WO1994010355A1 - Tole d'acier lamine a chaud a haute resistance excellente en allongement uniforme apres ecrouissage a froid et son procede de production - Google Patents
Tole d'acier lamine a chaud a haute resistance excellente en allongement uniforme apres ecrouissage a froid et son procede de production Download PDFInfo
- Publication number
- WO1994010355A1 WO1994010355A1 PCT/JP1993/001580 JP9301580W WO9410355A1 WO 1994010355 A1 WO1994010355 A1 WO 1994010355A1 JP 9301580 W JP9301580 W JP 9301580W WO 9410355 A1 WO9410355 A1 WO 9410355A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- steel
- steel sheet
- rolled steel
- uniform elongation
- strength hot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/021—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving particular fabrication steps or treatments of ingots or slabs
Definitions
- the present invention relates to a hot-rolled steel sheet for general and welded structures having excellent uniform elongation after cold working and high tensile strength, and a method for producing the same.
- Japanese Patent Application Laid-Open No. 57-16118 discloses a method for producing an electric resistance welded steel pipe for a low yield ratio oil well in which the C content is increased to 0.26 to 0.48%. Methods for producing a high yield strength ERW steel pipe with a low yield ratio of 0.10 to 0.20% are disclosed.In each case, a hot-rolled steel sheet with a low yield ratio is produced, and then the work hardening amount in cold forming is reduced. This is a method of manufacturing an electric resistance welded steel pipe that does not require heat treatment and is processed by limiting the amount of strain so that it does not become large. Further, Japanese Patent Application Laid-Open No.
- HEI 4-176818 discloses a ferrite without distortion and a P / R.
- a method for producing a steel pipe or a square pipe with excellent shochu characteristics obtained by controlling the cooling rate after the hot working and heat treatment of the phase structure has been proposed.
- the former does not always meet the demands of the industry, such as significantly impairing the weldability.
- JP-A-4-48048 discloses an oxide-based inclusion having a (Ti, Nb) (0, N) composite crystal phase of 0.5111 or less in a matrix of steel.
- JP-A-Hei 4-99248 states that oxide inclusions having a Ti ( ⁇ , N) compound crystal phase of 1 ⁇ m or less in the base metal of a steel are dispersed respectively to form a weld heat-affected zone.
- a technique for improving toughness is disclosed, the disperse phase and the purpose thereof are essentially different from the present invention.
- the higher the strength of the steel the higher the yield ratio and the lower the ductility, and therefore the lower the uniform elongation.
- uniform elongation is significantly reduced due to the effect of work hardening due to work strain.
- the present invention solves such a problem, and has excellent uniform elongation even after ordinary cold forming that does not reduce productivity into round and square steel pipes, section steel sheet piles, and the like. and high tensile strength (34Kgf ⁇ 2 or higher) and to provide a hot rolled steel sheet and a manufacturing method thereof. Disclosure of the invention
- the present inventors investigated in detail the chemical composition of steel, the relationship between the crystal structure and the obtained mechanical properties, and the relationship between the mechanical properties after cold forming and that of the material. Studied.
- the general contact and welding structural steel the most tension is used intensity.
- 34 to 62KgfZ Jour secondary hot-rolled steel sheet particularly for civil construction, between the left tensile strength and uniform elongation hot rolled The correlation (uniform elongation decreases as tensile strength increases) and their correlation after cold forming almost match and can be approximated by the same curve.
- N in steel increases, the material also increases.
- the strength of the cold-worked material also increases and the uniform elongation decreases, but when Ti is further added, the uniform elongation recovers and the above relationship is deviated, and even with high strength, a high uniform elongation can be obtained. I found that.
- FIG. Fig. 2 shows steel types S-1 and T-1 using the steel types S-1 (comparative example), S-2 (comparative example) and T-1 and T-2 (inventive examples) shown in Table 1.
- T-1 2 are the production processes B and S-2 shown in Table 2 are the TS (kgf / mm 2 ) of the as-rolled steel produced in production process C and the steel cold-worked into square steel pipes.
