Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
  • C08K5/37—Thiols
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B60—VEHICLES IN GENERAL
  • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
  • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
  • B60C1/0016—Compositions of the tread
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K9/00—Use of pretreated ingredients
  • C08K9/04—Ingredients treated with organic substances

Definitions

• This invention relates to a conjugated diene-based rubber composition reinforced with silica-based reinforcement together with a composite of carbon black supported non-silane coupling agent as 1-thioglycerol(3-mercapto-1,2-propanediol) and exclusive of 2,2′-benzothiazyl disulfide.
• the invention includes an article of manufacture, including a tire, having at least one component comprised of such rubber composition.
• carbon black and/or synthetic amorphous silica-based materials are conventionally used as particulate reinforcing fillers for the elastomer(s) of the rubber composition(s).
• a coupling agent is used together with the silica in order to couple, or otherwise enhance, its elastomer reinforcement effect for the elastomer(s) and such use of a coupling agent is well known to those having skill in such art.
• such coupling agents may be, for example, silane-based compounds which have one moiety (a silane-based moiety such as, for example, an alkoxysilane moiety) which is reactive with hydroxyl groups (e.g. silanol groups) on the surface of a synthetic amorphous silica and having another moiety (e.g. a polysulfide bridge) which becomes interactive with a conjugated diene-based elastomer.
• a silane-based moiety such as, for example, an alkoxysilane moiety
• hydroxyl groups e.g. silanol groups
• a synthetic amorphous silica e.g. a polysulfide bridge
• bis-(3-trialkoxysilylpropyl) polysulfides having an average of from 2 to 4 connecting sulfur atoms in their polysulfidic bridge are often used as a coupling agent (or adhesive) to enhance coupling of synthetic amorphous silicas, such as aggregates of precipitated silica, to various conjugated diene-based elastomers.
• a coupling agent or adhesive
• Use of such coupling agents is well known to those having skill in such art.
• silane-containing coupling agents, or adhesives which rely upon a reaction between the silane and hydroxyl groups (e.g. silanol groups) on the surface of a synthetic amorphous silica typically releases an alcohol as a by-product of such reaction.
• a reaction of a bis-(3-triethoxysilylpropyl) tetrasulfide coupling agent with silanol groups on the surface of a silica material releases ethanol as a by-product.
• the term “phr” is used to designate parts by weight of a material per 100 parts by weight of elastomer.
• the terms “rubber” and “elastomer” may be used interchangeably unless otherwise mentioned.
• the terms “vulcanized” and “cured” may be used interchangeably, as well as “unvulcanized” or “uncured”, unless otherwise indicated.
• a rubber composition which comprises
• hydroxyl groups e.g. silanol groups
• said coupling agent composite is mixed with said elastomer(s), according to one or more of the following:
• X is a radical selected from alkoxy radicals having from 1 through 3 carbon atoms, preferably selected from methoxy and ethoxy radicals, and from halogen radicals selected from at least one of chlorine and bromine radicals, preferably a chlorine radical;
• R is an alkyl radical having from 1 to 18 carbon atoms, preferably from 1 through 4 carbon atoms and more preferably selected from methyl and ethyl groups; and n is an integer of 1 through 3,
• an article of manufacture which contains at least one component comprised of the rubber composition of this invention.
• a tire which contains at least one component comprised of the rubber composition of this invention.
• a tire having a tread comprised of the rubber composition of this invention.
• the synthetic amorphous silica may be selected from aggregates of precipitated silica, which is intended to include precipitated aluminosilicates as a co-precipitated silica and aluminum, and from fumed (pyrogenically formed) silica, whereas the silica is preferably a precipitated silica.
• Such precipitated silica is, in general, well known to those having skill in such art.
• such precipitated silica may be precipitated by controlled addition of an acid such as, for example, hydrochloric acid or sulfuric acid, to a basic solution (e.g. sodium hydroxide) of a silicate, for example, sodium silicate, usually in the presence of an electrolyte, for example, sodium sulfate.
• a silicate for example, sodium silicate
• electrolyte for example, sodium sulfate
• Primary, colloidal silica particles typically form during such process which quickly coalesce to form aggregates of such primary particles and which are then recovered as precipitates by filtering, washing the resulting filter cake with water or an aqueous solution, and drying the recovered precipitated silica.
