WO1994007984A1 - Detergent composition comprising lime soap dispersant and lipase enzymes - Google Patents
Detergent composition comprising lime soap dispersant and lipase enzymes Download PDFInfo
- Publication number
- WO1994007984A1 WO1994007984A1 PCT/US1993/008875 US9308875W WO9407984A1 WO 1994007984 A1 WO1994007984 A1 WO 1994007984A1 US 9308875 W US9308875 W US 9308875W WO 9407984 A1 WO9407984 A1 WO 9407984A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- alkyl
- detergent composition
- composition according
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
Definitions
- machine dishwashing or rinsing detergent products are free from chlorine bleaches or phosphate builder compounds.
- spotting and filming effects are known to be a particular problem for machine dishwashing and rinsing products containing no chlorine bleach and/or no phosphate builder compound.
- the machine dishwashing or rinsing detergent compositions of the present invention are of particular value when formulated as compositions containing no chlorine bleach and no phosphate builder compound since they provide the abovementioned mitigation of spotting and filming effects for these formulations where spotting and filming is known to be a particular problem.
- the aluminosilicate ion exchange materials can be naturally occurring materials, but are preferably synthetically derived. A method for producing aluminosilicate ion exchange materials is discussed in US Patent No. 3,985,669. Synthetic crystalline aluminosilicate ion exchange materials are available under the designations Zeolite A, Zeolite B, Zeolite P, Zeolite X, Zeolite HS and mixtures thereof. Zeolite A has the formula
- a lipase unit is defined as the amound of lipase which produces l umol of titratable butyric acid per minute in a pH stat, where pH is 7.0, temperature is 30°C, and substrate is an emulsion of ributyrin and gum arabic in the presence of Ca ++ and NaCl in phosphate buffer.
- Anionic sulfonate surfactants suitable for use herein include essentially any sulfonate surfactants including, for example, the salts (eg : alkali metal salts) of C5-C2 0 linear alkylbenzene sulfonates, C -C22 primary or secondary alkane sulfonates, C 6 -C 24 olefin sulfonates, sulfonated polycarboxylic acids, alkyl glycerol sulfonates, fatty acyl glycerol sulfonates, fatty oleyl glycerol sulfonates, paraffin sulfonates, and any mixtures thereof.
- the salts eg : alkali metal salts
- C5-C2 0 linear alkylbenzene sulfonates C -C22 primary or secondary alkane sulfonates
- Anionic alkyl ethoxy carboxylate surfactant Anionic alkyl ethoxy carboxylate surfactant
- the mixed ethoxylated/propoxylated fatty alcohols have an alkyl chain length of from 10 to 18 carbon atoms, a degree of ethoxylation of from 3 to 30 and a degree of propoxylation of from 1 to 10.
- a pholytic surfactants can be incorporated into the detergent compositions herein. These surfactants can be broadly described as aliphatic derivatives of secondary or tertiary amines, or aliphatic derivatives of heterocyclic secondary and tertiary amines in which the aliphatic radical can be straight chain or branched.
- One of the aliphatic substituents contains at least about 8 carbon atoms, typically from about 8 to about 18 carbon atoms, and at least one contains an anionic water-solubilizing group, e.g., carboxy, sulfonate, sulfate. See U.S. Patent No. 3,929,678 to Laughlin et al., issued December 30, 1975 at column 19, lines 18-35 for examples of ampholytic surfactants.
