WO1994009357A1 - Procede de determination de la concentration d'une substance active renfermant un traceur dans des solutions de substance active - Google Patents

Procede de determination de la concentration d'une substance active renfermant un traceur dans des solutions de substance active Download PDF

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Publication number
WO1994009357A1
WO1994009357A1 PCT/EP1993/002702 EP9302702W WO9409357A1 WO 1994009357 A1 WO1994009357 A1 WO 1994009357A1 EP 9302702 W EP9302702 W EP 9302702W WO 9409357 A1 WO9409357 A1 WO 9409357A1
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WO
WIPO (PCT)
Prior art keywords
concentration
solution
cleaning
wavelength
light
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1993/002702
Other languages
German (de)
English (en)
Inventor
Thomas Müller-Kirschbaum
Alfred Laufenberg
Thomas VIENENKÖTTER
Mike Varpins
Alfred Werner-Busse
Friedhelm Siepmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to EP93921908A priority Critical patent/EP0664883A1/fr
Priority to FI951710A priority patent/FI951710A7/fi
Priority to JP6509574A priority patent/JPH08502359A/ja
Publication of WO1994009357A1 publication Critical patent/WO1994009357A1/fr
Priority to NO950429A priority patent/NO950429L/no
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
    • B08B9/08—Cleaning containers, e.g. tanks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Disinfection or sterilisation of materials or objects, in general; Accessories therefor
    • A61L2/26—Accessories
    • A61L2/28—Devices for testing the effectiveness or completeness of sterilisation or disinfection, e.g. indicators which change colour
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
    • B08B9/08—Cleaning containers, e.g. tanks
    • B08B9/20—Cleaning containers, e.g. tanks by using apparatus into or on to which containers, e.g. bottles, jars, cans are brought
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64—Fluorescence; Phosphorescence
    • G01N21/6428—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
    • G01N21/643—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes" non-biological material

