US3878880A - Composite casting method - Google Patents
Composite casting method Download PDFInfo
- Publication number
- US3878880A US3878880A US373514A US37351473A US3878880A US 3878880 A US3878880 A US 3878880A US 373514 A US373514 A US 373514A US 37351473 A US37351473 A US 37351473A US 3878880 A US3878880 A US 3878880A
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- United States
- Prior art keywords
- metal
- metalloid
- casting
- protective layer
- carbide
- Prior art date
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- Expired - Lifetime
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- 238000005266 casting Methods 0.000 title claims abstract description 86
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000002131 composite material Substances 0.000 title description 3
- 229910052751 metal Inorganic materials 0.000 claims abstract description 92
- 239000002184 metal Substances 0.000 claims abstract description 92
- 239000000463 material Substances 0.000 claims abstract description 86
- 238000005552 hardfacing Methods 0.000 claims abstract description 32
- 230000035939 shock Effects 0.000 claims abstract description 8
- 229910052752 metalloid Inorganic materials 0.000 claims description 63
- 150000002738 metalloids Chemical class 0.000 claims description 63
- 239000011241 protective layer Substances 0.000 claims description 46
- 238000000576 coating method Methods 0.000 claims description 43
- 239000011248 coating agent Substances 0.000 claims description 38
- 239000010410 layer Substances 0.000 claims description 29
- 229910052782 aluminium Inorganic materials 0.000 claims description 23
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 23
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 14
- 229910052802 copper Inorganic materials 0.000 claims description 14
- 239000010949 copper Substances 0.000 claims description 14
- 230000001788 irregular Effects 0.000 claims description 14
- 229910045601 alloy Inorganic materials 0.000 claims description 13
- 239000000956 alloy Substances 0.000 claims description 13
- 239000010941 cobalt Substances 0.000 claims description 12
- 229910017052 cobalt Inorganic materials 0.000 claims description 12
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 12
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 claims description 9
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims description 8
- QIJNJJZPYXGIQM-UHFFFAOYSA-N 1lambda4,2lambda4-dimolybdacyclopropa-1,2,3-triene Chemical compound [Mo]=C=[Mo] QIJNJJZPYXGIQM-UHFFFAOYSA-N 0.000 claims description 7
- 229910039444 MoC Inorganic materials 0.000 claims description 7
- 238000000151 deposition Methods 0.000 claims description 7
- 230000001681 protective effect Effects 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 239000010937 tungsten Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 4
- 230000003685 thermal hair damage Effects 0.000 claims description 2
- 230000008646 thermal stress Effects 0.000 claims description 2
- -1 TUNGSTEM CARBIDE Chemical compound 0.000 claims 1
- 150000001247 metal acetylides Chemical class 0.000 abstract description 5
- 239000003870 refractory metal Substances 0.000 abstract description 3
- 150000002739 metals Chemical class 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 230000002093 peripheral effect Effects 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 238000005336 cracking Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 238000004512 die casting Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000009750 centrifugal casting Methods 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 238000010120 permanent mold casting Methods 0.000 description 2
- 101100369915 Drosophila melanogaster stas gene Proteins 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 238000010285 flame spraying Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/0009—Cylinders, pistons
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B53/00—Internal-combustion aspects of rotary-piston or oscillating-piston engines
- F02B2053/005—Wankel engines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49229—Prime mover or fluid pump making
- Y10T29/4927—Cylinder, cylinder head or engine valve sleeve making
- Y10T29/49272—Cylinder, cylinder head or engine valve sleeve making with liner, coating, or sleeve
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
- Y10T29/49982—Coating
- Y10T29/49984—Coating and casting
Definitions
- ABSTRACT l l PP 373,514 A method of producing a casting of a basis metal having a transplanted facing of a very hard material.
