US4552741A - Method and apparatus for manufacturing synthesis gas - Google Patents

Method and apparatus for manufacturing synthesis gas Download PDF

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US4552741A
US4552741A US06/656,867 US65686784A US4552741A US 4552741 A US4552741 A US 4552741A US 65686784 A US65686784 A US 65686784A US 4552741 A US4552741 A US 4552741A
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synthesis gas
heat
reactor
solar energy
steam
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Eckhard Melchior
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MAN AG
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MAN Maschinenfabrik Augsburg Nuernberg AG
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Assigned to M.A.N. MASCHINENFABRIK AUGSBURGNURNBERG AKTIENGESELLSCHAFT, A CORP. OF WEST GERMANY reassignment M.A.N. MASCHINENFABRIK AUGSBURGNURNBERG AKTIENGESELLSCHAFT, A CORP. OF WEST GERMANY ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: MELCHIOR, ECKHARD
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S20/00—Solar heat collectors specially adapted for particular uses or environments
    • F24S20/20—Solar heat collectors for receiving concentrated solar energy, e.g. receivers for solar power plants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/068—Ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816—Heating by flames
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0827—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0866—Methods of heating the process for making hydrogen or synthesis gas by combination of different heating methods
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/40—Solar thermal energy, e.g. solar towers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

Definitions

  • the present invention relates to a method and to an apparatus for the manufacturing of synthesis gas, in particular hydrogen, through the catalytic conversion of hydrocarbons under the influence of heat.
  • Synthesis gases are produced in large quantities as mixtures or mixed products for the manufacture of such products as hydrocarbons, alcohols and ammonia. During the course of the chemical processes in the manufacture of such synthesis gases, there are encountered considerable energy losses which are covered or compensated for by the energy of fossil fuels primarily those based on petroleum.
  • the heating through solar energy can be carried out either directly by constructing the reactor or the steam reformer as a solar absorber, or indirectly through the utilization of intermediate heat carriers.
  • reactors which are connected in series, of which the reactor arranged upstream in the flow direction is heated by solar energy, and the reactor arranged downstream in the flow direction is heated through the combustion of the residual product from the synthesis gas production process.
  • the method is used for the production of ammonia via synthesis gas.
  • ammonia which is used in the manufacture of fertilizers is frequently the first product of a beginning or infant industrialization, which is used at or near the manufacturing location or neighborhood and induced with the utilization of the inventive method at the location of consumption; thereby eliminating the need for expensive infrastructures such as, for example, distribution networks or pipeline systems for remote energy distribution systems.
  • the flue gas heat from the combustion of residual products which is available at below the process temperature, can be completely utilized for the generation of the necessary process steam and for the preheating of air and feed stock for the ammonia process.
  • This utilization of the waste or exhaust leads to systems which spontaneously and self-sufficiently provide energy, and thereby additionally to a high overall efficiency in the utilization of solar energy.
  • the present invention also provides for a novel apparatus for implementing the inventive method, in which the apparatus includes at least one reactor with at least one catalyzer which is heatable with solar energy.
  • the raw material or feed stock is conveyed to a catalyzer 13 which is arranged in a reformer 12, through a fuel feed line, is particular a natural gas feed line 10, and through a feed pump 11.
  • the catalyzer 13 is constructed as a solar absorber which is exposed to solar radiation 14.
  • the above-mentioned first reformer with a catalyzer 13 has a secondary reformer with a catalyzer 15 connected thereto downstream thereof.
  • the natural gas 10 which is converted by the catalyzers 13 and 15 is conducted through a CO converter 17 to a pressure-changing adsorption washer 18, in which the hydrogen 19 is separated out and conducted off through a discharge conduit 20.
  • the residual product or residual gas 21 is conveyed to a storage 22, from which the combustible product is combusted, with the addition of air 23 in a reformer furnace 24 as needed so as to heat the secondary reactor with a catalyzer 15 whenever the available solar energy 14 is inadequate for the maintenance of a continuous operation.
  • the fuel in feed conduit 25 for the reformer furnace 24 is connected with the fuel supply 10 through a conduit 26 and a valve 27, such that, during a protracted lack of solar radiation and after consumption of the stored residual product, the reformer furnace 24 can be maintained in operation through the use of primary energy.
  • the final temperature of the primary reformer 12 is so selected that, similar to a Braun purifier process or at a subsequent pressure-changing adsorption process a major portion of the methane will not be converted. This renders possible more milder conditions for the operation of the catalyzer tubes 15 in the reformer furnace 24 and, subsequent to separation of the hydrogen 19 from the remaining reaction products 21, enables the residual gases 21 to be employed for sustaining the process with fossil fuels during periods when solar operation is not possible; for example, during the night, under cloudy skies, and thereby the maintenance of a continuous operation.
  • the solar energy, as well as the thermal energy of the flue gases 28 from the reformer furnace 24, are used for the generating of steam 29, as illustrated by the phantom lines.
  • the steam 29 is admixed with the fuel through an infeed conduit 31 for the reforming process.
  • the system as described herein in the utilization of hydrogen 19 for the production of ammonia is connected to an ammonia synthesis system which is generally identified by the reference numeral 32, herein, the available flue gas heat 28 which is below process temperature, besides being utilized for the generating of steam 29, is also used for preheating 33 air and feed stock material for the ammonia process.
  • the entire system thus represents a self-sustained energy system in which there is not only conserved primary energy, but there are also eliminated length pipelines which, under circumstances are needed for transport.
  • the heating thereof by solar energy can also be effected indirectly through the use of intermediate heat carriers, for example, such as a fluid.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
US06/656,867 1983-10-12 1984-10-02 Method and apparatus for manufacturing synthesis gas Expired - Fee Related US4552741A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3337078 1983-10-12
DE19833337078 DE3337078A1 (de) 1983-10-12 1983-10-12 Verfahren und vorrichtung zum herstellen von synthesegas

