WO2002100538A3 - Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/si02 katalysatoren - Google Patents

Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/si02 katalysatoren Download PDF

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Publication number
WO2002100538A3
WO2002100538A3 PCT/EP2002/006348 EP0206348W WO02100538A3 WO 2002100538 A3 WO2002100538 A3 WO 2002100538A3 EP 0206348 W EP0206348 W EP 0206348W WO 02100538 A3 WO02100538 A3 WO 02100538A3
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WO
WIPO (PCT)
Prior art keywords
production
side chains
cycloaliphatic compounds
hydrogenation
catalysts
Prior art date
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Ceased
Application number
PCT/EP2002/006348
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English (en)
French (fr)
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WO2002100538A2 (de
WO2002100538A8 (de
Inventor
Arnd Boettcher
Jan-Dirk Arndt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to KR20037016145A priority Critical patent/KR20040030664A/ko
Priority to JP2003503350A priority patent/JP2004529200A/ja
Priority to AU2002325235A priority patent/AU2002325235A1/en
Priority to US10/480,239 priority patent/US20040176549A1/en
Priority to EP02758224A priority patent/EP1404444A2/de
Publication of WO2002100538A2 publication Critical patent/WO2002100538A2/de
Publication of WO2002100538A3 publication Critical patent/WO2002100538A3/de
Publication of WO2002100538A8 publication Critical patent/WO2002100538A8/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/28—Ethers with hydroxy compounds containing oxirane rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/28—Ethers with hydroxy compounds containing oxirane rings
    • C07D303/30—Ethers of oxirane-containing polyhydroxy compounds in which all hydroxyl radicals are etherified with oxirane-containing hydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1405—Polycondensates modified by chemical after-treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Verfahren zur Herstellung von cycloaliphatischen Verbindungen (I), die Seitenketten mit Epoxidgruppen aufweisen durch heterogen-katalische Hydrierung einer Vebindung (II), die wenigstens eine carbocyclische, aromatische Gruppe und wenigstens eine Seitenkette mit wenigstens einer Epoxid-Gruppe aufweist, an einem Ruthenium-Katalisator, das dadurch gekennzeichnet ist, dass der Ruthenium-Katalysator erhältlich ist durch: i) ein oder mehrfaches Behandeln eines Trägermaterials auf Basis von amorphem Siliziumdioxid mit einer halogenfreien wässrigen Lösung einer niedermolekularen Rutheniumverbindung und anschliessendes Trocknen des behandelten Trägermaterials bei einer Temperatur unterhalb 200 °C; ii) Reduktion des in (i) erhaltenen Feststoffs mit Wasserstof bei einer Temperatur im Bereich von 100 bis 350 °C, wobei man Schritt (ii) unmittelbar im Anschluss an Schritt (i) durchführt.
PCT/EP2002/006348 2001-06-11 2002-06-10 Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/si02 katalysatoren Ceased WO2002100538A2 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
KR20037016145A KR20040030664A (ko) 2001-06-11 2002-06-10 Ｒｕ/ＳｉＯ2 촉매상 수소화에 의한 에폭시기 함유 측쇄를갖는 지환족 화합물의 제조 방법
JP2003503350A JP2004529200A (ja) 2001-06-11 2002-06-10 エポキシ基を有する側鎖を有する脂環式化合物（ｉ）の製造方法
AU2002325235A AU2002325235A1 (en) 2001-06-11 2002-06-10 Method for the production of cycloaliphatic compounds having side chains with epoxy groups by hydrogenation on ru/s102 catalysts
US10/480,239 US20040176549A1 (en) 2001-06-11 2002-06-10 Method for the production of cycloaliphatic compounds (1) having side chains with epoxy groups
EP02758224A EP1404444A2 (de) 2001-06-11 2002-06-10 Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/sio2 katalysatoren

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10128204A DE10128204A1 (de) 2001-06-11 2001-06-11 Verfahren zur Herstellung von cycloaliphatischen Verbindungen I, die Seitenketten mit Epoxidgruppen aufweisen
DE10128204.4 2001-06-11

Publications (3)

Publication Number Publication Date
WO2002100538A2 WO2002100538A2 (de) 2002-12-19
WO2002100538A3 true WO2002100538A3 (de) 2003-03-27
WO2002100538A8 WO2002100538A8 (de) 2003-11-20

Family

ID=7687862

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/006348 Ceased WO2002100538A2 (de) 2001-06-11 2002-06-10 Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/si02 katalysatoren