• Such method of preparing precipitated silica, and variations thereof, are well known to those having skill in such art.
• the carbon black with domains of exposed silica on its surface may be, for example, carbon black prepared by treatment of carbon black by reaction of an alkyl silane (e.g. an alkoxy silane) with carbon black or by co-fuming carbon black and silica at an elevated temperature.
• an alkyl silane e.g. an alkoxy silane
• co-fuming carbon black and silica at an elevated temperature See U.S. Pat. Nos. 5,679,728 and 6,028,137.
• the said 1-thioglycerol(3-mercapto-1,2-propanediol)/carbon black composite, exclusive of 2,2′-benzothiazyl disulfide, is provided as being supported on a carbon black carrier, as a composite of said thioglycerol and carbon black, in order to promote an improved dispersion of the material thioglycerol coupling agent in the rubber composition.
• the thioglycerol may be provided as being supported on a carbon black carrier by a process such as, for example, by dissolving the thioglycerol in a volatile organic solvent such as, for example acetone, and adding the solvent solution to the particulate carbon black, then removing the solvent.
• a silica coupler can be used to assist precipitated silica in the reinforcement of diene hydrocarbon elastomers without
• a silane based compound e.g. an alkoxysilane compound
• organo polysulfide compound e.g. a bis-(3-triethoxysilylpropyl) disulfide or tetrasulfide or a similar alcohol evolving silane coupler.
• organo polysulfide compound e.g. a bis-(3-triethoxysilylpropyl) disulfide or tetrasulfide or a similar alcohol evolving silane coupler.
• the adjacent hydroxyl groups of the 1-thioglycerol(3-mercapto-1,2-propanediol) react with hydroxyl groups (e.g. silanol groups) contained on the surface of the silica and the mercapto group of the 1-thioglycerol(3-mercapto-1,2-propanediol) interacts with the diene-based elastomer(s) of the rubber composition.
• hydroxyl groups e.g. silanol groups
• the 1-thioglycerol(3-mercapto-1,2-propanediol) of the carbon black composite interacts in situ within the elastomer host to form a silica coupler by forming a carbon-to-sulfur bond.
• a coupling agent is formed with a moiety (the 1-thioglycerolhydroxyl groups) reactive with hydroxyl groups on the surface of the silica, or silica-containing carbon black and another moiety (the mercapto group) which is reactive with at least one of said diene-based elastomers.
• the 1-thioglycerol(3-mercapto-1,2-propanediol) of the said carbon black composite and silica material may be individually mixed with a diene-based elastomer in an internal rubber mixer to a temperature in a range of from about 125° C. to about 190° C. wherein the said 1-thioglycerol(3-mercapto-1,2-propanediol) diol moiety is allowed to react with hydroxyl groups contained on the surface of said silica material in situ within the elastomer host.
• the precipitated silica is provided as a pre-hydrophobated silica which is hydrophobated prior to its addition to the elastomer (pre-hydrophobated).
• pre-hydrophobated silica which is hydrophobated prior to its addition to the elastomer (pre-hydrophobated).
• pre-hydrophobation of the silica material enables a more efficient mixing, or processing, of it within the elastomer host in that such pre-hydrophobation of the silica material (1) renders it more compatible with the diene-based elastomer and (2) substantially reduces a tendency for a precipitated silica to re-agglomerate with itself within the elastomer host.
• the accompanying in situ reaction of the diol moiety of 1-thioglycerol(3-mercapto-1,2-propanediol) of the carbon black composite enables both a more efficient mixing coupled with the associated reaction with only a minimal evolution of an alcohol, preferably no evolution of alcohol from the rubber composition.
• Representative alkylsilanes of Formula (I) are, for example, trichloro methyl silane, dichloro dimethyl silane, chloro trimethyl silane, trimethoxy methyl silane, dimethoxy dimethyl silane, methoxy trimethyl silane, trimethoxy propyl silane, trimethoxy octyl silane, trimethoxy hexadecyl silane, dimethoxy dipropyl silane, triethoxy methyl silane, triethoxy propyl silane, triethoxy octyl silane, and diethoxy dimethyl silane.
• various diene-based elastomers may be used such as, for example, homopolymers and copolymers of monomers selected from isoprene and 1,3-butadiene and copolymers of at least one diene selected from isoprene and 1,3-butadiene and a vinyl aromatic compound selected from styrene and alphamethyl styrene, preferably styrene.
