WO2002102740A1 - Engrais liquide biotechnologique - Google Patents

Engrais liquide biotechnologique Download PDF

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Publication number
WO2002102740A1
WO2002102740A1 PCT/CZ2002/000036 CZ0200036W WO02102740A1 WO 2002102740 A1 WO2002102740 A1 WO 2002102740A1 CZ 0200036 W CZ0200036 W CZ 0200036W WO 02102740 A1 WO02102740 A1 WO 02102740A1
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WO
WIPO (PCT)
Prior art keywords
mass
fertiliser
liquid
content
potassium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CZ2002/000036
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English (en)
Inventor
Zdenek Beran
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Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of WO2002102740A1 publication Critical patent/WO2002102740A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C1/00—Ammonium nitrate fertilisers
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/20—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation using specific microorganisms or substances, e.g. enzymes, for activating or stimulating the treatment
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F5/00—Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
    • C05F5/006—Waste from chemical processing of material, e.g. diestillation, roasting, cooking
    • C05F5/008—Waste from biochemical processing of material, e.g. fermentation, breweries
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00—Fertilisers characterised by their form
    • C05G5/20—Liquid fertilisers
    • C05G5/27—Dispersions, e.g. suspensions or emulsions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Definitions

  • the invention relates to a liquid biotechnological fertiliser based on by- products of industrial fermentation procedures applying sugar beet or sugar cane molasses as a culture substrate for micro-organisms, especially a fertiliser based on liquid residues from a separation of ferment spirit, citric acid and a sodium glutamate.
  • industrial biotechnologies such as production of ferment spirit and citric acid, sodium glutamate and other products of biotechnology.
  • the said liquid residues are in a form of a colloid solution with a high content of dry matter reaching up 70 % of mass. About 85 % of mass of the dry matter are combustible organic substances. From the point of view of application as a fertiliser for plant nourishment, the said matter is a nutrient substance with an organic character of bond of plant nutrients, containing all mineral matters necessary for plant nutrition. Research works have revealed that this nutrient substance manifest very positive properties as far as plant nutrition is concerned.
  • a typical composition of the substance is 40,0 % of mass of dry matter, 2,50 % of mass of nitrogen, 0,015 % of mass of phosphorus in a form of phosphorus oxide, 4,00 % of mass of potassium in a form of a potassium oxide, 0,15 % of mass of magnesium in a form of magnesium oxide, 1,0 % of mass of calcium in a form of calcium oxide, 0,10 % of mass of sulphur, 0,015 % of mass of iron, 0,003 % of mass of manganese, 0,002 % of mass of zinc, 0,0005 % of mass of copper, 0,0003 % of mass of boron and 0,00003 % of mass of molybdenum.
  • the nutrients being predominantly of natural origin are for plants very easily acceptable and therefore are all utilised by the plants without any rests. This is important especially as far as nitrogen is concerned or ecology taken into account.
  • substantial part of amount of nitrogen remains unused. Unused nitrogen later enters underground water, which are thus undesirably polluted by nitrogen oxides.
  • the fermentation residues usually containing 40 to 50 % of mass of dry matter are used for direct fertilisation as auxiliary substance improving soil parameters as far as the fertility is concerned. It is a drawback of such a direct fertilisation that the high content of micro-nutrients is accompanied by a relatively low content of nitrogen and potassium. By intensive process of fertilisation soil may receive an excess amount of potassium and micro-nutrients.
  • Such fertilisers exist in a form of a thick non-fluid paste, even of a gum character, prepared by adding several components containing nitrogen, phosphorus and potassium into alcohol fermentation residues.
  • the resulting products is difficult to be applied as such as it does not allow for utilisation of current agricultural mechanisms and moreover is stable only for several weeks.
  • a fertiliser consisting of dry solid granules, manufactured by a process comprising fluidised-bed drying and granulation of a thick paste, which is obtained by mixing inorganic agro-chemicals and liquid residues.
  • Such a rather complicated technology with high energy consumption results in a very expensive product.
  • the composition of liquid residues from a production of fermentation spirit is with respect to basic nutrients corrected by addition of solutions of ammonia salts of phosphorous acid or ammonia nitrate or ammonia sulphate.
  • the achieved effect is significantly limited as the higher concentration of ions of this soluble inorganic salts results in disintegration of a colloid system. There appear precipitates making application by a current agriculture mechanisms for liquid fertilisers hardly possible, if not even impossible. Significant improvement has been achieved by a solution described in the utility model CZ 8534.
  • the colloid solution of fermentation residues is fortified by nitrogen comprised in an organic matter, in urea.
  • Urea creates a non-polar solution and does not disrupt colloidal stability and fluidity of the final product It is an object of the invention to prepare a liquid fertiliser allowing for more simple but more effective utilisation of properties of fermentation residues for plant nutrition.
  • a liquid biotechnological fertiliser based on by-products of industrial fermentation procedures applying sugar beet or sugar cane molasses as a culture substrate for micro-organisms especially based on liquid residues from a separation of ferment spirit, citric acid and a sodium glutamate
  • the fertiliser in accordance with the invention comprising from 10 up to 50 % of mass of organic combustible substance matter of the liquid residues and up to 20 % of mass of potassium sulphate and/or potassium chloride, the content of potassium oxide in the fertiliser being within the range from 2 to 15 % of mass.
  • the said fertiliser may comprise at least 10 % of mass of urea.
  • the said fertiliser may comprise up to 50 % of mass of ammonium nitrate, the content of nitrogen in the fertiliser being within the range from 5 to 25 % of mass. Still further in accordance with the invention the fertiliser may comprise up to 30 % of mass of magnesium nitrate, the content of magnesium oxide in the fertiliser being within the range from 0,2 to 8,0 % of mass, stabilised
  • the organic bond of the original plant-derived potassium is stabilised through the addition of free potassium ions and of amiric urea nitrogen. This stabilisation allows for adjustment of the concentration of nitrogen and magnesium over a wide range without formation of precipitates and loss of fluidity of the final fertiliser.
  • the original material, the liquid fermentation residue having a form of a colloidal solution is in accordance with the invention further enriched with mineral nitrogen from ammonium nitrate and with magnesium from magnesium nitrate.
  • the fertiliser though having a high content of dry matter, has a character of a liquid, the liquid being stable by temperatures deep under zero degree of Celsius and capable of long-time storage.
  • the fertiliser may be applied by means if standard means of agriculture mechanisms.
  • the fertiliser shows significantly improved properties when compared with own original components.
  • the comprised organic component has a favourable influence upon bio-sorption of nutrients of the utilised agro- chemicals representing the substantial part of the fertiliser dry matter.
  • Organic bonds of the fertiliser nutrients favourably influence also a yield and quality of agriculture plants, improve soil parameters and regeneration of organic substances in the soil.
  • a fertiliser containing 33 % of mass of organic combustible matter of the liquid fermentation residue and 2 % of mass of the potassium sulphate. Total content of potassium oxide within the fertiliser amounted to 5 % of mass.
  • the fertiliser is suitable also for applications meeting demands of natural farming.
  • Example 1 by dissolving urea and ammonium nitrate and homogenising the obtained new mixture there was prepared a fertiliser comprising 17 % of mass of organic combustible matter of the liquid fermentation residue and 28 % of mass of urea and 15 % of mass of ammonium nitrate. Total content of nitrogen amounted to 20 % of mass and content of potassium oxide was 2,0
  • the liquid fertiliser in accordance with the invention is applicable as nutrient for field plants, vegetables, fruit trees and vines, and for mass agriculture production as well as for small growers and garden keepers.
  • the fertiliser may be also used for decomposition of organic materials, like straw and composts.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Botany (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Dispersion Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)