- the complex betaines for use herein have the formula R - (A) n - [N - (CHR ⁇ ) x ] y - N - Q (I)
- x can be O or an integer between 1 & 6.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Enzymes And Modification Thereof (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002145176A CA2145176C (en) | 1992-09-25 | 1993-09-20 | Detergent composition comprising lime soap dispersant and lipase enzymes |
| AT93922706T ATE201228T1 (de) | 1992-09-25 | 1993-09-20 | Verwendung einer kalkseifendispergator und lipasehaltige waschmittelzusammensetzung |
| EP93922706A EP0662118B1 (de) | 1992-09-25 | 1993-09-20 | Verwendung einer kalkseifendispergator und lipasehaltige waschmittelzusammensetzung |
| DE69330230T DE69330230T2 (de) | 1992-09-25 | 1993-09-20 | Verwendung einer kalkseifendispergator und lipasehaltige waschmittelzusammensetzung |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9220343.9 | 1992-09-25 | ||
| GB929220343A GB9220343D0 (en) | 1992-09-25 | 1992-09-25 | Detergent compositions |
| EP93870170 | 1993-08-13 | ||
| EP93870170.3 | 1993-08-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1994007984A1 true WO1994007984A1 (en) | 1994-04-14 |
Family
ID=26134995
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1993/008875 Ceased WO1994007984A1 (en) | 1992-09-25 | 1993-09-20 | Detergent composition comprising lime soap dispersant and lipase enzymes |
Country Status (5)
| Country | Link |
|---|---|
| AT (1) | ATE201228T1 (de) |
| CA (1) | CA2145176C (de) |
| DE (1) | DE69330230T2 (de) |
| ES (1) | ES2156586T3 (de) |
| WO (1) | WO1994007984A1 (de) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995004806A1 (en) * | 1993-08-10 | 1995-02-16 | The Procter & Gamble Company | Manual dishwashing composition comprising lipase enzymes and lime soap dispersant |
| WO1997043379A1 (en) * | 1996-05-15 | 1997-11-20 | The Procter & Gamble Company | Detergent compositions comprising specific lipolytic enzyme and lime soap dispersant |
| US5772786A (en) * | 1993-08-13 | 1998-06-30 | The Procter & Gamble Company | Detergent composition comprising lime soap dispersant and lipase enzymes |
| EP0835925A3 (de) * | 1996-09-09 | 1999-01-27 | Unilever N.V. | Maschinengeschirrspülmittelzusammensetzung enthaltend amphotere Polymere |
| US5963658A (en) * | 1997-01-27 | 1999-10-05 | University Of North Carolina | Method and apparatus for detecting an abnormality within a host medium |
| EP1090978A1 (de) * | 1999-10-09 | 2001-04-11 | Cognis Deutschland GmbH, Dep. Intellectual Properties | Feste Wasch-, Spül- und Reinigungsmittel enthaltend Entschäumergranulate |
| WO2007087258A3 (en) * | 2006-01-23 | 2008-12-04 | Procter & Gamble | A composition comprising a lipase and a bleach catalyst |
| RU2395565C2 (ru) * | 2006-01-23 | 2010-07-27 | Дзе Проктер Энд Гэмбл Компани | Композиция, содержащая липазу и катализатор отбеливания |
| US7786067B2 (en) | 2006-01-23 | 2010-08-31 | The Procter & Gamble Company | Composition comprising a lipase and a bleach catalyst |
| US9138393B2 (en) | 2013-02-08 | 2015-09-22 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for improving the appearance of aging skin |
| US9144538B2 (en) | 2013-02-08 | 2015-09-29 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for alleviating the signs of photoaged skin |
| WO2017220422A1 (en) * | 2016-06-23 | 2017-12-28 | Novozymes A/S | Use of enzymes, composition and method for removing soil |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1987000859A1 (en) * | 1985-08-09 | 1987-02-12 | Gist-Brocades N.V. | Novel lipolytic enzymes and their use in detergent compositions |
| EP0271153A2 (de) * | 1986-12-10 | 1988-06-15 | Unilever N.V. | Enzyme enthaltendes Reinigungsmittel |
| US4797223A (en) * | 1988-01-11 | 1989-01-10 | Rohm And Haas Company | Water soluble polymers for detergent compositions |
| EP0373850A1 (de) * | 1988-12-12 | 1990-06-20 | Unilever Plc | Enzymhaltige Detergenszusammensetzungen und ihre Verwendung |
| US4959179A (en) * | 1989-01-30 | 1990-09-25 | Lever Brothers Company | Stabilized enzymes liquid detergent composition containing lipase and protease |
| US5069809A (en) * | 1988-05-09 | 1991-12-03 | Lever Brothers Company, Division Of Conopco, Inc. | Enzymatic detergent and bleaching composition containing a specific rdna technique cloned lipase |
