WO1995001938A1 - Procede et dispositif de formage de plaques de verre et application de ce procede a l'obtention de vitrages de formes complexes - Google Patents
Procede et dispositif de formage de plaques de verre et application de ce procede a l'obtention de vitrages de formes complexes Download PDFInfo
- Publication number
- WO1995001938A1 WO1995001938A1 PCT/FR1994/000847 FR9400847W WO9501938A1 WO 1995001938 A1 WO1995001938 A1 WO 1995001938A1 FR 9400847 W FR9400847 W FR 9400847W WO 9501938 A1 WO9501938 A1 WO 9501938A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- bending
- glass
- counterform
- male form
- annular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B23/00—Re-forming shaped glass
- C03B23/02—Re-forming glass sheets
- C03B23/023—Re-forming glass sheets by bending
- C03B23/03—Re-forming glass sheets by bending by press-bending between shaping moulds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B23/00—Re-forming shaped glass
- C03B23/02—Re-forming glass sheets
- C03B23/023—Re-forming glass sheets by bending
- C03B23/035—Re-forming glass sheets by bending using a gas cushion or by changing gas pressure, e.g. by applying vacuum or blowing for supporting the glass while bending
- C03B23/0352—Re-forming glass sheets by bending using a gas cushion or by changing gas pressure, e.g. by applying vacuum or blowing for supporting the glass while bending by suction or blowing out for providing the deformation force to bend the glass sheet
- C03B23/0357—Re-forming glass sheets by bending using a gas cushion or by changing gas pressure, e.g. by applying vacuum or blowing for supporting the glass while bending by suction or blowing out for providing the deformation force to bend the glass sheet by suction without blowing, e.g. with vacuum or by venturi effect
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B23/00—Re-forming shaped glass
- C03B23/02—Re-forming glass sheets
- C03B23/023—Re-forming glass sheets by bending
- C03B23/025—Re-forming glass sheets by bending by gravity
- C03B23/0252—Re-forming glass sheets by bending by gravity by gravity only, e.g. sagging
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B23/00—Re-forming shaped glass
- C03B23/02—Re-forming glass sheets
- C03B23/023—Re-forming glass sheets by bending
- C03B23/03—Re-forming glass sheets by bending by press-bending between shaping moulds
- C03B23/0305—Press-bending accelerated by applying mechanical forces, e.g. inertia, weights or local forces
Definitions
- the present invention relates to techniques for forming glass sheets for the production of automotive safety glazing, toughened and / or assembled using plastic sheets. More specifically, the invention aims to improve forming techniques according to which the glass sheets are heated and conveyed in a horizontal position through an oven by a flat conveyor and then are bent in a thermally insulated enclosure before being pipes in a cooling station.
- Glazing with complex shapes is obtained essentially using two technologies:
- the first, mainly used for glazing assembled by laminating such as windshields, consists of placing cold, one or two sheets of glass on a frame whose peripheral geometry reproduces that which is desired
- the second mainly intended for tempered glazing, completely differentiates the stages of reheating glass sheets, heated in an oven which they pass through flat, conveyed by a bed of rollers or an air cushion, and the stages of forming which are carried out using tools which only work on the glass when its temperature is suitable.
- the tempering step requires a minimum temperature which requires overheating the glass in the oven (but then the optical quality is necessarily affected) and / or very quickly bending, which is only possible if the form sought is simple. It has certainly been proposed to preform the glazing before driving it to a bending station by pressing between a solid male form and a female form, the preforming being obtained by scrolling the glass at the end of the oven on rotating elements such as as rocket or diabolo type rollers or even as handlebars. But it should be known that these elements are themselves a significant source of defects and that it is practically impossible to correctly position the moving glass on such elements.
- Positioning before entering the preforming area is of course always possible, but its effectiveness is quite relative and again depends on the complexity of the desired shape, a "simple" shape being much more “tolerant” with regard to the quality of the positioning.
- the preforming due to rotating elements is cylindrical, or we indicated above, that the most complex shapes are spherical, with locally longitudinal radii of curvature and small transverse curves.
