US3855014A - Quenching oil composition and method of quenching metal - Google Patents

Quenching oil composition and method of quenching metal Download PDF

Info

Publication number: US3855014A
Authority: US; United States
Prior art keywords: metal; composition; quenching; compound; heated metal
Prior art date: 1973-06-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

US00373530A

Other languages

English (en)

Inventor

Vries D De

B Creech

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Atlantic Richfield Co

Original Assignee

Atlantic Richfield Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-06-25

Filing date

1973-06-25

Publication date

1974-12-17

1973-06-25 Application filed by Atlantic Richfield Co filed Critical Atlantic Richfield Co

1973-06-25 Priority to US00373530A priority Critical patent/US3855014A/en

1974-05-27 Priority to CA200,933A priority patent/CA1027831A/fr

1974-12-17 Application granted granted Critical

1974-12-17 Publication of US3855014A publication Critical patent/US3855014A/en

1991-12-17 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 135
238000010791 quenching Methods 0.000 title claims abstract description 80
230000000171 quenching effect Effects 0.000 title claims abstract description 69
238000000034 method Methods 0.000 title claims abstract description 26
229910052751 metal Inorganic materials 0.000 title claims description 101
239000002184 metal Substances 0.000 title claims description 101
229910052799 carbon Inorganic materials 0.000 claims abstract description 18
230000003647 oxidation Effects 0.000 claims abstract description 18
238000007254 oxidation reaction Methods 0.000 claims abstract description 18
238000010186 staining Methods 0.000 claims abstract description 13
150000004985 diamines Chemical class 0.000 claims abstract description 11
RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 claims abstract description 10
230000001050 lubricating effect Effects 0.000 claims abstract description 5
150000001875 compounds Chemical class 0.000 claims description 42
125000004432 carbon atom Chemical group C* 0.000 claims description 37
125000003118 aryl group Chemical group 0.000 claims description 18
125000002877 alkyl aryl group Chemical group 0.000 claims description 11
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 10
239000001257 hydrogen Substances 0.000 claims description 9
229910052739 hydrogen Inorganic materials 0.000 claims description 9
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 7
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
150000001342 alkaline earth metals Chemical class 0.000 claims description 7
229910052791 calcium Inorganic materials 0.000 claims description 7
239000011575 calcium Substances 0.000 claims description 7
XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical group C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 claims description 5
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 5
229910052783 alkali metal Inorganic materials 0.000 claims description 3
150000001340 alkali metals Chemical class 0.000 claims description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 7
150000002736 metal compounds Chemical class 0.000 abstract description 7
239000003921 oil Substances 0.000 description 60
-1 phenyl hexyl Chemical group 0.000 description 29
239000004215 Carbon black (E152) Substances 0.000 description 26
229930195733 hydrocarbon Natural products 0.000 description 26
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 9
125000000217 alkyl group Chemical group 0.000 description 8
150000001721 carbon Chemical class 0.000 description 7
125000003710 aryl alkyl group Chemical group 0.000 description 6
150000007514 bases Chemical class 0.000 description 6
238000009833 condensation Methods 0.000 description 6
230000005494 condensation Effects 0.000 description 6
150000002739 metals Chemical class 0.000 description 5
239000002480 mineral oil Substances 0.000 description 5
239000003208 petroleum Substances 0.000 description 5
125000001424 substituent group Chemical group 0.000 description 5