- FIG. 3 is a diagram showing a relationship between tensile strength) and Elu (%) (negative elongation).
- the steel of the present invention has excellent properties as general and welded structural steel.
- the present invention has been constructed based on these findings.
- C 0.040 to 0.25%
- N 0.0050 to 0.0150%
- Ti 0.003 to 0.050%
- TiN with a particle size of more than 1 m dispersed in the matrix at a rate of 0.0008 to 0.015%.
- Ceq. (WBS) is set to 0.10 to 0.45%, and a slab containing the above components is heated to 1000 to 1300 ° C for hot rolling and rolled, and rolled at a temperature not lower than the Ar 3 transformation point.
- % High tensile strength of 34 to 62 kgfZ band 2 which is excellent in uniform elongation after cold forming and a method for producing the same.
- Fig. 1 (A) is a 400X magnification micrograph showing the metallographic structure of the square section of the square steel pipe of the steel of the present invention (Table 4, No. T-2 (MID part, containing 15.2% of pearlite phase)). It is.
- FIG. 2 is a graph showing the relationship between tensile strength and uniform elongation of various hot rolled steel sheets and square steel pipes shown in Table 4.
- a molten steel produced in a melting furnace such as a converter or an electric furnace is manufactured into a steel slab through a continuous forging or ingot-bulking process, whereby C: 0.040 ⁇ 0.25%, N: 0.0050 ⁇ 0.0150% Ti: 0.003 ⁇ 0.050%, and carbon equivalent (Ceq.) Is in the range of 0.10 ⁇ 0.45%, low alloy consisting of the balance Fe and unavoidable impurities Manufacture billets.
- C is an important component in determining the strength of the steel and the amount of the pearlite phase in the steel structure.
- a hot-rolled steel sheet having a tensile strength of 34 kgf 2 or more if the pearlite phase in the structure is less than 5% in area fraction, uniform elongation after cold forming is significantly reduced. This is because the pearlite bears the strength and prevents the increase in the dislocation density of the ferrite, thereby maintaining its plastic deformability.
- the C content must be 0.04% or more. You. However, if it exceeds 0.25%, the weldability is impaired, so the upper limit was made 0.25%.
- N is added to steel to form a solid solution in the ground of funilite to increase the strength of the steel and reduce its plastic deformability.However, when N is added together with Ti, it forms TiN and reduces the solute N in the steel. It is an important element that not only restores plastic deformability but also acts on dispersion strengthening and imparts high strength and uniform elongation to steel. To do so, it is necessary to disperse TiN with an average particle size of more than 1 / m in the mother ground at a rate of 0.0008 to 0.015% by weight, and the amount of Ti for that purpose is effective in the range of 0.003 to 0.050%. is there. If the average particle size of TiN is less than 1 m, dispersion strengthening is not performed sufficiently.
- N should be at least 0.0050%, preferably 0.0080% or more, but if it exceeds 0.0150%, the strength is too high and the uniform elongation is reduced, so the upper limit was made 0.0150%.
- A1 in advance and deoxidize before adding Ti.
- Ti is added to the steel of the present invention for the above reasons, but a preferable range is 0.01 to 0.03%.
- the amount of this Ceq. Is specified in relation to strength and weldability and is less than 0.10% If it exceeds 0.45%, high strength can be obtained, but weldability is impaired. Therefore, limit Ceq. To the range of 0.10 to 0.45%.
- Si 0.01 to 0.7%
- Mn 0.1 to 2.0%
- Ni 0.05 to 1.0%
- Cr 0.05 to 1.0%
- Mo 0.02 to 0.5%
- V 0.005 to It can contain at least one selected from the group of 0.2%.
- the content is set to 0.025% or less and P + S ⁇ 0.04%, respectively.
- Cu 0.05-1.0%
- Nb 0.005-0.05%
- Al 0.001-0.1%
- B 0.0005-0.0020%
- Ca 0.0005-0.0070%
- REM Lanthanide series rare earths containing Y: At least one selected from the group of 0.001 to 0.050% can be contained.
