US8167993B2 - Asphalt emulsion priming compositions and methods of use - Google Patents

Asphalt emulsion priming compositions and methods of use Download PDF

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Publication number
US8167993B2
US8167993B2 US12/195,227 US19522708A US8167993B2 US 8167993 B2 US8167993 B2 US 8167993B2 US 19522708 A US19522708 A US 19522708A US 8167993 B2 US8167993 B2 US 8167993B2
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Prior art keywords
asphalt
weight
composition
asphalt emulsion
water
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US20090176014A1 (en
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Jean-Valery Martin
James Michael Hemsley, JR.
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Innophos Inc
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Innophos Inc
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Priority to US12/195,227 priority Critical patent/US8167993B2/en
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Assigned to ROYAL BANK OF CANADA, AS COLLATERAL AGENT reassignment ROYAL BANK OF CANADA, AS COLLATERAL AGENT PATENT SECURITY AGREEMENT (TL) Assignors: INNOPHOS, INC., INNOPHOS, LLC
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
    • C09D195/005—Aqueous compositions, e.g. emulsions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C08K5/19—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • C08L95/005—Aqueous compositions, e.g. emulsions

Definitions

  • the present invention is directed in one aspect to asphalt emulsion compositions for use in priming a granular surface such as a road bed.
  • the asphalt emulsion comprises asphalt, an amphoteric emulsifier, and water.
  • the present invention is directed to methods of using the asphalt emulsion priming composition on road beds to prepare the road bed for paving.
  • Application of the asphalt emulsion priming composition to a granular surface, such as a road bed, can provide several advantages, including reducing or eliminating dust generated by traffic on the granular surface.
  • Asphalt emulsion priming consists of application of a low viscosity asphalt emulsion to an absorbent surface, such as a granular base, in preparation for paving using an asphalt surface course.
  • Road construction typically involves preparation of a surface comprising a granular material, such as sand or gravel, for application of an asphalt surface course.
  • the granular material is often graded and packed to form a relatively flat, uniform surface for paving.
  • the asphalt surface course typically consists of asphalt and an aggregate which is mixed and applied to the surface of the prepared granular material in the road bed.
  • Asphalt emulsion priming compositions are formulated to penetrate rapidly into the absorbent surface to bind the granular material. Deep penetration is desirable to assure that the primed surface is not easily disrupted by traffic during road surfacing.
  • AEP provides several benefits.
  • AEP can partially waterproof treated areas to make them resistant to water erosion prior to application of the asphalt surface course. This can reduce or eliminate the need to repair the granular surface after a rainfall.
  • the AEP can provide an improved bond between the granular base and the asphalt surface course.
  • AEP compositions presently used typically include a petroleum distillate added to the asphalt.
  • the petroleum distillate lowers the viscosity of the asphalt to improve the penetration of the asphalt into the granular base.
  • One disadvantage of petroleum distillates is that vapors are released into the air as the AEP material sets. This constitutes a significant pollution source and potential health hazard for workers.
  • prior AEP compositions typically required an acidic or basic additive, such as hydrochloric acid or sodium hydroxide, to adjust the pH of the composition.
  • an acidic or basic additive such as hydrochloric acid or sodium hydroxide
  • an object of the present invention to provide an AEP composition that does not require use of a petroleum distillate or an additive to adjust the pH of the composition, and has acceptable properties to adequately penetrate a granular surface.
