WO1993005111A1 - Composition d'additifs a base de polymeres - Google Patents

Composition d'additifs a base de polymeres Download PDF

Info

Publication number
WO1993005111A1
WO1993005111A1 PCT/BE1992/000036 BE9200036W WO9305111A1 WO 1993005111 A1 WO1993005111 A1 WO 1993005111A1 BE 9200036 W BE9200036 W BE 9200036W WO 9305111 A1 WO9305111 A1 WO 9305111A1
Authority
WO
WIPO (PCT)
Prior art keywords
une
parties
ponderales
polymeres
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/BE1992/000036
Other languages
English (en)
Inventor
Andries Theodorus Son
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SPIDER NV
Original Assignee
SPIDER NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SPIDER NV filed Critical SPIDER NV
Publication of WO1993005111A1 publication Critical patent/WO1993005111A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
    • C08L23/0853—Ethylene vinyl acetate copolymers
    • C08L23/0861—Saponified copolymers, e.g. ethylene vinyl alcohol copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
    • C08L23/0853—Ethylene vinyl acetate copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
    • C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethylene-propylene or ethylene-propylene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers

Definitions

  • L'invention concerne une composition d'additifs a base de polymeres destines a des mat ⁇ ieres synthetigues, un proceede de preparation et utilisation demony-ci en tant ⁇ u'agents de compatibilite.
  • La composition consiste en des additifs multifonctionnels donating un spectre d'action le plus large possible, guiplast ease compatibles des melanges de mar mar matieres synthetigues differentes ou plus et ance compatibles liv residus, diarrhea sur base du present status, un agent de compatibilite d'affectation stricture.
  • La composition de polymeres ette l'ob et d'adjonction d'additifs pour ameliorer les proprietes du pole final auguel elle est ddleee, par example des agents stabilisants UV, des agents de stabilisation a la strict, des antistatigues, des anti-oxydants et des cires a base de polymeres.
  • La presente invention propose un agent de compatibilite multi- allowl gui
  • La presente invention concerne coordination un procede pour preparer la composition de polymere susdite, characterise en ce gu'on introduit le melange de polymeres, courtement pourvu des additifs susdits, dans la tremie d'une extrudeuse ou d'un melangeur.
  • Stamylan PHC 22 100% polypropylene 65%
  • Le melange de cet examples include est Psychitoneum a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, a, .
  • Le melange est moule par injection a une temperature de fusion de 230°C et une temperature du corps de la atrice de 40°C.
  • A:B:C:D 50-10:20-25:5-15:5-10 Melange Etirement Fluage Resi- Module Humidite a la lience de rupture IZOD flexion
  • A:B:C:D 30-40:10-25:20-30:0-5
  • Composition de polymeres selon 1' invention 5 A:B:C:D 60-80:10-20:5-15:5-25
  • Un melange Salmon de PVC (tres stable), de VLLDPE et d'une composition selon 1' invention procure un materiau gui demangee au PVC mou grass gui neflower pas de plastifiant. La rupture a 1'etirement est augmentee dans une tres grande measure.
  • Le melange est moule par injection a une temperature de fusion de 190° et une temperature de la matrice de 40°C.
  • L pression 10 bar et leesque de tours es possess (30 t/min). II s'avere gratisement gu 'u resultat optimal s Obtient apres melangeage suiv immediatement du moulage par injection dans un machine constitute au PVC.
  • Composition de polymeres selon 1'invention 5 A:B:C:D 60-80:10-20:5-15:5-25
  • A:B:C:D 60-80:10-20:9-15:5-25
  • Composition de polymeres selon 1' invention 5 A:B:C:D 60-80:10-20:5-25:5-25 Rupture a Fluage Resilience IZOD Module de 1'etirement flexion

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La composition de polymères selon l'invention comprend les additifs suivants à base de polymères dans les proportions suivantes: a) 1-89 parties pondérales d'un ou plusieurs copolymères d'éthylène-acétate de vinyle, pour augmenter les propriétés-barrière des composants de matière synthétique; b) 5-74 parties pondérales d'un ou plusieurs terpolymères à base d'éthyle, d'un composé acrylique et d'anhydride maléique; c) 5-25 parties pondérales d'un ou plusieurs caoutchoucs éthylène-propylène-diène et/ou caoutchouc trans-polyoctényl; et d) 0-69 parties pondérales d'un ou plusieurs copolymères en bloc styrène-butadiène ou styrène-isoprène-styrène et/ou copolymère éthylène-ester acrylique, pour augmenter la compatibilité des matières synthétiques contenant du styrène.
PCT/BE1992/000036 1991-09-02 1992-09-01 Composition d'additifs a base de polymeres Ceased WO1993005111A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BE9100817A BE1005364A5 (nl) 1991-09-02 1991-09-02 Samenstelling van polymeertoevoegstoffen voor kunststoffen werkwijze voor de voorbereiding en toepassing daarvan als compatibilisatoren.
BE9100817 1991-09-02

Publications (1)

Publication Number Publication Date
WO1993005111A1 true WO1993005111A1 (fr) 1993-03-18