Definitions

  • the invention relates to a method for determining the concentration of an active ingredient containing a tracer in aqueous or non-aqueous active ingredient solutions, in particular for cleaning or disinfecting containers such as bottles, kegs, boxes and tanks and / or pipelines in the food processing industry and be used for industrial cleaning in continuous washing systems, the concentration of the active ingredient in the solution being measured by determining its tracer content.
  • Such methods are preferably used in continuous cleaning systems in which the objects to be cleaned pass through cleaning solutions or disinfectant solutions, e.g. in bottle cleaning machines, container washing machines, cleaning systems for cleaning closed systems, such as pipes and tanks (ClP systems), and cleaning systems for metallic parts and textiles.
  • cleaning solutions or disinfectant solutions e.g. in bottle cleaning machines, container washing machines, cleaning systems for cleaning closed systems, such as pipes and tanks (ClP systems), and cleaning systems for metallic parts and textiles.
  • phase separation In cleaning systems for closed systems (ClP systems) in which the cleaning and disinfection solution is used several times, dilution effects also occur, for example, due to mixed phases in the pre-rinsing and post-rinsing.
  • stacking used cleaning solutions which are usually pushed out of the pipelines with fresh water, it is necessary to control up to what point in time or whether the returning solution is fed into the stacking container and from when the concentration of cleaning or disinfectant in the rinse water Collecting is no longer worthwhile and, above all, from what rinsing time the system can be refilled with food without fear of contamination with cleaning or disinfection chemicals. This process in CIP cleaning is referred to as "phase separation".
  • the precise measurement of the cleaning agent and disinfectant concentration in the cleaning or disinfecting solution or in the rinse water is of paramount importance.
  • the active substance concentrations in cleaning should be kept within narrow limits. For example, when cleaning refillable PET bottles (PET "polyethylene terephthalate), concentrations that are too high lead to stress corrosion cracking; if concentrations are too low, the bottles are also attacked and the cleaning result is insufficient.
  • the last step is often a disinfection step. In particular, contamination of foodstuffs with the frequently toxic disinfectants must be avoided and the rinsing process must therefore be monitored particularly carefully.
  • the previously known methods for determining the concentration have disadvantages.
  • the conductivity measurement is carried out as an online measurement method. So that fluctuations in the conductance
  • the safe implementation of this method requires a relatively high conductance of the active substance solution of at least 3 to 4 mS in the tap water, which only requires strongly alkaline, strongly acidic or high concentrations of others to result in measurement errors Solutions containing electrolytes is achieved.
  • metering proportional to the bottle throughput Another type of metering of active ingredient concentrates which is customary in practice is metering proportional to the bottle throughput. This method is based on the consideration that each bottle with the bottle cell carries a constant amount of cleaning solution out of the bath. Depending on the petrification of the bottle cells, the foam behavior of the solution and the control of the liquid flows between the different baths of industrial bottle cleaning machines changes this amount however. From operational practice it is known that when dosing according to the methods mentioned, the actual detergent concentration can deviate from the target concentration by 50% or more within a few days. If there are technical defects in the metering device, these can only be recognized and corrected after the complex manual concentration determination carried out at intervals of 1 to 5 days. In these cases, fluctuations in concentration occur in practice by a factor of up to about 40.
  • the object of the invention is therefore to create a solution with which a determination of the active substance concentration and, if necessary, a subsequent dosing is possible reliably, precisely, quickly, with little susceptibility to faults and continuously.
  • This object is achieved according to the invention with a method of the type described at the outset in that a fluorescent dye is used as the tracer and the fluorescent dye concentration in the solution is measured optically and the concentration of the active ingredient is determined accordingly from the measured values obtained.
  • the use of a fluorescence tracer has the great advantage over other tracer substances, such as, for example, potassium iodide, because of a greater chemical similarity, for example with regard to the molecular size, of the compounds which are active in cleaning and disinfection (surface-active) Substances) or the defoamers Behavior with regard to distribution, diffusion, absorption and thus drag-out.
  • concentration can be determined by fluorescence spectrometry using an optical system, the concentration of the fluorescent dye correlating directly with the concentration of the active substances, and a dosage control to avoid overdosing and underdosing is thus possible.
  • the fluorescent dye concentration is measured with the aid of an inline fluorescence sensor system and that the fluorescent dye concentration in the solution is between 0.01 and 10,000 ppm, in particular between 0.1 and 2,500 ppm.
  • the turbidity of the solution is determined simultaneously with the measurement of the fluorescent dye concentration, which is immediately possible.
  • the fluorescence measurement is carried out with the aid of a fiber optic directly in the solution to be measured or with the aid of a part of the solution which is continuously removed in the side stream.
  • the incident light contains only the wavelength of the excitation spectrum which is backscattered in the solution and by at least two filters in the proportion of the backscattered light with the excitation wavelength and the proportion of the light is divided with the emission wavelength, the portion of the backscattered light of the excitation wavelength being used for measuring the turbidity and the portion of the backscattered light of the emission wavelength being used for measuring the active substance concentration.
  • the fluorescence measurement is carried out in a side stream, it is preferably provided that the incident light at the long-wave end of the spectrum contains at most the excitation wavelength of the fluorescent dye, that only the wavelength range from the light emitted at right angles from the solution is used. in which the emission wavelength represents the minimum or contains only the emission wavelength itself, and that the opacity of the solution is determined by transmitted light without or after filtering to exclude the wavelength above the excitation wavelength with the aid of intensity measurements.
  • Salicylic acid or its salts in particular sodium salicylate, alkylbenzenesulfonates, e.g. Isopropylbenzenesulfonate, optical brighteners from the field of detergent production, fluorescein or sodium 3-oxypyrenetrisulfonic acid have been found to be advantageous.
  • the concentration of the active substance is determined from the measured intensity by means of a calibration curve which has been determined by measured intensities of at least two different concentrations of the active substance in the solution to be monitored.