- Hard [52] Cl. 164/9, 164/33, 164/46, facing materials such as refractory metals and ce- 59/5273; 164/95 mented carbides are sprayed by a metalizing gun in a [51] Int Cl. 822d 19/08 layer onto a core piece, an intermediate layer of metal [58] Field orselii'fffIIffIfffffI'ilkfil. 33, 46, 95, is b first layer brit- 164/1. 29/527 3 527 6 tle hard facing material from the thermal shock of casting temperatures, the core piece positioned in a [56] References Cited mold as at least a portion of the cavity wall thereof, an
- the casting and core piece are re- 2,074,007 3/l937 wlSSlCX' X moved from the mold and the core piece detached i from the casting, leaving the first layer as an integral 3:201:36 9/1968 11:: l64/l4 X part ofthe casting having a hard Surface 3433.284 3/l969 Webberc ct al.
- This invention relates to a method of producing cast objects, and more particularly to a method of producing such articles of a basis metal having at least a portion of the surface thereof coated with a transplanted hard material.
- Transplanted coatings are also known, such as the steel cylinder sleeves installed in aluminum alloy engine blocks by the method disclosed in US. Pat. No. 3,083,424.
- a cylindrical mandrel is sprayed with a coating of steel by a metalizing gun, the mandrel carrying the coating is then positioned in a die casting mold, and the cylinder block then cast around it.
- the coating being rough on what constitutes its exterior surface before casting, the molten aluminum alloy when injected into the mold under pressure makes a firm bond with the coating material.
- the casting and the mandrel are then removed from the mold and cooled, after which the mandrel is released by differen tial expansion of the parts when the casting is heated.
- the steel layer then remains as a sleeve in the engine block, having a surface on its interior diameter comparable with that of the mandrel, and requiring only honing to serve satisfactorily as a cylinder bore.
- a further object is to provide a method of producing castings of relatively soft basis metals having wear surfaces of harder materials.
- Another object is to provide a method of producing castings having transplanted coatings of refractory metals, cemented carbides, and other metalloid materials.
- Still another object is to provide a method of casting a basis metal over a transplant coating which is protected from the thermal shock of molten metal by a protective layer.
- This invention provides a method of making castings having transplanted coatings of hard metals and metalloid materials wherein the cracking of the transplant coating layer is avoided.
- the coating material is sprayed onto a mandrel or other core piece, then a protective layer of a metal having higher heat conductivity, high ductility, and a low modulus of elasticity is sprayed onto the coating material, forming a firm interlocking bond therewith.
- the core piece bearing the first and second layers is then positioned in a permanent mold and the casting formed, with the casting metal making a firm interlocking bond with the second layer.
- the heat of the casting metal is largely transferred rapidly away from the point or points of impingement on the second layer by the high thermal conductivity thereof, thus avoiding the production of an initial hot spot on the transplanted facing layer, which in the prior art has been a serious cause of cracking.
- the protective layer also has a thermal gradient across its thickness, and thus provides a small but significant delay before the full heat of the molten metal reaches the facing material, thus mitigating the thermal shock to the brittle facing material. This effect is enhanced by the fact that once in the mold the basis metal cools very rapidly, so that the facing material is never exposed to the full pouring temperature of the basis metal.
- the low modulus of elasticity and associated high ductility of the protective layer allow it to bear local stresses without transferring them across the interface to the brittle facing layer, which has previously been a cause of cracking, owing to the low coefficient of expansion, the low thermal conductivity, and the low ductility of the facing material.
- FIG. 1 is a cross-section of a peripheral housing for a trochoidal rotary engine, with its inner running surface having a transplanted coating according to the invention
- FIG. 2 is a semi-schematic view of a core piece in the course of being sprayed with the coating material and the protective layer; and l FIG. 3 is a semi-schematic view in cross-section of closed casting mold with the core piece of FIG. 2 in position for casting.
- FIG. 1 shows a cross-section, of such a peripheral housing 11, having a basically epitrochoidal inner surface bearing the hard facing lZand the second layer l3 according to theinvention.
- the housing 11 is formed of a castaluminum alloy or other lightweight basis metal 15 and may have cooling passages 14!, inlet and outlet passages 16 and 17 respectively, and a spark plug aperture 18, all of which openings are produced during the casting procedure by conventional coring techniques. Casting is carried out in a permanent mold, and the molten basis metal may be supplied by pressure feed, by pressure die-casting, or by centrifugal casting.