- the slab of low alloy steel adjusted to the above composition range is heated to 1000 to 1300 ° C for hot rolling and rolled, and rolling is completed at a temperature not lower than the Ar 3 transformation point, and 500 or more. Either air-cooled from the above temperature to obtain a thick plate, or rolled at 500 ° C or higher and air-cooled to obtain a hot-rolled steel strip.
- the lower limit of the heating temperature for hot rolling was set to 1000 ° C because, depending on the thickness of the steel sheet, the ferrite was strongly worked when the rolling end temperature was below the Ar 3 transformation point, and the dislocation density in the base metal This is to prevent the strength from increasing and the plastic deformability to be impaired, but when the temperature exceeds 1300 ° C, The upper limit is 1300 ° C because the product yield is significantly reduced due to oxidation of the product. The reason why the rolling end temperature is equal to or higher than the Ar 3 transformation point is also described above.
- the starting temperature of air cooling after rolling and the winding temperature are also set to a high temperature of 500 ° C or more in order to avoid unnecessary increase in the strength of the steel sheet.
- ⁇ having an average grain size of more than 1 m is finely dispersed and precipitated in the matrix at a ratio of 0.0008 to 0.015%, and as shown in FIG. Fine-grained ferrite toeperite (including some payites) containing 5% to 20% of the fine phase at a rate. Because having such a steel structure, the steel sheet of the present invention can be tensile strength with its excellent uniform elongation after cold working to obtain a high strength of 34 ⁇ SZkgfZmm 2.
- Fig. 1 (A) is a photomicrograph (400x) of the square section of a square steel pipe (MID) of the inventive steel T-12
- Fig. 1 (B) is a microstructure of the metal structure of the comparative steel S-2. Show. In the steel of the present invention shown in Fig.
- Fig. 1 shows the relationship between the tensile strength and the uniform elongation of the steel of the present invention and the comparative steel, focusing on the results in Table 4.
- the steels of the present invention (C-14, C-16, T-1, T-12, T-3, T-4) are stronger than the comparative steels. Despite its high degree, it maintains a large uniform elongation even after cold working. This is clearly shown in Fig. 2, which shows the relationship between the uniform elongation and strength after cold forming into a square steel pipe on an actual production line using the hot-rolled steel sheets of the present invention steel and the comparative steels and their materials as raw materials. Understood.
- Ceq. (WES) C + Si, 24 + Mn / 6 + Ni / 40 + Cr / 5 + Mo / 4 + V / 14
- Ratio C-1 A 5.7 31.1 43.0 42.0 22.2
- Step (ram) (kgfZ ⁇ 2) (kgf / image 2) ⁇ %)
- the present invention specifies the components in steel, forms a relatively large TiN, gives dispersion strengthening ability, and generates an effective pearlite phase in steel, thereby improving the normal productivity. even after having conducted a cold forming without lowering the tensile strength uniform elongation is excellent.
- 34 to 62KgfZ hide 2 Can produce a high-strength hot-rolled steel sheet having This high-strength hot-rolled steel sheet is extremely useful as a steel material for general and welded structures, particularly as a material for round and square steel pipes, shaped steel or sheet piles for civil engineering,
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Description
Claims