Abstract

La présente invention concerne un engrais liquide s'utilisant comme nutriants pour les cultures de plein champ, les légumes, les arbres fruitiers et les vignes, qu'il s'agisse de grandes cultures, de petites exploitations ou de jardins. Cet engrais liquide est fait à base des résidus liquides issus de la séparation de l'alcool de fermentation, de l'acide citrique et d'un glutamate de sodium. L'engrais de l'invention comprend pour 10 à 50 % de sa masse une substance organique combustible issue des résidus liquides, et pour 20 % au maximum de sa masse du sulfate de potassium et/ou du chlorure de potassium et/ou de chlorure de potassium, la teneur de l'engrais en oxyde de potassium restant dans une plage de 2 à 15 % de la masse. En outre, l'engrais peut comporter de l'urée pour au moins 10 % de sa masse, du nitrate d'ammonium pour 50 % au maximum de sa masse, la teneur en azote dans l'engrais restant dans une plage de 5 à 25 % de sa masse et/ou jusqu'à 30 % de nitrate de magnésium, la teneur en oxyde de magnésium dans l'engrais restant dans une plage de 0,2 à 8,0 de la masse.
PCT/CZ2002/000036 2001-06-18 2002-06-17 Engrais liquide biotechnologique Ceased WO2002102740A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CZPUV12101-01 2001-06-18
CZ200112101U CZ11501U1 (cs) 2001-06-18 2001-06-18 Kapalné biotechnologické hnojivo

Publications (1)

Publication Number Publication Date
WO2002102740A1 true WO2002102740A1 (fr) 2002-12-27

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ID=5475392

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CZ2002/000036 Ceased WO2002102740A1 (fr) 2001-06-18 2002-06-17 Engrais liquide biotechnologique