- FIG. 2 there is shown a core piece 19 in the process of being sprayed with the hard facing layer 12 and the protective layer 13 by a metalizing gun 21.
- the core piece 19 is formed of a suitable die material by the usual toolmaking techniques, having a peripheral surface in the form of the trochoid which is desired in the casting.
- the core piece is not limited to any specific form nor to positioning a hard facing material only on an interior surface of a casting.
- the term core piece embraces any portion of a mold wall and may have any form appropriate to position the facing material at the intended place in the casting.
- Such a core piece may be of any shape, whether curved, plane, or angular, and will be so formed that its coated surface will form at least a portion of a wall of the mold in which the casting is to be formed, leaving the hard facing material at the desired position of the cast object. No draft allowance need be provided for such core pieces, since they may be removed from the final casting by other means.
- the core piece 19 has its peripheral surface accurately formed and highly finished, and is of a thickness equal to the axial dimension of the trochoidal housing to be cast, plus a sufficient excess of thickness to allow finish machining of the axial sides of the casting to plane surfaces. In the case of other articles it may occur that no such finishing allowance need be provided.
- the surface of the core piece may be sprayed a coating of a release agent.
- a release agent as are commonly used in permanent mold casting practice are satisfactory.
- the salt-coated core piece will then be sprayed with the hard facing material, and after the casting is formed the salt may be dissolved by immersing the casting bearing the core piece in water.
- Other inexpensive water soluble salts will also serve as release agents.
- the temperature to which the core piece is heated before salt spraying is not critical, except that it should be hot enough to produce more or less instant drying of the water mist solution so that there are no runs which would cause local variations of thickness of the salt. About 400F has been found suitable.
- the core piece 19 has its peripheral surface sprayed with a layer 12 of the material desired as a hard facing.
- a layer 12 of the material desired as a hard facing may be hard metal, such as tungsten, cobalt, molybdenum, or high alloys of those metals; or it may be material such as a metal carbide, for example the carbides of tungsten, cobalt, molybdenum, or silicon carried in a cementing metal such as cobalt, or titanium carbide in a matrix of steel.
- a frequently used material for dispensing by metalizing guns comprises about 73% to about 88% tungsten carbide, preferably about 85% to 88%, with the remainder being cobalt as the cementing material.
- metalloid materials whether they are metals or carbides, and the materials of the protective second layer 13 will be designated as metal.
- the core piece 19 is given a coating 12 of metalloid material of the thickness selected.
- the actual thickness may vary from one job to another, and may be just that thickness desired for service in the finished casting when the type of service is such as to require no finishing of the hard facing beyond the surface provided by the core piece. Otherwise, the coating 12 may be of sufficient thickness to allow removal of some amount of the metalloid material in the finishing process, such as honing or grinding, or grinding followed by honing.
- the service thickness of the hard facing is to be from 0.002 to 0.006 inch after honing.
- the coating 12 as sprayed is from about 0.003 to about 0.007inch, as normal honing ordinarily removed no more than about 0.001 inch of material.
- the allowance for removal in the sprayed coating may be greater. It will be understood that these parameters are given by way of example only, and may vary widely for other requirements.
- the exterior surface of coating 12 as left by the metalizing gun is slightly pitted and irregular, having a distinct tooth.
- the protective layer of metal 13 which may be from three to twenty times as thick as the metalloid hard facing layer, preferably about six to twelve times as thick.
- the thickness selected will depend on several factors, such as the mass of metal to be cast around it, and the casting temperature of the basis metal; the melting point, thermal conductivity, and ductility of the metal of the protective layer; and the thermal conductivity, coefficient of thermal expansion, and resistance to thermal shock of the hard facing metalloid.
- the impact of the sprayed particles of protective metal 13 drives them into the irregularities of the surface of the metalloid coating 12, producing a firm interlocking bond of a strength equal to that of whichever of the two materials has the lesser strength.
