WO1998007765A3 - Verfahren zur anionischen polymerisation - Google Patents

Verfahren zur anionischen polymerisation Download PDF

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Publication number
WO1998007765A3
WO1998007765A3 PCT/EP1997/004497 EP9704497W WO9807765A3 WO 1998007765 A3 WO1998007765 A3 WO 1998007765A3 EP 9704497 W EP9704497 W EP 9704497W WO 9807765 A3 WO9807765 A3 WO 9807765A3
Authority
WO
WIPO (PCT)
Prior art keywords
alkyl
aryl
anionic polymerisation
metal alkyl
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1997/004497
Other languages
English (en)
French (fr)
Other versions
WO1998007765A2 (de
Inventor
Wolfgang Fischer
Hermann Gausepohl
Konrad Knoll
Stefan Laetsch
Wolfgang Loth
Christian Schade
Volker Warzelhan
Michel Fontanille
Alain Deffieux
Philippe Desbois
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27438412&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1998007765(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from DE1996133272 external-priority patent/DE19633272A1/de
Priority claimed from DE1996133273 external-priority patent/DE19633273A1/de
Priority claimed from DE1997115036 external-priority patent/DE19715036A1/de
Priority claimed from DE1997131419 external-priority patent/DE19731419A1/de
Priority to DE59707512T priority Critical patent/DE59707512D1/de
Priority to EP97941943A priority patent/EP0918805B2/de
Application filed by BASF SE filed Critical BASF SE
Priority to US09/242,464 priority patent/US6444762B1/en
Priority to JP51040198A priority patent/JP3838668B2/ja
Publication of WO1998007765A2 publication Critical patent/WO1998007765A2/de
Publication of WO1998007765A3 publication Critical patent/WO1998007765A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/50—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

Verfahren zur kontinuierlichen anionischen Polymerisation oder Copolymerisation von Styrol- oder Dienmonomeren mit Alkalimetallalkyl als Polymerisationsauslöser, die in Gegenwart eines Metallalkyls oder -aryls eines mindestens zweiwertig auftretenden Elements als Geschwindigkeitsregler vorgenommen wird, vorzugsweise unter nicht-isothermen Bedingungen und ohne Rückvermischung in einem Rohr- oder Rohrbündelreaktor, wobei vorzugsweise ein Metallalkyl oder -aryl A der Formel R1M1 und ein Metallalkyl oder -aryl B der Formel R2nM2 in einem molaren Verhältnis von B zu A von 0,1:1 bis 500:1 verwendet wird, in denen bedeuten M1: Li, Na oder K; R1: Wasserstoff, C¿1?-C20-Alkyl oder C6-C20-Aryl oder C7-C20-alkylsubstituiertes Aryl; M?2¿: ein n-wertiges Element der Gruppe 2a, 2b oder 3a des Periodensystems; und R2: Wasserstoff, Halogen, C¿1?-C20-Alkyl oder C6-C20-Aryl; sowie ein spezieller Initiator für die anionische Polymeriation, der keine Lewisbase enthält.
PCT/EP1997/004497 1996-08-19 1997-08-18 Verfahren zur anionischen polymerisation Ceased WO1998007765A2 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP51040198A JP3838668B2 (ja) 1996-08-19 1997-08-18 アニオン重合
US09/242,464 US6444762B1 (en) 1996-08-19 1997-08-18 Anionic polymerization process
DE59707512T DE59707512D1 (de) 1996-08-19 1997-08-18 Verfahren zur anionischen polymerisation
EP97941943A EP0918805B2 (de) 1996-08-19 1997-08-18 Verfahren zur anionischen polymerisation

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
DE19633273.7 1996-08-19
DE1996133272 DE19633272A1 (de) 1996-08-19 1996-08-19 Verfahren zur anionischen Polymerisation
DE1996133273 DE19633273A1 (de) 1996-08-19 1996-08-19 Verfahren zur anionischen Polymerisation
DE19633272.9 1996-08-19
DE1997115036 DE19715036A1 (de) 1997-04-11 1997-04-11 Verfahren zur kontrollierten anionischen Polymerisation von vinylaromatischen Monomeren
DE19715036.5 1997-04-11
DE19731419.8 1997-07-22
DE1997131419 DE19731419A1 (de) 1997-07-22 1997-07-22 Verfahren zur anionischen Polymerisation

Publications (2)

Publication Number Publication Date
WO1998007765A2 WO1998007765A2 (de) 1998-02-26
WO1998007765A3 true WO1998007765A3 (de) 1998-07-23

Family

ID=27438412

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1997/004497 Ceased WO1998007765A2 (de) 1996-08-19 1997-08-18 Verfahren zur anionischen polymerisation

Country Status (8)

Country Link
US (1) US6444762B1 (de)
EP (1) EP0918805B2 (de)
JP (1) JP3838668B2 (de)
KR (1) KR100487452B1 (de)
CN (1) CN1124289C (de)
DE (1) DE59707512D1 (de)
ES (1) ES2178784T5 (de)
WO (1) WO1998007765A2 (de)