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/256,224 US5509977A (en) | 1992-01-30 | 1993-10-29 | High strength hot rolled steel plates and sheets excellent in uniform elongation after cold working and process for producing the same |
| DE69325644T DE69325644T2 (de) | 1992-10-30 | 1993-10-29 | Hochfestes warmgewalztes Stahlblech mit hervorragender gleichmässiger Dehnung nach der Kaltverformung und Verfahren zu dessen Herstellung |
| EP93923674A EP0620289B1 (en) | 1992-10-30 | 1993-10-29 | High-strength hot-rolled steel sheet excellent in uniform elongation after cold working and process for producing the same |
| KR94702245A KR0121885B1 (en) | 1992-10-30 | 1994-06-27 | High strength hot-rolled steel sheet excellent in uniform elongation after cold working process for producing the same |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4292352A JPH0791618B2 (ja) | 1992-09-14 | 1992-10-30 | 冷間加工後の一様伸びの優れている引張強度34kgf/mm2以上の熱延鋼板およびその製造方法 |
| JP4/292352 | 1992-10-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1994010355A1 true WO1994010355A1 (fr) | 1994-05-11 |
Family
ID=17780694
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP1993/001580 Ceased WO1994010355A1 (fr) | 1992-01-30 | 1993-10-29 | Tole d'acier lamine a chaud a haute resistance excellente en allongement uniforme apres ecrouissage a froid et son procede de production |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5509977A (ja) |
| EP (1) | EP0620289B1 (ja) |
| KR (1) | KR0121885B1 (ja) |
| CA (1) | CA2124838C (ja) |
| DE (1) | DE69325644T2 (ja) |
| WO (1) | WO1994010355A1 (ja) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104060163A (zh) * | 2013-09-12 | 2014-09-24 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种冷成型用热轧钢板及其制造方法 |
| CN104060164A (zh) * | 2013-09-12 | 2014-09-24 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种冷成型用热轧钢板及其制造方法 |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2753399B1 (fr) * | 1996-09-19 | 1998-10-16 | Lorraine Laminage | Tole d'acier lamine a chaud pour emboutissage profond |
| ES2275310T3 (es) * | 1997-07-28 | 2007-06-01 | Exxonmobil Upstream Research Company | Procedimiento para la produccion de aceros soldables de resistencia ultra-alta con tenacidad superior. |
| GB9803535D0 (en) * | 1998-02-19 | 1998-04-15 | Dawson Const Plant Ltd | Sheet piling |
| DE19821797C1 (de) * | 1998-05-15 | 1999-07-08 | Skf Gmbh | Verfahren zur Herstellung von gehärteten Teilen aus Stahl |
| US7552776B2 (en) | 1998-12-07 | 2009-06-30 | Enventure Global Technology, Llc | Anchor hangers |
| US7055608B2 (en) | 1999-03-11 | 2006-06-06 | Shell Oil Company | Forming a wellbore casing while simultaneously drilling a wellbore |
| WO2001064968A1 (en) * | 2000-03-02 | 2001-09-07 | Sumitomo Metal Industries, Ltd. | Color crt mask frame, steel plate for use therein, process for producing the steel plate, and color crt having the frame |
| KR20020049925A (ko) * | 2000-12-20 | 2002-06-26 | 이구택 | 파이프 가공성이 우수한 미니밀 열연강판 및 그 제조방법 |
| US7410000B2 (en) | 2001-01-17 | 2008-08-12 | Enventure Global Technology, Llc. | Mono-diameter wellbore casing |
| GB2414749B (en) | 2001-11-12 | 2006-06-28 | Enventure Global Technology | Mono diameter wellbore casing |
| JP2005525509A (ja) | 2001-11-27 | 2005-08-25 | エクソンモービル アップストリーム リサーチ カンパニー | 天然ガス車両のためのcng貯蔵及び送出システム |
| US6852175B2 (en) * | 2001-11-27 | 2005-02-08 | Exxonmobil Upstream Research Company | High strength marine structures |
| GB2406126B (en) | 2002-06-10 | 2006-03-15 | Enventure Global Technology | Mono-diameter wellbore casing |