- the protective metal 13 generally has a melting point lower than that of the hard facing metalloid 12, but not lower than the melting point of the casting metal 15, and it may be higher than that of the casting metal. Metal 13 must also have higher thermal conductivity than the metalloid, greater ductility, and a lower modulus of elasticity.
- metalloid materials referred to above have low moduli, low thermal conductivity, and very low coefficients of thermal expansion, with the exception of pure cobalt, which is comparable with iron.
- tungsten carbide with cobalt as the cementing material is very low in all these characteristics. It is this relative inability to conduct heat and to expand which is responsible for the cracking of the metalloids when molten metal is cast in direct contact with them.
- the term aluminum family includes pure aluminum and alloys thereof containing or more aluminum
- the term copper family includes pure copper and alloys thereof containing 70% or more copper.
- Both the aluminum family and the copper family are particularly suitable metals for the protective layer 13 when the casting 15 is to be formed of one of the usual lightweight casting metals, such as alloys of aluminum, magnesium, or zinc.
- the members of both the aluminum family and the copper family have theral conductivities several times as high as those of the friietalloids of hardfacing l2, and hence are capable of carrying heat rapidly around the facing metalloid from the points of first contact of the casting metal. Further,
- the exterior surface of the protective layer 13 exposed to the mold cavity, as left by the metalizing gun, will be pitted and irregular just as that of the hard coating.
- the casting metal under the pressure of the mold feed therefore unites firmly with it to provide an interlocking bond of great strength.
- the melting point of the members of the copper family, although much below that of the metalloids, is nevertheless far above that of the casting metals, so that there is no danger of impairing the integrity of a protective layer from the copper family by the temperature of the molten basis metal.
- a member of the aluminum family is desired for the protective layer, a member may be chosen which has a melting point at least as high as, or a few degrees higher than, that of the basis metal. Pure aluminum, for instance, has a melting point of 660C,
- the common aluminum casting alloys melt at various lower temperatures.
- the melting points of the magnesium casting alloys are comparable with those of 7 aluminum, and the melting points of the zinc casting 1 alloys are very much lower. Further, even if the melting temperatures of the protective layer and the basis metal should be the same, the casting metal chills rapidly after being fed into the mold, and if the protective metal approached its melting point an additional input of heat would still be necessary to push it over the threshold of liquidus, which additional input would not be available.
- FIG. 3 there is shown semischematically a permanent mold assembly 22, which in theexample shown is a pressure die-casting mold, but may also be a pressurefed mold or a mold for centrifugal casting.
- the requisite pressure for urging the casting metal into a firm interlocking bond with the rough surface of the protective layer may be provided by any of these methods.
- the mold 22 includes an ejector die portion 23, a cover die 24, and side pieces 26.
- the core piece 19 bearing its metalloid layer 12 and its protective layer 13 are shown in position for casting; layers 12 and 13 are shown with their thicknesses much exaggerated for clarity of illustration.
- Core piece 19 bears one or more extensions 27 fitting into sockets 28 in the ejector die to locate it.
- a mold cavity is thus formed between the core piece 19 and the other parts of the assembly.
- the die assembly has also a shot sleeve 31 communicating with the mold cavity and a ram 32 for injecting the molten casting metal. In other forms of permanent mold casting the corresponding feed means will be provided.
- Knockout pins 33 are provided for ejecting a com- 6 pleted casting.
- the mold cavity is fed with molten basis metal and the casting is formed.
- the cooling of the lightweight casting metals such as alloys of aluminum, magnesium, or zinc, is so rapid that the mold may be opened almost immediately after the casting shot, the time varying somewhat in accordance with the thickness of the heaviest section of the casting.
- the core piece bearing the hard facing is of simple form and not entirely surrounded by the casting it is sometimes possible to eject the casting with-the core piece remaining in the mold, especially if a mold release was used on the core piece before depositing the metalloid coating. Otherwise, as in the example shown, the casting is ejected from the mold with the core piece retained in the casting, and allowed to cool. If the salt spray has been used on the core piece, the two parts may be immersed in water after cooling, where the salt will gradually dissolve and allow the core piece to be pulled free. However, this is a rather slow procedure, and it is desirable to make the core piece available as soon as possible for further casting.