Country Status (2)

Country Link
CZ (1) CZ11501U1 (fr)
WO (1) WO2002102740A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102010245A (zh) * 2010-06-09 2011-04-13 徐维康 氨基酸浓缩液肥及其制备方法
US9663411B2 (en) 2012-11-29 2017-05-30 Liquid Fertiliser Systems Pty Ltd Fermented soil additive
CN107827621A (zh) * 2017-12-19 2018-03-23 崔迎雪 一种种植芦荟专用肥料
CN108395310A (zh) * 2017-07-31 2018-08-14 海宁文硕科技咨询有限公司 改良的有机肥的制作方法
CN108658671A (zh) * 2018-06-28 2018-10-16 靖西市秀美边城农业科技有限公司 一种保水长效的大果山楂树专用肥料的制备方法
CN108911835A (zh) * 2018-06-28 2018-11-30 靖西市秀美边城农业科技有限公司 一种利用味精废弃液制备复合肥的方法
CN112205232A (zh) * 2020-10-16 2021-01-12 茶陵县景丰农业发展有限公司 一种茶树的种植方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5344367A (en) 1976-09-28 1978-04-21 Godo Shusei Kk Fertilizer paste
JPS57111294A (en) * 1980-12-27 1982-07-10 Taki Chemical Liquid fertilizer
US4604125A (en) 1983-06-15 1986-08-05 Eni-Ente Nazionale Idrocarburi Solid composition of organic fertilizer and of organo-mineral fertilizer
JPS61222980A (ja) * 1985-03-27 1986-10-03 多木化学株式会社 液状肥料の安定化方法
DE4324823A1 (de) 1992-08-21 1994-02-24 Hofschneider Miroslav Rn Dr Flüssiges organisch-mineralisches Düngemittel auf der Grundlage von Melasseschlempen und Verfahren zu dessen Herstellung
WO1997026228A1 (fr) 1996-01-18 1997-07-24 Miroslav Hofschneider Engrais
DE29906019U1 (de) * 1998-04-06 1999-06-17 Lear, a.s., Brno Flüssiges Düngemittel auf Basis der Abfälle aus dem Bioverfahren

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5344367A (en) 1976-09-28 1978-04-21 Godo Shusei Kk Fertilizer paste
JPS57111294A (en) * 1980-12-27 1982-07-10 Taki Chemical Liquid fertilizer
US4604125A (en) 1983-06-15 1986-08-05 Eni-Ente Nazionale Idrocarburi Solid composition of organic fertilizer and of organo-mineral fertilizer
JPS61222980A (ja) * 1985-03-27 1986-10-03 多木化学株式会社 液状肥料の安定化方法
DE4324823A1 (de) 1992-08-21 1994-02-24 Hofschneider Miroslav Rn Dr Flüssiges organisch-mineralisches Düngemittel auf der Grundlage von Melasseschlempen und Verfahren zu dessen Herstellung
WO1997026228A1 (fr) 1996-01-18 1997-07-24 Miroslav Hofschneider Engrais
DE29906019U1 (de) * 1998-04-06 1999-06-17 Lear, a.s., Brno Flüssiges Düngemittel auf Basis der Abfälle aus dem Bioverfahren

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 197822, Derwent World Patents Index; Class C04, AN 1978-39397A, XP002214791 *
DATABASE WPI Section Ch Week 198233, Derwent World Patents Index; Class C04, AN 1982-69335E, XP002214789 *
DATABASE WPI Section Ch Week 198646, Derwent World Patents Index; Class A97, AN 1986-301569, XP002214790 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102010245A (zh) * 2010-06-09 2011-04-13 徐维康 氨基酸浓缩液肥及其制备方法
US9663411B2 (en) 2012-11-29 2017-05-30 Liquid Fertiliser Systems Pty Ltd Fermented soil additive
US10047017B2 (en) 2012-11-29 2018-08-14 Liquid Fertiliser Systems Pty Ltd Fermented soil additive
CN108395310A (zh) * 2017-07-31 2018-08-14 海宁文硕科技咨询有限公司 改良的有机肥的制作方法
CN107827621A (zh) * 2017-12-19 2018-03-23 崔迎雪 一种种植芦荟专用肥料
CN108658671A (zh) * 2018-06-28 2018-10-16 靖西市秀美边城农业科技有限公司 一种保水长效的大果山楂树专用肥料的制备方法
CN108911835A (zh) * 2018-06-28 2018-11-30 靖西市秀美边城农业科技有限公司 一种利用味精废弃液制备复合肥的方法
CN112205232A (zh) * 2020-10-16 2021-01-12 茶陵县景丰农业发展有限公司 一种茶树的种植方法

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Publication number Publication date
CZ11501U1 (cs) 2001-09-06

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