WO1996038599A1 - Procede et dispositif pour revetir une bande metallique d'un metal ou d'un alliage a plus bas point de fusion ou de liquide que celui du materiau constituant la bande - Google Patents
Procede et dispositif pour revetir une bande metallique d'un metal ou d'un alliage a plus bas point de fusion ou de liquide que celui du materiau constituant la bande Download PDFInfo
- Publication number
- WO1996038599A1 WO1996038599A1 PCT/CH1996/000191 CH9600191W WO9638599A1 WO 1996038599 A1 WO1996038599 A1 WO 1996038599A1 CH 9600191 W CH9600191 W CH 9600191W WO 9638599 A1 WO9638599 A1 WO 9638599A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- strip
- metal
- alloy
- enclosure
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0036—Crucibles
- C23C2/00361—Crucibles characterised by structures including means for immersing or extracting the substrate through confining wall area
- C23C2/00362—Details related to seals, e.g. magnetic means
Definitions
- the present invention relates to a method and a device for coating a metal strip with a metal or an alloy with a lower melting point or with liquidus than that of the material constituting the strip, according to which the strip is preheated and entrains it from bottom to top through a bath of said metal or of said alloy brought to a temperature higher than that of preheating the strip, then cools this strip at the outlet of said bath to a temperature lower than that of solidification of said metal or alloy.
- High speed wire coating methods have already been proposed which are passed from bottom to top through a bath of molten metal or alloy. Such methods are described, for example, in US-3,523,815, US-2,565,677, US-3,484,280 and US-4, 169,426.
- the strips are generally thin, ⁇ 1 mm thick and even ⁇ 0.5 mm, most often. Consequently, the edge of the strip, which, given its surface, develops the lowest driving force on the molten metal when moving this strip from bottom to top, is also the part of the strip which is in front of the largest mass of liquid, that is to say all the liquid metal located between the edge of the strip and the edge of the rectangular opening, taking into account the necessary clearance between this edge and this edge.
- the width of the opening will be between 0.7 and ⁇ 20 mm, that is to say a width between approximately 2 and 7 times the width of l edge, with a distance of 2 to 4 mm between the edge and the narrow edge of the rectangular opening, hence the difficulty in solving the problem of leaks.
- the problem of homogeneous heating of the strip is also more complex than that of heating a wire. This probably explains why this coating technique was essentially reserved for the wire, or, in the case of bands, to one side only, thus avoiding the problems linked to leaks at the edges of the band, mentioned above.
- the object of the present invention is precisely to propose a solution making it possible to extend the use of this method to a flat strip.
- the subject of the present invention is a process for coating a metal strip with a metal or an alloy with a lower melting point or with liquidus than that of the material constituting the strip, according to claim 1.
- One of the essential advantages of this process is to have a layer of liquid metal in contact with the strip having only a very small volume, of the order of 200 cl per meter of width of the strip.
- the coating of the strip therefore stops very quickly from the moment when the supply of the liquid metal layer which it passes through ceases. This makes it possible to obtain very great flexibility of use, to stop the installation, to change the coating metal or the strip without having large volumes of metal to be removed from the installation, as is the case. with conventional installations where the strip is immersed in a metal bath resulting in the immobilization of very large volumes of metal.
- Another advantage of the process according to the invention is that it allows to obtain homogeneous coatings having small thicknesses between 10-20 ⁇ m depending on the operating conditions.
- Figure 1 is a general sectional elevation view of this embodiment.
- FIG. 2 is a detail view in section along the line II-II in FIG. 1.
- Figure 3 is a sectional view along line III-III of Figure 2.
- the preheating of the ribbon 13 was preferably of the order of 410 "C, although tests were carried out between 390 ° C and 470 ° C, while the temperature of the molten alloy was generally of the order of 510 * 0.
- the coating thicknesses essentially varied, as has already been said, depending on the presence or not of the upper inserts 15a, 15b.
- the minimum thickness obtained under these conditions was 12 ⁇ m; without insert, this minimum thickness was 20 ⁇ m.
- the parameters influencing the thickness of the coating are the preheating temperature of the strip and its speed of movement.
- the thickness of the coating is dependent on the preheating temperature of the tape and the space between the tape and the inserts. No significant influence was found in the two cases with regard to the temperature of the molten metal or the coating alloy.
- the maximum coating thicknesses measured were of the order of 80 ⁇ m.
- FIG. 4 shows the influence of the dimension e (FIG. 3) corresponding to the horizontal surface of the lower molybdenum inserts 14a, 14b on the leaks of molten metal as a function of the height of the bath h in the interior space 10.
- Two curves are plotted on this diagram, one corresponding to a total space (on both sides) between the strip and the width of the lower opening 11 of 1.2 mm and the other to a space of 2 mm. These curves represent the limit from which a bandless metal leak occurs for an opening 11 34 mm in length.
- the preheating temperature was a big influence on the appearance of the coating.
- the coating did not have good adhesion and several small holes were observed in the coating .
