WO2004100307A2 - Système de protection anti-corrosion pour vitrage d'antenne et vitrage d'antenne - Google Patents

Système de protection anti-corrosion pour vitrage d'antenne et vitrage d'antenne Download PDF

Info

Publication number
WO2004100307A2
WO2004100307A2 PCT/FR2004/001055 FR2004001055W WO2004100307A2 WO 2004100307 A2 WO2004100307 A2 WO 2004100307A2 FR 2004001055 W FR2004001055 W FR 2004001055W WO 2004100307 A2 WO2004100307 A2 WO 2004100307A2
Authority
WO
WIPO (PCT)
Prior art keywords
voltage
glazing
passivation
electronic element
line
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2004/001055
Other languages
English (en)
French (fr)
Other versions
WO2004100307A8 (fr
WO2004100307A3 (fr
Inventor
Helmut MÄUSER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Original Assignee
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Glass France SAS, Compagnie de Saint Gobain SA filed Critical Saint Gobain Glass France SAS
Priority to EP04742619A priority Critical patent/EP1632007B1/de
Priority to KR1020057020767A priority patent/KR101061935B1/ko
Priority to DE602004020466T priority patent/DE602004020466D1/de
Priority to JP2006505826A priority patent/JP4874091B2/ja
Priority to CN2004800187510A priority patent/CN1816939B/zh
Priority to PL04742619T priority patent/PL1632007T3/pl
Publication of WO2004100307A2 publication Critical patent/WO2004100307A2/fr
Publication of WO2004100307A3 publication Critical patent/WO2004100307A3/fr
Anticipated expiration legal-status Critical
Publication of WO2004100307A8 publication Critical patent/WO2004100307A8/fr
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/27Adaptation for use in or on movable bodies
    • H01Q1/32Adaptation for use in or on road or rail vehicles
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/12Supports; Mounting means
    • H01Q1/1271Supports; Mounting means for mounting on windscreens
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/005Anodic protection
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/02Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
    • C23F13/04Controlling or regulating desired parameters
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/02Arrangements for de-icing; Arrangements for drying-out ; Arrangements for cooling; Arrangements for preventing corrosion
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/12Supports; Mounting means

