WO2000077143A1 - Produit de nettoyage - Google Patents

Produit de nettoyage Download PDF

Info

Publication number
WO2000077143A1
WO2000077143A1 PCT/US1999/013463 US9913463W WO0077143A1 WO 2000077143 A1 WO2000077143 A1 WO 2000077143A1 US 9913463 W US9913463 W US 9913463W WO 0077143 A1 WO0077143 A1 WO 0077143A1
Authority
WO
WIPO (PCT)
Prior art keywords
alkyl
composition according
polymer
acid
cleaning composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1999/013463
Other languages
English (en)
Inventor
Alan Edward Sherry
Alex Cedeno
Ivano Schiavi
Jan Bertrem
Agmed Gourari
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to PCT/US1999/013463 priority Critical patent/WO2000077143A1/fr
Priority to AU46844/99A priority patent/AU4684499A/en
Priority to CA002374534A priority patent/CA2374534A1/fr
Priority to EP99973905A priority patent/EP1185604A1/fr
Priority to JP2001503984A priority patent/JP2003524681A/ja
Priority to AU14656/00A priority patent/AU1465600A/en
Priority to PCT/US1999/025912 priority patent/WO2000077144A1/fr
Priority to MXPA01013283A priority patent/MXPA01013283A/es
Priority to ARP000102955A priority patent/AR021446A1/es
Publication of WO2000077143A1 publication Critical patent/WO2000077143A1/fr
Priority to ZA200109900A priority patent/ZA200109900B/xx
Priority to US10/020,710 priority patent/US20030017960A1/en
Anticipated expiration legal-status Critical
Priority to US11/215,194 priority patent/US7256165B2/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3749—Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3792—Amine oxide containing polymers