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US4552741A true US4552741A (en) 1985-11-12

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US (1) US4552741A (fr)
EP (1) EP0137467A3 (fr)
JP (1) JPS6096505A (fr)
DE (1) DE3337078A1 (fr)
ES (1) ES8505313A1 (fr)

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5006131A (en) * 1985-06-27 1991-04-09 Stone & Webster Engineering Corporation Apparatus for production of synthesis gas using convective reforming
US5039510A (en) * 1983-03-25 1991-08-13 Imperial Chemical Industries Plc Steam reforming
US5110559A (en) * 1989-06-29 1992-05-05 Hitachi, Ltd. Hydrogen generating apparatus
US5181937A (en) * 1985-06-27 1993-01-26 Stone & Webster Engineering Corp. Apparatus for production of synthesis gas using convective reforming
US5226477A (en) * 1990-08-03 1993-07-13 China Petro-Chemical Corporation System for recovery and utilization of exhaust heat from a reformer
WO2003049853A1 (fr) * 2000-05-08 2003-06-19 Midwest Research Institute Procede de reaction a flux aerosol heliothermique
WO2003076334A1 (fr) * 2002-03-07 2003-09-18 The Regents Of The University Of Colorado Procede de reaction heliothermique a paroi fluide
US20030182861A1 (en) * 2000-05-08 2003-10-02 Weimer Alan W. Solar-thermal fluid-wall reaction processing
US20050192362A1 (en) * 2003-10-01 2005-09-01 Domingo Rodriguez Process for converting heavy crude oils and petroleum coke to syngas using external source of radiation
US20060013765A1 (en) * 2004-07-14 2006-01-19 The Boeing Company Method for producing hydrogen gas by steam methane reforming using solar energy
US20060048808A1 (en) * 2004-09-09 2006-03-09 Ruckman Jack H Solar, catalytic, hydrogen generation apparatus and method
US20060188433A1 (en) * 2000-05-08 2006-08-24 Weimer Alan W Metal-oxide based process for the generation of hydrogen from water splitting utilizing a high temperature solar aerosol flow reactor
US20070098602A1 (en) * 2003-10-01 2007-05-03 Philipp Haueter Apparatus for gasification of carbonaceous solid materials
EP1808927A1 (fr) * 2006-01-17 2007-07-18 Samsung SDI Co., Ltd. Système de reformage de carburant et système de pile à combustible comprenant celui-ci
CN100376468C (zh) * 2005-03-07 2008-03-26 中国科学院工程热物理研究所 一种将太阳能转换为燃料化学能的方法及装置
US20080173533A1 (en) * 2007-01-22 2008-07-24 John Carlton Mankins Process and method of making space-solar fuels and other chemicals
US20100242354A1 (en) * 2009-06-09 2010-09-30 Sundrop Fuels, Inc. Systems and methods for reactor chemistry and control
US20100305221A1 (en) * 2007-05-11 2010-12-02 Basf Se Method for producing synthesis gas
US8814961B2 (en) 2009-06-09 2014-08-26 Sundrop Fuels, Inc. Various methods and apparatuses for a radiant-heat driven chemical reactor
WO2016169865A1 (fr) * 2015-04-22 2016-10-27 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procede de conversion thermochimique d'une charge carbonee mis en œuvre en continu dans un reacteur utilisant au moins en partie l'energie du rayonnement solaire
US9663363B2 (en) 2009-06-09 2017-05-30 Sundrop Fuels, Inc. Various methods and apparatuses for multi-stage synthesis gas generation
DE102016204326A1 (de) * 2016-03-16 2017-09-21 Deutsches Zentrum für Luft- und Raumfahrt e.V. Solare Schwefelwasserstoff- und Kohlenstoffdioxid-Reformierung zur Erzeugung von Synthesegas und Kohlenstoffdisulfid
CN108190834A (zh) * 2018-01-31 2018-06-22 昆明理工大学 一种节能环保型太阳能甲醇重整制氢反应器
US11325090B1 (en) * 2019-12-09 2022-05-10 Precision Combustion, Inc. Catalytic solar reactor
US12233392B2 (en) 2019-12-09 2025-02-25 Precision Combustion Inc. Reactor for endothermic reaction
DE102016204326B4 (de) 2016-03-16 2025-09-25 Deutsches Zentrum für Luft- und Raumfahrt e.V. Solare Schwefelwasserstoff- und Kohlenstoffdioxid-Reformierung zur Erzeugung von Synthesegas und Kohlenstoffdisulfid

