US3704716A US 3704716 A US3704716 A US 3704716A US 884850 A US884850 A US 884850A US 3704716D A US3704716D A US 3704716DA US 3704716 A US3704716 A US 3704716A
- Authority
- US
- United States
- Prior art keywords
- tobacco
- air
- water
- screen
- chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 241000208125 Nicotiana Species 0.000 title claims abstract description 139
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 139
- 238000000034 method Methods 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 50
- 238000001035 drying Methods 0.000 claims abstract description 41
- 238000004108 freeze drying Methods 0.000 claims abstract description 18
- 238000012545 processing Methods 0.000 claims abstract description 9
- 230000000694 effects Effects 0.000 claims abstract description 6
- 238000007710 freezing Methods 0.000 claims description 20
- 230000008014 freezing Effects 0.000 claims description 20
- 239000000835 fiber Substances 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 10
- 238000009736 wetting Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 230000003750 conditioning effect Effects 0.000 claims description 2
- 235000019504 cigarettes Nutrition 0.000 abstract description 13
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 abstract description 3
- 229960002715 nicotine Drugs 0.000 abstract description 3
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 3
- 238000004891 communication Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 241001658044 Beata Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/18—Other treatment of leaves, e.g. puffing, crimpling, cleaning
- A24B3/182—Puffing
- A24B3/185—Puffing by impregnating with a liquid and subsequently freezing and evaporating this liquid
Definitions
- the tobacco preferably in [2]] Appl 884,850 shredded form, is moistenedwith water to a pointat Wl'llCh its volume 15 approximately twice the initial volume, conveyed on a continuously moving conveyor [52] U.S. Cl. ..13l/140 P, 131/136 i a freeze chamber and then i a freeze drying [5 l llll. Cl. ..A24b 03/18 chamber wherein air at substantially atmospheric pres Fleld of Search sure and at about 0 F is passed over the tobacco 131/17 34/5 99/199 shreds to effect drying. The drying is carried out to a 561 R f d point at which 90 percent of the moisture is removed.
- a technique em- UNITED STATES PATENTS ploying floating the tobacco on water and subsequently lifting the tobacco therefrom by a screen 3,438,792 4/1969 Kruger ..99/199 may be employed Further, the fi l drying may be 2,596,183 5/1952 "131/140 complished in two stages utilizing two drying cham- 3,5l3,857 5/1970 Silvei'man ..l3l/l40 bers 3,245,l5l 4/1966 Eichmanns ..34/5
- freeze drying In conventional freeze drying, a frozen article is placed in a vacuum chamber wherein heat is supplied to the frozen article to cause the moisture in the article to pass from the solid state to the gaseous state without passing through a liquid state.
- freeze drying- is done by the limited volume batch process. Continuously supplying frozen tobacco to a vacuum chamber and continuously withdrawing tobacco therefrom would render it extremely expensive to maintain a sufficiently high vacuum in the chamber for the conventional freeze drying process.
- a continuous process for the preparation of fibrous material, such as tobacco for cigarettes.
- frozen tobacco is continuously supplied to a drying chamber through which cool air is circulated at essentially atmospheric pressure.
- the moving air sweeps away the water vapor above the tobacco to reduce the pressure of the water vapor at the surface of the tobacco.
- a high vacuum as used in conventional freeze drying, is useful to facilitate this transfer.
- dry cool air blown past the article to sweep away water-vapor molecules as they reach the surface of the article can also be used, as described more fully in Science, Vol. 130, l 1 Sept. I959, pages 628-629, and in Meat, July and Aug. 1963, pages 34 and 26, respectively.
- Frozen shredded tobacco which has a high freezing point and a relatively large surface area per unit of mass is especially well suited to this type of drying.
- frozen tobacco is moved continuously while being frozen, as through a freezing 0 about a percent to 13 percent moisture content) and chamber, and while being freeze dried, as through a drying chamber through which cool air is circulated at in the form of shrunken shreds.
- the tobacco is first moistenedfor expansion, either by passing the tobacco under a water spray or floating the tobacco in a body of water. In the latter instance, a wire mesh conveyor passes through the surface of the water to raise and drain the water soaked tobacco.
- the expanded tobacco is subsequently freeze dried as described above, the tobacco 'will remain in the expanded condition even after drying.