239000010913 used oil Substances 0.000 description 5
229910000975 Carbon steel Inorganic materials 0.000 description 4
239000000654 additive Substances 0.000 description 4
239000010962 carbon steel Substances 0.000 description 4
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 4
235000010446 mineral oil Nutrition 0.000 description 4
150000005002 naphthylamines Chemical class 0.000 description 4
239000011347 resin Substances 0.000 description 4
229920005989 resin Polymers 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
239000011149 active material Substances 0.000 description 3
125000002947 alkylene group Chemical group 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
150000002431 hydrogen Chemical class 0.000 description 3
JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 2
CTTVKXMURPTCOF-UHFFFAOYSA-N 4-[2-[4-(dimethylamino)phenyl]propan-2-yl]-n,n-dimethylaniline Chemical compound C1=CC(N(C)C)=CC=C1C(C)(C)C1=CC=C(N(C)C)C=C1 CTTVKXMURPTCOF-UHFFFAOYSA-N 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
229910000831 Steel Inorganic materials 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
125000005024 alkenyl aryl group Chemical group 0.000 description 2
125000003342 alkenyl group Chemical group 0.000 description 2
125000005018 aryl alkenyl group Chemical group 0.000 description 2
238000001816 cooling Methods 0.000 description 2
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
239000011521 glass Substances 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
YZZTZUHVGICSCS-UHFFFAOYSA-N n-butan-2-yl-4-[[4-(butan-2-ylamino)phenyl]methyl]aniline Chemical compound C1=CC(NC(C)CC)=CC=C1CC1=CC=C(NC(C)CC)C=C1 YZZTZUHVGICSCS-UHFFFAOYSA-N 0.000 description 2
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 2
239000010959 steel Substances 0.000 description 2
FCTALLDRCBVIQN-UHFFFAOYSA-N 1,1'-biphenyl;naphthalen-1-amine Chemical class C1=CC=C2C(N)=CC=CC2=C1.C1=CC=CC=C1C1=CC=CC=C1 FCTALLDRCBVIQN-UHFFFAOYSA-N 0.000 description 1
ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 description 1
CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
101100264195 Caenorhabditis elegans app-1 gene Proteins 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
238000004566 IR spectroscopy Methods 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
102100035115 Testin Human genes 0.000 description 1
101710070533 Testin Proteins 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000003513 alkali Substances 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
125000003493 decenyl group Chemical group [H]C([*])=C([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
VILAVOFMIJHSJA-UHFFFAOYSA-N dicarbon monoxide Chemical group [C]=C=O VILAVOFMIJHSJA-UHFFFAOYSA-N 0.000 description 1
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical class C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 1
125000005066 dodecenyl group Chemical group C(=CCCCCCCCCCC)* 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229940097789 heavy mineral oil Drugs 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
238000007654 immersion Methods 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
239000010687 lubricating oil Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
LAMTXWQPHWUMLX-UHFFFAOYSA-N n-butan-2-ylaniline Chemical compound CCC(C)NC1=CC=CC=C1 LAMTXWQPHWUMLX-UHFFFAOYSA-N 0.000 description 1
VIVZTUCNTFHGLE-UHFFFAOYSA-N n-dodecyl-n-phenylnaphthalen-1-amine Chemical class C=1C=CC2=CC=CC=C2C=1N(CCCCCCCCCCCC)C1=CC=CC=C1 VIVZTUCNTFHGLE-UHFFFAOYSA-N 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000010992 reflux Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
125000005063 tetradecenyl group Chemical group C(=CCCCCCCCCCCCC)* 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
239000002966 varnish Substances 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
- C21D1/58—Oils
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/027—Neutral salts thereof
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/402—Castor oils
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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Definitions

