Classifications

• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/26—Methods of annealing
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
  • C21D8/10—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
  • C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes

Definitions

• the present invention relates to a process for producing welded steel pipes with a high degree of strength, ductility and deformability, in particular line pipes, using the UOE-process. More particularly, the invention relates to a heat post-treatment of the popes after the welding and sizing operation.
• the yield strength of sheet metal employed in the manufacture of pipes by cold molding, for example by the UOE-process has to exceed at least a minimum specified value, so as to reliably and safely prevent flow of the finished pipe.
• Pipes made of high-strength steel with a yield strength R t0,5 ⁇ 550 MPa can meet these requirements in practice only by having a comparatively high initial upper yield strength ratio due to the viscosity and deformation characteristics that have to be met at the same time.
• Current industry standards require a maximum upper yield strength ratio of, for example, 0.93 according to API5L, which due to work hardening during molding and sizing of the pipes is difficult to achieve in series production, requires complex manufacturing technology and increases production cost.
• the cold-forming process reduces the integral deformation reserve due to the required high initial yield strength ratio for higher grade steel.
• a process referred to as “bake hardening” for increasing the strength of components is known from DE 196 10 675 C1.
• This process refers to an artificial aging process associated with enamel baking.
• the component is preferably coated in a zinc bath through which the previously cold-rolled tape passes.
• the zinc bath temperatures are in a range between 450-470° C.
• German Pat. No. DE 196 10 675 C1 discloses a steel with the following composition in wt. %:
• the remainder is iron with steel-making related impurities.
• Cold rolling is followed by a heat treatment, preferably in a hot-dip galvanizing apparatus or in a continuous annealing furnace.
• the micro-structure is comprised of a ferritic matrix in which martensite is incorporated in form of islands.
• the minimum characteristic values attainable by the conventional process are as follows:
• the essential elements favored in the process disclosed in German Pat. No. DE 196 10 675 C 1 are aluminum and silicon.
• the element silicon is maintained at a low concentration in order to suppress the formation of red scale during hot-rolling.
• Red scale poses the danger of drawing in scale that causes surface inhomogeneities when the tape is pickled.
• a high aluminum fraction promotes formation of ferrite during annealing between the conversion temperatures A c1 , and A c3 .
• Addition of aluminum also improves the adhesion characteristic of zinc as well as of the zinc-iron alloy layers. The formation of pearlite is moved to significantly longer times and can therefore be suppressed with the achievable cooling rates.
• High-strength steels such as grade X65 steel, have a ratio of yield strength to tensile stress of >0.70, other steels have a ratio in the range between the 0.80-0.93.
• the invention is directed to a process for producing welded steel pipes with a high degree of strength, ductility and deformability.
• the invention incorporates a heat post-treatment after the welding and sizing operation.
• a steel sheet with a composition (in wt. %) of 0.02 to 0.20% carbon; 0.05 to 0.50% silicon; 0.50 to 2.50% manganese; and 0.003 to 0.06% aluminum, the remainder representing iron with steel-making related impurities, is cold-formed into a pipe shape, welded and sized.
• the so obtained pipe undergoes heat post-treatment in a temperature range of 100-300° C. wherein the holding time is adapted to the pipe wall thickness.
• the pipe is subsequently cooled in air or by forced cooling.
• the holding time depends primarily on the wall thickness of the heated component and to a lesser extent on the type of heat supply.
• the pipe produced in this manner has the same high mechanical strength as conventionally produced pipes, but has more than twice the deformation reserves, without exceeding the upper limit for the ratio of yield strength to tensile stress set by current industry standards.
• the heat treatment can be performed in a continuous annealing furnace or by passage through an induction coil and/or induction furnace.
• the heat treatment can be performed in conjunction with the application of an outside insulation layer which can be a mono-layer or a multi-layer structure.
• the holding time can vary in extreme cases between seconds and several hours.
• the pipes can be welded with a helical seam or a straight seam.
• Pipes having a straight seam can be presized before the heat treatment by a combined application of cold-expansion and cold-reduction, wherein the order and the degree of expansion and reduction is determined by the requested pipe profile.
• Optimal results are achieved when the minimum initial yield strength of the sheet metal matches the minimum yield strength of the pipe after subtracting the increase of the yield strength due to cold-forming and heat treatment effects.
• a pipe fabricated in this way is resistant to aging and has particularly homogeneous properties along the periphery of the pipe.
• additional elements can optionally be added to the alloys up to the previously described upper limits.
• up to 0.02% phosphorus; up to 0.06% titanium; up to 0.20% chromium; up to 0.50% molybdenum; up to 0.30% nickel; up to 0.10% niobium; up to 0.08% vanadium; up to 0.50% copper; up to 0.030% nitrogen; and up to 0.005% boron can be added. Addition of these fractions may, for example, enhance certain mechanical properties for a specified wall thickness of the product.
• a pipe with 56′′ outside diameter and 19.1 mm wall from X100 steel can be manufactured using a conventional process.
• the steel sheet requires a 2.0% yield strength of R p2.0 >710 MPa and a tensile strength of R m ⁇ 770 MPa. Since the final strength properties are determined by the initial values of the steel sheet and by work-hardening during forming and sizing of the pipes to the nominal diameter, the finished pipe may have a ratio of yield strength to tensile stress which limits the ability of the component to change its form when subjected to an inside pressure.