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3802555A1 (de) * 1988-01-28 1989-08-03 Linde Ag Verfahren zum betreiben einer synthesegasanlage und anlage zur durchfuehrung des verfahrens
DE3933285A1 (de) * 1989-10-05 1991-04-18 Steinmueller Gmbh L & C Verfahren zur kontinuierlichen erzeugung von synthesegas durch solare reformierung von methan und vorrichtung zur durchfuehrung des verfahrens
DE19955676B4 (de) * 1999-11-19 2004-06-03 Uhde Gmbh Verfahren zur Herstellung von Synthesegas in Verbindung mit einer Druckwechsel-Adsorptionsanlage
CN104671205A (zh) * 2013-11-28 2015-06-03 七台河宝泰隆甲醇有限公司 双转化炉的甲醇合成系统

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2592591A (en) * 1949-08-29 1952-04-15 William W Odell Manufacture of combustible gas
US3785953A (en) * 1971-11-09 1974-01-15 Antar Petroles Atlantique Process for carrying out endothermic catalytic reactions
US4162290A (en) * 1976-11-19 1979-07-24 Pullman Incorporated Parallel steam reformers to provide low energy process
US4233268A (en) * 1971-11-16 1980-11-11 Institut Francais Du Petrole Apparatus for hydrocarbon conversion
US4391793A (en) * 1979-02-12 1983-07-05 Interatom, Internationale Atomreaktorbau Gmbh Plant for thermochemical water dissociation by solar energy

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2438949A1 (de) * 1974-08-14 1976-02-26 Juergen Dipl Ing Rheinlaender Methanumsetzung mit hilfe konzentrierter sonnenenergie
FR2366217A1 (fr) * 1975-08-27 1978-04-28 Comp Generale Electricite Dispositif generateur d'hydrogene
FR2330640A1 (fr) * 1975-11-04 1977-06-03 Comp Generale Electricite Procede de preparation d'hydrogene a partir de l'eau, utilisant l'energie solaire
US4019868A (en) * 1976-03-24 1977-04-26 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Solar hydrogen generator
CH617503A5 (fr) * 1976-08-13 1980-05-30 Battelle Memorial Institute
DE3047257A1 (de) * 1980-12-16 1982-07-08 Didier Engineering Gmbh, 4300 Essen Verfahren zur erzeugung von ammoniak-synthesegas

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2592591A (en) * 1949-08-29 1952-04-15 William W Odell Manufacture of combustible gas
US3785953A (en) * 1971-11-09 1974-01-15 Antar Petroles Atlantique Process for carrying out endothermic catalytic reactions
US4233268A (en) * 1971-11-16 1980-11-11 Institut Francais Du Petrole Apparatus for hydrocarbon conversion
US4162290A (en) * 1976-11-19 1979-07-24 Pullman Incorporated Parallel steam reformers to provide low energy process
US4391793A (en) * 1979-02-12 1983-07-05 Interatom, Internationale Atomreaktorbau Gmbh Plant for thermochemical water dissociation by solar energy

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
Kirk Othmer, Encyclopedia of Chemical Technology, Third Edition, vol. 12 (1980), John Wiley & Sons, p. 944. *
Kirk-Othmer, Encyclopedia of Chemical Technology, Third Edition, vol. 12 (1980), John Wiley & Sons, p. 944.
Strelzoff, Technology and Manufacture of Ammonia (1981), John Wiley & Sons, pp. 104 110. *
Strelzoff, Technology and Manufacture of Ammonia (1981), John Wiley & Sons, pp. 104-110.