ABSTRACT An improved method for quenching is also disclosed.
the present invention relates to improved quenching oil compositions and methods for using same. More particularly, the present invention relates to quenching oil compositions having both improved anti-staining properties and improved resistance to oxidation, and to an improved method for quenching heated metals.
Quenching oil compositions used, for example, to quench heated metals, must provide efficient cooling without detrimentally affecting the metal being quenched.
Certain prior art quenching oil compositions have shown a tendency to cause stains to be formed on the metal. These stains, at best, require additional processing to remove and may require that the metal be scrapped. Therefore, it would be advantageous to provide a quenching oil composition having improved antistaining properties.
quenching oil compositions are normally in use over a protracted period of time, they are subject to deterioration by oxidation. Therefore, it would be advantageous to provide a quenching oil composition having improved resistance to oxidation.
one of the primary objects of the present invention is to provide a quenching oil composition having improved anti-staining properties.
Another object of the present invention is to provide a quenching oil composition having improved resistance toward oxidation.
An additional object of the present invention is to provide an improved method of quenching heated metal. Other objects and advantages of the present invention will become apparent hereinafter.
An improved quenching oil composition which comprises a major amount of quench oil of lubricating viscosity having a minimum flash point of at least about 250F., a minor amount sufficient to improve the anti-staining properties of the composition of at least one metal phenate compound of a phenolic component having the following structure OII on on I i 1 l IR ly-@+R' R' I s l j R Ron I 3 wherein R is selected from the group consisting of hydrogen and monovalent essentially hydrocarbon radicals containing up to about 5 carbon atoms and mixtures thereof, n is an integer from zero to about 6, prefwherein R is selected from the group consisting of hydrogen and monovalent hydrocarbon radicals containing from 1 to about 30, preferably from about 6 to about 18, carbon atoms, a is an integer from zero to 7, preferably zero to l inclusive and D is a monovalent hydrocarbon radical containing from 1 to about 30, preferably from about 1 to about 18 carbon atoms.
the quenching oil compositions further comprise a minor amount sufficient to further improve the resistance to oxidation of the composition of at least one diamine component having the fOllOWino em
R R R and R areindependently selected from the group consisting of hydrogen, alkyl having from 1 to about 12 carbon atoms, and aryl, aralkyl, alkaryl having from 6 to about 22 carbon atoms
B is selected from the group consisting of divalent aromatic-containing hydrocarbon radicals and substituted divalent aromatic-containing hydrocarbon radicals containing from 6 to about 30, preferably from about 6 to about 24 carbon atoms.
the quench oil of lubricating viscosity used in the present invention may be eithernaturally occurring or synthetically made. It may be animal, vegetable or minera] in character, with mineral oils being preferred. However, because of the relatively high temperatures of many quenching operations, the oil should have a minimum flash point of at least about 250F. and preferably in the range from about 250F. to about 500F., or higher.
suitable lubricating oils include those having a viscosity in the range from about 50 SUS to about 1000 SUS, preferably from about 50 SUS to about 300 SUS, at 100F. These oils may be refined or otherwise processed to produce the desired quality. Petroleum oils are especially preferred.
a specific example of the quench oil used in the present compositions is a petroleum derived oil mixture having a viscosity of about 200 SUS at 100F. Combinations or mixtures of two or more such quenching oils in a single quenching composition are often used to provide the desired physical properties and these mixtures are, therefore, within the scope of the invention.
the quench oil comprises ,a major amount, preferably at least about and more preferably at least about by weight of the total composition.
additives which are known to increase the initial rate, and therefore, the overall rate, of cooling of quenching oil compositions may be included in the quench oils.
heavy mineral oil fractions e.g., petroleum resins, having minimum flash points in the range from about 400F. to about 700F. and viscosities in the range from about 200 SUS to about 2000 SUS at 210F. are suitable for use in these quench oils.
this additive be of naturally occurring mineral oil origin, e.g., such as the petroleum resins noted above, various synthetic materials, such as olefin polymers, also are suitable.
these additives comprise from about 0.5 to about 20%, preferably from about i to about by weight of the quench oil.
the metal phenate compounds useful in the quenching oil compositions of the present invention are preferably oil-soluble.