  • the active substance containing the fluorescent dye is metered or metered in aqueous or non-aqueous active substance solution, the metering or metering being controlled by a regulating device which verifies the actual concentration determined with a predetermined target concentration ⁇ is the same.
  • pre-rinse and rinse water in cleaning systems for closed systems are separated from the aqueous or non-aqueous active ingredient solutions in which the phase - J o -
  • Separation is controlled by a device which compares the determined concentration of the active ingredient with a predetermined target concentration and controls control devices, for example valves, for phase separation in accordance with the comparison result.
  • the method can be used advantageously for measuring the active substance concentration in the caustic baths and water zones of industrial bottle cleaning machines, for measuring the active substance concentration of cleaning or disinfectant solutions for closed systems (ClP systems) in the food industry or for measuring the active substance Use substance concentrations in industrial continuous washing plants, in particular for the cleaning of metal sheets or textiles, the objects to be cleaned, which run through, carry out a part of the active substance solution from the active substance baths.
  • FIG. 1 is a schematic diagram of a device for carrying out the method according to the invention
  • Fig. 2 shows another device for performing the method and in the
  • the light is then guided to a measuring head 4 via the fiber optics 3.
  • a second fiber bundle backscattered light is guided via a rapidly rotating filter wheel 5 onto a light-sensitive electronic component 6, for example a photodiode.
  • the filter wheel contains on the one hand a filter which corresponds in wavelength to the excitation wavelength of the dye, and on the other hand contains a filter which has a wavelength in a spectral range the emission wavelength.
  • the filters and the dye must be selected so that the wavelength ranges of the filters do not overlap and the absorption and emission wavelengths of the dye are sufficiently far apart.
  • the intensity received by the light-sensitive sensor from the wavelength range of the absorption spectrum corresponds to the backscattered portion of light in the solution and is a measure of the cloudiness and thus contamination of the cleaning or disinfecting solution.
  • the intensity in the range of the emission wavelength is a direct measure of the concentration of the fluorescent dye in the cleaning or disinfecting solution and correlates with the active substance content to be tracked.
  • the arrangement with an optical fiber optic has, in addition to the above-mentioned basic advantages of using a fluorescence marker, the additional advantage that the measuring head 4 can be used at any point within closed pipe systems directly in the pipe within the liquid flow. - I -
  • the structure shown in FIG. 2, which is mounted in a housing 14, can be used as an example.
  • the cleaning or disinfection solution flows in from below through a flow-through cell 10 and flows out at the cuvette head, so that air and foam bubbles that have been introduced are in any case easily discharged from the inside of the cuvette with the liquid flow directed against gravity.
  • a light source 1 a which emits a spectrum containing the excitation wavelength with sufficient intensity, is located in a light-tight housing 2 a, which contains a bushing for an electrical connection 3 a and a light outlet 4 a, which can be represented by a suitable lens.
  • the propagating light cone or the light bundle parallelized by the lens passes through an optical filter 5a, which either passes only the wavelength range of the excitation (bandpass) or only a wavelength range that contains the excitation wavelength as the maximum wavelength (shortpass).
  • the filtered light beam is converted into a parallel light beam by an optional aperture 6a, which is narrower in width than the cuvette.
  • light of the excitation wavelength is partially absorbed by the fluorescent dye present in the cleaning or disinfecting solution.
  • the dye molecules emit light in all directions in accordance with the emission wavelength. Light is also deflected and scattered by turbidities present in the cleaning or disinfecting solution.
  • a filter 8 Through a diaphragm 7 arranged orthogonally to the direction of incidence, fluorescent light reaches a filter 8.
  • This filter only allows light of the emission wavelength (bandpass) or a wavelength range in which the absorption wavelength represents the lower limit (longpass). This ensures that only fluorescent light is detected by the light-sensitive detector device 9 located behind the filter 8.
  • Light emerging from the cuvette 10 in the direction of irradiation strikes a filter 12 through an aperture 11.
  • This filter is optional and can be omitted with the advantage of the higher light intensity. If a filter is installed, a filter can be selected which transmits the excitation spectrum (bandpass) or in which the excitation wavelength corresponds to the upper limit of the transmission range (short pass). In a straight line you will notice the light-sensitive measuring device 13 light which has passed through the cuvette. Its intensity is determined by the cloudiness of the cleaning and disinfecting solution.
  • the dye pyranine is used.
  • the excitation wavelength in the pH range above pH 7 is 450 nm
  • the emission wavelength is 520 nm.
  • Filter 5a is a short pass with a cutoff wavelength of 450 nm
  • filter 8 is a long pass with a cutoff wavelength of 500 nm or a bandpass filter 520 nm and a specified spectral width of +/- 10 nm
  • the filter 12 and the lens 4a are omitted.
  • the light source la is a halogen direct current lamp
  • the light-sensitive detectors 9, 13 are two structurally identical photodiodes which react in the spectral range from 250 to 1,100 nm to incident light with a proportional voltage signal.
  • Test measurements relate to a typical cleaning bath and pure water as a solvent and a cleaning bath in which the dye solution is gradually diluted
  • FIG. 3 and 4 show the measurement signal (diode voltage in volts) obtained perpendicular to the direction of irradiation with the diode 9 for the fluorescence component as a function of the concentration of the fluorescence tracer pyranine in ppm.
  • the intensities are expected to be lower when using a bandpass filter, for example for a wavelength of 520 nm (FIG. 3) - about ten times as expected than when using a long pass filter, in the example for wavelengths above 500 nm (FIG.
  • the measurement signal (diode voltage in volts) for the intensity of the transmitted light (transmitted light component) as a function of the concentration of the fluorescence tracer pyranine in ppm.
  • the measured values for water are again marked with squares, those for strongly cloudy cleaning baths with circles and those for the cleaning bath diluted with water with triangles.
  • the measurements clearly show the influence of turbidity on the transmitted light, which is measured with the diode 13. With increasing tracer content, the intensity decreases linearly in a straight line direction even with constant turbidity, because a growing proportion of the irradiated primary intensity is emitted in lateral directions.
  • the diode 9 can be used to convert the turbidity of the cleaning or disinfection solution without the fluorescent dye component (indicated in the diode voltage of the transmitted light signal) in a simple manner, as the surprisingly empirically found nutritional formula shows: - -
  • TRcp £ turbidity in the solution with the concentration CF (in ppm) of the fluorescent dye (in V),