• the typical requirement for integral elongation of ⁇ up ⁇ 2% for high-strength pipes was hardly ever achieved or without a sufficient safety margin.
• a pipe is cold-formed, welded and sized to a desired diameter starting with a TM-rolled sheet having the composition 0.02 to 0.20% carbon, 0.05 to 0.50% silicon, 0.50 to 2.50% manganese, and 0.003 to 0.06% aluminum, with the remainder being iron containing production-related impurities.
• the pipe is subjected to heat treatment at a temperature in the range of 100-300° C. with a holding time that is adapted to the thickness of the pipe wall and can range from seconds to several hours.
• the pipe is subsequently cooled with air or by forced cooling.
• the steel sheet need only have a 2.0% yield strength of R p2.0 ⁇ 640 MPa instead of ⁇ 710 MPa, and a tensile strength of R m ⁇ 770 MPa.
• the yield strength can vary around the above value depending on the analysis of the employed steel grade and the degree of strain during the transformation from a steel sheet to a pipe.
• the exemplary steel grade yields the following analysis (in wt. %):
• the heat treatment according to the invention improves the mechanical parameters of the material, in particular the yield strength, so that the required minimum values can be reliably achieved with this process.
• the term “reliably achieved with this process” is intended to indicate that the increase represents a reserve which makes it possible to tolerate common variations with respect to alloy composition, wall thickness, rolling parameters, etc. As a result, the required minimum value could still be attained even if a combination of several unfavorable parameter were present simultaneously. This obviates the need for special measures that would otherwise be required with conventional processes.
• pipes conditioned by such heat treatment resist aging at operating temperatures below the heat treatment temperature, for example 200° C. Accordingly, the mechanical characteristic of a pipeline made from those pipes is not expected to experience further changes during the operating life of the pipeline.
• the steel sheet can have lower initial yield strength values and a lower ratio of yield strength to tensile stress while still attaining the specified pipe quality or grade. This makes it also possible to increase the elongation before reduction of the area to values of A g ⁇ 8.5% on the steel sheet and to values of A g ⁇ 6.5% on the pipe. In this way, twice the deformability of conventionally produced pipes can be achieved, so that the requirements for reliably providing an integral component reserve ⁇ up ⁇ 2% can be safely satisfied within the framework of the production-related variations even for pipe grades of X 100.
• Heat treatment with an induction furnace can preferably be integrated in a facility where insulation is applied to the outside of the pipe.
• the pipe or another component passes through the induction coil or induction furnace to heat the pipe for the purpose of applying a mono-layer or multi-layer insulation.
• This induction heating step can be used to simultaneously increase the parameters indicative of the mechanical strength to suitable levels, because the temperature required for applying the insulation is also in the proposed range of 100-300° C.
• the strength and deformation characteristics measured in an acceptance test after application of the insulation are therefore controlling for the entire useful life for of a pipeline.
• Sheet metal and tapes with a lower initial yield strength can hence advantageously be employed, since they require a smaller forming force for forming an open seam pipe. This advantage is particularly important for thick-wall pipes.
• the proposed heat treatment also helps to reproducibly maintain a small ratio of yield strength to tensile stress and provides a more uniform strength characteristic advantageous for series production. Unlike conventionally produced pipes, the component has hence higher deformation reserves against ductile fracture.
• the effect obtained by providing a more uniform strength characteristic can be enhanced by additionally conditioning the pipes that have been produced with the UOE-process with the process proposed in German Pat. No. DE 195 22 790 A1.
• the characteristic properties of pipes can be tailored for specific applications, for example depending if the pipes are subjected to inside or outside pressure.
• the compositional range of the steel sheet in conjunction with the heat post-treatment according to the present invention yields the most favorable results concerning variations of the values along the periphery of the pipe and from one pipe to another, as well as concerning a potential reserve for dimensional changes available to a component.
• the process of the invention can be applied to pipes having a straight welded seam as well as a helically welded seam (also referred to as serpentine pipes) produced by the HFI and UOE process.
• the increase in yield strength in the peripheral direction of the pipe as a result of the heat post-treatment depends on the steel composition, the C and N fraction in forced solution and the parameters of the pipe manufacturing process. As presently understood, this increase can reach 18% of the R t0.5 yield strength measured on the expanded pipe in circular tensile tests. For unexpanded pipes, such as HFI pipes, increases of up to 12% are achieved according to recent observations. The tensile strength R m increases as a result of the heat post-treatment by approximately 20 MPa.

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• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Physics & Mathematics (AREA)
• Thermal Sciences (AREA)
• Crystallography & Structural Chemistry (AREA)
• Mechanical Engineering (AREA)
• Materials Engineering (AREA)
• Metallurgy (AREA)
• Organic Chemistry (AREA)
• Manufacturing & Machinery (AREA)
• Heat Treatment Of Articles (AREA)
• Heat Treatment Of Steel (AREA)

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• 2000
  • 2000-05-10 CA CA002373064A patent/CA2373064C/fr not_active Expired - Fee Related
  • 2000-05-10 DE DE50014515T patent/DE50014515D1/de not_active Expired - Lifetime
  • 2000-05-10 WO PCT/DE2000/001513 patent/WO2000068443A2/fr not_active Ceased
  • 2000-05-10 JP JP2000617212A patent/JP2002544377A/ja active Pending
  • 2000-05-10 EP EP00943586A patent/EP1204772B1/fr not_active Expired - Lifetime
• 2001
  • 2001-11-13 US US10/033,379 patent/US6648209B2/en not_active Expired - Fee Related

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