US3935012A - Photosensitive sheet materials - Google Patents

Photosensitive sheet materials Download PDF

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Publication number
US3935012A
US3935012A US05/378,526 US37852673A US3935012A US 3935012 A US3935012 A US 3935012A US 37852673 A US37852673 A US 37852673A US 3935012 A US3935012 A US 3935012A
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US
United States
Prior art keywords
reactant
sheet
light
sheet material
acid
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US05/378,526
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English (en)
Inventor
Gilbert L. Eian
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
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Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Priority to US05/378,526 priority Critical patent/US3935012A/en
Priority to SE7408694A priority patent/SE7408694L/xx
Priority to IT5205474A priority patent/IT1016388B/it
Priority to AU71109/74A priority patent/AU485672B2/en
Priority to DE2433831A priority patent/DE2433831A1/de
Priority to BR569874A priority patent/BR7405698D0/pt
Priority to GB3085974A priority patent/GB1479472A/en
Priority to FR7424094A priority patent/FR2237219B1/fr
Priority to JP7970374A priority patent/JPS5039927A/ja
Priority to ZA00744453A priority patent/ZA744453B/xx
Application granted granted Critical
Publication of US3935012A publication Critical patent/US3935012A/en
Anticipated expiration legal-status Critical
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/675—Compositions containing polyhalogenated compounds as photosensitive substances
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
    • G03C5/56—Processes using photosensitive compositions covered by the groups G03C1/64 - G03C1/72 or agents therefor
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