Cited By (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5039510A (en) * 1983-03-25 1991-08-13 Imperial Chemical Industries Plc Steam reforming
US5006131A (en) * 1985-06-27 1991-04-09 Stone & Webster Engineering Corporation Apparatus for production of synthesis gas using convective reforming
US5181937A (en) * 1985-06-27 1993-01-26 Stone & Webster Engineering Corp. Apparatus for production of synthesis gas using convective reforming
US5110559A (en) * 1989-06-29 1992-05-05 Hitachi, Ltd. Hydrogen generating apparatus
US5226477A (en) * 1990-08-03 1993-07-13 China Petro-Chemical Corporation System for recovery and utilization of exhaust heat from a reformer
US20060140848A1 (en) * 2000-05-08 2006-06-29 Weimer Alan W Solar-thermal fluid-wall reaction processing
US20060188433A1 (en) * 2000-05-08 2006-08-24 Weimer Alan W Metal-oxide based process for the generation of hydrogen from water splitting utilizing a high temperature solar aerosol flow reactor
US20030182861A1 (en) * 2000-05-08 2003-10-02 Weimer Alan W. Solar-thermal fluid-wall reaction processing
US20030208959A1 (en) * 2000-05-08 2003-11-13 Weimer Alan W Solar thermal aerosol flow reaction process
US6872378B2 (en) 2000-05-08 2005-03-29 Midwest Research Institute Solar thermal aerosol flow reaction process
WO2003049853A1 (fr) * 2000-05-08 2003-06-19 Midwest Research Institute Procede de reaction a flux aerosol heliothermique
US7033570B2 (en) 2000-05-08 2006-04-25 Regents Of The University Of Colorado Solar-thermal fluid-wall reaction processing
WO2003076334A1 (fr) * 2002-03-07 2003-09-18 The Regents Of The University Of Colorado Procede de reaction heliothermique a paroi fluide
US20070098602A1 (en) * 2003-10-01 2007-05-03 Philipp Haueter Apparatus for gasification of carbonaceous solid materials
US20050192362A1 (en) * 2003-10-01 2005-09-01 Domingo Rodriguez Process for converting heavy crude oils and petroleum coke to syngas using external source of radiation
US7176246B2 (en) 2003-10-01 2007-02-13 Intevep, S.A. Process for converting heavy crude oils and petroleum coke to syngas using external source of radiation
US7449158B2 (en) 2003-10-01 2008-11-11 Intevep, S.A. Apparatus and gasification of carbonaceous solid materials
US20060013765A1 (en) * 2004-07-14 2006-01-19 The Boeing Company Method for producing hydrogen gas by steam methane reforming using solar energy
US7537750B2 (en) * 2004-07-14 2009-05-26 United Technologies Corporation Method for producing hydrogen gas by steam methane reforming using solar energy
US20060048808A1 (en) * 2004-09-09 2006-03-09 Ruckman Jack H Solar, catalytic, hydrogen generation apparatus and method
CN100376468C (zh) * 2005-03-07 2008-03-26 中国科学院工程热物理研究所 一种将太阳能转换为燃料化学能的方法及装置
US20070166580A1 (en) * 2006-01-17 2007-07-19 Ju Yong Kim Fuel reforming system having movable heat source and fuel cell system comprising the same
EP1808927A1 (fr) * 2006-01-17 2007-07-18 Samsung SDI Co., Ltd. Système de reformage de carburant et système de pile à combustible comprenant celui-ci
US7824813B2 (en) 2006-01-17 2010-11-02 Samsung Sdi Co., Ltd. Fuel reforming system having movable heat source and fuel cell system comprising the same
US20080173533A1 (en) * 2007-01-22 2008-07-24 John Carlton Mankins Process and method of making space-solar fuels and other chemicals
US8691181B2 (en) * 2007-05-11 2014-04-08 Basf Se Method for producing synthesis gas
US20100305221A1 (en) * 2007-05-11 2010-12-02 Basf Se Method for producing synthesis gas
US20100249468A1 (en) * 2009-06-09 2010-09-30 Sundrop Fuels, Inc. Systems and methods for an integrated solar driven chemical plant