- a cylindrical preforming makes it possible to approach only one of these radii of curvature.
- Opposed to these cold technologies are hot technologies in which the forming cell is an integral part of the furnace or at least is thermally insulated so as to maintain there a temperature substantially identical to the temperature of the glass as it leaves the furnace.
- the glass is transferred from the conveyor to a male shape whose shape it follows under the effect of a vacuum (EP 3 391, EP-241 355), of a current of hot air ascending (EP-169,770) or gravity (WO-91/17962).
- the bending is completed using an annular frame open in its center used in the event of pressing as a female counterform or more simply as a support during a bending due to the fall on this annular frame ("drop forming").
- the force acting during the pre-mage is also used for the conveyor / male form transfer.
- a suction plate takes charge of the volume to deposit it on a lower convex shape, with a concavity facing downwards. All these processes have in common a preforming effected by means of a solid male form against which the entire surface of the flat glass sheet is applied, with the possible exception of a small marginal portion.
- glass plate is understood to mean, according to the invention, a sheet of glass or possibly a stack of two or three sheets of glass superimposed upon entering the oven as will be detailed below.
- the method according to the invention thus provides for the formation of a blank before the pressing phase, said blank being spherically curved.
- the central part of the glazing is advantageously free from any contact with a tool, which allows the glass to flow freely and to compensate for the non-developability of the shape imposed by the male shape by local thinning.
- a preforming phase is provided during which the glass plate is applied against the male form by purely pneumatic forces. During this preforming phase, the central part of the glass plate is in contact with the male shape and therefore can no longer be stretched. However, a significant portion of the surface of the glass plate is still free from contact with the forming tools so that the glass can still deform so as to envelop the male form.
- the forming process according to the invention thus successively consists in the formation of a blank, the resumption of this blank by the solid male shape and a finishing by pressing.
- a three-step process cannot be conceive that in the context of a hot technology, where the glass is in a substantially isothermal enclosure, as are the bending tools which remain there permanently, so that there is normally no parasitic heat exchange which disturbs the optics.
- a blank is created which itself has a non-developable shape.
- the central part of the glass sheet is advantageously free from any contact; due to the action of the forces of gravity, it will thus be able to create in this central part extension constraints which lead to an elongation of this central part (which results locally in a slight thinning of the glass).
- the material near the edges can creep towards the central part. The undesired undulations do not form during pressing against the male form, the deformation which still has to undergo the periphery of the glass sheet is very small and there is then no more "excess" of glass.
- the central part of the sheet is that which necessarily meets the form of male bending in the first place. As soon as this contact is established, it is no longer possible to extend the central part so that the periphery of the glazing cannot completely envelop the male form, the creep of the material can only act on a peripheral portion. marginal which does not allow true compensation, so that the ripples are formed.
- the method according to the invention results in a more uniform treatment of the entire surface of the glass sheet because the central part is in contact with the male shape for a period substantially identical to that of the rest of the glass sheet, the distance to travel to reach the male shape being, due to the gravity roughing step, approximately the same for all points on the surface of the glass plate. This results in an improvement in optical quality.
- the process according to the invention is similar to the forming processes usually used for the production of laminated glazing. Nevertheless, he must It should be emphasized that this is indeed a so-called tempering process where the glass enters the flat bending cell and at the bending temperature, a single tool being used to treat all volumes.
- the method according to the invention makes it possible to transfer the glass, after bending, to a tempering frame.
- a bending installation such as that described in the aforementioned patent application EP-A-520 886 and which comprises a horizontal oven terminated by that of bending , where a temperature close to the bending temperature of the glass sheet is maintained, this bending cell comprising a glass support member in the extension of the plane of transport of the glass sheet - preferably of the air cushion type -, a male shape with convexity turned downwards, disposed above said support member, a concave annular counterform, formed by a continuous frame open at its center, movable between a low position under said transport plane and a position high in the vicinity of the male form and means for controlling the speed of movement of the annular form between its high position and its low position.