- a faster way of securing the core piece is to reheat the casting rapidly by application of heat to the outside, or to the side away from the core piece. Since the lightweight casting alloys have high coefficients of thermal expansion, the basis metal of the casting will soon expand enough to free its grip on the core piece, only a few thousandths of an inch being required.
- core piece as used herein may be any wall or portion of a wall of a permanent mold which is initially given the metalloid coating and the protective metal layer before forming the casting.
- the method of producing a casting having a surface coated with hard facing material comprising:
- metalloid hard facing material selected from the group consisting of tungsten, cobalt, molybdenum, tungsten carbide, cobalt carbide, molybdenum carbide, silicon carbide, and titanium carbide on a portion of a mold constituting at least a part of a mold cavity, the metalloid coating having an exposed irregular surface,
- molten basis metal selected from the group consisting of alloys of aluminum, magnesium, and
- the metal of the protective layer having higher thermal conductivity than the metalloid material to distribute the heat of the basis metal rapidly around the metalloid material from the point of impact of the injected basis material against the protective layer, the metal of the protective layer having greater ductility than the metalloid material in order to absorb thermal stresses with minimum transmission thereof to the metalloid material, the protective layer being from three to twenty times the thickness of the metalloid material to provide a thermal gradient across its thickness to delay transmission of heat to the metalloid material, and the metal of the protective layer having a melting point lower than that of the metalloid but at least as high as that of the basis metal to preclude fusing of the protective layer, the combination of properties of the thermal layerpreventing thermal damage to the metalloid coating from thermal shock of the casting procedure,
- the metalloid material is tungsten carbide and the metal of the protective layer is a member of the aluminum family.
- metalloid material is tungsten carbide and the metal of the protective layer is a member of the copper family 4.
- metalloid material is molybdenum carbide and the'metal of the protective layer is a member of the aluminum family.
- metalloid material is molybdenum carbide and the metal of the protective layer is a member of the copper family.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Coating By Spraying Or Casting (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US373514A US3878880A (en) | 1973-06-25 | 1973-06-25 | Composite casting method |
| CA196,756A CA1021919A (fr) | 1973-06-25 | 1974-04-03 | Pieces de fonte a surface dure |
| US512412A US3920412A (en) | 1973-06-25 | 1974-10-07 | Hard-surfaced castings and method of producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US373514A US3878880A (en) | 1973-06-25 | 1973-06-25 | Composite casting method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3878880A true US3878880A (en) | 1975-04-22 |
Family
ID=23472710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US373514A Expired - Lifetime US3878880A (en) | 1973-06-25 | 1973-06-25 | Composite casting method |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US3878880A (fr) |
| CA (1) | CA1021919A (fr) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3921701A (en) * | 1973-08-20 | 1975-11-25 | Ford Motor Co | Method for improving bond between transplanted coating and die-casting |
| US4362480A (en) * | 1980-04-01 | 1982-12-07 | Mitsubishi Denki Kabushiki Kaisha | Rotary roller vane pump made of specific materials |