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Immunology (AREA)
  • General Health & Medical Sciences (AREA)
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  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • General Physics & Mathematics (AREA)
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  • Analytical Chemistry (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)
  • Cleaning In General (AREA)

Abstract

Procédé de détermination de la concentration d'une substance active renfermant un traceur dans des solutions aqueuses ou non aqueuses de substance active. La concentration est mesurée par détermination de sa teneur en traceur. On utilise comme traceur un colorant fluorescent, la concentration en colorant fluorescent dans la solution étant mesurée par voie optique, ce qui permet d'obtenir à partir des valeurs mesurées, la concentration en substance active. Cette concentration peut être déterminée, avec possibilité, le cas échéant, d'un dosage complémentaire, de façon fiable, précise, rapide, avec peu de risque de perturbation, et en continu.
PCT/EP1993/002702 1992-10-13 1993-10-04 Procede de determination de la concentration d'une substance active renfermant un traceur dans des solutions de substance active Ceased WO1994009357A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP93921908A EP0664883A1 (fr) 1992-10-13 1993-10-04 Procede de determination de la concentration d'une substance active renfermant un traceur dans des solutions de substance active
FI951710A FI951710A7 (fi) 1992-10-13 1993-10-04 Menetelmä merkkiainetta sisältävän tehoaineen konsetraation määrittämi seksi tehoaineliuoksessa
JP6509574A JPH08502359A (ja) 1992-10-13 1993-10-04 活性物質溶液中のトレーサーを含む活性物質濃度の決定方法
NO950429A NO950429L (no) 1992-10-13 1995-02-06 Fremgangsmåte for bestemmelse av konsentrasjonen av en tracerholdig aktiv bestanddel i en opplösning av den aktive bestanddel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4234466A DE4234466A1 (de) 1992-10-13 1992-10-13 Verfahren zum Bestimmen der Konzentration eines einen Tracer enthaltenden Wirkstoffes in Wirkstofflösungen
DEP4234466.2 1992-10-13