• conjugated diene-based elastomers are, for example, cis 1,4-polyisoprene (natural and synthetic), cis 1,4-polybutadiene, styrene/butadiene copolymers (aqueous emulsion polymerization prepared and organic solvent solution polymerization prepared), medium vinyl polybutadiene having a vinyl 1,2-content in a range of about 15 to about 90 percent, isoprene/butadiene copolymers, styrene/isoprene/butadiene terpolymers.
• Tin coupled elastomers may also be used, such as, for example, tin coupled organic solution polymerization prepared styrene/butadiene co-polymers, isoprene/butadiene copolymers, styrene/isoprene copolymers, polybutadiene and styrene/isoprene/butadiene terpolymers.
• particulate reinforcement for the rubber composition may be particulate synthetic amorphous silica, or a combination of carbon black and amorphous silica (exclusive of silica treated carbon black), usually of an amount in a range of about 25 to about 100 alternately about 35 to about 90, phr. If a combination of such carbon black and silica is used, usually at least about 5 phr of carbon black and at least 10 phr of silica are used. For example, a weight ratio of silica to carbon black ranging from about 1/5 to 5/1 might be used.
• silica Commonly employed synthetic amorphous silica, or siliceous pigments, used in rubber compounding applications can be used as the silica in this invention, including precipitated siliceous pigments and fumed (pyrogenic) silica wherein aggregates of precipitated silicas are usually preferred.
• the precipitated silica aggregates preferably employed in this invention are precipitated silicas such as, for example, those obtained by the acidification of a soluble silicate, e.g., sodium silicate and may include co-precipitated silica and a minor amount of aluminum.
• Such silicas might usually be characterized, for example, by having a BET surface area, as measured using nitrogen gas, preferably in the range of about 40 to about 600, and more usually in a range of about 50 to about 300 square meters per gram.
• the BET method of measuring surface area is described in the Journal of the American Chemical Society , Volume 60, Page 304 (1930).
• the silica may also be typically characterized by having a dibutylphthalate (DBP) absorption value in a range of about 50 to about 400 cm 3 /100 g, and more usually about 100 to about 300 cm 3 /100 g.
• DBP dibutylphthalate
• the rubber composition would be compounded by methods generally known in the rubber compounding art, such as mixing the various sulfur-vulcanizable constituent rubbers with various commonly used additive materials such as, for example, curing aids, such as sulfur, activators, retarders and accelerators, processing additives, such as oils, resins including tackifying resins, silicas, and plasticizers, fillers, pigments, fatty acid, zinc oxide, waxes, antioxidants and antiozonants, peptizing agents and reinforcing materials such as, for example, carbon black.
• curing aids such as sulfur, activators, retarders and accelerators
• processing additives such as oils, resins including tackifying resins, silicas, and plasticizers
• fillers pigments, fatty acid, zinc oxide, waxes, antioxidants and antiozonants
• peptizing agents and reinforcing materials such as, for example, carbon black.
• the additives mentioned above are selected and commonly used in conventional amounts.
• Typical amounts of tackifier resins comprise about 0.5 to about 10 phr, usually about 1 to about 5 phr.
• processing aids comprise about 1 to about 50 phr.
• processing aids can include, for example, aromatic, napthenic, and/or paraffinic processing oils.
• Typical amounts of antioxidants comprise about 1 to about 5 phr. Representative antioxidants may be, for example, diphenyl-p-phenylenediamine and others, such as, for example, those disclosed in The Vanderbilt Rubber Handbook (1978), Pages 344 through 346.
• Typical amounts of antiozonants comprise about 1 to 5 phr.
• Typical amounts of fatty acids, if used, which can include stearic acid comprise about 0.5 to about 3 phr.
• Typical amounts of zinc oxide comprise about 1 to about 10 phr.
• Typical amounts of waxes comprise about 1 to about 5 phr. Often microcrystalline waxes are used.
• Typical amounts of peptizers comprise about 0.1 to about 1 phr.
• the vulcanization is conducted in the presence of a sulfur vulcanizing agent.
• suitable sulfur vulcanizing agents include elemental sulfur (free sulfur) or sulfur donating vulcanizing agents, for example, an amine disulfide, polymeric polysulfide or sulfur olefin adducts.
• the sulfur vulcanizing agent is elemental sulfur.
