UST896010I4 - Defensive publication - Google Patents
Defensive publication Download PDFInfo
- Publication number
- UST896010I4 UST896010I4 US896010DH UST896010I4 US T896010 I4 UST896010 I4 US T896010I4 US 896010D H US896010D H US 896010DH US T896010 I4 UST896010 I4 US T896010I4
- Authority
- US
- United States
- Prior art keywords
- fiber
- emulsion
- ion
- flame retarder
- phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000839 emulsion Substances 0.000 abstract description 11
- 150000002500 ions Chemical class 0.000 abstract description 10
- -1 PHOSPHORUS COMPOUND Chemical class 0.000 abstract description 7
- 239000000835 fiber Substances 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 4
- 229910052736 halogen Inorganic materials 0.000 abstract description 3
- 150000002367 halogens Chemical class 0.000 abstract description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 abstract description 3
- PQYJRMFWJJONBO-UHFFFAOYSA-N Tris(2,3-dibromopropyl) phosphate Chemical group BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr PQYJRMFWJJONBO-UHFFFAOYSA-N 0.000 abstract description 2
- 150000001334 alicyclic compounds Chemical class 0.000 abstract description 2
- 150000007824 aliphatic compounds Chemical class 0.000 abstract description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 abstract description 2
- 150000001491 aromatic compounds Chemical class 0.000 abstract description 2
- LJBYAHZVNSISKR-UHFFFAOYSA-N bis(2,3-dibromopropyl) (2,3,4-tribromophenyl) phosphate Chemical compound BrCC(Br)COP(=O)(OCC(Br)CBr)OC1=CC=C(Br)C(Br)=C1Br LJBYAHZVNSISKR-UHFFFAOYSA-N 0.000 abstract description 2
- 238000010494 dissociation reaction Methods 0.000 abstract description 2
- 230000005593 dissociations Effects 0.000 abstract description 2
- 239000003995 emulsifying agent Substances 0.000 abstract description 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 2
- 239000011574 phosphorus Substances 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- LRSNDFOWYYKLHB-UHFFFAOYSA-N tris(2,3-dibromophenyl) phosphate Chemical compound BrC1=CC=CC(OP(=O)(OC=2C(=C(Br)C=CC=2)Br)OC=2C(=C(Br)C=CC=2)Br)=C1Br LRSNDFOWYYKLHB-UHFFFAOYSA-N 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 3
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 description 1
- XFRVAVQHCGGZLT-UHFFFAOYSA-N BrC(CNP(NCC(CBr)Br)(NCC(CBr)Br)=O)CBr Chemical compound BrC(CNP(NCC(CBr)Br)(NCC(CBr)Br)=O)CBr XFRVAVQHCGGZLT-UHFFFAOYSA-N 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
Definitions
- the positive ion is an alkali metal ion, or an ion corresponding to the structure R +1 RI%IH R wherein R is H or an organic radical having from 1 to 20' carbon atoms, and
- the negative ion is an ion corresponding to the structure R o-i O wherein R is a monovalent aliphatic radical having 8 to 20 carbon atoms, and (C) based on the weight of (A), (B) and (C), from 5090 weight percent of a flame retarder which can be (1) an aliphatic, alicyclic or aromatic compound of at least 6 carbons and containing from about 4085 weight percent halogen, or (2) an aliphatic, alicyclic or aromatic phosphorus compound of at least 6 carbon atoms and containing from about 40-85 weight percent halowherein the pH of the emulsion is in the range of 1-7, the viscosity of the emulsion is in the range of 2,000- 50,000 centipoise, and the emulsion is stable for at least 100 days.
- a flame retarder which can be (1) an aliphatic, alicyclic or aromatic compound of at least 6 carbons and containing from about 4085 weight percent halogen, or (2)
- the flame retarder can be tris(2,3-dibromopropyl)phosphate, bis(2 bromoethyl) 2,5 dibromophenyl phosphate, bis(bromochloropropyl) bromochloropropyl phosphonate, tris(dibromophenyl) phosphate, di(2,3-di bromopropyl) tribromophenyl phosphate, N,N',N tris- (2,3-dibromopropyl) phosphoric triamide or
- the fiber is heated in a temperature range of about 175-220 C. for a suflicient time to cause a portion of the flame retarder to diifuse into the fiber structure.
- the fiber can be po1y(ethylene terephthalate) or poly(1,4-cyclohexylenedimethylene terephthalate).