Publications (1)

Publication Number Publication Date
WO1994009357A1 true WO1994009357A1 (fr) 1994-04-28

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PCT/EP1993/002702 Ceased WO1994009357A1 (fr) 1992-10-13 1993-10-04 Procede de determination de la concentration d'une substance active renfermant un traceur dans des solutions de substance active

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EP (1) EP0664883A1 (fr)
JP (1) JPH08502359A (fr)
DE (1) DE4234466A1 (fr)
FI (1) FI951710A7 (fr)
WO (1) WO1994009357A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0680694A3 (fr) * 1994-05-02 1996-01-10 Nalco Chemical Co Compositions des biocides fluorescentes pour utilisation dans des systèmes aqueux.
US5919707A (en) * 1994-12-22 1999-07-06 Nalco Chemical Company Monitoring of rolling oil emulsions
WO2001017356A1 (fr) * 1999-09-03 2001-03-15 Avecia Limited Polymere antimicrobien
WO2006135938A2 (fr) 2005-06-17 2006-12-21 Nalco Company Methode fluorometrique de surveillance de systeme de nettoyage en place
CN101454434B (zh) * 2006-05-22 2011-11-16 迪瓦西公司 清洗玻璃容器的方法
CN101080484B (zh) * 2004-12-17 2012-11-14 迪瓦西公司 润滑传送机系统的方法
CN109983339A (zh) * 2016-11-14 2019-07-05 株式会社竹中工务店 地基注入剂浓度推定系统

Families Citing this family (16)

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DE4440667C2 (de) * 1994-11-04 1997-01-09 Inst Bioprozess Analysenmesst Verfahren und Vorrichtung zur Ermittlung vorbestimmter chemischer Substanzen
GB9422392D0 (en) * 1994-11-05 1995-01-04 Cognitive Solutions Ltd Detector for chemical analysis
EP0764479B1 (fr) * 1995-09-22 1999-06-30 GEA Till GmbH & Co. Procédé de nettoyage des récipients
US5658798A (en) * 1996-02-08 1997-08-19 Nalco Chemical Company Detection of process components in food process streams by fluorescence
US5922606A (en) * 1997-09-16 1999-07-13 Nalco Chemical Company Fluorometric method for increasing the efficiency of the rinsing and water recovery process in the manufacture of semiconductor chips
DE19945392A1 (de) * 1999-09-22 2001-03-29 Robert Nusko Gerät zur Bestimmung von Tensidgehalten
DE10048391A1 (de) * 2000-09-29 2002-04-25 Schuelke & Mayr Gmbh UV-A-Tracer-haltige Desinfektionsmittel und Verfahren zur Bestimmung des Verdünnungsgrades von Desinfektionsmitteln mittels UV-A-Tracer
DE10257716B4 (de) * 2002-12-11 2005-12-29 Institut für Textilchemie der Deutschen Institute für Textil- und Faserforschung Stuttgart Optischer Sensor zur Bestimmung von Farbstoffkonzentrationen in flüssigen Medien und Verfahren zu dessen Betrieb
WO2004071681A1 (fr) * 2003-02-13 2004-08-26 Cleansolve Holding Aps. Surveillance et gestion d'un processus de nettoyage, et controle de la proprete
DE102004060431B4 (de) * 2004-12-14 2006-10-19 Walter Werne Vorrichtung zur Ermittlung der Gemischzusammensetzung beliebiger Medien
DE102007016237A1 (de) * 2007-04-04 2008-10-09 Fink Tec Gmbh Verfahren zur Bestimmung der Konzentration mindestens eines in einem Nutzfluidum gelösten Stoffes
US20130078730A1 (en) * 2011-09-23 2013-03-28 Michael J. Murcia Method for monitoring and control of a wastewater process stream
DE102011015188A1 (de) * 2010-03-29 2011-09-29 Herbert Kannegiesser Gmbh Verfahren zur Nassbehandlung, insbesondere zum Reinigen, von Gegenständen
US8352207B2 (en) * 2010-03-31 2013-01-08 Ecolab Usa Inc. Methods for calibrating a fluorometer
US9937535B2 (en) 2013-03-14 2018-04-10 Ecolab Usa Inc. Method and system for operating a CIP pre-flush step using fluorometric measurements of soil content
CN108444878B (zh) * 2018-04-20 2024-03-26 浙江大学 一种便携式航空喷施作业的雾滴沉积效果测量装置和方法