the metals which may be used to form the metal phenate compounds suitable for the present compositions include the alkaline earth metals such as barium, calcium, strontium, and magnesium; the alkali metals such as sodium, potassium and lithium; and polyvalent metals such as lead, tin, zinc, aluminum, copper, mercury, vanadium, chromium, molybdenum, manganese, iron, cobalt and nickel.
the alkali and, particularly, the alkaline earth metals are preferred.
the most preferred metal for use in the phenate compounds is calcium.
these metal phenate compounds comprise from about 0.1 to about preferably from about 0.5 to about 8%, by weight of the total quenching oil composition.
the metal phenate compounds useful in the present invention may. be referred to as carbon linked polyphenate metal compounds.
the carbon link between phenyl groups can contain as many as about 5 carbon atoms, it is preferred that this carbon link contain only one carbon atom.
the phenolic component comprise the following structure on on l I l l g R R n R wherein each R, R and R and n are as previously defined.
the monovalent essentially hydrocarbon radicals from which each R is independently selected include alkyl and alkenyl groups containing from about 3 to about 20, preferably from about 8 to about 20, carbon atoms; aryl, aralkyl, alkaryl, aryl alkenyl and alkenyl aryl groups containing from about 6 to about 20, preferably from about 8 to about carbon atoms.
the divalent essentially hydrocarbon radicals from which each R is independently selected include alkylene groups containing from l to about 5 carbon atoms.
Suitable alkyl groups include propyl, butyl, pentyl, octyl, decyl, dodecyl, tetradecyl, stearyl and the like.
Suitable alkenyl groups include propenyl, butenyl, pentenyl, octenyl, decenyl, dodecenyl, tetradecenyl, oleic and the like.
Suitable aryl, aralkyl, alkaryl, aryl alkenyl and alkenyl aryl groups include phenyl, naphthyl, phenyl ethyl, phenyl hexyl, phenyl octyl, phenyl tetradecyl, naphthyl hexyl, naphthyl octyl, ethyl phenyl, hexyl phenyl, octyl phenyl, tetradecyl phenyl, hexyl naphthyl, octyl naphthyl, phenyl ethenyl, phenyl hexenyl, phenyl octenyl, phenyl tetradecenyl, naphthyl hexenyl, naphthyl octenyl, phenyl tetrade
essentially hydrocarbon radicals may include non-hydrocarbonaceous substituents thus forming substituted monovalent and divalent essentially hydrocarbon radicals.
Suitable substituents include those which do not materially interfere with the effectiveness, e.g., anti-staining properties, of the metal phenate compound.
Typical examples of such noninterferring substituents include OH,
each R be an alkyl group, more preferably the same alkyl group, containing from about 8 to about 20 carbon atoms, and that each R contain 1 carbon atom. At least one R may contain a carbonyl carbon atom or itself be a carbonyl group.
the carbony] functionality can result from oxidation of a hydrocarbon radical R. For example, if R' is methylene, oxidation willproduce a carbonyl group.
At least one of the terminal phenyl groups of the metal phenate compound may be further substituted with non-interferring radicals, both monovalent essentially hydrocarbon radicals containing from about 8 to about 20 carbon atoms and non-hydrocarbon radicals, i.e., radicals which do not materially interfere with the effectiveness of the phenate compound in the compositions of the present invention.
non-interferring radicals both monovalent essentially hydrocarbon radicals containing from about 8 to about 20 carbon atoms and non-hydrocarbon radicals, i.e., radicals which do not materially interfere with the effectiveness of the phenate compound in the compositions of the present invention.
Groups including, for example, R and non-hydrocarbon radicals such as OH,
halide and the like radicals may be substituted on the terminal phenyl groups.
a radical selected from the group consisting of may form at least part of a substituent on at least one of the terminal phenyl groups.
the carbon linked poly-phenate metal compounds suitable for use in the present invention may be prepared by conventional procedures well known in the art, for example, as disclosed in US. Pat. No. 2,736,701. These phenate metal compounds can be prepared by condensing an alkylated phenol with a low molecular weight aldehyde, preferably formaldehyde, in the presence of a basic compound, e.g., hydroxide, of the desired metal. This basic compound may act both to catalyze the condensation, although other condensation catalysts such as sulfuric acid and other strong mineral acids may be used, and to react with the phenolic hydroxy groups to form the desired polyphenate metal compound.
a basic compound e.g., hydroxide
the condensation may be catalyzed by one basic compound and the phenolic hydroxy groups reacted with a different basic compound. However, it is preferred to use the same basic compound to perform both functions. It may be necessary to add additional basic compound after the condensation has stopped in order to form the desired metal phenate compound.
the condensation and phenolic hydroxy group reaction conditions are well known in the art.
the naphthyl amines suitable for use in the present invention comprise a broad class of compounds.