- the support member is integral with an assembly comprising a plate mounted under the bending cell, outside the thermally insulated enclosure, carrying, in addition to this support member, the insulating floor of the bending cell and the annular counterform, the means for controlling the speed of movement of the annular form being constituted by a system for controlling the motor assembly of the annular counterform.
- Such an installation can be used for obtaining thermally toughened glazing, provided of course of adding a quenching station and means for transferring curved glazing from the bending cell to the quenching station. It can also be used for the simultaneous bending of several sheets of glass which are then superimposed on each other (generally in pairs) at the entrance to the oven, the stack being lifted by the annular counterform, brought into contact with the male form after a while sufficient to allow roughing, pressed against the male form by a depression created at the periphery of the glass sheet and then pressed against the male form using the annular contr ⁇ form. After this passage, the glass sheets are kept for a few moments in contact with the male form, the time to lower the lower counterform and to introduce in the male form a recovery frame which transfers the glass sheets to a cooling station. control.
- the method according to the invention has the remarkable feature that no real modification of the installation (with the exception of changing the bending tools to adapt to the desired shape) is necessary to go from production to another, only the cycle times devoted to raising the annular frame and pressing are to be modulated to transform an installation for toughened glazing into an installation for laminated glazing. It applies in particular to the production of glazing locally presenting a criterion of non-developability greater than 5, glazing which cannot be obtained with good optical quality and high curve precision with the methods known in the art.
- Figures 1 to 4 a schematic side view of a forming according to the method according to the invention of a pair of glass sheets,
- Figure 5 a schematic representation of a glazing unit having a non-developability criterion reaches the value 5, with a mesh seen in elevation (Figure 5.1), from the front ( Figure 5.2) and three-quarters (Figure 5.3),
- Figure 6 the view of a target reflected by the glazing of Figure 5.
- FIGS. 1 to 4 illustrate the implementation of the invention with an installation similar to that described in patent application EP-520 886 the content of which must be considered as incorporated herein and to which it is referred for more details regarding the details of implementation.
- Such an installation comprises a reheating oven with a conveyor preferably constituted by a flat bed of rollers 1.
- the glass sheets At the exit of the oven, the glass sheets, at a temperature of the order of 650 ° C if they have to undergo an operation thermal quenching, or of the order of 550 ° C if it is the preparation of laminated glazing, penetrating into the bending cell where they are then supported by a support member, such as by example a hot air cushion, here symbolized by a box 2.
- a support member such as by example a hot air cushion, here symbolized by a box 2.
- a support member such as by example a hot air cushion, here symbolized by a box 2.
- a box comprising a plurality of individual compartments transverse to the axis of the conveyor; this type of air cushion makes it possible to avoid the imbalance of the cushion when the glazing arrives, when only the front edge of the latter is vertical to the air cushion.
- French patent application 92/08482 filed on July 9, 1992.
- This bending cell, thermally insulated enclosure further comprises a convex male shape 3, provided with means suitable for keeping in contact with a glass sheet and a concave annular counterform 4 moved between a low position under the plane of conveying the sheets of glass and a high position in the vicinity of the male form.
- Shape and counterform are referenced to each other and only move vertically.
- these stops are preferably frustoconical stops, a larger diameter at the top than at the bottom, so as to position not only the bottom glass sheet but also the top sheet which, intended to form the concave side of the laminated glazing, is normally slightly smaller than the sheet lower, convex side.
- these stops are retractable.
- the focusing stops are preferably in reference with respect to the upper male shape, itself referenced with respect to the annular counterform, all these parts being obtained with high machining precision and preferably being produced from cast iron or refractory steel casting.
- the annular frame is lifted for example by means of motorized screw jacks, said screws being preferably placed outside the thermally insulated enclosure .
- the stroke of these screw jacks is fully controlled, over their entire length and not only when approaching the male form.
- the glass takes off slightly from the annular frame ( Figure 3) and is pressed against the convex surface of the male form.