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating With Molten Metal (AREA)
Abstract
Description
Claims
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96913420A EP0828864A1 (fr) | 1995-05-29 | 1996-05-17 | Procede et dispositif pour revetir une bande metallique d'un metal ou d'un alliage a plus bas point de fusion ou de liquide que celui du materiau constituant la bande |
| JP8536072A JPH11505885A (ja) | 1995-05-29 | 1996-05-17 | ストリップを形成する材料よりも低い融点または液相点を有する金属または合金で金属ストリップを被膜する方法及び装置 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH157895 | 1995-05-29 | ||
| CH1578/95-5 | 1995-05-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1996038599A1 true WO1996038599A1 (fr) | 1996-12-05 |
Family
ID=4213698
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CH1996/000191 Ceased WO1996038599A1 (fr) | 1995-05-29 | 1996-05-17 | Procede et dispositif pour revetir une bande metallique d'un metal ou d'un alliage a plus bas point de fusion ou de liquide que celui du materiau constituant la bande |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0828864A1 (fr) |
| JP (1) | JPH11505885A (fr) |
| WO (1) | WO1996038599A1 (fr) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998001595A1 (fr) * | 1996-07-05 | 1998-01-15 | Mannesmann Ag | Dispositif pour revetir des bandes de metal par immersion en bain chaud |
| EP0933442A1 (fr) * | 1998-01-29 | 1999-08-04 | Le Four Industriel Belge | Dispositif et procédé pour le contrÔle de l'épaisseur d'un revêtement de métal liquide sur un filament métallique |
| EP1225245A1 (fr) * | 2001-01-17 | 2002-07-24 | Recherche Et Developpement Du Groupe Cockerill Sambre | Procédé pour éviter l'entraínement de particules de zinc sur une tole galvanisée |
| EP1760166B1 (fr) * | 2005-09-02 | 2016-09-14 | Korea Bundy Co., Ltd. | Méthode de fabrication d'un tube en acier ayant une résistance à la corrosion amèliorée |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3264692A (en) * | 1964-04-29 | 1966-08-09 | Gen Electric | Inlet orifice for continuous casting apparatus |
| DE1900019A1 (de) * | 1968-01-02 | 1969-07-31 | Armco Steel Corp | Drahtueberziehungsverfahren |
| DE2247356A1 (de) * | 1972-09-27 | 1974-03-28 | Battelle Institut E V | Verfahren zum kontinuierlichen herstellen von langgestreckten, fadenverstaerkten leichtmetallformteilen |
| JPS56151163A (en) * | 1980-04-22 | 1981-11-24 | Mitsubishi Electric Corp | Dip forming device |
-
1996
- 1996-05-17 WO PCT/CH1996/000191 patent/WO1996038599A1/fr not_active Ceased
- 1996-05-17 JP JP8536072A patent/JPH11505885A/ja active Pending
- 1996-05-17 EP EP96913420A patent/EP0828864A1/fr not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3264692A (en) * | 1964-04-29 | 1966-08-09 | Gen Electric | Inlet orifice for continuous casting apparatus |
| DE1900019A1 (de) * | 1968-01-02 | 1969-07-31 | Armco Steel Corp | Drahtueberziehungsverfahren |
| DE2247356A1 (de) * | 1972-09-27 | 1974-03-28 | Battelle Institut E V | Verfahren zum kontinuierlichen herstellen von langgestreckten, fadenverstaerkten leichtmetallformteilen |
| JPS56151163A (en) * | 1980-04-22 | 1981-11-24 | Mitsubishi Electric Corp | Dip forming device |
Non-Patent Citations (1)
| Title |
|---|
| PATENT ABSTRACTS OF JAPAN vol. 6, no. 36 (M - 115) 5 March 1982 (1982-03-05) * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998001595A1 (fr) * | 1996-07-05 | 1998-01-15 | Mannesmann Ag | Dispositif pour revetir des bandes de metal par immersion en bain chaud |
| EP0933442A1 (fr) * | 1998-01-29 | 1999-08-04 | Le Four Industriel Belge | Dispositif et procédé pour le contrÔle de l'épaisseur d'un revêtement de métal liquide sur un filament métallique |
| EP1225245A1 (fr) * | 2001-01-17 | 2002-07-24 | Recherche Et Developpement Du Groupe Cockerill Sambre | Procédé pour éviter l'entraínement de particules de zinc sur une tole galvanisée |
| WO2002057505A1 (fr) * | 2001-01-17 | 2002-07-25 | Recherche Et Developpement Du Groupe Cockerill Sambre | Procede pour eviter l'entrainement de particules de zinc sur une tole galvanisee |
| EP1760166B1 (fr) * | 2005-09-02 | 2016-09-14 | Korea Bundy Co., Ltd. | Méthode de fabrication d'un tube en acier ayant une résistance à la corrosion amèliorée |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH11505885A (ja) | 1999-05-25 |
| EP0828864A1 (fr) | 1998-03-18 |
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