Definitions

  • the present invention relates to the technical field of cleaning compositions for surfaces, especially ceramic, steel, plastic, glass and/or painted surfaces and process for cleaning such surfaces.
  • the composition of the present invention comprises a surface substantive polymer as an essential component thereof.
  • surface substantive it is meant a polymer that is capable of modifying the surface by adhering or in some way associating with the surface to be cleaned such that it remains on the surface during and after the cleaning process. Such adhesion or association may be for example by: covalent interaction; electrostatic interaction; hydrogen bonding; or van der waals forces.
  • the polymer modifies the surface by rendering it hydrophilic meaning that the contact angle between water and the surface, after the surface has been treated with the polymer-containing composition, is less than 50°, more preferably less than 40°, more preferably less than 30°, most preferably 20° or less.
  • the contact angle is measured according to the American Standard Test Method for measuring contact angle, designation number D5725- 95 using the apparatus commercially sold under the trade name Contact Angle Measuring System G10 by Kruss.
  • the polymer is capable of durably modifying the surface to render it hydrophilic, providing a surface contact angle between water and the surface of less than 50°, more preferably less than 40°, more preferably less than 30°, most preferably 20° or less.
  • a surface contact angle between water and the surface of less than 50°, more preferably less than 40°, more preferably less than 30°, most preferably 20° or less.
  • the hydrophilic surface modification is maintained for at least one rinse, preferably at least three rinses, more preferably at least five rinses, more preferably at least seven rinses, most preferably at least ten rinses or even at least thirty rinses carried out according to the rinse test method described herein.
  • suitable vinylpyrrolidone homopolymers for use herein have an average molecular weight of from 1 ,000 to 100,000,000, preferably from 2,000 to 10,000,000, more preferably from 5,000 to 1 ,000,000, and most preferably from 50,000 to 500,000.
  • Said anti-resoiling agent preferably further comprises from 0.5% to 20%, by weight of the oligomer, of a crystallinity- reducing stabiliser, for example an anionic surfactant such as linear sodium dodecylbenzenesulfonate or a member selected from xylene-, cumene-, and toluene- sulfonates or mixtures thereof, these stabilizers or modifiers being introduced into the synthesis vessel, all as taught in U.S. 5,415,807, Gosselink, Pan, Kellett and Hall, issued May 16, 1995.
  • Suitable monomers for the above anti-resoiling agent include Na-2-(2-hydroxyethoxy)-ethanesulfonate, DMT, Na- dimethyl-5-sulfoisophthalate, EG and PG.
  • each R is selected from the group consisting of R2, R c .
  • each R4 is independently selected from the group consisting of H, C1-C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-C20 arylalkyl, aminoalkyl, alkylaminoalkyl, dialkylaminoalkyl, piperidinoalkyl, morpholinoalkyl, cycloalkylaminoalkyl and hydroxyalkyi;
  • Preferred amine oxide surfactants to be used according to the present invention are amine oxides having the following formula R1 R2 3NO wherein R1 is a hydrocarbon chain comprising from 1 to 30 carbon atoms, preferably from 6 to 20, more preferably from 8 to 16, most preferably from 8 to 12, and wherein R2 and R3 are independently substituted or unsubstituted, linear or branched hydrocarbon chains comprising from 1 to 4 carbon atoms, preferably from 1 to 3 carbon atoms, and more preferably are methyl groups.
  • R1 may be a saturated, substituted or unsubstituted linear or branched hydrocarbon chain.
  • Suitable amine oxides for use herein are for instance natural blend C8-C10 amine oxides as well as C12-C16 amine oxides commercially available from Hoechst.
  • Suitable zwitterionic surfactants for use herein contain both a cationic hydrophilic group, i.e., a quaternary ammonium group, and anionic hydrophilic group on the same molecule at a relatively wide range of pH's.
  • the typical anionic hydrophilic groups are carboxylates and sulfonates, although other groups like sulfates, phosphonates, and the like can be used.
  • a generic formula for the zwitterionic surfactants to be used herein is :
  • compositions of the present invention may comprise a chelating agent as a preferred optional ingredient.
  • a chelating agent may be any of those known to those skilled in the art such as the ones selected from the group comprising phosphonate chelating agents, amino carboxylate chelating agents, other carboxylate chelating agents, polyfunctionally-substituted aromatic chelating agents, ethylenediamine N,N'- disuccinic acids, or mixtures thereof.
  • Polyfunctionally-substituted aromatic chelating agents may also be useful in the compositions herein. See U.S. patent 3,812,044, issued May 21 , 1974, to Connor et al. Preferred compounds of this type in acid form are dihydroxydisulfobenzenes such as 1 ,2-dihydroxy -3,5-disulfobenzene.
  • a preferred biodegradable chelating agent for use herein is ethylene diamine N,N'- disuccinic acid, or alkali metal, or alkaline earth, ammonium or substitutes ammonium salts thereof or mixtures thereof.
  • Preferred amongst those cyclic compounds are dipicolinic acid and chelidanic acid.
  • Another preferred lipase herein is obtained by cloning the gene from Humicola lanuginosa and expressing the gene in Aspergillus oryza. as host, as described in European Patent Application, EP-A-0258 068, which is commercially available from Novo Industri A/S, Bagsvaerd, Denmark, under the trade name Lipolase. This lipase is also described in U.S. Patent 4,810,414, Huge-Jensen et al, issued March 7, 1989.
  • suds controlling agents may include alkali metal (e.g., sodium or potassium) fatty acids, or soaps thereof, containing from about 8 to about 24, preferably from about 10 to about 20 carbon atoms.
  • alkali metal e.g., sodium or potassium
  • soaps thereof containing from about 8 to about 24, preferably from about 10 to about 20 carbon atoms.
  • compositions can comprise a silicone/silica mixture in combination with fumed nonporous silica such as AerosilR.
  • Citric acid is commercially available as an aqueous solution from Jungbunzlauer under the trade name Citric acid®.
  • the compositions according to the present invention may comprise up to 15% by weight of the total composition of a pH buffer, or mixtures thereof, preferably from 0.001% to 10%, more preferably from 0.001% to 5% and most preferably from 0.005% to 3%.
  • Such materials typically have vapour pressures lower than that of the average perfume material. Also, they typically have molecular weights of about 200 and above, and are detectable at levels below those of the average perfume material.
  • Perfume ingredients useful herein, along with their odor character, and their physical and chemical properties, such as boiling point and molecular weight, are given in "Perfume and Flavor Chemicals (Aroma Chemicals),” Steffen Arctander, published by the author, 1969, incorporated herein by reference.
  • compositions herein may be packaged in a variety of suitable packaging known to those skilled in the art, depending on the form of the composition.
  • the liquid compositions are preferably packaged in conventional bottles that do not chemical react with the composition being stored.
  • the bottles are preferably made of plastic.
  • a preferred spray dispenser herein is a container wherein the means for delivering the composition comprises an electrically driven pump and a spray arm. Said spray arm is either extended or extendible and has at least one aperture so that in operation, the composition is pumped by said electrically driven pump from the container, through the spray arm to the aperture from which it is dispensed. It is preferred that the spray arm communicates with the container by means of a flexible connector.
  • the spray arm may have at least one aperture located along its length. The spray arm makes it easier to control where the composition is sprayed and therefore, the accuracy with which the composition is applied is increased.
  • PVNO is polyvinyl pyridine N-oxide supplied by Reilly having molecular weight

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Vehicle Cleaning, Maintenance, Repair, Refitting, And Outriggers (AREA)