- the tobacco is fed preferably by a continuously moving belt from a'source of supply through the wetting step to a succession of separate chambers, in each of which a separate treatment is performed on the tobacco, so that fully processed tobacco is continuously delivered from the final downstream chamber.
- FIGS. 1A and 1B are side views, in cross section, of apparatus constructed in accordance with one form of the invention for preparing tobacco for use in cigarettes, showing schematically one form of apparatus for'supplying air of the desired temperature and relative humidity to one of the chambers.
- FIG. 2 is a fragmentary plan view of the apparatus of FIG. 1;
- FIG. 3 is a side view, in cross-section, of apparatus constructed according to one feature of the invention.
- FIGS. 1A and 1B DESCRIPTION OF THE PREFERRED EMBODIMENT
- a conveyor 8 mounted on conveyor frame 9 (FIG. 2) has an endless wire mesh conveyor belt 10, with a horizontal upper run 11.
- Tobacco Tl which is shredded (to, say, 50 cuts per inch) and dry (say 10 percent to 13 percent moisture) is continuously deposited on the downstream end of the conveyor from a supply conveyor 12.
- a plurality of sprinkler manifolds 13 above the upper run 11 of the belt extend across the conveyor to continuously discharge water on the belt 10, the tobacco T1 falling onto the belt, and the tobacco in the belt.
- the tobacco expands typically 2.6 times and contains percent to percent moisture.
- the wet, expanded, tobacco is designated as T2.
- the conveyor 8 extends through inlet and outlet openings 14a, 14b of an enclosed insulated freezing chamber 14 through which cold air, at about F, is circulated tov freeze the wet tobacco which is continuously moving through the chamber 14 on the belt '10.
- the frozen tobacco is indicated as T3. 7
- the conveyor 8. extends through inlet and outlet openings 15a, 15b of an insulated drying chamber 15.
- the chamber 15, which is enclosed, has an air inlet opening 16 in communication with an inlet duct 17 and has an outlet opening 18 in communication with art outlet duct 19.
- air is drawn from chamber 15 and through duct 19 by a blower 20 connected to the duct 19.
- The'blower 20' discharges air through a cooling chamber 21 where the air iscooled to typically 20 by a refrigerator unit 22. Moisture is condensed out of the air in the cooling chamber and when the air, which is carried through heater '23 to inlet duct 17', is sub sequently heated in the heater to about 30, the air becomes very dry.
- the dry air from heater 23 passes into the inlet duct 17 for circulation through chamber 15.
- the final temperature of the air introduced to the chamber 15 can be regulated by the adjustable knob-24 on'theelectric power supply 25 which transmits electrical energy to the heating elements 26.
- Another method of supplying dry air would be to circulate the air through a bed of solid particulate dessicant, such as silica gel or materials known commercially as molecular sieves.
- dry relative humidity less that 10 percent and cool air (about F) is continuously circulated through the chamber 15.
- air at the temperature and relative humidity indicated is preferred, it is only necessary that the air have a temperature and humidity so that the wet bulb temperature thereof is below the freezing point of the water soaked tobacco.
- the dry cool air circulating through chamber 15 penetrates the frozen tobacco T3 and sweeps away the water molecules from the surface of the shredded tobacco, which has a relatively large surface area.
- the rate of release of the water vapor from the frozen tobacco T3 is controlled primarily by the water vapor pressure at the surface of the tobacco rather than by total gas pressure.
- a vacuum is used to reduce the water-vapor pressure at the surface of the article being freeze-dried, the circulating dry, cool air will also effectively reduce the water-vapor pressure at the surface of material, such as the fibrous shredded tobacco.
- the water vapor in the shredded tobacco will pass directly to gaseous vapor without passing through the liquid stage.
- This sublimation of the vapor in the tobacco will completely dry the tobacco, without shrinking the tobacco from the expanded state, if the continuously moving tobacco is exposed for a sufficiently long time to the cool dry air of the drying chamber 15, which, for convenience, may be referred to as a first drying chamber. If the tobacco is exposed for a lesser time to the air circulating through chamber 15, the tobacco will be only partially dried. The partially dried tobacco is indicated at T4.