| US5078898A (en) * | 1987-11-02 | 1992-01-07 | Novo Nordisk A/S | Detergent compositions comprising pseudomonas lipase and a specific protease |
-
1993
- 1993-09-20 ES ES93922706T patent/ES2156586T3/es not_active Expired - Lifetime
- 1993-09-20 AT AT93922706T patent/ATE201228T1/de not_active IP Right Cessation
- 1993-09-20 CA CA002145176A patent/CA2145176C/en not_active Expired - Fee Related
- 1993-09-20 WO PCT/US1993/008875 patent/WO1994007984A1/en not_active Ceased
- 1993-09-20 DE DE69330230T patent/DE69330230T2/de not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1987000859A1 (en) * | 1985-08-09 | 1987-02-12 | Gist-Brocades N.V. | Novel lipolytic enzymes and their use in detergent compositions |
| EP0271153A2 (de) * | 1986-12-10 | 1988-06-15 | Unilever N.V. | Enzyme enthaltendes Reinigungsmittel |
| US5078898A (en) * | 1987-11-02 | 1992-01-07 | Novo Nordisk A/S | Detergent compositions comprising pseudomonas lipase and a specific protease |
| US4797223A (en) * | 1988-01-11 | 1989-01-10 | Rohm And Haas Company | Water soluble polymers for detergent compositions |
| US5069809A (en) * | 1988-05-09 | 1991-12-03 | Lever Brothers Company, Division Of Conopco, Inc. | Enzymatic detergent and bleaching composition containing a specific rdna technique cloned lipase |
| EP0373850A1 (de) * | 1988-12-12 | 1990-06-20 | Unilever Plc | Enzymhaltige Detergenszusammensetzungen und ihre Verwendung |
| US4959179A (en) * | 1989-01-30 | 1990-09-25 | Lever Brothers Company | Stabilized enzymes liquid detergent composition containing lipase and protease |
Non-Patent Citations (2)
| Title |
|---|
| LINFIELD, Tenside Sust. Det., Volume 27, pages 159-161 (1990). * |
| NAGARAJAN and MASLER, Polymeric Lime Soap Dispersants, Cosmetic and Toiletries, Volume 104, pages 71-73 (1989). * |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995004806A1 (en) * | 1993-08-10 | 1995-02-16 | The Procter & Gamble Company | Manual dishwashing composition comprising lipase enzymes and lime soap dispersant |
| US5772786A (en) * | 1993-08-13 | 1998-06-30 | The Procter & Gamble Company | Detergent composition comprising lime soap dispersant and lipase enzymes |
| WO1997043379A1 (en) * | 1996-05-15 | 1997-11-20 | The Procter & Gamble Company | Detergent compositions comprising specific lipolytic enzyme and lime soap dispersant |
| EP0835925A3 (de) * | 1996-09-09 | 1999-01-27 | Unilever N.V. | Maschinengeschirrspülmittelzusammensetzung enthaltend amphotere Polymere |
| US5963658A (en) * | 1997-01-27 | 1999-10-05 | University Of North Carolina | Method and apparatus for detecting an abnormality within a host medium |
| EP1090978A1 (de) * | 1999-10-09 | 2001-04-11 | Cognis Deutschland GmbH, Dep. Intellectual Properties | Feste Wasch-, Spül- und Reinigungsmittel enthaltend Entschäumergranulate |
| WO2007087258A3 (en) * | 2006-01-23 | 2008-12-04 | Procter & Gamble | A composition comprising a lipase and a bleach catalyst |
| RU2395565C2 (ru) * | 2006-01-23 | 2010-07-27 | Дзе Проктер Энд Гэмбл Компани | Композиция, содержащая липазу и катализатор отбеливания |
| US7786067B2 (en) | 2006-01-23 | 2010-08-31 | The Procter & Gamble Company | Composition comprising a lipase and a bleach catalyst |
| US8022027B2 (en) | 2006-01-23 | 2011-09-20 | The Procter & Gamble Company | Composition comprising a lipase and a bleach catalyst |
| US9138393B2 (en) | 2013-02-08 | 2015-09-22 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for improving the appearance of aging skin |
| US9144538B2 (en) | 2013-02-08 | 2015-09-29 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for alleviating the signs of photoaged skin |
| WO2017220422A1 (en) * | 2016-06-23 | 2017-12-28 | Novozymes A/S | Use of enzymes, composition and method for removing soil |
| US11001787B2 (en) | 2016-06-23 | 2021-05-11 | Novozymes A/S | Use of enzymes, composition and method for removing soil |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2145176A1 (en) | 1994-04-14 |
| DE69330230D1 (de) | 2001-06-21 |
| DE69330230T2 (de) | 2002-02-28 |
| ES2156586T3 (es) | 2001-07-01 |
| CA2145176C (en) | 1999-07-13 |
| ATE201228T1 (de) | 2001-06-15 |
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