Country Status (8)

Country Link
US (1) US20040176549A1 (de)
EP (1) EP1404444A2 (de)
JP (1) JP2004529200A (de)
KR (1) KR20040030664A (de)
CN (1) CN1239488C (de)
AU (1) AU2002325235A1 (de)
DE (1) DE10128204A1 (de)
WO (1) WO2002100538A2 (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005061106A1 (de) * 2003-12-22 2005-07-07 Basf Aktiengesellschaft Ruthenium-heterogenkatalysator, verfahren zur hydrierung einer carbocyclischen aromatischen gruppe und kernhydrierte bisglycidylether der bisphenole a und f
DE10361157A1 (de) * 2003-12-22 2005-07-21 Basf Ag Ruthenium-Heterogenkatalysator und Verfahren zur Herstellung eines Bisglycidylethers der Formel I
DE102005027567A1 (de) 2005-06-14 2006-12-21 Basf Ag Verfahren zum Passivieren von metallischen Oberflächen mit Säuregruppen aufweisenden Polymeren
US20080200703A1 (en) * 2005-06-22 2008-08-21 Basf Aktiengesellschaft Heterogeneous Ruthenium Catalyst and Method For Hydrogenating a Carboxylic Aromatic Group, in Particular For Producing Core Hydrogenated Bisglycidyl Ether Bisphenols A and F
DE102005029200A1 (de) * 2005-06-22 2006-12-28 Basf Ag Katalysator und Verfahren zur Hydrierung von hydrierbare Gruppen enthaltenden organischen Verbindungen
CN101198570B (zh) * 2005-08-26 2011-11-02 旭化成化学株式会社 环烯烃的制造方法
DE102005062354A1 (de) * 2005-12-23 2007-06-28 Basf Ag Verfahren zur Umsetzung eines aromatischen Kohlenwasserstoffs in Gegenwart von Wasserstoff
CN102256919B (zh) 2008-12-17 2014-06-25 巴斯夫欧洲公司 生产取代的环己基甲醇的连续方法
WO2011082991A2 (de) 2009-12-15 2011-07-14 Basf Se Katalysator und verfahren zur hydrierung von aromaten
WO2015138129A1 (en) 2014-03-12 2015-09-17 Dow Global Technologies Llc Process for regenerating catalyst used in hydrogenation of aromatic epoxides
CN106103420B (zh) 2014-03-12 2019-07-23 陶氏环球技术有限责任公司 环氧树脂组合物
CN114570361B (zh) * 2022-03-30 2023-01-06 福州大学 一种用于氨分解制氢Ru基催化剂及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3336241A (en) * 1963-11-12 1967-08-15 Shell Oil Co Process for preparing epoxy compounds and resulting products
US5334790A (en) * 1992-02-26 1994-08-02 Catalytica Process and catalyst for partially hydrogenating aromatics to produce cycloolefins
US6130344A (en) * 1997-11-27 2000-10-10 Mitsubishi Chemical Corporation Process for producing compound having epoxy group

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3629632A1 (de) * 1986-08-30 1988-03-03 Basf Ag Verfahren zur herstellung von 2,2-di-(p-glycidoxi-cyclohexyl)-propan
JP2814711B2 (ja) * 1990-07-13 1998-10-27 三菱化学株式会社 シクロオレフィンの製造法
DE4414089A1 (de) * 1994-04-22 1995-10-26 Basf Ag Verfahren zur selektiven Hydrierung von aromatischen Gruppen in Gegenwart von Epoxygruppen

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3336241A (en) * 1963-11-12 1967-08-15 Shell Oil Co Process for preparing epoxy compounds and resulting products
US5334790A (en) * 1992-02-26 1994-08-02 Catalytica Process and catalyst for partially hydrogenating aromatics to produce cycloolefins
US6130344A (en) * 1997-11-27 2000-10-10 Mitsubishi Chemical Corporation Process for producing compound having epoxy group

Also Published As

Publication number Publication date
WO2002100538A2 (de) 2002-12-19
CN1239488C (zh) 2006-02-01
WO2002100538A8 (de) 2003-11-20
AU2002325235A8 (en) 2005-10-13
DE10128204A1 (de) 2002-12-12
EP1404444A2 (de) 2004-04-07
US20040176549A1 (en) 2004-09-09
AU2002325235A1 (en) 2002-12-23
JP2004529200A (ja) 2004-09-24
KR20040030664A (ko) 2004-04-09
CN1535175A (zh) 2004-10-06

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