the general structural formula for these compounds is as follows R N H wherein R is selected from the group consisting of hydrogen and monovalent hydrocarbon radicals containing from I to about 30, preferably from about 6 to about 18 carbon atoms, a is an integer from zero to 7, preferably zero to l inclusive, D is a monovalent hydrocarbon radical containing from I to about 30, preferably from about 1 to about 18 carbon atoms. Included among the monovalent hydrocarbon radicals contemplated by the present invention are, for example, alkyl, aryl, aralkyl, alkaryl and substituted counterparts of these radicals.
Suitable amines include phenyl alphaor betanaphthylamine, octylphenyl alphaor betanaphthylamine, alpha-alpha, alpha-beta or beta-beta dinaphthylamines, various phenanthrylanthyrl-naphthylamines, xylyl naphthylamines, dodecyl phenyl naphthylamines, biphenyl naphthylamines and phenyl naphthylamines alkylated with olefins containing from about 8 to 24 carbon atoms per molecule.
olefins include pinene, a-methylstyrene, and the like.
R is a radical selected from the group consisting of aryl and alkaryl containing from 6 to about 18 carbon atoms, especially phenyl alpha naphthylamine, are of particular usefulness in the present invention and are, therefore, the more preferred class of compounds for use in the present invention.
the naphthylamines often comprise from about 0.01% to about 5%, preferably from about 0.1% to about 2%, by weight of the total quenching oil composition.
R and R be H, i.e., hydrogen.
alkyl groups from which R, R R and R may be selected include methyl, ethyl, isopropyl, sec-butyl, cyclohexyl, octyl, nonyl, decyl and the like.
Examples of the aryl, aralkyl and alkaryl groups from which R R R and R may be selected include phenyl, benzyl, phenyl ethyl, phenyl isopropyl, phenyl octyl, phenyl decyl, tolyl, isopropyl phenyl, octyl phenyl, decyl phenyl and the like.
Examples of the divalent aromatic-containing hydrocarbon radicals from which B may be selected include phenylene, alkylene diphenylene and phenylene dialkylene wherein the alkylene groups contain from 1 to about 12 carbon atoms, and the like radicals.
divalent hydrocarbon radicals may be substituted with minor amounts of essentially noninterferring oxygen, sulfur and the like.
suitable substituted divalent aromatic-containing hydrocarbon radicals include divalent diphenyl ethers, and diphenyl sulfides and the like.
the following diamine components are among those preferred: Bis-(N- sec-butyl-p-amino phenyl) methane; N-isopropyl-N'- phenyl-p-phenylene diamine; N-cyclohexyl-N-phenylp-phenylene diamine; 2,2-Bis-(p-N,N- dimethylaminophenyl) propane and mixtures thereof.
quenching oil compositions of the present invention may contain other agents such as antifoam agents, corrosion inhibitors, etc.
compositions of the present invention are particularly useful in a method of quenching heated metal which comprises contacting the heated metal with such composition at conditions to cool the metal. Prior to such contacting the metal is heated to an elevated temperature, e.g., from about 1000F. to about 2500F. During the course of such contacting, the heated metal is preferably immersed in the quenching oil composition. Metals, such as carbon steel, which require quenching during, for example, manufacture and/or fabrication, may be treated using the present method.
compositions were blended at slightly elevated temperatures, i.e., from about F. to about l30F., to insure proper mixing. These compositions were as follows:
This carbon bridged calcium phenate compound is derived from the condensation of alkyl phenol with formaldehyde. The material contained 2.4% by weight of calcium.
Infra-red spectrometry indicates the phenatc salt contains carbonyl functionality which may be located at either or both a carbon bridge or as part of a substituent on a terminal phenyl group. Based upon molecular weight considerations and elemental analysis, the phenate compound comprises 6 aromatic nuculi with single carbon atom bridges in between.
a mixture of about 50% by weight of active material in a mineral oil carrier comprises mono-sulflde linked calcium phenate compound derived from dodecyl phenol.
compositions were tested using a laboratory staining test which is known to give a reasonable comparative correlation with staining properties of such compositions in actual quenching operation.
the staining test used involves passing air through a 3000 cc. quantity of the oil composition being tested.
the oil is contained in an open steel beaker and is subjected to constant stirring.
the oil is heated to and maintained at 350F. using a chrome immersion heater. Air is bubbled through the oil at a rate of 0.1 cu.ft./ hour using a sintered glass dispersing tip.
the tendency for varnish and/or carbonaceous formation on the 5 heater is periodically observed. The longer the time before deposits form, the better the anti-staining properties of the oil composition.
physical tests on the oil at approximately 100 hour intervals are made by re-
the oxidation test used involves passing air through a 150 cc. sample of the oil composition being tested.
the composition is placed in a glass flask equipped with a reflux condenser.
the oil is heated to and maintained at 342F. using an external heating source. Air is bubbled into the oil at the rate of 10 liters/hour for 175 hours. After this period, various physical tests are carried out on the used oil composition to determine the degree of oxidation.