• sulfur vulcanizing agents are used in an amount ranging from about 0.5 to about 4 phr, or even, in some circumstances, up to about 8 phr.
• Accelerators are used to control the time and/or temperature required for vulcanization and to improve the properties of the vulcanizate.
• a single accelerator system may be used, i.e., primary accelerator.
• a primary accelerator(s) is used in total amounts ranging from about 0.5 to about 4, preferably about 0.8 to about 1.5, phr.
• combinations of a primary and a secondary accelerator might be used with the secondary accelerator being used in smaller amounts (of about 0.05 to about 3 phr) in order to activate and to improve the properties of the vulcanizate.
• Combinations of these accelerators might be expected to produce a synergistic effect on the final properties and are somewhat better than those produced by use of either accelerator alone.
• delayed action accelerators may be used which are not affected by normal processing temperatures but produce a satisfactory cure at ordinary vulcanization temperatures.
• Vulcanization retarders might also be used.
• Suitable types of accelerators that may be used in the present invention are amines, disulfides, guanidines, thioureas, thiazoles, thiurams, sulfenamides, dithiocarbamates and xanthates.
• the primary accelerator is a sulfenamide.
• the secondary accelerator is preferably a guanidine, dithiocarbamate or thiuram compound.
• the mixing of the rubber composition can be accomplished by methods known to those having skill in the rubber mixing art.
• the ingredients are typically mixed in at least two stages, namely, at least one non-productive stage followed by a productive mix stage.
• the final curatives are typically mixed in the final stage which is conventionally called the “productive” mix stage in which the mixing typically occurs at a temperature, or ultimate temperature, lower than the mix temperature(s) than the preceding non-productive mix stage(s).
• the rubber, and fillers such as silica and silica treated carbon black and adhesive agent, are mixed in one or more non-productive mix stages.
• the terms “non-productive” and “productive” mix stages are well known to those having skill in the rubber mixing art.
• a one liter, open-top, glass reactor was charged with 25 grams (g) of N330 carbon black suspended by stirring in 50 milliliters (ml) of acetone solvent. To the suspension is then added 25 g of 1-thioglycerol (3-mercapto-1,2-propanediol), with continued stirring at about 25° C. for about 30 minutes.
• the acetone solvent was removed under reduced pressure with stirring to yield 50.8 g of particles as a composite of carbon black and 1-thioglycerol (3-mercapto-1,2-propanediol) in a weight ratio of about 50/50 and thereby composed of about 50 percent by weight of the carbon black and about 50 percent by weight the 1-thioglycerol (3-mercapto-1,2-propanediol).
• Rubber compositions comprised of natural rubber and solution SBR with carbon black and silica as reinforcements were prepared as shown in Table 1 and are identified herein as Samples A-C.
• the first non-productive mixing step was conducted for about 4 minutes to a temperature of about 160° C.
• the final productive mixing step was conducted for about 2 minutes to a final temperature of about 110° C.
• Sample A is a Control Sample in which no silica coupler was added.
• Sample B is a Control Sample in which an ethoxysilane/polysulfide coupling agent is added during the second non-productive mixing step.
• Sample C represents a practice of this invention in which a non-silane coupling agent as the carbon black composite of Example I herein is added during the second non-productive mixing step.
• Control Samples A and B and Sample C are shown in the following Table 1.
• Sample C in which the non-silane, non polysulfide coupling agent/carbon black composite, which is the subject of this invention shows improvement in several of the measured properties, namely increased 100 percent and 300 percent modulus, tensile strength, hardness, E′ stiffness with greatly reduced DIN abrasion which leads to improved treadwear while maintaining tire durability and handling properties.
• Sample C in which the non-silane, non polysulfide coupling agent/carbon black composite, which is the subject of this invention shows improvement in several of the measured properties, namely reduced DIN abrasion (reduced cm 3 rubber loss) with comparable tensile strength and increased E′ stiffness.
• reduced DIN abrasion reduced cm 3 rubber loss
• This is also considered herein to be significant because maintained stiffness will lease to increased tread durability and handling qualities.

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• 2001
  • 2001-01-08 US US09/756,538 patent/US6534584B2/en not_active Expired - Fee Related
• 2002
  • 2002-01-03 EP EP02000116A patent/EP1221461A1/en not_active Withdrawn
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