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A PROCESS WHERE AN EMULSION CONTAINING A FLAME RETARDER IS APPLIED TO THE SURFACE OF A POLYESTER FIBER AND THE FIBER IS SUBSEQUENTLY HEATED TO DIFFUSE THE FLAME RETARDER INTO THE FIBER. THE EMULSION CONSISTS ESSENTIALLY OF: (A) WATER, (B) AN EMULSIFIER SYSTEM WHICH IS A POSITIVE AND NEGATIVE ION IN DISSOCIATION EQUILIBRIUM WHEREIN: (1) THE POSITIVE ION IS AN ALKALI METAL ION, OR AN ION CORESPONDING TO THE STRUCTURE ((R-)3NH)+1 WHEREIN R IS H OR AN ORGANIC RADICAL HAVING FROM 1 TO 20 CARBON ATOMS, AND (2) THE NEGATIVE ION IS AN ION CORRESPONDING TO THE STRUCTURE ((R1-O-)2P(=O)-O-)-1 WHEREIN R1 IS A MONOVALENT ALIPHATIC RADICAL HAVING 8 TO 20 CARBON ATOMS, AND (C) BASED ON THE WEIGHT OF (A), (B) AND (C), FROM 50 TO 90 WEIGHT PERCENT OF A FLAME RETARDER WHICH CAN BE (1) AN ALIPHATIC, ALICYCLIC OR AROMATIC COMPOUND OF AT LEAST 6 CARBOND AND CONTAINING FROM ABOUT 40-85 WEIGHT PERCENT HALOGEN, OR (2) AN ALIPHATIC, ALICYCLIC OR AROMATIC PHOSPHORUS COMPOUND OF AT LEAST 6 CARBON ATOMS AND CONTAINING FROM ABOUT 40-85 WEIGHT PERCENT HALOGEN, WHEREIN THE PH OF THE EMULSION IS IN THE RANGE OF 1-7, THE VISCOSITY OF THE EMULSION IS IN THE RANGE OF 2,00050,000 CENTIPOISE, AND THE EMULSION IS STABLE FOR AT LEAST 100 DAYS. THE FLAME RETARDER CAN BE TRIS(2,3-DIBROMOPROPYL)PHOSPHATE, BIS(2 - BROMOETHYL) 2,5 - DIBROMOPHENYL PHOSPHATE, BIS(BROMOCHLOROPROPYL) BROMOCHLOROPROPYL PHOSPHONATE, TRIS(DIBROMOPHENYL) PHOSPHATE, DI(2,3-DIBROMOPROPYL) TRIBROMOPHENYL PHOSPHATE, N, N'', N" TRIS(2,3-DIBROMOPROPYL) PHOSPHORIC TRIAMIDE OR ((BR-)3-PHENYL)-O-P(=O)(-NH-CH2-CH2-BR)2 (R1-O-P(=O)(-O-)2)-2 (R1-O-S(=O)(=O-)(-O-))-1 ACCORDING TO THE PROCESS, THE FIBER IS HEATED IN A TEMPERATURE RANGE OF ABOUT 175-220*C. FOR A SUFFICIENT TIME TO CAUSE A PORTION OF THE FLAME RETARDER TO DIFFUSE INTO THE FIBER STRUCTURE. THE FIBER CAN BE POLY(EHYLENE TEREPHTHALATE) OR POLY(1,4-CYCLOHEXYLENEDIMETHYLENE TEREPHTHALATE).
Description
LlCllON UNITED STATES PATENT OFFICE Published at the request oi. the applicant or owner in accordance with the Notice of Dec. 16, 1969, S69 O.G. 687. The abstracts of Defensive Publication applications are identified by distinctly numbered series and are arranged chronologically. The heading of each abstract indicates the number of pages of specification, including claims and sheets of drawings contained in the application as originally filed. The files of these applications are available to the public for inspection and reproduction may be purchased for 30 cents a sheet.
Defensive Publication applications have not been examined as to the merits of alleged invention. The Patent Ofiice makes no assertion as to the novelty of the disclosed subject matter.
PUBLISHED MARCH 7, 1972 T896,010 EMULSIONS AND USES THEREOF Wayne W. Lochmaier, 312 Hamilton Drive, Kingsport, Tenn. 37663 Filed Nov. 18, 1970, Ser. No. 90,811 Int. Cl. (309k 3/28 US. Cl. 117-136 No Drawing. 20 Pages Specification A process where an emulsion containing a flame retarder is applied to the surface of a polyester fiber and the fiber is subsequently heated to diffuse the flame retarder into the fiber. The emulsion consists essentially of:
(A) water, (B) an emulsifier system which is a positive and negative ion in dissociation equilibrium wherein:
(1) the positive ion is an alkali metal ion, or an ion corresponding to the structure R +1 RI%IH R wherein R is H or an organic radical having from 1 to 20' carbon atoms, and
(2) the negative ion is an ion corresponding to the structure R o-i O wherein R is a monovalent aliphatic radical having 8 to 20 carbon atoms, and (C) based on the weight of (A), (B) and (C), from 5090 weight percent of a flame retarder which can be (1) an aliphatic, alicyclic or aromatic compound of at least 6 carbons and containing from about 4085 weight percent halogen, or (2) an aliphatic, alicyclic or aromatic phosphorus compound of at least 6 carbon atoms and containing from about 40-85 weight percent halowherein the pH of the emulsion is in the range of 1-7, the viscosity of the emulsion is in the range of 2,000- 50,000 centipoise, and the emulsion is stable for at least 100 days. The flame retarder can be tris(2,3-dibromopropyl)phosphate, bis(2 bromoethyl) 2,5 dibromophenyl phosphate, bis(bromochloropropyl) bromochloropropyl phosphonate, tris(dibromophenyl) phosphate, di(2,3-di bromopropyl) tribromophenyl phosphate, N,N',N tris- (2,3-dibromopropyl) phosphoric triamide or According to the process, the fiber is heated in a temperature range of about 175-220 C. for a suflicient time to cause a portion of the flame retarder to diifuse into the fiber structure. The fiber can be po1y(ethylene terephthalate) or poly(1,4-cyclohexylenedimethylene terephthalate).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9081170A | 1970-11-18 | 1970-11-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UST896010I4 true UST896010I4 (en) | 1972-03-07 |
Family
ID=22224433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US896010D Pending UST896010I4 (en) | 1970-11-18 | 1970-11-18 | Defensive publication |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | UST896010I4 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4348306A (en) | 1972-10-25 | 1982-09-07 | White Chemical Corporation | Flame retardants |
-
1970
- 1970-11-18 US US896010D patent/UST896010I4/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4348306A (en) | 1972-10-25 | 1982-09-07 | White Chemical Corporation | Flame retardants |
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