Definitions

  • This invention relates to the recording of lightimages and to sheet materials useful therein. More specifically, the invention relates to sheet materials having a light-sensitive layer which on exposure to a light-image liberates a first reactant material, which first reactant then causes a visible change to occur in a companion sheet or layer by interaction with a second reactant material contained therein.
  • the invention relates to light-sensitive intermediate sheet materials containing a light-sensitive source of hydrogen halide together with an acid-cleavable adduct of a first reactant material and a reaction inhibitor therefore, and in which sheet is contained a controlled small amount of an acid acceptor.
  • the invention relates to the interaction of the light-sensitive intermediate sheet, after exposure to a light-image, with a receptor or print sheet or layer containing a second reactant, to produce on the latter sheet well-defined corresponding or inverse high contrast image and background areas.
  • the improvement in contrast obtained by the practice of the invention may frequently be illustrated in terms of the increase in gamma as derived from the characteristic, or D log E, curves of sensitometric data, as will be shown hereinafter in more detail.
  • the invention has made possible the preparation, by a process involving reflex exposure of the light-sensitive sheet in contact with a printed original, of color projection transparencies which project reverse or negative copy having white images and intensely colored backgrounds.
  • useful acid acceptor materials may be either organic or inorganic, certain classes of organic basic-nitrogen compounds are found to be particularly effective and are presently preferred. These materials are not oxidized by any agents produced in the coatings by photolysis.
  • Their conjugate acids have pKa values of at least 3.3.
  • the acid acceptors contain no hydrogen-heteroatom bonds with dissociation energies less than 85 kilocalories/mole unless the pKa value of the conjugate acid is at least 4.6.
  • Photolyzable organic halogen compounds are known to dissociate upon exposure to actinic radiation, to yield halogen free radicals. These free radicals are good hydrogen abstractors and in presence of hydrogen donors will form hydrogen halide. Suitable hydrogen donors are invariably present in the compositions and coatings of this invention, e.g., as the adduct, as the film-forming binder, as residual traces of organic solvent, or as the organic halogen compound itself; and exposure to light of coatings containing these materials in conjunction with the organic halogen compounds therefore results in formation of hydrogen halide.
  • Photolyzable organic halogen compounds which have been found useful in these constructions include hexabromoethane, tris(tribromomethyl)-s-triazine, and particularly the ester and urethane derivatives of tribromoethanol such as 2,2,2-tribromoethyl-benzoate, -2-furoate, -3-chlorobenzoate, -3,4-dichlorobenzoate, -2,4-dichlorobenzoate, -1-naphthoate, -2-naphthoate, -N-phenylcarbamate, which derivative materials provide improved thermal stability.
  • tribromoethanol such as 2,2,2-tribromoethyl-benzoate, -2-furoate, -3-chlorobenzoate, -3,4-dichlorobenzoate, -2,4-dichlorobenzoate, -1-naphthoate, -2-naphth
  • the print sheet or layer suitable for forming a black image on a white background contains as the second reactant a reducible metal salt, e.g., a silver salt, together with a hindered phenol reducing agent and a toner for the silver image.
  • a reducible metal salt e.g., a silver salt
  • a hindered phenol reducing agent e.g., a hindered phenol reducing agent
  • a toner for the silver image.
  • Reduction of a portion of the silver salt to the metal by reaction with a reducing agent obtained from light-struck areas of the intermediate sheet or layer then catalyzes the heat-induced reduction of the remaining silver salt by the less reactive hindered phenol to form the visible image.
  • Reducing agents such as 4-methoxy-1-naphthol and hydroquinone are useful as co-reactants for such silver salt coatings.
  • These same reducing agents are likewise found useful as co-reactants for reducible dyes, such for example as N,N-diethyl-2-chloro-2'-methylindoaniline or sodium 2,3',6-trichloro-indophenol, causing decolorization of the dye.
  • these organic reducing agents readily combine with suitable reaction inhibitors, notably the dihydropyrans, to form acid-cleavable adducts which no longer act as reducing agents for the silver salt or the reducible dye.
  • reducing agents which are stable solids at normal room temperatures, are readily volatilizable at moderately elevated temperatures of the order of 130° C., and accordingly are easily transferred in vapor form from the intermediate sheet to a superposed print sheet.
  • first reactants for the practice of the invention may be identified as reducing agents for silver.
  • Other classes of reactants which undergo or cause a visible change on reaction with a co-reactant and which form an acid-cleavable adduct are useful in other systems.
  • Reaction-inhibited acid-cleavable adducts of these reducing agents for silver may be formed with a wide variety of organic compounds containing vinyl ether linkages, including compounds of such classes as the alkyl vinyl ethers, the dihydropyrans, and polyvinyl compounds such as glycoldivinyl ethers and glyceroltrivinyl ethers.
  • organic compounds containing vinyl ether linkages including compounds of such classes as the alkyl vinyl ethers, the dihydropyrans, and polyvinyl compounds such as glycoldivinyl ethers and glyceroltrivinyl ethers.
  • adducts of the dihydropyrans are preferred in the practice of this invention.
  • the amount of adduct must be sufficient to provide a concentration of reducing agent which will, on reaction with the reactant of the print sheet or layer, form or catalyze a distinctly visible change.
  • the amount of photolyzable material must then be sufficient to produce an amount of hydrogen halide sufficient to cause cleavage of the adduct.