  • Another object of the present invention is to provide methods of applying the AEP composition to a surface, such as a granular surface being prepared for paving.
  • FIG. 1 is a chart showing the depth of penetration of the asphalt emulsion priming compositions described in Table 3.
  • FIG. 2 is a chart showing the depth of penetration of the asphalt emulsion priming compositions described in Table 4 in Red Clay Sand.
  • FIG. 3 is a chart showing the depth of penetration of the asphalt emulsion priming compositions described in Table 4 in AB Base.
  • the present invention is directed to an asphalt emulsion priming (AEP) composition that does not contain any petroleum distillates to adjust the viscosity of the asphalt composition.
  • AEP composition does not contain any acidic or basic additives, such as hydrochloric acid or sodium hydroxide, used to adjust the pH of the composition.
  • the AEP composition comprises asphalt, water and an amphoteric emulsifier.
  • the amphoteric emulsifier is a betaine. If desired, other emulsifiers may also be added to the AEP composition.
  • the AEP composition may include a polymer.
  • the polymer is selected from the group consisting of polyisoprene, polynorbornene, polybutadiene, butyl rubber, random ethylene/propylene (EP) copolymers, random ethylene/propylene/diene (EPDM) terpolymers, styrene-butadiene copolymers, styrene-butadiene-styrene block copolymers or acrylic polymers.
  • the AEP composition also includes a natural oil extracted from plants.
  • the natural oil may further improve the viscosity of the AEP composition.
  • the natural oil is d-limonene. Unlike organic solvents formed from petroleum distillates, natural oils such as d-limonene do not present or create environmental or health hazards.
  • the AEP composition is typically first formulated as a concentrate that is further diluted with water for application to an absorbent surface, such as a granular surface which is being prepared for paving, to prime the surface.
  • the AEP concentrate composition/water mixture has good penetration into a granular surface.
  • the primed granular surface is resistant to water erosion, generates little or no dust in wind or from traffic over the surface, and provides a bond between the granular base and the asphalt pavement.
  • the AEP compositions of the present invention do not include any petroleum distillates to adjust the viscosity of the asphalt or the emulsion. In addition, there is no need to adjust the pH of the AEP composition using acidic or basic additives such as hydrochloric acid or sodium hydroxide.
  • the present invention is directed generally to an AEP composition using amphoteric emulsifiers.
  • the AEP compositions do not contain any organic solvents made from petroleum distillates. As a result, the AEP composition does not release volatile organics into the air that may cause environmental or human health problems.
  • the AEP compositions of the present invention comprise asphalt, an amphoteric emulsifier and water.
  • the AEP composition comprises between about 30% by weight to about 95% by weight asphalt, between about 0.1% by weight to about 3% by weight of an amphoteric emulsifier, and sufficient water to complete the emulsion to form the AEP composition.
  • the amount of water required is between about 10% by weight to 40% by weight.
  • the AEP composition comprises between about 60% to 65% by weight asphalt.
  • the AEP composition is stable for extended storage.
  • the AEP composition is further diluted with water immediately prior to application to the granular surface. The diluted AEP composition is less stable for storage than the undiluted AEP composition.
  • AEP compositions of the present invention No petroleum distillates are added to the AEP compositions of the present invention.
  • the AEP composition does not require acidic or basic additives, such as for example hydrochloric acid or sodium hydroxide, to adjust the pH of the composition.
  • amphoteric emulsifier Any appropriate amphoteric emulsifier may be used in the present invention.
  • the amphoteric emulsifier is a betaine having either formula I or formula II:
  • amphoteric emulsifiers having formulas I or II above may also be used.