- a second insulated drying chamber 30 may be provided, directly downstream (with respect to the direction of tobacco travel on the conveyor 8) from the first drying chamber 15.
- the conveyor 8 extends through inlet and outlet openings 30a, 30b in the chamber 30 and carries the tobacco through thatchamber for completion of the drying.
- the drying is completed quickly by the circulation of warm (say l00 F), dry (say 10 percent relative humidity) air through the chamber.
- warm (say l00 F) dry (say 10 percent relative humidity) air through the chamber.
- dry air'at the temperature and humidity indicated is preferred, it .is only necessary that the air beata temperature and humidity so that the wet bulb temperature thereof is above the freezing point of the partially freeze dried tobacco.
- the completely dried tobacco is indicated at T5.
- the tobacco As the remaining vapor in the tobacco dries in chamber 30, the vapor passes through the liquid stage before finally evaporating. For this reason, it ispreferable to freeze dry at least 90 percent of the moisture from the tobacco in chamber 15 so that there will not be a significant shrinkage of the tobacco when the remaining vapor passes through the liquid stage in chamber 30.
- I v d After the final drying, the tobacco is completely dry and brittle, although remaining in the expanded state of over twice the size'of the original tobacco T1.
- the tobacco moves on conveyor 8 through inlet opening and outlet opening 31a, 31b of an insulated rehumidifying chamber 3].
- Warm moist air (of, for example, 80 percent relative humidity and 80F) is circulated through the chamber to add moisture, say 10 percent to 13 percent to the dry tobacco.
- the rehumidified tobacco is'indicated at T6.
- the tobacco thus is carried by the wire mesh conveyor successively and continuously through a wetting operation, and insulated chambers 14, 15, 30, 31 for separate treatment in each of the chambers while the tobacco is moved through the chambers.
- the tobacco in its processed form is continuously discharged through opening 31b of the final downstream chamber
- the tobacco Tl may, instead, be dropped into a tank 40 from the supply conveyor 12.
- the tank 40 is filled with water which soaks the tobacco to a moisture content of 70 to 90 percent.
- the downstream end of a conveyor 41 has a drum 42 mounted in the tank 40 below the surface of the water; An endless wire mesh conveyor belt 42, having an upper run 43 and a lower run 44, is received over drum 42.
- the wire mesh conveyor belt which defines a continuous screen, has small closely spaced openings through which excess water drains.
- Two vertically spaced drums 45, 46 are positioned above the tank at the downstream end thereof.
- the upper run 43 of the conveyor belt is received over the upper drum 45 and the lower run 44 of the conveyor belt is received over the lower drum 46.
- the upper run 43 of the conveyor belt extends through a series of chambers similar to the construction shown in FIGS. 1A and 1B.
- a method of processing shrunken shredded tobacco to effect expansion thereof comprising the steps of moistening the tobacco having an initial moisture of about percent with water to swell the shredded fibrous particles thereof, to about twice the initial volume and having about 70 percent to 80 percent moisture continuously moving the swollen fibers to a freeze chamber wherein cold air at about 32F.
- a method according to claim 4 wherein said air at atmospheric pressure is at a temperature of about 30 F. with a relative humidity of less than 10 percent.
- a method of processing shrunken shredded tobacco comprising the steps of wetting the material with water to swell the shredded fibrous particles thereof, continuously moving the swollen fibers to a freeze chamber for freezing, continuously moving the frozen fibers from the freeze chamber to a first drying chamber, passing air at atmospheric pressure and a cool temperature through the first drying chamber to freeze dry the frozen fibers to a point where approximately 90 percent of the moisture is removed therefrom as they move continuously through the first drying chamber with the wet bulb temperature of said cool air being below the freezing point of the water soaked tobacco, continuously moving the partially freeze dried fibrous particles from the first drying chamber to a second drying chamber, and passing air which is substantially warmer than said cool air through the second drying chamber to further dry the tobacco particles.
- a process for preparing tobacco the steps of distributing an even floating layer of tobacco shreds on a body of water to swell them, lifting a screen through the water surface to raise the tobacco shreds from the water and to drain the water from the shreds through the screen, freezing the soaked shreds on the screen, and freeze drying the tobacco shreds while they remain on said screen by passing air through the tobacco and screen.