- operating on a blank in accordance with the invention and not on a flat glass sheet has at least two advantages: the first is that the distance to be traveled by all the points of the glass sheet is substantially identical, the second is that the contact between the central part of the glass sheet and the male counterform is much less brutal: the preforming can be compared more to a masking operation than to a punching operation as is sometimes the case with the methods known in the art. Thanks to this softer contact, the optical quality of the glass is further improved.
- the last step shown in Figure 4 is the pressing step using the annular counterform.
- it is simply a simple finishing step to perfect the geometry of the edges, which is not intended to create compression stresses in order to compensate for the excess material, ci having already been "absorbed” by the creep which takes place during roughing.
- the breakage rates are lower, if only because the risks of generating residual stresses are reduced, the glazing being already very close to its final shape and the risks of optical marking are also lower.
- the glass sheet or sheets are kept in contact with the male form while the annular counterform is lowered under the plane of the conveying plane of the flat glass and to introduce a frame in the male form. for recovering the curved glass sheet or sheets.
- this frame leads the curved glazing into a controlled cooling station, for example by a radiant cooling station or in a quenching station, the recovery frame being in the latter case, suitable for the evacuation of quenching air.
- FIG. 5 represents a form of glazing whose developability criterion is locally greater than 5, in particular due to a very strong curve near the wings.
- this shape can be produced with excellent optical quality as shown in FIG. 6 where the real image of the reflection is taken up. of a grid pattern projected onto a glazing obtained according to the invention inclined at 45 °, corresponding to the theoretical shape of Figure 5. The deformation of the pattern is particularly slight.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Abstract
Description
Claims
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| UA95028194A UA42701C2 (uk) | 1993-07-09 | 1994-07-07 | Спосіб опуклого згинання скляної пластини та пристрій для його здійснення |
| DE69421371T DE69421371T2 (de) | 1993-07-09 | 1994-07-07 | Verfahren und vorrichtung zum formen von glasscheiben und anwendung dieses verfahren zur herstellung von fenstern mit komplexer form |
| JP1995503870A JP3911532B6 (ja) | 1993-07-09 | 1994-07-07 | ガラス板を成形するための方法と装置、及び複雑な形状のガラスの製造へのそれらの使用 |
| CA002143650A CA2143650C (fr) | 1993-07-09 | 1994-07-07 | Procede et dispositif de formage de plaques de verre et application de ce procede a l'obtention de vitrages de formes complexes |
| SK306-95A SK281438B6 (sk) | 1993-07-09 | 1994-07-07 | Spôsob ohýbania plošného skleneného dielca a zariadenie na jeho vykonávanie |
| KR1019950700980A KR100316860B1 (ko) | 1993-07-09 | 1994-07-07 | 유리판을성형하기위한방법및장치,및당해방법을이용하는창유리의제조방법 |
| BR9405505-0A BR9405505A (pt) | 1993-07-09 | 1994-07-07 | Processo e dispositivo de recurvamento de uma palca de vidro aquecida. |
| PL94307861A PL176752B1 (pl) | 1993-07-09 | 1994-07-07 | Sposób profilowania tafli szkła i urządzenie do profilowania tafli szkła |