Abstract

La présente invention concerne un produit de nettoyage qui comprend un polymère substantif de surface, destiné à nettoyer des surfaces, en particulier les surfaces extérieures d'un véhicule.
PCT/US1999/013463 1999-06-15 1999-06-15 Produit de nettoyage Ceased WO2000077143A1 (fr)

Priority Applications (12)

Application Number Priority Date Filing Date Title
PCT/US1999/013463 WO2000077143A1 (fr) 1999-06-15 1999-06-15 Produit de nettoyage
AU46844/99A AU4684499A (en) 1999-06-15 1999-06-15 Cleaning compositions
MXPA01013283A MXPA01013283A (es) 1999-06-15 1999-11-03 Composiciones limpiadoras.
EP99973905A EP1185604A1 (fr) 1999-06-15 1999-11-03 Composition de nettoyage
JP2001503984A JP2003524681A (ja) 1999-06-15 1999-11-03 洗浄組成物
AU14656/00A AU1465600A (en) 1999-06-15 1999-11-03 Cleaning compositions
PCT/US1999/025912 WO2000077144A1 (fr) 1999-06-15 1999-11-03 Composition de nettoyage
CA002374534A CA2374534A1 (fr) 1999-06-15 1999-11-03 Composition de nettoyage contenant une surface polymere substantive
ARP000102955A AR021446A1 (es) 1999-06-15 2000-06-15 Composiciones de limpieza
ZA200109900A ZA200109900B (en) 1999-06-15 2001-11-30 Cleaning compositions.
US10/020,710 US20030017960A1 (en) 1999-06-15 2001-12-14 Cleaning compositions
US11/215,194 US7256165B2 (en) 1999-06-15 2005-08-30 Cleaning compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1999/013463 WO2000077143A1 (fr) 1999-06-15 1999-06-15 Produit de nettoyage

Publications (1)

Publication Number Publication Date
WO2000077143A1 true WO2000077143A1 (fr) 2000-12-21

Family

ID=22272971

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US1999/013463 Ceased WO2000077143A1 (fr) 1999-06-15 1999-06-15 Produit de nettoyage
PCT/US1999/025912 Ceased WO2000077144A1 (fr) 1999-06-15 1999-11-03 Composition de nettoyage

Family Applications After (1)

Application Number Title Priority Date Filing Date
PCT/US1999/025912 Ceased WO2000077144A1 (fr) 1999-06-15 1999-11-03 Composition de nettoyage

Country Status (8)

Country Link
EP (1) EP1185604A1 (fr)
JP (1) JP2003524681A (fr)
AR (1) AR021446A1 (fr)
AU (2) AU4684499A (fr)
CA (1) CA2374534A1 (fr)
MX (1) MXPA01013283A (fr)
WO (2) WO2000077143A1 (fr)
ZA (1) ZA200109900B (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6562142B2 (en) 2001-01-30 2003-05-13 The Procter & Gamble Company System and method for cleaning and/or treating vehicles and the surfaces of other objects
US6664218B1 (en) * 2002-09-17 2003-12-16 Colgate-Palmolive Co Cleaning composition containing a hydrophilizing polymer
EP1362907A3 (fr) * 2002-05-17 2004-04-28 The Clorox Company Composition pour faciliter le nettoyage des surfaces dures et des films polymériques gélifiés
US6869028B2 (en) 2000-06-14 2005-03-22 The Procter & Gamble Company Spraying device
US7256165B2 (en) 1999-06-15 2007-08-14 The Procter & Gamble Company Cleaning compositions
US7264678B2 (en) 2000-06-14 2007-09-04 The Procter & Gamble Company Process for cleaning a surface
US7381279B2 (en) 2000-06-14 2008-06-03 The Procter & Gamble Company Article for deionization of water
US7741265B2 (en) 2007-08-14 2010-06-22 S.C. Johnson & Son, Inc. Hard surface cleaner with extended residual cleaning benefit
JP2018150523A (ja) * 2017-03-10 2018-09-27 花王株式会社 硬質表面用液体洗浄剤組成物

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4671013B2 (ja) * 2001-09-26 2011-04-13 栗田工業株式会社 塗工バッキングロールの洗浄方法
JP2008169361A (ja) * 2007-01-15 2008-07-24 Nicca Chemical Co Ltd 樹脂表面用洗浄剤及び樹脂表面の洗浄方法
JP6644638B2 (ja) * 2016-05-27 2020-02-12 花王株式会社 硬質表面用液体洗浄剤組成物
EP3569683B1 (fr) 2018-05-15 2020-10-14 The Procter & Gamble Company Compositions acides liquides pour le nettoyage des surfaces dures fournissant une maintenance améliorée de la brillance de surface et une prévention des marques d'eau et des marques d'éclaboussures