compositions were blended at 45 slightly elevated temperatures. These compositions, along with Composition 1, are as follows:
Composition 5 which includes both phenyl-a-naphthylamine and 4,4'-methylene-bis-N- sec-butylaniline, possesses superior oxidation resistance. This is particularly suprising in view of the fact that 4,4-methylene-bis-N-sec-butyl-aniline alone,
COMPOSITION l 3 4 5 6 7 Weight Percent Component Mineral Oil 200 SUS Petroleum Resin, 1000 SUS at 210F. 5.0 5.0 5.0 5.0 5.0 5.0 5.0
Composition 4 provides little or no oxidation resistance.
the present quenching oil compositions which contain both a carbon linked poly-phenate metal compound and a naphthylamine have unexpectedly improved anti-stain properties and oxidation resistance.
Compounded oils having the same chemical compositions as Compositions 3 and are employed to rapidly cool carbon steel from a temperature of about 1650F.
the carbon steel to be cooled is brought into contact with the compounded oil by immersing the steel in the oil. It is found that both compounded oils are effective to rapidly cool the carbon steel.
a quenching oil composition comprising a major amount of quench oil of lubricating viscosity having a minimum flash point of at least about 250F.', a minor amount sufficient to improve the anti-staining properties of said composition of at least one metal phenate compound of a phenolic component having the following structure an (
each R is independently selected from the group consisting of monovalent essentially hydrocarbon radicals containing from about 3 to about 20 carbon atoms, each R is independently selected from the group consisting of divalent essentially hydrocarbon radicals containing from 1 to 5 carbon atoms and a carbonyl group, each R is independently selected from the group consisting of non-interferring hydrocarbon radicals containing up to about 20 carbon atoms, noninterferring non-hydrocarbon radicals,
R is selected from the group consisting of hydrogen and monovalent essentially hydrocarbon radicals containing up to about 5 carbon atoms and mixtures thereof, n is an integer from zero to about 6 and P, X and T are each integers from zero to 3; and a minor amount sufficient to improve the resistance to oxidation of said composition of at least one naphthyl amine having the following structure phenate compound is present in an amount from about 0.1% to about by weight of the total composition and said naphthyl amine is present in an amount from 10 about 0.01 to about 5% by weight of the total composition.
composition of claim 2 wherein said metal phenate compound is a compound of a metal selected from the group consisting of alkali metal and alkaline 15 earth metal.
composition of claim 3 wherein said metal phenate compound is a compound of an alkaline earth metal and each R is a radical independently selected from the group consisting of aryl and alkaryl containing from 6 to about 8 carbon atoms.
composition of claim 4 wherein said metal phenate compound is a compound of calcium.
composition of claim 5 wherein said phenolic component has the following structure:
each R contains from about 8 to about 20 carbon atoms and each R contains 1 carbon atom.
each R contains from about 8 to about 20 carbon atoms, each R contains 1 carbon atom and said naphthyl amine is phenyl alpha naphthylamine.
composition of claim 1 which further comprises a minor amount sufficient to further improve the resistance to oxidation of said composition of at least one diamine component having the following structure:
R R R and R are independently selected from the group consisting of hydrogen, alkyl having from 1 to about 12 carbon atoms, and aryl, aralkyl, alkaryl having from 6 to about 22 carbon atoms
B is selected from the group consisting of divalent aromatic-containing hydrocarbon radicals and substituted divalent aromatic-containing hydrocarbon radicals containing from 6 to about 30 carbon atoms.
composition of claim 9 wherein said metal phenate compound is present in an amount from about 0.1% to about 15% by weight of the total composition and said naphthyl amine is present in an amount from about 0.01% to about 5% by weight of the total composition and said diamine component is present in an amount from about 0.01% to about 5% by weight of the total composition.
composition of claim 10 wherein said metal phenate compound is a compound of an alkaline earth metal and each R is a radical independently selected from the group consisting of aryl and alkaryl containing from 6 to about 8 carbon atoms, R and R are hydrogen, and B contains from 6 to about 24 carbon atoms, 12.
composition of claim 11 wherein said metal phenate compound is a compound of calcium, said phenolic component has the following structure l l RI I I XjLMT l l H n R wherein each R contains from about 8 to about carbon atoms, each R contains 1 carbon atom and said naphthylamine is phenyl alpha naphthylamine and said diamine component is selected from the group consisting of Bis-(N-sec-butyl-p-amino phenyl)methane; N- isopropyl-N'-phenyl-p-phenylene diamine; N- cyclohexyl-N'-phenyl-p-phenylene diamine; 2,2-Bis(p- N,N-dimethylaminophenyl) propane and mixtures thereof.