| EP94922885A EP0660809B1 (fr) | 1993-07-09 | 1994-07-07 | Procede et dispositif de formage de plaques de verre et application de ce procede a l'obtention de vitrages de formes complexes |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9308455A FR2707283B1 (fr) | 1993-07-09 | 1993-07-09 | Procédé et dispositif de formage de plaques de verre et application de ce procédé à l'obtention de vitrages de formes complexes. |
| FR93/08455 | 1993-07-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1995001938A1 true WO1995001938A1 (fr) | 1995-01-19 |
Family
ID=9449098
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/FR1994/000847 Ceased WO1995001938A1 (fr) | 1993-07-09 | 1994-07-07 | Procede et dispositif de formage de plaques de verre et application de ce procede a l'obtention de vitrages de formes complexes |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US6044662A (fr) |
| EP (1) | EP0660809B1 (fr) |
| KR (1) | KR100316860B1 (fr) |
| CN (2) | CN1651345A (fr) |
| BR (1) | BR9405505A (fr) |
| CO (1) | CO4230130A1 (fr) |
| CZ (1) | CZ288093B6 (fr) |
| DE (1) | DE69421371T2 (fr) |
| ES (1) | ES2139748T3 (fr) |
| FR (1) | FR2707283B1 (fr) |
| PL (1) | PL176752B1 (fr) |
| PT (1) | PT660809E (fr) |
| RU (1) | RU2121983C1 (fr) |
| SK (1) | SK281438B6 (fr) |
| TR (1) | TR28871A (fr) |
| UA (1) | UA42701C2 (fr) |
| WO (1) | WO1995001938A1 (fr) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ297663B6 (cs) * | 2001-02-06 | 2007-02-28 | Saint-Gobain Glass France | Zpusob a zarízení pro ohýbání sklenených tabulí po dvojicích |
| WO2010136702A1 (fr) | 2009-05-27 | 2010-12-02 | Saint-Gobain Glass France | Vitrage a faible niveau de double image |
| WO2012022904A1 (fr) | 2010-08-20 | 2012-02-23 | Saint-Gobain Glass France | Miroir bombe par pressage |
| WO2012049433A1 (fr) | 2010-10-15 | 2012-04-19 | Saint-Gobain Glass France | Procede de bombage et support de trempe thermique |
| WO2019129980A1 (fr) | 2017-12-29 | 2019-07-04 | Saint-Gobain Glass France | Procede de bonbage de feuille de verre |
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| AU2003221375A1 (en) | 2002-03-13 | 2003-09-22 | Asahi Glass Company, Limited | Method of bend molding glass plate and apparatus |
| FR2852951B1 (fr) * | 2003-03-26 | 2007-02-16 | Saint Gobain | Procede de bombage de feuilles de verre par pressage et aspiration |
| FR2855168B1 (fr) * | 2003-05-19 | 2007-03-30 | Saint Gobain | Bombage de vitrages par gravite sur une multiplicite de supports |
| RU2245852C1 (ru) * | 2003-07-09 | 2005-02-10 | Федеральное государственное унитарное предприятие "Научно-исследовательский институт комплексных испытаний оптико-электронных приборов и систем" (ФГУП НИИКИ ОЭП) | Способ изготовления оптических деталей с асферическими поверхностями |
| US7437892B2 (en) * | 2004-04-21 | 2008-10-21 | Ppg Industries Ohio, Inc. | Apparatus having vacuum applying facilities and method of using vacuum to bend and/or shape one or more sheets |
| EP1591425A1 (fr) * | 2004-04-26 | 2005-11-02 | Glaverbel | Dispositif et procédé de bombage d'une feuille de verre |
| US20080103461A1 (en) * | 2006-10-31 | 2008-05-01 | Johnson Kroy D | Appliance for delivering a composition, the appliance having an outer fibrous layer and inner liquid-impermeable layer |
| US7975509B2 (en) * | 2007-06-27 | 2011-07-12 | Pilkington North America, Inc. | Glass bending process |
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| CN102173568B (zh) * | 2011-02-18 | 2012-11-07 | 福耀玻璃工业集团股份有限公司 | 一种弯曲玻璃板的方法和装置 |
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| EP0183418A1 (fr) * | 1984-11-23 | 1986-06-04 | Glasstech, Inc. | Procédé et appareil de formage de feuilles de verre |