| US4492545A (en) * | 1981-04-06 | 1985-01-08 | Kayaba Kogyo Kabushiki Kaisha | Cam ring for vane pump |
| US4682939A (en) * | 1986-03-25 | 1987-07-28 | Commercial Shearing, Inc. | Gear pump or motor with tooth tips of dissimilar metal |
| US4724819A (en) * | 1987-01-23 | 1988-02-16 | Precision National Plating Services, Inc. | Cylinder liner reconditioning process and cylinder liner produced thereby |
| US4758139A (en) * | 1985-10-30 | 1988-07-19 | Mazda Motor Corporation | Side housing for a rotary piston engine and a method for manufacturing the same |
| US5080056A (en) * | 1991-05-17 | 1992-01-14 | General Motors Corporation | Thermally sprayed aluminum-bronze coatings on aluminum engine bores |
| US5149257A (en) * | 1989-03-29 | 1992-09-22 | Diesel Kiki Co., Ltd. | Compressor with a cylinder having improved seizure resistance and improved wear resistance, and method of manufacturing the cylinder |
| US5255433A (en) * | 1991-04-10 | 1993-10-26 | Alcan International Limited | Engine block cylinder liners made of aluminum alloy composites |
| US6005214A (en) * | 1996-06-26 | 1999-12-21 | Cramer; Margaret D. | Method of making wear resistant material lined housings |
| US6044820A (en) * | 1995-07-20 | 2000-04-04 | Spx Corporation | Method of providing a cylinder bore liner in an internal combustion engine |
| WO2001032336A1 (fr) * | 1999-11-05 | 2001-05-10 | Valtion Teknillinen Tutkimuskeskus | Procede de revetement sur piece moulee |
| US6345439B2 (en) * | 1998-11-10 | 2002-02-12 | Kioritz Corp. | Method for manufacturing a cylinder for internal combustion engine |
| WO2009012837A1 (fr) * | 2007-07-24 | 2009-01-29 | Brinkmann Pumpen K.H. Brinkmann Gmbh & Co. Kg | Procédé pour fabriquer un corps de machine comportant une chambre de fluide à surface durcie |
| US20100054930A1 (en) * | 2008-09-04 | 2010-03-04 | Morrison Jay A | Turbine vane with high temperature capable skins |
| US8714920B2 (en) | 2010-04-01 | 2014-05-06 | Siemens Energy, Inc. | Turbine airfoil to shround attachment |
| US8914976B2 (en) | 2010-04-01 | 2014-12-23 | Siemens Energy, Inc. | Turbine airfoil to shroud attachment method |
| US9987700B2 (en) | 2014-07-08 | 2018-06-05 | Siemens Energy, Inc. | Magnetically impelled arc butt welding method having magnet arrangement for welding components having complex curvatures |
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| US3083424A (en) * | 1959-05-07 | 1963-04-02 | Nat Lead Co | Method for producing coated die castings |
| US3244852A (en) * | 1964-01-06 | 1966-04-05 | Avco Corp | Process for making electric discharge machining electrode |
| US3401736A (en) * | 1963-08-27 | 1968-09-17 | Bridgestone Cycle Ind Co | Process for formation of non-abrasive refractory rubbing surface having high thermal conductivity by casting |
| US3433284A (en) * | 1966-01-14 | 1969-03-18 | Gen Motors Corp | Method of casting a pitted surface |
| US3689986A (en) * | 1967-04-01 | 1972-09-12 | Nippon Piston Ring Co Ltd | Method of casting composite cam shafts |
| US3797101A (en) * | 1972-11-27 | 1974-03-19 | Nl Industries Inc | Method of making die castings having multi-layer coated surfaces |
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|---|---|---|---|---|
| US2074007A (en) * | 1934-08-03 | 1937-03-16 | Union Carbide & Carbon Corp | Method of making articles of cobaltchromium-tungsten alloys |
| US3083424A (en) * | 1959-05-07 | 1963-04-02 | Nat Lead Co | Method for producing coated die castings |
| US3401736A (en) * | 1963-08-27 | 1968-09-17 | Bridgestone Cycle Ind Co | Process for formation of non-abrasive refractory rubbing surface having high thermal conductivity by casting |
| US3244852A (en) * | 1964-01-06 | 1966-04-05 | Avco Corp | Process for making electric discharge machining electrode |
| US3433284A (en) * | 1966-01-14 | 1969-03-18 | Gen Motors Corp | Method of casting a pitted surface |