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US00373530A 1973-06-25 1973-06-25 Quenching oil composition and method of quenching metal Expired - Lifetime US3855014A (en)

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US00373530A US3855014A (en)	1973-06-25	1973-06-25	Quenching oil composition and method of quenching metal
CA200,933A CA1027831A (fr)	1973-06-25	1974-05-27	Huiles de trempe

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US00373530A US3855014A (en)	1973-06-25	1973-06-25	Quenching oil composition and method of quenching metal

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EP0688878A1 (fr) *	1994-06-23	1995-12-27	Elpatronic Ag	Procédé et dispositif pour le post-traitement de tÔles soudées
US6239082B1 (en) *	1998-04-03	2001-05-29	Exxon Research And Engineering Company	Petroleum quench oil
WO2003052146A1 (fr) *	2001-12-18	2003-06-26	The Lubrizol Corporation	Compositions d'huile de trempe
WO2003052145A1 (fr) *	2001-12-18	2003-06-26	The Lubrizol Corporation	Compositions d'huile de trempe
CN107250388A (zh) *	2015-02-18	2017-10-13	出光兴产株式会社	热处理油组合物
CN107250389A (zh) *	2015-02-18	2017-10-13	出光兴产株式会社	热处理油组合物
EP3371335A4 (fr) *	2015-11-02	2019-06-19	Applied Nano Surfaces Sweden AB	Articles en acier revêtus de lubrifiant solide, procédé et appareil pour leur fabrication et huile de trempe utilisée dans la fabrication
US10435177B2 (en)	2006-02-17	2019-10-08	Earthstone International Llc	Foamed glass composite arrestor beds having predetermined failure modes
CN111020135A (zh) *	2019-11-15	2020-04-17	山东硕力新材料科技有限公司	一种环保难燃淬火油的制备方法
US11970288B2 (en)	2006-02-17	2024-04-30	Earthstone International Llc	Method for slowing an aircraft using a foamed glass composite runway
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US4214924A (en) *	1978-10-27	1980-07-29	Pennwalt Corporation	Method of improving surface characteristic of heat-treated metal
EP0688878A1 (fr) *	1994-06-23	1995-12-27	Elpatronic Ag	Procédé et dispositif pour le post-traitement de tÔles soudées
US5639012A (en) *	1994-06-23	1997-06-17	Elpatronic Ag	Process and device for the posttreatment of welded compound panels
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WO2003052145A1 (fr) *	2001-12-18	2003-06-26	The Lubrizol Corporation	Compositions d'huile de trempe
US20050039832A1 (en) *	2001-12-18	2005-02-24	Sweet William R	Quenching oil compositions
US7358217B2 (en)	2001-12-18	2008-04-15	The Lubrizol Corporation	Quenching oil compositions
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US11970288B2 (en)	2006-02-17	2024-04-30	Earthstone International Llc	Method for slowing an aircraft using a foamed glass composite runway
US10435177B2 (en)	2006-02-17	2019-10-08	Earthstone International Llc	Foamed glass composite arrestor beds having predetermined failure modes
US12065264B2 (en)	2014-06-11	2024-08-20	Earthstone International Llc	Method for using a foamed glass composite material
CN107250389A (zh) *	2015-02-18	2017-10-13	出光兴产株式会社	热处理油组合物
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CN107250388A (zh) *	2015-02-18	2017-10-13	出光兴产株式会社	热处理油组合物
US10704111B2 (en)	2015-11-02	2020-07-07	Applied Nano Surfaces Sweden Ab	Solid lubricant-coated steel articles, method and apparatus for manufacturing thereof and quenching oil used in the manufacturing
EP3371335A4 (fr) *	2015-11-02	2019-06-19	Applied Nano Surfaces Sweden AB	Articles en acier revêtus de lubrifiant solide, procédé et appareil pour leur fabrication et huile de trempe utilisée dans la fabrication
CN111020135A (zh) *	2019-11-15	2020-04-17	山东硕力新材料科技有限公司	一种环保难燃淬火油的制备方法