AU2010258840B2 (en) * 2009-06-09 2015-10-01 Sundrop Fuels, Inc. Systems and methods for solar-thermal gasification of biomass
US20100242353A1 (en) * 2009-06-09 2010-09-30 Sundrop Fuels, Inc. Systems and methods for biomass grinding and feeding
US20100243961A1 (en) * 2009-06-09 2010-09-30 Sundrop Fuels, Inc. Systems and methods for quenching, gas clean up, and ash removal
US20100247387A1 (en) * 2009-06-09 2010-09-30 Sundrop Fuels, Inc. Systems and methods for biomass gasifier reactor and receiver configuration
WO2010144537A1 (fr) * 2009-06-09 2010-12-16 Sundrop Fuels, Inc. Systèmes et procédés de gazéification thermique solaire de biomasse
WO2010144547A1 (fr) * 2009-06-09 2010-12-16 Sundrop Fuels, Inc. Systèmes et méthodes pour des opérations cycliques dans un procédé de synthèse de carburant
US8378151B2 (en) 2009-06-09 2013-02-19 Sundrop Fuels, Inc. Systems and methods for an integrated solar driven chemical plant
US20100242354A1 (en) * 2009-06-09 2010-09-30 Sundrop Fuels, Inc. Systems and methods for reactor chemistry and control
US8709112B2 (en) 2009-06-09 2014-04-29 Sundrop Fuels, Inc. Systems and methods for quenching, gas clean up, and ash removal
US8771387B2 (en) 2009-06-09 2014-07-08 Sundrop Fuels, Inc. Systems and methods for solar-thermal gasification of biomass
US8814961B2 (en) 2009-06-09 2014-08-26 Sundrop Fuels, Inc. Various methods and apparatuses for a radiant-heat driven chemical reactor
US8821599B2 (en) 2009-06-09 2014-09-02 Sundrop Fuels, Inc. Systems and methods for biomass gasifier reactor and receiver configuration
US20100249251A1 (en) * 2009-06-09 2010-09-30 Sundrop Fuels, Inc. Systems and methods for cyclic operations in a fuel synthesis process
US9150803B2 (en) 2009-06-09 2015-10-06 Sundrop Fuels, Inc. Systems and methods for biomass grinding and feeding
US9150802B2 (en) 2009-06-09 2015-10-06 Sundrop Fuels, Inc. Systems and methods for an indirect radiation driven gasifier reactor and receiver configuration
US9663363B2 (en) 2009-06-09 2017-05-30 Sundrop Fuels, Inc. Various methods and apparatuses for multi-stage synthesis gas generation
FR3035394A1 (fr) * 2015-04-22 2016-10-28 Commissariat Energie Atomique Procede de conversion thermochimique d'une charge carbonee mis en œuvre en continu dans un reacteur utilisant au moins en partie l'energie du rayonnement solaire.
WO2016169865A1 (fr) * 2015-04-22 2016-10-27 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procede de conversion thermochimique d'une charge carbonee mis en œuvre en continu dans un reacteur utilisant au moins en partie l'energie du rayonnement solaire
DE102016204326A1 (de) * 2016-03-16 2017-09-21 Deutsches Zentrum für Luft- und Raumfahrt e.V. Solare Schwefelwasserstoff- und Kohlenstoffdioxid-Reformierung zur Erzeugung von Synthesegas und Kohlenstoffdisulfid
DE102016204326B4 (de) 2016-03-16 2025-09-25 Deutsches Zentrum für Luft- und Raumfahrt e.V. Solare Schwefelwasserstoff- und Kohlenstoffdioxid-Reformierung zur Erzeugung von Synthesegas und Kohlenstoffdisulfid
CN108190834A (zh) * 2018-01-31 2018-06-22 昆明理工大学 一种节能环保型太阳能甲醇重整制氢反应器
CN108190834B (zh) * 2018-01-31 2021-04-09 昆明理工大学 一种节能环保型太阳能甲醇重整制氢反应器
US11325090B1 (en) * 2019-12-09 2022-05-10 Precision Combustion, Inc. Catalytic solar reactor
US12233392B2 (en) 2019-12-09 2025-02-25 Precision Combustion Inc. Reactor for endothermic reaction

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EP0137467A2 (fr) 1985-04-17
EP0137467A3 (fr) 1987-04-08

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