| BR0314627A (pt) | 2002-09-20 | 2005-07-26 | Enventure Global Technology | Tampão de fundo para uso em conexão com um aparelho para formar um encamisamento de furo de poço de diâmetro único, aparelho conectável a uma tubulação de perfuração para formar um encamisamento de furo de poço de diâmetro único, e, método para formar um encamisamento de furo de poço de diâmetro único |
| US7503393B2 (en) | 2003-01-27 | 2009-03-17 | Enventure Global Technology, Inc. | Lubrication system for radially expanding tubular members |
| CA2517208C (en) | 2003-02-26 | 2008-06-03 | Enventure Global Technology | Apparatus for radially expanding and plastically deforming a tubular member |
| GB2419913B (en) * | 2003-08-14 | 2008-03-05 | Enventure Global Technology | Expandable Tubular |
| US20070267110A1 (en) * | 2006-05-17 | 2007-11-22 | Ipsco Enterprises, Inc. | Method for making high-strength steel pipe, and pipe made by that method |
| CN102337479A (zh) * | 2011-10-21 | 2012-02-01 | 天津大学 | 适用于单晶金刚石切削的超细晶钢及其制备方法 |
| KR101382888B1 (ko) * | 2012-03-16 | 2014-04-08 | 주식회사 포스코 | 재질편차가 적고, 가공성이 우수한 유정관용 열연강판 및 이의 제조방법 |
| EP3091123A1 (de) | 2015-05-08 | 2016-11-09 | Siemens Aktiengesellschaft | Verfahren und vorrichtung zur erhöhung eines feststoffgehalts bei einem grundstoff, steuereinrichtung, anlage zur bearbeitung eines grundstoffs und papierfabrik |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6227519A (ja) * | 1985-07-26 | 1987-02-05 | Nippon Steel Corp | 超細粒熱延高張力鋼板の製造方法 |
| JPH02267222A (ja) * | 1989-04-10 | 1990-11-01 | Nippon Steel Corp | 低降状比複合組織型高張力厚肉熱延鋼板の製造方法 |
| JPH0379716A (ja) * | 1989-08-23 | 1991-04-04 | Kawasaki Steel Corp | 溶接性の良好な低降伏比高張力鋼の製造方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5819430A (ja) * | 1981-07-27 | 1983-02-04 | Kobe Steel Ltd | 高降伏比高延性型非調質熱延高張力鋼板の製造法 |
| US4880480A (en) * | 1985-01-24 | 1989-11-14 | Kabushiki Kaisha Kobe Seiko Sho | High strength hot rolled steel sheet for wheel rims |
| JPS62174323A (ja) * | 1986-01-24 | 1987-07-31 | Kobe Steel Ltd | 溶接性に優れた降伏強度50kgf/mm2以上を有する非調質厚肉鋼板の製造法 |
| JP2811226B2 (ja) * | 1990-07-02 | 1998-10-15 | 新日本製鐵株式会社 | 車体補強用鋼管 |
-
1993
- 1993-10-29 WO PCT/JP1993/001580 patent/WO1994010355A1/ja not_active Ceased
- 1993-10-29 US US08/256,224 patent/US5509977A/en not_active Expired - Fee Related
- 1993-10-29 CA CA002124838A patent/CA2124838C/en not_active Expired - Fee Related
- 1993-10-29 DE DE69325644T patent/DE69325644T2/de not_active Expired - Fee Related
- 1993-10-29 EP EP93923674A patent/EP0620289B1/en not_active Expired - Lifetime
-
1994
- 1994-06-27 KR KR94702245A patent/KR0121885B1/ko not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6227519A (ja) * | 1985-07-26 | 1987-02-05 | Nippon Steel Corp | 超細粒熱延高張力鋼板の製造方法 |
| JPH02267222A (ja) * | 1989-04-10 | 1990-11-01 | Nippon Steel Corp | 低降状比複合組織型高張力厚肉熱延鋼板の製造方法 |
| JPH0379716A (ja) * | 1989-08-23 | 1991-04-04 | Kawasaki Steel Corp | 溶接性の良好な低降伏比高張力鋼の製造方法 |
Non-Patent Citations (1)
| Title |
|---|
| See also references of EP0620289A4 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104060163A (zh) * | 2013-09-12 | 2014-09-24 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种冷成型用热轧钢板及其制造方法 |
| CN104060164A (zh) * | 2013-09-12 | 2014-09-24 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种冷成型用热轧钢板及其制造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2124838A1 (en) | 1994-05-11 |
| KR0121885B1 (en) | 1997-12-04 |
| DE69325644T2 (de) | 2000-04-13 |
| CA2124838C (en) | 1998-07-14 |
| EP0620289A1 (en) | 1994-10-19 |
| EP0620289A4 (en) | 1995-03-29 |
| US5509977A (en) | 1996-04-23 |
| EP0620289B1 (en) | 1999-07-14 |
| DE69325644D1 (de) | 1999-08-19 |
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