WO2000005175A2 - Verfahren und vorrichtung zur kapazitiven demineralisierung von ionen enthaltenden flüssigkeiten - Google Patents
Verfahren und vorrichtung zur kapazitiven demineralisierung von ionen enthaltenden flüssigkeiten Download PDFInfo
- Publication number
- WO2000005175A2 WO2000005175A2 PCT/DE1999/002220 DE9902220W WO0005175A2 WO 2000005175 A2 WO2000005175 A2 WO 2000005175A2 DE 9902220 W DE9902220 W DE 9902220W WO 0005175 A2 WO0005175 A2 WO 0005175A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- voltage
- ions
- filter
- container
- capacitor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F1/4691—Capacitive deionisation
Definitions
- the invention relates to a method and a device for the capacitive demineralization of liquids containing ions.
- Publication W098 / 17587 describes methods and devices for water treatment, in particular demineralization and decarbonization, relating to the prior art.
- the problem is considered to be that it is important to carry out the electrode reaction below the water decomposition voltage of 1.23 V, since otherwise H + ions form at the anode, which
- ERSATZBL ⁇ TT (RULE 26) would lower value again.
- the success of the process is limited to the oxygen present in the water and its electrochemical conversion at the cathode.
- W098 / 17587 it is proposed in W098 / 17587 to form the necessary OH ⁇ ions by electrolytically decomposing water at the cathode.
- a diaphragm is intended to prevent the OH " ions from recombining with H + ions formed on the cathode.
- an arrangement of high-capacity electrodes which preferably consist of a conductive material with an extremely high surface area, is used in a filter container with a filter or diaphragm wall.
- the ions contained in the liquid are passed through the filter wall of the filter container in a next process step and form an on the electrode surface so-called bilayer layer.
- a series of clocked voltage peaks is then introduced into this bilayer layers, which represent a supersaturated solution, which leads to the precipitation of microcrystalline structures resulting from ionic compounds. These microcrystalline structures can then be removed from the filter container.
- a closed cup-shaped filter wall with a pore size that surrounds the highly capacitive electrodes is preferably used as the diaphragm or filter wall, which largely prevents water from penetrating, but allows the ions having a hydration shell to pass through.
- Suitable filtration methods or other retention methods can be used to remove the precipitated microcrystalline structures.
- dissolved ions that cannot be precipitated by introducing the clocked voltage peaks can preferably be detached by suitable depolarization or polarity reversal of the capacitor elements or high-capacity electrodes and removed from the medium by binding to suitable surfaces or by clocked flushing processes.
- the device according to the invention can, in particular for large-scale use, preferably be constructed modularly and in the form of an aander, in order to increase the efficiency and to make the polarization reversal possible without major electrical losses. Further details, features and advantages of the invention result from the following description of an embodiment with reference to the drawing.
- the figure shows a device 1 which, in the embodiment shown, has an outer container 2 with an inlet 3 and an outlet 4 for a liquid containing ions which can be introduced into the interior 5.
- a filter container 6 is arranged in the interior 5 of the container 2.
- the filter container 6 has a filter / diaphragm wall 7.
- the filter container 6 encloses a treatment room 17, in which two highly capacitive electrodes or capacitor elements are preferably arranged in the form of capacitor plates 8, 9 with a very high surface area. If necessary, a diaphragm can also be arranged between the capacitor plates 8, 9.
- the capacitor plates 8, 9 are electrically connected to a first voltage source 10.
- the container 2 also has an unpressurized outlet 11 through which precipitated microcrystalline structures can be removed from the treatment room 17 in a suitable manner, for example by appropriate differential pressure conditions.
- the figure also illustrates a generating device 12 for introducing voltage peaks into the space between the capacitor plates 8, 9.
- This generating device 12 has a voltage source 13 and, in the example, a coil 14, which is arranged around the capacitor plates 8, 9 in the embodiment shown in the figure.
- a coil 14 which is arranged around the capacitor plates 8, 9 in the embodiment shown in the figure.
- the liquid or the liquid medium is first introduced via the inlet 3 into the interior 5 of the container 2.
- ions migrate through the diaphragm wall 7, which leads to the formation of two bilayer layers 15, 16 on the capacitor plates 8, 9.
