WO1995025112B1 - Preparation de complexes de metal monocyclopentadienyle par substitution nucleophile de complexes de metal bis(cyclopentadienyle) - Google Patents
Preparation de complexes de metal monocyclopentadienyle par substitution nucleophile de complexes de metal bis(cyclopentadienyle)Info
- Publication number
- WO1995025112B1 WO1995025112B1 PCT/US1995/002996 US9502996W WO9525112B1 WO 1995025112 B1 WO1995025112 B1 WO 1995025112B1 US 9502996 W US9502996 W US 9502996W WO 9525112 B1 WO9525112 B1 WO 9525112B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- cyclopentadienyl
- bis
- silyl
- metal complexes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Abstract
L'invention concerne des dérivés de monocyclopentadiényle pontés d'un métal de groupe 4. Ces dérivés sont préparés par mise en contact d'un complexe de métal bis(cyclopentadiényle) correspondant avec un dérivé de métal alcalin ou un dérivé de métal terreux alcalin d'un ligand d'hydrocarbyle R, qui est éventuellement substitué par un ou plusieurs groupes amino, phosphino, éther, thioéther ou silyle. Les complexes de métal du groupe 4 bis(cyclopentadiényle) peuvent être préparés par mise en contact d'un composé correspondant à une des formules (Cp)3MQnXt, (Cp)2MQnXt+1, or CpMQnXt+2 avec un composé d'un sel dianonique correspondant à la formule: (L+x)y(Cp*-Z-Y)-2 ou ((LX')+x)y(Cp*-Z-Y)-2. L'invention a également pour objet un catalyseur de polymérisation d'addition comprenant un complexe de métal du groupe 4 bis(cyclopentadiényle) et un cocatalyseur d'activation, et un processus de polymérisation d'addition utilisant un catalyseur de ce type.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP95914001A EP0750625B1 (fr) | 1994-03-14 | 1995-03-13 | Preparation de complexes de metal monocyclopentadienyle par substitution nucleophile de complexes de metal bis(cyclopentadienyle) |
| DE69507692T DE69507692T2 (de) | 1994-03-14 | 1995-03-13 | Herstellung von monocyclopentadienylmetallkomplexe durch nukleophile substitution von bis (cyclopentadienyl)metallkomlexe |
| JP7524093A JPH09510449A (ja) | 1994-03-14 | 1995-03-13 | ビス（シクロペンタジエニル）金属錯体の求核性置換によるモノシクロペンタジエニル金属錯体の製造 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/209,344 US5504224A (en) | 1994-03-14 | 1994-03-14 | Preparation of monocyclopentadienyl metal complexes by nucleophilic substitution of bis(cyclopentadienyl) metal complexes |
| US08/209,344 | 1994-03-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO1995025112A1 WO1995025112A1 (fr) | 1995-09-21 |
| WO1995025112B1 true WO1995025112B1 (fr) | 1995-10-12 |
Family
ID=22778399
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1995/002996 Ceased WO1995025112A1 (fr) | 1994-03-14 | 1995-03-13 | Preparation de complexes de metal monocyclopentadienyle par substitution nucleophile de complexes de metal bis(cyclopentadienyle) |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US5504224A (fr) |
| EP (1) | EP0750625B1 (fr) |
| JP (1) | JPH09510449A (fr) |
| CA (1) | CA2185567A1 (fr) |
| DE (1) | DE69507692T2 (fr) |
| ES (1) | ES2126890T3 (fr) |
| WO (1) | WO1995025112A1 (fr) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6265338B1 (en) * | 1989-09-13 | 2001-07-24 | Exxon Chemical Patents, Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin copolymer production catalysts |
| DE19522013A1 (de) * | 1995-06-21 | 1997-01-02 | Hoechst Ag | Übergangsmetallverbindung |
| EP0885231A4 (fr) * | 1996-11-22 | 2000-02-09 | Boulder Scient Co | Synthese de titanocenes |
| US6218557B1 (en) * | 1996-11-22 | 2001-04-17 | Boulder Scientific Company | Synthesis of titanocenes |
| US6015916A (en) * | 1999-02-02 | 2000-01-18 | Boulder Scientific Company | Constrained geometry metallocene catalyst complexes |
| US6127446A (en) * | 1999-05-03 | 2000-10-03 | General Electric Company | Irradiation-curable silicone compositions, photo-active platinum (IV) compounds, and method |
| US6825295B2 (en) * | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| ES2379243T3 (es) * | 1999-12-10 | 2012-04-24 | Dow Global Technologies Llc | Complejos de metal del grupo 4 sustituidos, catalizadores y procedimiento de polimerización de olefinas |
| JP2002145927A (ja) * | 2000-11-08 | 2002-05-22 | National Institute Of Advanced Industrial & Technology | 末端にハロゲン原子を有するオレフィン系重合体の製法、末端にｉ族、ｉｉ族またはｉｉｉ族の金属含有基を有するオレフィン系重合体の製法およびオレフィン系ブロック共重合体の製法 |
| US20030226566A1 (en) * | 2002-06-06 | 2003-12-11 | Dhuper Sunil Kumar | Endotracheal tube with aerosol delivery apparatus II |
| US8074649B2 (en) | 2002-07-18 | 2011-12-13 | Aeon Research And Technology, Inc. | Endotracheal tube with feature for delivering aerosolized medication |
| GB0401348D0 (en) * | 2004-01-22 | 2004-02-25 | Bp Chem Int Ltd | Polymerisation process |
| US9498592B2 (en) | 2012-01-23 | 2016-11-22 | Aeon Research And Technology, Inc. | Modular pulmonary treatment system |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD324194A7 (de) * | 1988-12-28 | 1992-05-07 | Buna Chem Werke Veb | Metallacyclische homoleptische verbindungen |
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5026798A (en) * | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| RU2118203C1 (ru) * | 1990-06-22 | 1998-08-27 | Экксон Кэмикал Пейтентс Инк. | Каталитическая система для получения полиолефинов и композиция, используемая для полимеризации олефинов |
| JP3275211B2 (ja) * | 1991-05-20 | 2002-04-15 | ザ ダウ ケミカル カンパニー | 付加重合触媒の製造方法 |
| US5374696A (en) * | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
-
1994
- 1994-03-14 US US08/209,344 patent/US5504224A/en not_active Expired - Fee Related
-
1995
- 1995-03-13 JP JP7524093A patent/JPH09510449A/ja not_active Ceased
- 1995-03-13 WO PCT/US1995/002996 patent/WO1995025112A1/fr not_active Ceased
- 1995-03-13 CA CA002185567A patent/CA2185567A1/fr not_active Abandoned
- 1995-03-13 EP EP95914001A patent/EP0750625B1/fr not_active Expired - Lifetime
- 1995-03-13 DE DE69507692T patent/DE69507692T2/de not_active Expired - Fee Related
- 1995-03-13 ES ES95914001T patent/ES2126890T3/es not_active Expired - Lifetime
- 1995-06-06 US US08/469,192 patent/US5659054A/en not_active Expired - Fee Related
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