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DE19721400A1 (de) * 1997-05-22 1998-11-26 Basf Ag Verfahren zur Herstellung von Dienpolymerisatlösungen in vinylaromatischen Monomeren
CN1119361C (zh) 1998-02-07 2003-08-27 巴斯福股份公司 制备抗冲改性的热塑性模塑组合物的工艺
DE19806774A1 (de) 1998-02-18 1999-08-19 Basf Ag Verfahren zur retardierten anionischen Polymerisation
DE19806772A1 (de) 1998-02-18 1999-08-19 Basf Ag Verfahren zur Herstellung einer Initiatorzusammensetzung zur retardierten anionischen Polymerisation
DE19806785A1 (de) 1998-02-18 1999-08-19 Basf Ag Verfahren zur Herstellung von Blockcopolymeren durch retardierten anionischen Polymerisation
DE19806775A1 (de) 1998-02-18 1999-08-19 Basf Ag Verfahren zur retardierten anionischen Polymerisation
DE19843687A1 (de) * 1998-09-24 2000-03-30 Basf Ag Verfahren zur anionischen Polymerisation von Dienen
US6455651B1 (en) 1999-04-23 2002-09-24 Kraton Polymers U.S. Llc Uniform initiation of anionic polymerization using organo-substituted alkali metal initiators
US6391981B1 (en) 1999-04-23 2002-05-21 Kraton Polymers Us Llc Increased throughput in the manufacture of anionic polymers by reduction in polymer cement viscosity through the addition of metal alkyls
EP1177220B1 (de) * 1999-04-23 2005-03-02 KRATON Polymers Research B.V. Verfahren zum anionisch polymerisieren von monomeren mit einem monofunktionellen anionischen polymerisierungsinitiator
KR20020009617A (ko) 1999-05-21 2002-02-01 스타르크, 카르크 입체적으로 우세한 킬레이트 촉매를 사용하는 스티렌 용액상태의 고무 재료의 제조 방법
DE19936566A1 (de) 1999-08-04 2001-02-08 Basf Ag Verfahren zum Herstellen einer Lösung von Dienpolymerisaten in vinylaromatischen Verbindungen sowie zum Herstellen von schlagzähen vinylaromatischen Polymeren durch Polymerisation dieser Lösung
DE19954818A1 (de) 1999-11-13 2001-05-17 Basf Ag Verfahren zur anionischen Polymerisation von vinylaromatischen Monomeren
WO2001077199A1 (fr) * 2000-04-07 2001-10-18 Riken Composition catalytique et procede de production de copolymere
DE10022504A1 (de) * 2000-05-10 2001-11-15 Basf Ag Anionisch polymerisiertes, schlagzähes Polystyrol mit Kapselteilchenmorphologie
JP2002128941A (ja) * 2000-08-16 2002-05-09 Asahi Kasei Corp 押出発泡スチレンボード
DE60107187T2 (de) 2000-10-17 2005-11-03 Société de Technologie Michelin Verfahren zur Herstellung eines Dienelastomers durch anionische Polymerisation
US6979717B2 (en) 2001-08-13 2005-12-27 Moore Eugene R Anionic process design for rapid polymerization of polystyrene without gel formation and product produced there from
JP5105676B2 (ja) * 2001-09-27 2012-12-26 旭化成ケミカルズ株式会社 スチレン樹脂の製造方法
DE10152116A1 (de) * 2001-10-23 2003-04-30 Basf Ag Verfahren zur kontinuierlichen anionischen Polymerisation von schlagzähem Polystyrol
DE10218161A1 (de) * 2002-04-23 2003-11-13 Basf Ag Initiatorzusammensetzung und Verfahren zur anionischen Polymerisation
ES2307979T3 (es) 2002-07-11 2008-12-01 Kraton Polymers Research B.V. Copolimeros estirenicos de bloques y el procedimiento para su preparacion.
US6657028B1 (en) * 2002-08-01 2003-12-02 Albemarle Corporation Anionic polymerization process
US7157283B2 (en) * 2002-08-02 2007-01-02 3M Innovative Properties Company Continuous process for the production of combinatorial libraries of modified materials
US7632916B2 (en) * 2002-08-02 2009-12-15 3M Innovative Properties Company Process to modify polymeric materials and resulting compositions
DE10250280A1 (de) * 2002-10-28 2004-05-13 Basf Ag Verfahren zur anionischen Polymerisation von schlagzähem Polystyrol
DE10307058A1 (de) * 2003-02-19 2004-09-02 Basf Ag Verfahren zur anionischen Polymerisation von α-Methylstyrol
DE10350998A1 (de) * 2003-10-30 2005-06-02 Basf Ag Verfahren zur anionischen Polymerisation von Monomeren in α-Methylstyrol
DE102004008199A1 (de) * 2004-02-18 2005-09-01 Basf Ag Verbessertes Verfahren zur Herstellung von schlagzähem Polystyrol
JP2005281688A (ja) * 2004-03-01 2005-10-13 Nippon Soda Co Ltd アニオン重合体の製造方法
US7351777B2 (en) * 2005-03-30 2008-04-01 Moore Eugene R Retarded anionic polymerization of vinyl aromatic monomers using insoluble or heterogeneous retardants
ES2473893T3 (es) * 2005-06-15 2014-07-08 Nippon Soda Co., Ltd. Método para producir un pol�mero
CN100415776C (zh) * 2006-05-22 2008-09-03 北京化工大学 用于控制丁二烯均聚物和共聚物微观结构的方法
US20080058482A1 (en) * 2006-08-29 2008-03-06 3M Innovative Properties Company Continuous process polymerization of (meth)acrylate copolymers
HUE066094T2 (hu) 2016-04-05 2024-07-28 Albemarle Corp Szénhidrogénnel oldható só-hidrid katalizátor hidrogénnel közvetített só-hidrid alapú anionos láncátviteli polimerizációhoz és az ebbõl elõállított polimereloszlási készítmények és az elõállításához szükséges folyamat
CN107556415B (zh) * 2016-06-30 2020-06-09 中国石油化工股份有限公司 一种液体聚共轭二烯烃橡胶及其制备方法
CN107556416B (zh) * 2016-06-30 2020-06-09 中国石油化工股份有限公司 一种液体聚异戊二烯橡胶及其制备方法
KR102159608B1 (ko) * 2016-12-22 2020-09-25 주식회사 엘지화학 변성 개시제 제조방법 및 제조장치
KR101857392B1 (ko) * 2017-01-03 2018-06-19 주식회사 엘지화학 변성 공액디엔계 중합체 제조방법
CN109251264B (zh) * 2017-07-14 2021-04-13 中国石油化工股份有限公司 低顺式聚丁二烯橡胶及其制备方法和hips树脂及其制备方法
CN109485791B (zh) * 2017-09-13 2021-10-19 中国石油化工股份有限公司 线形丁苯共聚物及其制备方法和组合物以及芳族乙烯基树脂及其制备方法
CN109503763B (zh) * 2017-09-14 2021-11-19 中国石油化工股份有限公司 丁二烯-异戊二烯共聚物及其制备方法和芳族乙烯基树脂及其制备方法
KR102154046B1 (ko) * 2017-10-26 2020-09-09 주식회사 엘지화학 연속식 중합에 의한 공액디엔계 중합체의 제조방법
CN114574132A (zh) * 2022-05-09 2022-06-03 常熟东南塑料有限公司 一种耐高温酚醛树脂胶黏剂及其制备方法
CN115124645B (zh) * 2022-07-20 2023-07-21 大连理工大学 一类具有结晶性的交替结构聚烯烃材料及其制备方法