- the steps ofdisbulb temperature is below the freezing point of the water soaked tobacco, and finish drying the tobacco while it remains on the screen by passing air through the tobacco and screen with the air at a temperature and relative humidity such that its wet bulb temperature is above the freezing point of the partially freeze dried tobacco.
Landscapes
- Manufacture Of Tobacco Products (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US88485069A | 1969-12-15 | 1969-12-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3704716A true US3704716A (en) | 1972-12-05 |
Family
ID=25385560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US884850A Expired - Lifetime US3704716A (en) | 1969-12-15 | 1969-12-15 | Method for continuous preparation of tobacco |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3704716A (fr) |
| BE (1) | BE759484A (fr) |
| BR (1) | BR7024217D0 (fr) |
| CA (1) | CA931459A (fr) |
| DE (1) | DE2057147A1 (fr) |
| FR (1) | FR2072442A5 (fr) |
| GB (2) | GB1326549A (fr) |
| NL (1) | NL7018188A (fr) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3817259A (en) * | 1971-11-12 | 1974-06-18 | Fmc Corp | Method of and apparatus for turgor conditioning tobacco |
| US3991772A (en) * | 1973-01-05 | 1976-11-16 | Smitherm Industries, Inc. | Methods of and apparatus for expanding tobacco |
| US5711320A (en) * | 1993-04-20 | 1998-01-27 | Comas-Costruzional Machine Speciali-S.P.A. | Process for flavoring shredded tobacco and apparatus for implementing the process |
| CN103120359A (zh) * | 2013-02-27 | 2013-05-29 | 湖北中烟工业有限责任公司 | 一种卷烟叶丝干燥方法 |
| CN109744566A (zh) * | 2019-03-18 | 2019-05-14 | 云南中烟工业有限责任公司 | 一种干燥设备及其使用方法 |
| WO2020001491A1 (fr) * | 2018-06-26 | 2020-01-02 | 中国科学院理化技术研究所 | Procédé d'expansion à basse température de tabac haché respectueux de l'environnement à faible empreinte carbone |
| WO2021066748A1 (fr) * | 2019-10-01 | 2021-04-08 | Universal Angel Corp | Appareil et procédé de séchage de consommables |
| CN114304697A (zh) * | 2021-12-23 | 2022-04-12 | 秦皇岛烟草机械有限责任公司 | 一种烟丝干燥方法 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2289979C1 (ru) * | 2005-07-08 | 2006-12-27 | Олег Иванович Квасенков | Способ получения ароматизированного табака с повышенной заполняющей способностью |
| RU2289988C1 (ru) * | 2005-07-08 | 2006-12-27 | Олег Иванович Квасенков | Способ производства ароматизированного экспандированного табака |
| RU2289992C1 (ru) * | 2005-07-12 | 2006-12-27 | Олег Иванович Квасенков | Способ увеличения объема табака |
| RU2289990C1 (ru) * | 2005-07-12 | 2006-12-27 | Олег Иванович Квасенков | Способ повышения заполняющей способности табака |
| RU2289994C1 (ru) * | 2005-07-12 | 2006-12-27 | Олег Иванович Квасенков | Способ экспандирования табака |
| RU2289989C1 (ru) * | 2005-07-12 | 2006-12-27 | Олег Иванович Квасенков | Способ увеличения заполняющей способности табака |
| RU2307558C1 (ru) * | 2006-03-10 | 2007-10-10 | Олег Иванович Квасенков | Способ изготовления ароматизированной экспандированной табачной жилки |
| RU2306812C1 (ru) * | 2006-03-15 | 2007-09-27 | Олег Иванович Квасенков | Способ изготовления экспандированной табачной жилки |
| RU2306822C1 (ru) * | 2006-03-15 | 2007-09-27 | Олег Иванович Квасенков | Способ выработки ароматизированной экспандированной табачной жилки |
| RU2307560C1 (ru) * | 2006-03-15 | 2007-10-10 | Олег Иванович Квасенков | Способ выработки экспандированной табачной жилки |