  • the amount of acid acceptor must be sufficient to remove all or substantially all of any hydrogen halide released in the unexposed or partially exposed areas but insufficient to remove the excess over such amounts which may be liberated at the fully exposed areas, thereby to cause a distinct difference in appearance between image and background areas of the developed print, generally observable as an improvement in contrast.
  • the amount of acid acceptor required will be well within the range of 0.01 to 2.0 moles per mole of organic halogen compound, and usually within the preferred narrower range of 0.3 to 1.2 moles.
  • Differences in optical contrast may be estimated visually but are more accurately determined by sensitometric measurements, an increase in contrast being represented as an increase in gamma.
  • the light-sensitive sheet containing the photosensitive organic halogen compound and the acid-cleavable reactant adduct, together with the acid acceptor when present is exposed through an optical step wedge and is then heated against a suitable receptor sheet to develop a corresponding sequence of images.
  • the optical density of the images is then measured and plotted against the relative exposure on a logarithmic scale, the slope of the curve representing the gamma or contrast value.
  • An indication of relative photographic speed may simultaneously be obtained if the exposure is controlled to provide minimum recognizable exposure at the same point on the wedge in each instance.
  • the accompanying drawing presents a series of D log E curves obtained in this manner as will be further described hereinafter.
  • a coating composition is prepared containing:binder (cellulose acetate butyrate) 2.8solvent (methylethyl ketone) 47.1(1,2-dichloroethane) 6.6adduct of tertiarybutyl hydroquinone 1.0tris-(tribromomethyl)-s-triazine 0.5spectral sensitizer 0.025
  • control coating A One-tenth of the composition is coated as control coating A.
  • Other tenth-parts are added different amounts of piperazine as acid acceptor, these mixtures providing coating B-E.
  • the coatings are applied to clear polyester film from a 3.0 mil (0.075 mm.) coating orifice and permitted to dry, all operations being conducted in the dark or under an appropriate safelight, to provide a series of photosensitive intermediates.
  • the adduct is prepared from 1:2 molar proportions of t-butyl hydroquinone and dihydropyran by combining under anhydrous conditions in the presence of catalytic amounts of strong acid.
  • the spectral sensitizer is the dibutyl ether of the leuco form of Vat Violet 7 (C.I. 59320).
  • a receptor sheet is prepared by coating clear polyester film from a 3.0 mil (0.075 mm.) orifice with a solution containing,
  • the dye is N,N-diethyl-2-chloro-2'-methylindoaniline.
  • the sheet is an intense blue color.
  • Segments of the intermediates are exposed to light from a high intensity tungsten filament source through a log ⁇ 2 step wedge for the time indicated in the following tabulation, and then placed against the receptor sheet and heated at 130° C. for 5 seconds. Exposure time is selected to assure that the full range of density variation is obtained in the print.
  • the ratio expressed is the number of moles of piperazine per mole of tris-(tribromomethyl)-s-triazine.
  • the coated films containing the various acid acceptor compounds in the amounts indicated in place of the piperazine as used in the photosensitive intermediate sheets of Example 1, are exposed through the step wedge and heated against the blue receptor sheet all as previously described.
  • the results in terms of resultant gamma values are shown in the following tabulation, which additionally sets forth the parts by weight of the acid acceptor and the pKa of its conjugate acid in each case.
  • the stock solution contains:
  • the adduct is prepared from 4-methoxy-1-naphthol and dihydropyran in equimolar proportions.
  • One-half of the solution is coated at 3 mils (0.075 mm.) on polyester film as a control.
  • the two films are exposed through a step wedge and heated against a blue receptor film prepared by coating polyester film with 3 mils (0.075 mm.) of a solution prepared by dissolving 0.025 part of the sodium salt of 2,3',6-trichloroindophenol in 10 parts of a 5% solution of hydroxypropyl cellulose in methanol, and drying.
  • a blue receptor film prepared by coating polyester film with 3 mils (0.075 mm.) of a solution prepared by dissolving 0.025 part of the sodium salt of 2,3',6-trichloroindophenol in 10 parts of a 5% solution of hydroxypropyl cellulose in methanol, and drying.
  • gamma values are obtained:
  • Copies of printed graphic originals are prepared by exposure of the intermediate sheets in contact with the original, i.e., by reflex exposure, followed by heating the exposed intermediate against the receptor sheet.
  • the copy made with the sheet containing the acid acceptor is visibly better in contrast than is the copy made with the control sheet.
  • an intermediate sheet containing the adduct of two moles of dihydropyran and one mole of hydroquinone as the source of reducing agent, cellulose acetate butyrate as the binder, and hexabromoethane as the photosensitive halogen compound is compared with an otherwise identical sheet containing an acid acceptor of the same kind and in the same amount as in Example 3.
  • the exposed sheets are heated in contact with a print film containing four parts of the blue-green (cyan) dye N,N-diethyl-2,6-dichloro-2'-methylindoaniline in 50 parts of ethyl cellulose. Contrast is improved by incorporation of the acid acceptor, the gamma value being increased from 1.5 for the control to 3.5 for the improved sheet.
  • An intermediate sheet containing 24.4 parts binder, 4.75 parts anhydrous potassium carbonate, 10 parts dihydropyran adduct of t-butylhydroquinone, 6 parts of tris-(tribromomethyl)-s-triazine, and 0.3 parts perylene is compared with an otherwise identical sheet from which the potassium carbonate is omitted, by exposure through a step wedge and heating against a blue film as described under Example 2. Contrast of prints obtained with the sheet containing the potassium carbonate is markedly greater than of those obtained with the control sheet.