  • the amphoteric emulsifier is cocoamidopropylbetaine.
  • the amphoteric emulsifier is cocoamidohydropropylsultaine.
  • the AEP composition is prepared by heating the asphalt to reduce the viscosity of the asphalt sufficiently for emulsification.
  • the asphalt is heated to a temperature of between about 130° C. and 180° C., and more preferably to a temperature of about 140° C. prior to mixing.
  • the amphoteric emulsifier and water are combined by mixing at a temperature ranging from about room temperature up to about 80° C.
  • the heated asphalt and the amphoteric emulsifier/water mixture are combined and fed to a colloidal mill (a high shear mixer) to create an emulsified asphalt-in-water AEP concentrate composition.
  • the AEP concentrate is stable as an emulsion in storage for an extended time, and it can be used as a concentrate or combined with water as described below to prime a granular surface for paving.
  • the AEP concentrate composition described above may be applied directly to a granular surface to prime the surface for paving, in preferred embodiments, the AEP concentrate is further diluted with water prior to application to the granular surface to form a Penetrating Emulsion Primer (PEP).
  • PEP Penetrating Emulsion Primer
  • the amount of water used in the PEP is selected to achieve a desired degree of penetration.
  • the AEP concentrate is mixed with sufficient water to result in a mixture having between about 50% to about 70% water, and between about 30% to about 50% of the AEP composition.
  • the PEP is not stable for extended times and is typically applied to the granular surface within a short time after mixing.
  • the PEP is spread on the prepared absorbent surface, such as the granular surface of a road bed.
  • the material is spread on the surface using equipment known to those skilled in the art.
  • the PEP is applied to the granular surface by spraying.
  • Sufficient material is spread on the surface to achieve the desired penetration of the granular surface by a desired quantity of asphalt.
  • the AEP composition or the PEP is spread on the surface at a rate of about 2 kg/m 2 of asphalt. Where a PEP composition (diluted AEP composition) is used, the amount of the PEP spread depends on the degree of dilution.
  • the PEP is spread at a rate of between about 3 kg/m 2 to about 15 kg/m 2 .
  • multiple applications of the AEP composition or the AEP/water mixture may be spread on the surface to achieve the desired amount of asphalt on the granular surface.
  • the AEP composition or the PEP composition After the AEP composition or the PEP composition is spread on the granular surface, it is allowed sufficient time to penetrate the granular surface and cure before any traffic is allowed to run on the surface. In a preferred embodiment, the AEP composition or the PEP composition is allowed to cure undisturbed on the surface for at least one hour, and preferably between about 3 hours and 5 hours.
  • one or more polymers may be added to the AEP composition.
  • the polymers used may be any known to those skilled in the art for use in asphalt compositions, such as polyisoprene, polynorbornene, polybutadiene, butyl rubber, random ethylene/propylene (EP) copolymers, random ethylene/propylene/diene (EPDM) terpolymers, styrene-butadiene copolymers, styrene-butadiene-styrene block copolymers or acrylic polymers.
  • the polymer is preferably composed partially (the remaining part being composed of one or a number of polymers mentioned above or other polymers) or entirely of one or a number of random or block copolymers of styrene and of a conjugated diene, such as butadiene, isoprene, chloroprene, carboxylated butadiene or carboxylated isoprene, and more particularly of one or a number of copolymers chosen from block copolymers, with or without a random hinge, of styrene and of butadiene, of styrene and of isoprene, of styrene and of chloroprene, of styrene and of carboxylated butadiene or alternatively of styrene and of carboxylated isoprene.
  • a conjugated diene such as butadiene, isoprene, chloroprene, carboxylated butadiene or carboxyl