| RU2306827C1 (ru) * | 2006-03-22 | 2007-09-27 | Олег Иванович Квасенков | Способ выработки экспандированной табачной жилки |
| RU2306828C1 (ru) * | 2006-03-22 | 2007-09-27 | Олег Иванович Квасенков | Способ производства экспандированной табачной жилки |
| CN111011148A (zh) * | 2019-11-25 | 2020-04-17 | 山东临沂烟草有限公司 | 旺长期风雹重灾烟田的管理方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2596183A (en) * | 1944-12-02 | 1952-05-13 | American Mach & Foundry | Method for increasing the volume of shredded tobacco |
| US3245151A (en) * | 1966-04-12 | Method for treating textiles | ||
| US3438792A (en) * | 1965-12-28 | 1969-04-15 | Lamb Weston Inc | Combined freeze drying-air drying process of dehydrating food products |
| US3513857A (en) * | 1967-12-26 | 1970-05-26 | Philip Morris Inc | Process for the treatment of tobacco stems |
-
0
- BE BE759484D patent/BE759484A/fr unknown
-
1969
- 1969-12-15 US US884850A patent/US3704716A/en not_active Expired - Lifetime
-
1970
- 1970-11-02 CA CA097114A patent/CA931459A/en not_active Expired
- 1970-11-03 GB GB5215570A patent/GB1326549A/en not_active Expired
- 1970-11-03 GB GB5789271A patent/GB1326550A/en not_active Expired
- 1970-11-20 DE DE19702057147 patent/DE2057147A1/de active Pending
- 1970-11-26 FR FR7042506A patent/FR2072442A5/fr not_active Expired
- 1970-11-27 BR BR224217/70A patent/BR7024217D0/pt unknown
- 1970-12-14 NL NL7018188A patent/NL7018188A/xx unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3245151A (en) * | 1966-04-12 | Method for treating textiles | ||
| US2596183A (en) * | 1944-12-02 | 1952-05-13 | American Mach & Foundry | Method for increasing the volume of shredded tobacco |
| US3438792A (en) * | 1965-12-28 | 1969-04-15 | Lamb Weston Inc | Combined freeze drying-air drying process of dehydrating food products |
| US3513857A (en) * | 1967-12-26 | 1970-05-26 | Philip Morris Inc | Process for the treatment of tobacco stems |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3817259A (en) * | 1971-11-12 | 1974-06-18 | Fmc Corp | Method of and apparatus for turgor conditioning tobacco |
| US3991772A (en) * | 1973-01-05 | 1976-11-16 | Smitherm Industries, Inc. | Methods of and apparatus for expanding tobacco |
| US5711320A (en) * | 1993-04-20 | 1998-01-27 | Comas-Costruzional Machine Speciali-S.P.A. | Process for flavoring shredded tobacco and apparatus for implementing the process |
| CN103120359A (zh) * | 2013-02-27 | 2013-05-29 | 湖北中烟工业有限责任公司 | 一种卷烟叶丝干燥方法 |
| CN103120359B (zh) * | 2013-02-27 | 2014-11-12 | 湖北中烟工业有限责任公司 | 一种卷烟叶丝干燥方法 |
| WO2020001491A1 (fr) * | 2018-06-26 | 2020-01-02 | 中国科学院理化技术研究所 | Procédé d'expansion à basse température de tabac haché respectueux de l'environnement à faible empreinte carbone |
| CN110638084A (zh) * | 2018-06-26 | 2020-01-03 | 中国科学院理化技术研究所 | 一种低碳环保的烟丝低温膨胀工艺 |
| CN109744566A (zh) * | 2019-03-18 | 2019-05-14 | 云南中烟工业有限责任公司 | 一种干燥设备及其使用方法 |
| WO2021066748A1 (fr) * | 2019-10-01 | 2021-04-08 | Universal Angel Corp | Appareil et procédé de séchage de consommables |
| CN114304697A (zh) * | 2021-12-23 | 2022-04-12 | 秦皇岛烟草机械有限责任公司 | 一种烟丝干燥方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| BR7024217D0 (pt) | 1973-02-15 |
| NL7018188A (fr) | 1971-06-17 |
| DE2057147A1 (de) | 1971-07-08 |
| FR2072442A5 (fr) | 1971-09-24 |
| GB1326549A (en) | 1973-08-15 |
| BE759484A (fr) | 1971-04-30 |
| GB1326550A (en) | 1973-08-15 |
| CA931459A (en) | 1973-08-07 |
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