- microcrystalline structures precipitate, which by means of special devices, such as, for example, filtration devices, pass through the pressure-free outlet 11 of FIG Device 1 can be withdrawn. Ions that cannot precipitate can be removed from the container by rinsing processes or by binding to suitable surfaces.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Molecular Biology (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Description
Claims
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/744,525 US6485624B1 (en) | 1998-07-21 | 1999-07-21 | Method and device for capacitative demineralization of liquids which contain ions |
| EP99948651A EP1098853B1 (de) | 1998-07-21 | 1999-07-21 | Verfahren und vorrichtung zur kapazitiven demineralisierung von ionen enthaltenden flüssigkeiten |
| CA002378039A CA2378039C (en) | 1998-07-21 | 1999-07-21 | Process and apparatus for the capacitive demineralization of liquids containing ions |
| AU61860/99A AU6186099A (en) | 1998-07-21 | 1999-07-21 | Method and device for capacitative demineralization of fluids containing ions |
| AT99948651T ATE212005T1 (de) | 1998-07-21 | 1999-07-21 | Verfahren und vorrichtung zur kapazitiven demineralisierung von ionen enthaltenden flüssigkeiten |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19832822A DE19832822A1 (de) | 1998-07-21 | 1998-07-21 | Verfahren und Vorrichtung zur kapazitiven Demineralisierung von Ionen enthaltenden Flüssigkeiten |
| DE19832822.2 | 1998-07-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2000005175A2 true WO2000005175A2 (de) | 2000-02-03 |
| WO2000005175A3 WO2000005175A3 (de) | 2000-04-27 |
Family
ID=7874829
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/DE1999/002220 Ceased WO2000005175A2 (de) | 1998-07-21 | 1999-07-21 | Verfahren und vorrichtung zur kapazitiven demineralisierung von ionen enthaltenden flüssigkeiten |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6485624B1 (de) |
| EP (1) | EP1098853B1 (de) |
| AT (1) | ATE212005T1 (de) |
| AU (1) | AU6186099A (de) |
| CA (1) | CA2378039C (de) |
| DE (1) | DE19832822A1 (de) |
| WO (1) | WO2000005175A2 (de) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2817318A1 (fr) | 2000-11-24 | 2002-05-31 | Coflexip | Conduite tubulaire flexible |
| EP1447382A1 (de) * | 2003-02-12 | 2004-08-18 | Bonferraro S.p.A. | Methode zur Bestimmung der Effizienz von Wasserenthärtern und Vorrichtung zu deren Ausführung |
| EP3749617A4 (de) * | 2018-02-07 | 2021-10-13 | Orler, Anthony, J. | Elektromagnetische fluidtrennung und -kombination |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6686207B2 (en) * | 2001-10-12 | 2004-02-03 | Massachusetts Institute Of Technology | Manipulating micron scale items |
| DE102009054308A1 (de) | 2009-11-24 | 2011-05-26 | Aqua-Fair Gmbh | Vorrichtung für eine elektromagnetische Behandlung eines in einem Rohr strömenden Fluids |
| DE102013020288A1 (de) | 2013-12-09 | 2015-06-11 | Aqua-Fair Gmbh | Verfahren für eine elektromagnetische Behandlung eines in einem Rohr strömenden Fluids |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3716459A (en) | 1969-10-16 | 1973-02-13 | Brown John Constr | Electrochemical processes |
| CH677922A5 (de) | 1989-01-04 | 1991-07-15 | Hans Lueber | |
| DE4003516C2 (de) | 1990-02-06 | 1994-06-23 | Heraeus Elektrochemie | Elektrodenelement für elektrolytische Zwecke und dessen Verwendung |
| US5425858A (en) * | 1994-05-20 | 1995-06-20 | The Regents Of The University Of California | Method and apparatus for capacitive deionization, electrochemical purification, and regeneration of electrodes |
| DE4421608A1 (de) | 1994-06-21 | 1996-01-04 | Finke Gretel Geb Offinger | Verfahren zur anodischen Oxydation von organischen Verbindungen, Entsalzungsanlagen vorzuschalten, welche Membranen für ihren Betrieb verwenden |
| EP0951448A1 (de) * | 1996-10-17 | 1999-10-27 | Maitron Chemiefreie Wasserbehandlung G.M.B.H. | Verfahren und vorrichtung zur elektrophysikalischen wasserbehandlung |
-
1998
- 1998-07-21 DE DE19832822A patent/DE19832822A1/de not_active Ceased
-
1999
- 1999-07-21 CA CA002378039A patent/CA2378039C/en not_active Expired - Fee Related
- 1999-07-21 AT AT99948651T patent/ATE212005T1/de active
- 1999-07-21 EP EP99948651A patent/EP1098853B1/de not_active Expired - Lifetime
- 1999-07-21 US US09/744,525 patent/US6485624B1/en not_active Expired - Fee Related
- 1999-07-21 AU AU61860/99A patent/AU6186099A/en not_active Abandoned
- 1999-07-21 WO PCT/DE1999/002220 patent/WO2000005175A2/de not_active Ceased
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2817318A1 (fr) | 2000-11-24 | 2002-05-31 | Coflexip | Conduite tubulaire flexible |
| EP1447382A1 (de) * | 2003-02-12 | 2004-08-18 | Bonferraro S.p.A. | Methode zur Bestimmung der Effizienz von Wasserenthärtern und Vorrichtung zu deren Ausführung |
| EP3749617A4 (de) * | 2018-02-07 | 2021-10-13 | Orler, Anthony, J. | Elektromagnetische fluidtrennung und -kombination |
Also Published As
| Publication number | Publication date |
|---|---|
| US6485624B1 (en) | 2002-11-26 |
| ATE212005T1 (de) | 2002-02-15 |
| CA2378039A1 (en) | 2000-02-03 |
| DE19832822A1 (de) | 2000-03-09 |
| EP1098853B1 (de) | 2002-01-16 |
| WO2000005175A3 (de) | 2000-04-27 |
| CA2378039C (en) | 2009-09-22 |
| EP1098853A2 (de) | 2001-05-16 |
| AU6186099A (en) | 2000-02-14 |
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