  • the copolymer of styrene and of conjugated diene, and in particular each of the abovementioned copolymers, preferably has a styrene content by weight ranging from 5% to 50%.
  • the weight-average molecular weight of the copolymer of styrene and of conjugated diene, and in particular that of the copolymers described above, can be, for example, between 10,000 and 600,000 daltons and preferably lies between 30,000 and 400,000 daltons.
  • the copolymer of styrene and of conjugated diene is preferably chosen from di- or tri-block copolymers of styrene and of butadiene, of styrene and of isoprene, of styrene and of carboxylated butadiene or alternatively of styrene and of carboxylated isoprene which have styrene contents and weight-average molecular weights which lie within the ranges defined above.
  • one or more natural plant oils are added to the AEP or the PEP composition.
  • the natural plant oils should be selected such that they do not cause any adverse environmental or human health effects.
  • the natural plant oil is an essential oil.
  • the natural plant oil is d-limonene.
  • the natural plant oil comprises up to about 35% by weight of the PEP composition.
  • the natural plant oil comprises between about 2% by weight and 15% by weight of the total weight of the PEP composition.
  • the natural plant oil is preferably added to the dilution water prior to the addition of the AEP composition.
  • Surfactants may also be added to the PEP composition to improve the ability of the mixture to penetrate granular material. Any appropriate surfactant may be used in the PEP composition. In a preferred embodiment, the surfactant is Lodyne S-100.
  • the surfactant comprises between about 0.01% to 5% by weight of the total weight of the PEP composition.
  • the surfactant is preferably added to the dilution water before the addition of the AEP composition.
  • pH adjustment of the AEP composition is generally not required to use the composition to prime a granular surface, it may be desirable to adjust the pH due to the nature of the aggregate that will be used in the paving material to be applied to the surface.
  • the pH may be adjusted as desired using hydrochloric acid, sodium hydroxide or phosphoric acid.
  • the penetration depth was measured for prior art compositions using a petroleum distillate organic solvent and compared to the penetration depth for various embodiments of the compositions of the present invention.
  • the mixture of the AEP composition and water were 50/50 by weight.
  • the amounts of emulsifier, surfactant or natural plant oil are relative to the total weight of the AEP/water mixture.
  • AEP composition An example of the method for preparing a quantity of the AEP composition on a laboratory scale is provided below.
  • the process for preparing the AEP composition is intended to be exemplary only, and it is not intended to limit the scope of the invention in any way.
  • a mill that operates on gravity flow is used to mix the emulsifier and the asphalt.
  • the mill has a pumping capability to circulate a quantity of the product to a reservoir.
  • the mill includes a rotor that is 7.5 inches in diameter and operates at about 3450 rpm.
  • the gap between the rotor and stator is 0.025 inches.
  • the typical batch size using this equipment is about 3000 grams.
  • the mill is first preheated using hot water.
  • the emulsifier solution is prepared on a bench and placed in an oven to maintain the desired temperature, typically between 100° F. and 140° F.
  • Asphalt blends are also prepared on the bench and placed in an oven to maintain the temperature at about 290° F.
  • the emulsifier solution, at temperature is poured into the reservoir, and asphalt is then added to the reservoir over a period of several seconds.
  • the material in the reservoir is stirred by hand with a metal spatula.
  • the mill is run and the material is recirculated through the reservoir for a period of about 60 seconds. The material is then discharged from the mill into a container for testing.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Road Paving Structures (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
US12/195,227 2007-08-23 2008-08-20 Asphalt emulsion priming compositions and methods of use Expired - Fee Related US8167993B2 (en)