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4368146A (en) * 1979-01-12 1983-01-11 Lever Brothers Company Light duty hand dishwashing liquid detergent composition
WO1995000611A1 (fr) * 1993-06-25 1995-01-05 Verona Inc. Composition de nettoyant de sols en bois dur contenant de l'alkyl pyrrolidone
WO1997033963A1 (fr) * 1996-03-14 1997-09-18 The Procter & Gamble Company Compositions d'agents de nettoyage du verre presentant de bonnes caracteristiques de formation de films/trainees a fonctionnalite polymeres d'oxydes aminiques
WO1997043373A1 (fr) * 1996-05-13 1997-11-20 Bausch & Lomb Incorporated Composition et procede pour inhiber le depot proteinique sur des lentilles de contact
US5759980A (en) * 1997-03-04 1998-06-02 Blue Coral, Inc. Car wash
EP0859046A1 (fr) * 1997-02-14 1998-08-19 The Procter & Gamble Company Compositions liquides de nettoyage pour surfaces dures
EP0919610A1 (fr) * 1997-10-31 1999-06-02 The Procter & Gamble Company Compositions liquides acides pour enlever le tartre emballées dans un atomiseur

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4368146A (en) * 1979-01-12 1983-01-11 Lever Brothers Company Light duty hand dishwashing liquid detergent composition
WO1995000611A1 (fr) * 1993-06-25 1995-01-05 Verona Inc. Composition de nettoyant de sols en bois dur contenant de l'alkyl pyrrolidone
WO1997033963A1 (fr) * 1996-03-14 1997-09-18 The Procter & Gamble Company Compositions d'agents de nettoyage du verre presentant de bonnes caracteristiques de formation de films/trainees a fonctionnalite polymeres d'oxydes aminiques
WO1997043373A1 (fr) * 1996-05-13 1997-11-20 Bausch & Lomb Incorporated Composition et procede pour inhiber le depot proteinique sur des lentilles de contact
EP0859046A1 (fr) * 1997-02-14 1998-08-19 The Procter & Gamble Company Compositions liquides de nettoyage pour surfaces dures
US5759980A (en) * 1997-03-04 1998-06-02 Blue Coral, Inc. Car wash
EP0919610A1 (fr) * 1997-10-31 1999-06-02 The Procter & Gamble Company Compositions liquides acides pour enlever le tartre emballées dans un atomiseur

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7256165B2 (en) 1999-06-15 2007-08-14 The Procter & Gamble Company Cleaning compositions
US6869028B2 (en) 2000-06-14 2005-03-22 The Procter & Gamble Company Spraying device
US7264678B2 (en) 2000-06-14 2007-09-04 The Procter & Gamble Company Process for cleaning a surface
US7381279B2 (en) 2000-06-14 2008-06-03 The Procter & Gamble Company Article for deionization of water
US6562142B2 (en) 2001-01-30 2003-05-13 The Procter & Gamble Company System and method for cleaning and/or treating vehicles and the surfaces of other objects
US7322534B2 (en) 2001-06-06 2008-01-29 The Procter And Gamble Company Spraying device
EP1752524A3 (fr) * 2002-05-17 2007-07-25 The Clorox Company Composition pour faciliter le nettoyage des surfaces dures et des films polymériques gélifiés
EP1362907A3 (fr) * 2002-05-17 2004-04-28 The Clorox Company Composition pour faciliter le nettoyage des surfaces dures et des films polymériques gélifiés
US6926745B2 (en) * 2002-05-17 2005-08-09 The Clorox Company Hydroscopic polymer gel films for easier cleaning
US7470290B2 (en) 2002-05-17 2008-12-30 The Clorox Company Hydroscopic polymer gels for easier cleaning
US7699941B2 (en) 2002-05-17 2010-04-20 The Clorox Company Polymeric surface treatment compositions
US7700540B2 (en) 2002-05-17 2010-04-20 The Clorox Company Hard surface cleaning composition
US6664218B1 (en) * 2002-09-17 2003-12-16 Colgate-Palmolive Co Cleaning composition containing a hydrophilizing polymer
US7741265B2 (en) 2007-08-14 2010-06-22 S.C. Johnson & Son, Inc. Hard surface cleaner with extended residual cleaning benefit
JP2018150523A (ja) * 2017-03-10 2018-09-27 花王株式会社 硬質表面用液体洗浄剤組成物

Also Published As

Publication number Publication date
JP2003524681A (ja) 2003-08-19
AR021446A1 (es) 2002-07-17
MXPA01013283A (es) 2002-06-04
AU4684499A (en) 2001-01-02
EP1185604A1 (fr) 2002-03-13
AU1465600A (en) 2001-01-02
ZA200109900B (en) 2003-05-28
CA2374534A1 (fr) 2000-12-21
WO2000077144A1 (fr) 2000-12-21

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