Family

ID=3885680

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/BE1992/000036 Ceased WO1993005111A1 (fr) 1991-09-02 1992-09-01 Composition d'additifs a base de polymeres

Country Status (2)

Country Link
BE (1) BE1005364A5 (fr)
WO (1) WO1993005111A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0711809A1 (fr) * 1994-11-10 1996-05-15 TECNOFILM S.p.A. Composition thermoplastique ayant une résistance élevée à l'abraison

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0287140A1 (fr) * 1987-03-13 1988-10-19 van der Groep, Lambertus Adrianus Composition polymère, procédé pour sa fabrication, et l'application de cette composition
US4806597A (en) * 1987-10-29 1989-02-21 General Electric Company Composition comprising aromatic polycarbonate, polyolefin, ethylene vinyl alcohol copolymer, and a modified hydrogenated alkylidene vinyl aromatic block copolymer
EP0316037A1 (fr) * 1987-11-05 1989-05-17 van der Groep, Lambertus Adrianus Composition polymère, procédé pour sa fabrication et composition polymère thermoplastique
WO1990005759A1 (fr) * 1988-11-15 1990-05-31 Ferro Corporation Compositions polymeres compatibilisees avec des copolymeres de bloc styrene, et articles produits avec ces compositions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0287140A1 (fr) * 1987-03-13 1988-10-19 van der Groep, Lambertus Adrianus Composition polymère, procédé pour sa fabrication, et l'application de cette composition
US4806597A (en) * 1987-10-29 1989-02-21 General Electric Company Composition comprising aromatic polycarbonate, polyolefin, ethylene vinyl alcohol copolymer, and a modified hydrogenated alkylidene vinyl aromatic block copolymer
EP0316037A1 (fr) * 1987-11-05 1989-05-17 van der Groep, Lambertus Adrianus Composition polymère, procédé pour sa fabrication et composition polymère thermoplastique
WO1990005759A1 (fr) * 1988-11-15 1990-05-31 Ferro Corporation Compositions polymeres compatibilisees avec des copolymeres de bloc styrene, et articles produits avec ces compositions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0711809A1 (fr) * 1994-11-10 1996-05-15 TECNOFILM S.p.A. Composition thermoplastique ayant une résistance élevée à l'abraison

Also Published As

Publication number Publication date
BE1005364A5 (nl) 1993-07-06

Similar Documents

Publication Publication Date Title
Halimatudahliana et al. The effect of various compatibilizers on mechanical properties of polystyrene/polypropylene blend
Fayt et al. MOLECULAR DESIGN OF MULTICOMPONENT POLYMER SYSTEMS. XII. DIRECT OBSERVATION OF THE LOCATION OF A BLOCK COPOLYMER IN LOW-DENSITY POLYETHYLENE-POLYSTYRENE BLENDS.
CA2523890A1 (fr) Reseaux polymeres
WO2012080404A1 (fr) Copolymere polyamide-polyolefine
JP2003535176A (ja) 表面耐久性の改善されたポリオレフィン材料
WO1997046620A1 (fr) Thermoplastiques a flexibilite et transparence amelioree
EP0418129B1 (fr) Alliages à base d'un copolymère éthylène alcool vinylique à propriété barrière aux gaz, thermoformable et/ou résistant à la flexion répétée
CA2224504A1 (fr) Melanges de polymere a blocs polyamides et de copolymeres a motifs vinylaromatiques et motifs anhydride
US6255395B1 (en) Masterbatches having high levels of resin
US9631078B2 (en) Compatibilizer based on interpenetrating polymer networks (IPN) for recycling polymer blends
WO1993005111A1 (fr) Composition d'additifs a base de polymeres
EP1539879A1 (fr) Composition de polyolefine presentant une meilleure resistance a l'abrasion
EP0815172B1 (fr) Systeme de compatibilisation de polymeres immiscibles
FR2849855A1 (fr) Composition thermoplastiques renforcees aux chocs comprenant un polyamide et un copolymere a blocs
ES2412359T3 (es) Copolímeros de etileno-propileno adecuados para la modificación de aceites lubricantes y proceso para la preparación de los mismos
EP0605381B2 (fr) Compositions de polymères pour applications médicales
Lee et al. Preparation of poly (butylene terephthalate)/oxazoline containing polystyrene graft copolymer through melt-blending and their application as a compatibilizer in polycarbonate/polystyrene blend
JP3503352B2 (ja) 熱可塑性エラストマー組成物
EP1045007A1 (fr) Compositions de résines thermoplastiques comprenant une phase dispersée rigide
CA2474551A1 (fr) Composition de polymeres styreniques antistatiques
EP0811038A1 (fr) Composition comprenant un fluoroelastomere et un polyamide thermoplastique et film obtenu
Jeziórska Studies on reactive compatibilisation of polyamide 6/poly (butylene terephthalate) blends by low molecular weight bis-oxazoline
JP2001220513A (ja) 熱可塑性エラストマー組成物
JPH05239277A (ja) 熱可塑性成形材料
FR2618791A1 (fr) Compositions de polymeres comprenant du polyfluorure de vinylidene et un elastomere, leur preparation et leurs utilisations

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): FI JP US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
122 Ep: pct application non-entry in european phase