  • a stock solution for the intermediate sheet coating is prepared as in Example 2 except that the methoxynaphthol adduct of Example 3 replaces the adduct of t-butylhydroquinone.
  • Portions with and without acid acceptors are coated, the dried sheets are exposed through the step wedge at exposures selected to indicate sensitivity, and the exposed samples are then heated against a transparent receptor sheet containing a silver salt, a hindered phenol reducing agent, and a toning agent and available from Minnesota Mining and Manufacturing Company as Type 659 Transparency. Results are as here tabulated:
  • a control example containing no acid acceptor is found to cause complete darkening of the receptor sheet.
  • Each of the intermediate sheets of the foregoing examples contains a spectral sensitizer for the photosensitive organic halogen compound, and is therefore capable of activation by visible light as obtained from an incandescent tungsten filament. In the absence of the sensitizer it is found necessary to employ a different light source.
  • a control intermediate sheet is prepared using a coating solution containing:
  • a second intermediate sheet is similarly prepared but with the addition to the solution of 0.006 part of 1,8-bis-(dimethylamino)-naphthalene.
  • VYNS vinyl chloride-vinyl acetate
  • ADrews "54S” diazo acid-stabilized diazonium salt
  • a difunctional dihydropyran is prepared by reacting together equimolar quantities of 3,4-dihydro-2H-pyran-2-methanol and tolylene-2,4-diisocyanate in benzene using a small amount of triethylenediamine as catalyst.
  • the bisdihydropyran product is converted to a polymeric tetrahydropyranyl ether (adduct) by reaction with tert-butyl hydroquinone in 1:1 molar ratio in benzene, using p-toluenesulfonic acid as catalyst.
  • Light-sensitive intermediate sheets are prepared with the polymeric ether adduct and both with and without an acid acceptor, the dried coatings having the following composition:
  • the sheets are exposed through a step wedge and corresponding images are developed by heating the exposed strips against a blue receptor sheet containing the reducible dye N,N-diethyl-2-chloro-2'-methylindoaniline and formulated as described in Example 1.
  • the addition of the small amount of 1,8-bis(dimethylamino)naphthalene is found to impart improved contrast. In the absence of this compound, the blue areas of the developed receptor sheet show lowered color intensity.
  • a transparent intermediate is prepared by application to a transparent polyester film of a coating containing:
  • the intermediate is placed against a graphic original printed in black ink on white paper, and the original is exposed through the intermediate.
  • the latter is then heated against a receptor sheet coated with a composition containing:
  • the areas corresponding to the background areas of the original are rendered colorless, while the areas corresponding to the printed characters of the original retain their clear blue color.
  • the copy serves as an excellent color projection transparency, the projected image appearing in intense blue characters against a white background.
  • polyester film is applied to polyester film as a thin uniform coating and dried.
  • the dry coating weighs 0.21 gram/sq. ft. (2.1 g./sq.m.)
  • the resulting intermediate sheet is placed in reflex position against a printed original having black indicia on a white background and the printed surface is exposed through the intermediate for 18 seconds to light from a bank of incandescent filament lamps.
  • the sheet is then placed in face-to-face contact with a transparent receptor sheet having a coating containing a silver soap, a hindered phenol reducing agent, and a toning agent ("Type 659" Transparency) and the composite is heated by repeated passes through a hot roll heating device sufficient to develop a dense black appearance at areas corresponding to the unprinted areas of the original. Areas corresponding to the black printed areas of the original remain clear and transparent. Intermediate areas are likewise faithfully inversely reproduced. As many as 90-100 lines per inch are faithfully copied.
  • the print serves as a highly effective projection transparency.
  • Sheet materials having separate layers on a single backing for example with a silver salt coating beneath a light-sensitive coating, as well as transfer of reactant by solvent transfer or in other ways, are also contemplated as being within the ambit of the invention.
  • Combinations of reactants may be used, and other non-inventive variations as will become apparent in the light of the foregoing description are likewise contemplated.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)
  • Medicinal Preparation (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
US05/378,526 1973-07-12 1973-07-12 Photosensitive sheet materials Expired - Lifetime US3935012A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
US05/378,526 US3935012A (en) 1973-07-12 1973-07-12 Photosensitive sheet materials
SE7408694A SE7408694L (sv) 1973-07-12 1974-07-02 Ljuskensligt arkmaterial.
AU71109/74A AU485672B2 (en) 1973-07-12 1974-07-11 Photosensitive sheet materials
DE2433831A DE2433831A1 (de) 1973-07-12 1974-07-11 Lichtempfindliche blattmaterialien
IT5205474A IT1016388B (it) 1973-07-12 1974-07-11 Materiale in fogli fotosensibile
BR569874A BR7405698D0 (pt) 1973-07-12 1974-07-11 Aperfeicoamento em material em folha sensivel a luz
GB3085974A GB1479472A (en) 1973-07-12 1974-07-11 Photosensitive sheet materials
FR7424094A FR2237219B1 (pt) 1973-07-12 1974-07-11
JP7970374A JPS5039927A (pt) 1973-07-12 1974-07-11
ZA00744453A ZA744453B (en) 1973-07-12 1974-07-11 Photosensitive sheet materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/378,526 US3935012A (en) 1973-07-12 1973-07-12 Photosensitive sheet materials