Also Published As

Publication number	Publication date
CA1027831A (fr)	1978-03-14

Publication	Publication Date	Title
US3855014A (en)	1974-12-17	Quenching oil composition and method of quenching metal
US2910439A (en)	1959-10-27	Corrosion inhibited compositions
RU2051170C1 (ru)	1995-12-27	Смазочное масло для двигателей внутреннего сгорания
US2850453A (en)	1958-09-02	Corrosion inhibited oil compositions
US4157309A (en)	1979-06-05	Mannich base composition
US4039461A (en)	1977-08-02	Polyalkylene glycol polyalkylene polyamine succinimide dispersants for lubricant fluids
US3573206A (en)	1971-03-30	Lubricant compositions
JPH0361718B2 (fr)	1991-09-20
US3509214A (en)	1970-04-28	Oil soluble oxidized naphthylamine compositions
US3528917A (en)	1970-09-15	Sulfurized calcium alkylphenolate lubricant compositions
US2340036A (en)	1944-01-25	Lubricant composition
US2647873A (en)	1953-08-04	Lubricating compositions
US4720350A (en)	1988-01-19	Oxidation and corrosion inhibiting additives for railway diesel crankcase lubricants
DE3874117T2 (de)	1993-01-07	Aliphatische substituierte aromatische kohlenwasserstoffe fuer die beherrschung des schwarzschlamms in schmiermitteln.
US3442807A (en)	1969-05-06	Novel boron esters and stabilization of oxidizable organic substances therewith
US5205945A (en)	1993-04-27	Multifunctional additives
US4966721A (en)	1990-10-30	N-N'-dihydrocarbyl substituted phenylene diamine-derived condensation products as antioxidants and lubricant compositions
US3745117A (en)	1973-07-10	Lubricating oil composition
US3846318A (en)	1974-11-05	Antioxidant and extreme pressure lubricating oil additive
US3123570A (en)	1964-03-03	Lubricating oil composition of improved
US4456541A (en)	1984-06-26	Antioxidant diamine
US4005021A (en)	1977-01-25	Oil-soluble reaction products of (a) a high molecular weight olefin polymer, acrylonitrile, chlorine, an amine and maleic anhydride, with (g) an aliphatic amines; and lubricant compositions containing the same
US2763615A (en)	1956-09-18	Carboxylic acid derivatives and lubricants containing them
US2295053A (en)	1942-09-08	Hydrocarbon oils containing organic trisulphides as oxidation inhibitors
US3248361A (en)	1966-04-26	Hydrocarbon lubricating oil composition