| US3689986A (en) * | 1967-04-01 | 1972-09-12 | Nippon Piston Ring Co Ltd | Method of casting composite cam shafts |
| US3797101A (en) * | 1972-11-27 | 1974-03-19 | Nl Industries Inc | Method of making die castings having multi-layer coated surfaces |
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3921701A (en) * | 1973-08-20 | 1975-11-25 | Ford Motor Co | Method for improving bond between transplanted coating and die-casting |
| US4362480A (en) * | 1980-04-01 | 1982-12-07 | Mitsubishi Denki Kabushiki Kaisha | Rotary roller vane pump made of specific materials |
| US4492545A (en) * | 1981-04-06 | 1985-01-08 | Kayaba Kogyo Kabushiki Kaisha | Cam ring for vane pump |
| US4758139A (en) * | 1985-10-30 | 1988-07-19 | Mazda Motor Corporation | Side housing for a rotary piston engine and a method for manufacturing the same |
| US4682939A (en) * | 1986-03-25 | 1987-07-28 | Commercial Shearing, Inc. | Gear pump or motor with tooth tips of dissimilar metal |
| US4724819A (en) * | 1987-01-23 | 1988-02-16 | Precision National Plating Services, Inc. | Cylinder liner reconditioning process and cylinder liner produced thereby |
| US5149257A (en) * | 1989-03-29 | 1992-09-22 | Diesel Kiki Co., Ltd. | Compressor with a cylinder having improved seizure resistance and improved wear resistance, and method of manufacturing the cylinder |
| US5255433A (en) * | 1991-04-10 | 1993-10-26 | Alcan International Limited | Engine block cylinder liners made of aluminum alloy composites |
| US5080056A (en) * | 1991-05-17 | 1992-01-14 | General Motors Corporation | Thermally sprayed aluminum-bronze coatings on aluminum engine bores |
| US6044820A (en) * | 1995-07-20 | 2000-04-04 | Spx Corporation | Method of providing a cylinder bore liner in an internal combustion engine |
| US6005214A (en) * | 1996-06-26 | 1999-12-21 | Cramer; Margaret D. | Method of making wear resistant material lined housings |
| US6345439B2 (en) * | 1998-11-10 | 2002-02-12 | Kioritz Corp. | Method for manufacturing a cylinder for internal combustion engine |
| WO2001032336A1 (fr) * | 1999-11-05 | 2001-05-10 | Valtion Teknillinen Tutkimuskeskus | Procede de revetement sur piece moulee |
| US20100178518A1 (en) * | 2007-07-24 | 2010-07-15 | Brinkmann Pumpen K.H. Brinkmann Gmbh & Co. Kg | Method for Manufacturing a Machine Housing Having a Surface-Hardened Fluid Chamber |
| JP2009542454A (ja) * | 2007-07-24 | 2009-12-03 | ブリンクマン プンペン ケー.ハー.ブリンクマン ゲーエムベーハー ウント コー.ケーゲー | 表面が硬化された流体チャンバを有する機械ハウジングの製造方法 |
| WO2009012837A1 (fr) * | 2007-07-24 | 2009-01-29 | Brinkmann Pumpen K.H. Brinkmann Gmbh & Co. Kg | Procédé pour fabriquer un corps de machine comportant une chambre de fluide à surface durcie |
| US8003912B2 (en) | 2007-07-24 | 2011-08-23 | Brinkmann Pumpen K. H. Brinkmann Gmbh & Co. Kg | Method for manufacturing a machine housing having a surface-hardened fluid chamber |
| CN101541461B (zh) * | 2007-07-24 | 2012-07-18 | 布林克曼泵业K.H.布林克曼两合公司 | 具有表面硬化的流体腔的机器外壳的加工方法 |
| US20100054930A1 (en) * | 2008-09-04 | 2010-03-04 | Morrison Jay A | Turbine vane with high temperature capable skins |
| US8215900B2 (en) | 2008-09-04 | 2012-07-10 | Siemens Energy, Inc. | Turbine vane with high temperature capable skins |
| US8714920B2 (en) | 2010-04-01 | 2014-05-06 | Siemens Energy, Inc. | Turbine airfoil to shround attachment |
| US8914976B2 (en) | 2010-04-01 | 2014-12-23 | Siemens Energy, Inc. | Turbine airfoil to shroud attachment method |
| US9987700B2 (en) | 2014-07-08 | 2018-06-05 | Siemens Energy, Inc. | Magnetically impelled arc butt welding method having magnet arrangement for welding components having complex curvatures |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1021919A (fr) | 1977-12-06 |
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