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US12/195,227 US8167993B2 (en) 2007-08-23 2008-08-20 Asphalt emulsion priming compositions and methods of use

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US (1) US8167993B2 (pl)
EP (1) EP2190929B1 (pl)
JP (1) JP5341892B2 (pl)
KR (1) KR101261310B1 (pl)
CN (2) CN105349041A (pl)
AU (1) AU2008288971B2 (pl)
BR (1) BRPI0815676B1 (pl)
CA (1) CA2698218C (pl)
ES (1) ES2441400T3 (pl)
MX (1) MX2010001933A (pl)
NZ (1) NZ583385A (pl)
PL (1) PL2190929T3 (pl)
WO (1) WO2009026390A1 (pl)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3818107A4 (en) * 2018-07-02 2022-06-29 Heritage Research Group Composition and method for treating an asphalt pavement with a void-filling asphalt emulsion

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8808445B2 (en) * 2008-12-30 2014-08-19 William B. Coe Asphalt-rubber compositions and systems and methods for preparing same
US20150376410A1 (en) * 2013-02-08 2015-12-31 Praphot ISSARIYAKUL Cationic asphalt emulsion for prime coat
US9321915B2 (en) * 2013-05-31 2016-04-26 Lion Copolymer Geismar, Llc Solvent-free method for making ethylene propylene diene polymer latex
WO2016033603A1 (en) 2014-08-29 2016-03-03 Iowa State University Research Foundation, Inc. Improved asphalt products and materials and methods of producing them
CN104231819A (zh) * 2014-09-03 2014-12-24 天长市开林化工有限公司 一种杀菌内墙乳胶漆
CA2992496C (en) * 2015-07-15 2024-01-16 Ergon Asphalt & Emulsions, Inc. Biobased asphalt rejuvenating emulsion
US10961395B2 (en) 2016-02-29 2021-03-30 Iowa State University Research Foundation, Inc. Rejuvenation of vacuum tower bottoms through bio-derived materials
US10570286B2 (en) 2016-08-30 2020-02-25 Iowa State University Research Foundation, Inc. Asphalt products and methods of producing them for rejuvenation and softening of asphalt
KR102033942B1 (ko) * 2019-03-26 2019-10-21 네오에버텍 (주) 친환경 바이오 용매를 포함하는 복합방수 기초재 및 이의 제조방법
WO2021055815A1 (en) 2019-09-18 2021-03-25 Iowa State University Research Foundation, Inc. Biosolvents useful for improved asphalt products utilizing recycled asphalt pavement or other brittle asphalt binders such as vacuum tower bottom
CN111777945B (zh) * 2020-07-31 2022-01-11 辽宁省交通科学研究院有限责任公司 一种高性能含砂雾封层材料及其制备方法
US12297150B2 (en) 2020-10-12 2025-05-13 Iowa State University Research Foundation, Inc. Maintenance treatments useful for improving the performance of aged or brittle resinous binders in paving or roofing
EP4301928B1 (en) * 2021-03-03 2024-12-04 Heritage Research Group, LLC Layered material

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4209337A (en) 1978-03-06 1980-06-24 Th. Goldschmidt Ag Preparation of hardenable binding agents based on cement and bituminous emulsions
US4496474A (en) 1982-12-20 1985-01-29 Akzona Incorporated Asphalt emulsions comprising N-aliphatic-1,3-diaminopentane emulsifier and process
US5271767A (en) * 1991-10-07 1993-12-21 Asphalt Control Systems Inc. Odor-free hot-mix asphalt composition
US5362316A (en) * 1993-02-05 1994-11-08 Imperbel America Corporation Resinous cut-back compositions and methods of preparing the same
US5558702A (en) * 1995-03-24 1996-09-24 Witco Corporation Asphalt emulsions containing amphoteric emulsifier
US5667577A (en) * 1995-03-24 1997-09-16 Witco Corporation Filled asphalt emulsions containing betaine emulsifier
US5667576A (en) * 1995-03-24 1997-09-16 Witco Corporation Asphalt emulsions
US5928418A (en) 1995-12-04 1999-07-27 Kao Corporation Asphalt emulsion
US6494944B1 (en) 2000-03-02 2002-12-17 Akzo Nobel N.V. Amine oxides as asphalt emulsifiers
US6511954B1 (en) 2000-11-20 2003-01-28 Scoda America, Inc. Oil degreaser with absorbent and method
US6540822B2 (en) * 2001-03-20 2003-04-01 Akzo Nobel N.V. Polybetaines as asphalt emulsifiers
US6730158B1 (en) * 2002-10-23 2004-05-04 Ervin Merritt Asphaltic concrete and method of making same
US6840991B2 (en) * 2001-01-24 2005-01-11 Kao Corporation Asphalt emulsion composition
RO119953B1 (ro) 2003-12-05 2005-06-30 Poll Chimic S.A. Emulsie de bitum
US7037955B2 (en) * 2003-05-02 2006-05-02 Odor Managements, Inc. Additives and methods for reducing odor
WO2007034081A1 (fr) * 2005-09-22 2007-03-29 Eurovia Nouvelle composition a base d'emulsion de bitume

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4534964A (en) * 1982-10-04 1985-08-13 Richardson-Vicks Inc. Hair conditioning shampoo
DE3345786A1 (de) * 1983-12-17 1985-06-27 Bayer Ag, 5090 Leverkusen Kationische kautschuklatices, verfahren zu ihrer herstellung und ihre verwendung
CA2216173C (en) * 1995-03-24 2004-09-21 Witco Corporation Asphalt emulsions
JP3957389B2 (ja) * 1998-02-13 2007-08-15 昭和シェル石油株式会社 アスファルト乳剤