Publications (1)

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US3935012A true US3935012A (en) 1976-01-27

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US05/378,526 Expired - Lifetime US3935012A (en) 1973-07-12 1973-07-12 Photosensitive sheet materials

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US (1) US3935012A (pt)
JP (1) JPS5039927A (pt)
BR (1) BR7405698D0 (pt)
DE (1) DE2433831A1 (pt)
FR (1) FR2237219B1 (pt)
GB (1) GB1479472A (pt)
IT (1) IT1016388B (pt)
SE (1) SE7408694L (pt)
ZA (1) ZA744453B (pt)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4082879A (en) * 1975-08-04 1978-04-04 Minnesota Mining And Manufacturing Company Stabilized transparent receptor sheet
WO1980002751A1 (en) * 1979-06-05 1980-12-11 Minnesota Mining & Mfg Photothermographic stabilizers
US4260677A (en) * 1976-03-12 1981-04-07 Minnesota Mining And Manufacturing Company Thermographic and photothermographic materials having silver salt complexes therein
US4347310A (en) * 1977-10-14 1982-08-31 Asahi Kasei Kogyo Kabushiki Kaisha Heat developable silver image forming materials

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2320578A1 (fr) * 1975-08-04 1977-03-04 Minnesota Mining & Mfg Feuilles receptrices transparentes stabilisees

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3146348A (en) * 1961-09-25 1964-08-25 Minnesota Mining & Mfg Heat-sensitive copy-sheet
US3476562A (en) * 1963-05-06 1969-11-04 Bell & Howell Co Light sensitive composition comprising an organic amine and an organic halogen compound in a hydrophilic binder
US3502476A (en) * 1965-10-20 1970-03-24 Konishiroku Photo Ind Light-sensitive photographic materials
US3533792A (en) * 1967-12-26 1970-10-13 Horizons Research Inc Dry working photographic process utilizing a non-silver photosensitive composition
US3544321A (en) * 1966-07-21 1970-12-01 Bell & Howell Co Stabilization of organic photosensitive material
US3617288A (en) * 1969-09-12 1971-11-02 Minnesota Mining & Mfg Propenone sensitizers for the photolysis of organic halogen compounds
US3640718A (en) * 1968-04-10 1972-02-08 Minnesota Mining & Mfg Spectral sentization of photosensitive compositions

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3146348A (en) * 1961-09-25 1964-08-25 Minnesota Mining & Mfg Heat-sensitive copy-sheet
US3476562A (en) * 1963-05-06 1969-11-04 Bell & Howell Co Light sensitive composition comprising an organic amine and an organic halogen compound in a hydrophilic binder
US3502476A (en) * 1965-10-20 1970-03-24 Konishiroku Photo Ind Light-sensitive photographic materials
US3544321A (en) * 1966-07-21 1970-12-01 Bell & Howell Co Stabilization of organic photosensitive material
US3533792A (en) * 1967-12-26 1970-10-13 Horizons Research Inc Dry working photographic process utilizing a non-silver photosensitive composition
US3640718A (en) * 1968-04-10 1972-02-08 Minnesota Mining & Mfg Spectral sentization of photosensitive compositions
US3617288A (en) * 1969-09-12 1971-11-02 Minnesota Mining & Mfg Propenone sensitizers for the photolysis of organic halogen compounds

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4082879A (en) * 1975-08-04 1978-04-04 Minnesota Mining And Manufacturing Company Stabilized transparent receptor sheet
US4260677A (en) * 1976-03-12 1981-04-07 Minnesota Mining And Manufacturing Company Thermographic and photothermographic materials having silver salt complexes therein
US4347310A (en) * 1977-10-14 1982-08-31 Asahi Kasei Kogyo Kabushiki Kaisha Heat developable silver image forming materials
WO1980002751A1 (en) * 1979-06-05 1980-12-11 Minnesota Mining & Mfg Photothermographic stabilizers
US4288536A (en) * 1979-06-05 1981-09-08 Minnesota Mining And Manufacturing Company Photothermographic stabilizers

Also Published As

Publication number Publication date
FR2237219B1 (pt) 1978-02-03
SE7408694L (sv) 1975-01-13
JPS5039927A (pt) 1975-04-12
GB1479472A (en) 1977-07-13
AU7110974A (en) 1976-01-15
BR7405698D0 (pt) 1975-05-20
FR2237219A1 (pt) 1975-02-07
IT1016388B (it) 1977-05-30
DE2433831A1 (de) 1975-01-30
ZA744453B (en) 1975-07-30

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