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| WO1993006052A1 (fr) * | 1991-09-27 | 1993-04-01 | Tamglass Engineering Oy | Procede de cintrage et de trempe de feuilles de verre |
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| SU1239105A1 (ru) * | 1985-01-28 | 1986-06-23 | Всесоюзный научно-исследовательский институт технического и специального строительного стекла | Установка дл горизонтального прессовани и закалки листового стекла |
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- 1994-07-05 CO CO94029133A patent/CO4230130A1/es unknown
- 1994-07-06 TR TR00621/94A patent/TR28871A/xx unknown
- 1994-07-07 RU RU95108246A patent/RU2121983C1/ru not_active IP Right Cessation
- 1994-07-07 CN CNA2004100880686A patent/CN1651345A/zh active Pending
- 1994-07-07 UA UA95028194A patent/UA42701C2/uk unknown
- 1994-07-07 DE DE69421371T patent/DE69421371T2/de not_active Expired - Fee Related
- 1994-07-07 KR KR1019950700980A patent/KR100316860B1/ko not_active Expired - Fee Related
- 1994-07-07 PT PT94922885T patent/PT660809E/pt unknown
- 1994-07-07 WO PCT/FR1994/000847 patent/WO1995001938A1/fr not_active Ceased
- 1994-07-07 SK SK306-95A patent/SK281438B6/sk not_active IP Right Cessation
- 1994-07-07 PL PL94307861A patent/PL176752B1/pl not_active IP Right Cessation
- 1994-07-07 CN CNB941904687A patent/CN1239419C/zh not_active Expired - Fee Related
- 1994-07-07 EP EP94922885A patent/EP0660809B1/fr not_active Expired - Lifetime
- 1994-07-07 CZ CZ1995593A patent/CZ288093B6/cs not_active IP Right Cessation
- 1994-07-07 ES ES94922885T patent/ES2139748T3/es not_active Expired - Lifetime
- 1994-07-07 BR BR9405505-0A patent/BR9405505A/pt not_active IP Right Cessation
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| US4778507A (en) * | 1986-08-12 | 1988-10-18 | Asahi Glass Company Ltd. | Method for bending glass plates |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ297663B6 (cs) * | 2001-02-06 | 2007-02-28 | Saint-Gobain Glass France | Zpusob a zarízení pro ohýbání sklenených tabulí po dvojicích |
| WO2010136702A1 (fr) | 2009-05-27 | 2010-12-02 | Saint-Gobain Glass France | Vitrage a faible niveau de double image |
| WO2012022904A1 (fr) | 2010-08-20 | 2012-02-23 | Saint-Gobain Glass France | Miroir bombe par pressage |
| WO2012049433A1 (fr) | 2010-10-15 | 2012-04-19 | Saint-Gobain Glass France | Procede de bombage et support de trempe thermique |
| WO2019129980A1 (fr) | 2017-12-29 | 2019-07-04 | Saint-Gobain Glass France | Procede de bonbage de feuille de verre |
Also Published As
| Publication number | Publication date |
|---|---|
| CZ59395A3 (en) | 1996-01-17 |
| CO4230130A1 (es) | 1995-10-19 |
| PT660809E (pt) | 2000-04-28 |
| CN1111906A (zh) | 1995-11-15 |
| CN1239419C (zh) | 2006-02-01 |
| EP0660809A1 (fr) | 1995-07-05 |
| BR9405505A (pt) | 1999-09-08 |
| KR950703492A (ko) | 1995-09-20 |
| UA42701C2 (uk) | 2001-11-15 |
| TR28871A (tr) | 1997-08-06 |
| CN1651345A (zh) | 2005-08-10 |
| US6044662A (en) | 2000-04-04 |
| FR2707283A1 (fr) | 1995-01-13 |
| FR2707283B1 (fr) | 1995-09-22 |
| PL307861A1 (en) | 1995-06-26 |
| EP0660809B1 (fr) | 1999-10-27 |
| US6138477A (en) | 2000-10-31 |
| DE69421371D1 (de) | 1999-12-02 |
| CZ288093B6 (cs) | 2001-04-11 |
| JPH08501272A (ja) | 1996-02-13 |
| ES2139748T3 (es) | 2000-02-16 |
| SK30695A3 (en) | 1995-07-11 |
| DE69421371T2 (de) | 2000-05-11 |
| JP3911532B2 (ja) | 2007-05-09 |
| SK281438B6 (sk) | 2001-03-12 |
| KR100316860B1 (ko) | 2002-02-28 |
| RU2121983C1 (ru) | 1998-11-20 |
| PL176752B1 (pl) | 1999-07-30 |
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