Patent Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4209337A (en) 1978-03-06 1980-06-24 Th. Goldschmidt Ag Preparation of hardenable binding agents based on cement and bituminous emulsions
US4496474A (en) 1982-12-20 1985-01-29 Akzona Incorporated Asphalt emulsions comprising N-aliphatic-1,3-diaminopentane emulsifier and process
US5271767A (en) * 1991-10-07 1993-12-21 Asphalt Control Systems Inc. Odor-free hot-mix asphalt composition
US5362316A (en) * 1993-02-05 1994-11-08 Imperbel America Corporation Resinous cut-back compositions and methods of preparing the same
US5558702A (en) * 1995-03-24 1996-09-24 Witco Corporation Asphalt emulsions containing amphoteric emulsifier
US5667577A (en) * 1995-03-24 1997-09-16 Witco Corporation Filled asphalt emulsions containing betaine emulsifier
US5667576A (en) * 1995-03-24 1997-09-16 Witco Corporation Asphalt emulsions
US5928418A (en) 1995-12-04 1999-07-27 Kao Corporation Asphalt emulsion
US6494944B1 (en) 2000-03-02 2002-12-17 Akzo Nobel N.V. Amine oxides as asphalt emulsifiers
US6511954B1 (en) 2000-11-20 2003-01-28 Scoda America, Inc. Oil degreaser with absorbent and method
US6840991B2 (en) * 2001-01-24 2005-01-11 Kao Corporation Asphalt emulsion composition
US6540822B2 (en) * 2001-03-20 2003-04-01 Akzo Nobel N.V. Polybetaines as asphalt emulsifiers
US6730158B1 (en) * 2002-10-23 2004-05-04 Ervin Merritt Asphaltic concrete and method of making same
US7037955B2 (en) * 2003-05-02 2006-05-02 Odor Managements, Inc. Additives and methods for reducing odor
US7306666B2 (en) * 2003-05-02 2007-12-11 Odor Management, Inc. Additives and method for reducing odor
RO119953B1 (ro) 2003-12-05 2005-06-30 Poll Chimic S.A. Emulsie de bitum
WO2007034081A1 (fr) * 2005-09-22 2007-03-29 Eurovia Nouvelle composition a base d'emulsion de bitume
US20090064898A1 (en) 2005-09-22 2009-03-12 Eurovia Novel bitumen emulsion-based composition
US7767015B2 (en) * 2005-09-22 2010-08-03 Eurovia Bitumen emulsion-based composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Terminology of Polymers Containing Ionizable or Ionic Groups and of Polymers Containing Ions", Hess, et al., Pure Appl. Chem., vol. 78, No. 11, pp. 2067-2074, 2006.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3818107A4 (en) * 2018-07-02 2022-06-29 Heritage Research Group Composition and method for treating an asphalt pavement with a void-filling asphalt emulsion

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NZ583385A (en) 2012-06-29
EP2190929B1 (en) 2013-10-02
AU2008288971A1 (en) 2009-02-26
CN105349041A (zh) 2016-02-24
BRPI0815676B1 (pt) 2019-06-04
ES2441400T3 (es) 2014-02-04
EP2190929A1 (en) 2010-06-02
CN101784612A (zh) 2010-07-21
EP2190929A4 (en) 2012-05-02
CA2698218A1 (en) 2009-02-26
WO2009026390A1 (en) 2009-02-26
US20090176014A1 (en) 2009-07-09
CA2698218C (en) 2015-11-24
KR101261310B1 (ko) 2013-05-07
AU2008288971B2 (en) 2012-02-02
JP2010536999A (ja) 2010-12-02
BRPI0815676A2 (pt) 2015-02-18
PL2190929T3 (pl) 2014-03-31
KR20100080510A (ko) 2010-07-08
JP5341892B2 (ja) 2013-11-13
MX2010001933A (es) 2010-05-03

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