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FR1019006A (fr) * 1950-05-24 1953-01-15 Procédé d'auto-contrôle colorimétrique de la concentration d'une solution détersive
US4475813A (en) * 1982-08-30 1984-10-09 Milton Roy Company Divergent light optical systems for liquid chromatography
US4783314A (en) * 1987-02-26 1988-11-08 Nalco Chemical Company Fluorescent tracers - chemical treatment monitors
EP0320086A2 (fr) * 1987-12-11 1989-06-14 Diversey Corporation Traceur analytique visuel et méthode pour la détection et l'analyse quantitative de produits chimiques de traitement de l'eau
EP0365815A1 (fr) * 1988-10-14 1990-05-02 Nalco Chemical Company Surveillance continue dans le courant d'eau d'une tour de refroidissement

Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
FR1019006A (fr) * 1950-05-24 1953-01-15 Procédé d'auto-contrôle colorimétrique de la concentration d'une solution détersive
US4475813A (en) * 1982-08-30 1984-10-09 Milton Roy Company Divergent light optical systems for liquid chromatography
US4783314A (en) * 1987-02-26 1988-11-08 Nalco Chemical Company Fluorescent tracers - chemical treatment monitors
EP0320086A2 (fr) * 1987-12-11 1989-06-14 Diversey Corporation Traceur analytique visuel et méthode pour la détection et l'analyse quantitative de produits chimiques de traitement de l'eau
EP0365815A1 (fr) * 1988-10-14 1990-05-02 Nalco Chemical Company Surveillance continue dans le courant d'eau d'une tour de refroidissement

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0680694A3 (fr) * 1994-05-02 1996-01-10 Nalco Chemical Co Compositions des biocides fluorescentes pour utilisation dans des systèmes aqueux.
CN1069162C (zh) * 1994-05-02 2001-08-08 诺尔科化学公司 用作改进的抗微生物剂的荧光杀生物剂组合物
US5919707A (en) * 1994-12-22 1999-07-06 Nalco Chemical Company Monitoring of rolling oil emulsions
WO2001017356A1 (fr) * 1999-09-03 2001-03-15 Avecia Limited Polymere antimicrobien
US6706855B1 (en) 1999-09-03 2004-03-16 Avecia Limited Antimicrobial polymer
CN101080484B (zh) * 2004-12-17 2012-11-14 迪瓦西公司 润滑传送机系统的方法
WO2006135938A2 (fr) 2005-06-17 2006-12-21 Nalco Company Methode fluorometrique de surveillance de systeme de nettoyage en place
EP1891418A4 (fr) * 2005-06-17 2013-07-10 Nalco Co Methode fluorometrique de surveillance de systeme de nettoyage en place
CN101454434B (zh) * 2006-05-22 2011-11-16 迪瓦西公司 清洗玻璃容器的方法
CN109983339A (zh) * 2016-11-14 2019-07-05 株式会社竹中工务店 地基注入剂浓度推定系统

Also Published As

Publication number Publication date
EP0664883A1 (fr) 1995-08-02
FI951710A0 (fi) 1995-04-10
JPH08502359A (ja) 1996-03-12
FI951710L (fi) 1995-04-10
FI951710A7 (fi) 1995-04-10
DE4234466A1 (de) 1994-04-14

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