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DE1272548B (de) * 1966-11-09 1968-07-11 Vnii Sint Kauchuka Im Akademik Verfahren zur Polymerisation von Isopren
DE1292848B (de) * 1966-12-13 1969-04-17 Vnii Sint Kaucuka Verfahren zur Polymerisation und Mischpolymerisation von Diolefinen
DE2263104A1 (de) * 1972-01-21 1973-07-26 Shell Int Research Verfahren zur herstellung eines polymers eines konjugierten diens durch loesungspolymerisation
EP0595119A1 (de) * 1992-10-24 1994-05-04 BASF Aktiengesellschaft Verfahren zur Herstellung einer vinylaromatischen Verbindung

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WO1997033923A1 (fr) 1996-03-14 1997-09-18 Asahi Kasei Kogyo Kabushiki Kaisha Procede de preparation de polymeres vinyliques, initiateur de polymerisation de monomeres vinyliques et composition de resine styrenique

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DE1272548B (de) * 1966-11-09 1968-07-11 Vnii Sint Kauchuka Im Akademik Verfahren zur Polymerisation von Isopren
DE1292848B (de) * 1966-12-13 1969-04-17 Vnii Sint Kaucuka Verfahren zur Polymerisation und Mischpolymerisation von Diolefinen
DE2263104A1 (de) * 1972-01-21 1973-07-26 Shell Int Research Verfahren zur herstellung eines polymers eines konjugierten diens durch loesungspolymerisation
EP0595119A1 (de) * 1992-10-24 1994-05-04 BASF Aktiengesellschaft Verfahren zur Herstellung einer vinylaromatischen Verbindung

Also Published As

Publication number Publication date
KR100487452B1 (ko) 2005-05-09
DE59707512D1 (de) 2002-07-18
CN1231679A (zh) 1999-10-13
EP0918805A2 (de) 1999-06-02
EP0918805B1 (de) 2002-06-12
JP2000516286A (ja) 2000-12-05
CN1124289C (zh) 2003-10-15
KR20000068199A (ko) 2000-11-25
US6444762B1 (en) 2002-09-03
EP0918805B2 (de) 2007-08-22
ES2178784T5 (es) 2008-02-01
JP3838668B2 (ja) 2006-10-25
WO1998007765A2 (de) 1998-02-26
ES2178784T3 (es) 2003-01-01

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