Definitions

  • the invention relates to an anti-corrosion protection system for antenna glazing with a surface conducting structure having the features of the preamble of claim 1.
  • Glass windows of vehicles, glass and / or plastic are very often provided with electrically conductive structures, for example to heat them and / or to form antenna structures.
  • the surface structures are screen printed (thick film technique) from an electrically conductive silver paste, which is then consolidated by firing.
  • Antenna lines or parts thereof are also often conducted on the surface of the transparent substrate; these can also be used for power supply (remote power supply, for example from a tuner) of high frequency electronic elements (HF), such as antenna amplifiers and the like, arranged directly on the glazed antenna.
  • HF high frequency electronic elements
  • an active antenna can be formed in total.
  • the lines themselves must not radiate and have a characteristic impedance defined, constant over the length. This requirement can be met by two or more parallel coplanar conductors with constant spacing and constant width.
  • Embodiments of such signal lines and active antennas are described in DE-A1-39 11 178 where, to form coplanar signal and power lines on an antenna glazing made of dielectric material, the The actual line is combined with one or two ground tracks laid in parallel.
  • the supply voltage for the amplifier (s) is applied as an offset DC voltage on one of the conductors.
  • Amplifiers are associated with electronic elements to separate the offset DC voltage as the operating voltage of the RF signals.
  • the signal line is then applied in service a potential difference of 12 VDC between the signal conductor and the ground. This difference in potential, applied to a coplanar line in the thick film technique, already leads in 5 minutes to first corrosion phenomena, by salt spray test according to DIN 50021-SS. After 10 minutes, there is a massive corrosion of the conductive structure.
  • Said salt spray test simulates the corrosive effects for the lifetime of the component in a greatly shortened period of time; its application to antenna structures placed on vehicle windows is however not prescribed until now.
  • the problem underlying the invention is to provide effective protection against electrical corrosion for antenna glazings with a conductive structure with surface lines conducting the voltage.
  • the invention proposes for this purpose an anti-corrosion protection system for an antenna glazing with a conductive structure, comprising at least one multipole line formed by structural parts arranged parallel to each other on the surface of the antenna.
  • glazing unit for transmitting HF signals as well as for connecting an electronic element HF to a supply voltage, characterized in that the system comprises input means for introducing a so-called passivation voltage which is located in the field of passivation of the material of the line against corrosion in the line and in the electronic element HF and in that the system comprises operating means for exploiting said passivation voltage as supply voltage in the electronic element HF.
  • the invention can make it possible to dispense with an additional passive coating on the line.
  • the value of the passivation voltage will be determined individually for the material of the line to be protected against corrosion. It is generally possible to determine a marked passivation range depending on the value of the external voltage or passivation, in which the corrosion current (proportional to the rate of disintegration of the metal) is minimized or even tends to zero, which means that no corrosion no longer occurs.
  • a sufficient corrosion inhibiting effect (“active" range) is not obtained, whereas in the case of voltages that are too high (greater than the "priming potential"), a a state called “transpassive” appears, in which the protective effect no longer acts and the corrosion current again increases sharply.
  • the operating means can be separated from the electronic element HF or even integrated in this element for its direct supply by the passivation voltage.
  • Preferred voltage values for passivation of the materials usually used for such conductive structures have been determined in the range of 0.75 to 1.8 V DC or AC voltage.
  • the input means may comprise a voltage source which is integrated in an apparatus connected in service to the electronic element HF, such as a tuner.
  • the passivation voltage according to the invention may be alternating and preferably be sinusoidal and be in the frequency range greater than 2000 Hz, preferably between 2000 and 4000 Hz or around 3000 Hz. A maximum of passivation has been determined.
  • the passivation mode which are several orders of magnitude lower than the 1.5 mA values permitted in the automotive sector.
  • the invention also proposes a method of using an active antenna glazing with an antenna structure as well as with at least one multipole line formed by structural parts arranged parallel to each other on the glazing surface for transmitting RF signals as well as for connecting an electronic element HF to a supply voltage, characterized in that the line and the connected electronic element HF are supplied with a voltage of passivation situated in the field of the passivation of the material of the line against corrosion and superimposable on the HF signals, and in that this passivation voltage is used, directly or after adaptation, as the supply voltage of the element HF electronics.
  • the invention also proposes a vehicle antenna glazing comprising an electronic element HF designed for a specific operating voltage and capable of being powered by a multipolar line (4) disposed on a surface of the glazing, characterized in that elements
  • the electronic matching elements are associated with the electronic element HF for conversion of a passivation voltage supplied to the electronic element HF by the line for electrical passivation of the line, at the operating voltage.
  • the glazing may comprise a rectifier and voltage converter which is associated with the electronic element HF, said rectifier and voltage converter converting said supplied AC voltage into a DC voltage suitable for supplying an amplifier of electronic element HF.
  • the electronic element HF can be fixed on a surface of the glazing.
  • the electronic element HF can be inserted into a laminated glazing unit.
  • the multipolar line may be composed coplanar of at least two conductive tracks deposited next to each other on a surface of the glazing, at a constant distance from one another.
  • the multipole line may also consist of at least two conductive tracks deposited one above the other on a surface of the glazing, at a constant distance from one another.
  • FIG. 1 is an overview of an antenna glazing with an antenna structure and a coplanar signal and power line made on the surface of the glazing;
  • FIG. 2 shows a detailed view of the assembly of an electronic element HF and elements of the anti-corrosion protection.
  • an antenna glazing 1 is provided with a field of heating and antenna 2, which has been fabricated in known manner by screen printing a predetermined pattern of structure into an electrically conductive baking paste. Details of this structure known per se are not represented here; it will only be indicated that several narrow conductor tracks 2L extend transversely over the field of view of the glazing 1, between the two relatively wide lateral collector bars 2S, which are close to the edge of the glazing 1.
  • the two collector bars 2S can be connected in a manner not shown in detail to an electric heating voltage, which circulates a current in the conductive tracks electrically connected in parallel with each other.
  • HF high frequency signals
  • a signal and power supply line 4 made in a known manner in coplanar bipolar form on the surface of the glazing unit 1 along its edge. extends to an appropriate interface 5 (multiple connector, flat conductor, plug-in connection) on the edge of the glazing 1.
  • interface 5 multiple connector, flat conductor, plug-in connection
  • connections are made to the receiving apparatus ( radio, tuner, TV, ...) as well as to a voltage source not shown.
  • the supply voltage for the heating field itself can also be connected here.
  • Such multipole interfaces are in themselves part of the state of the art (see for example DE-PS 195 36 131) and will therefore not be discussed in detail here. No further attention will be given to shielding measures that may be necessary and the like, because these are commonplace for those skilled in the art.
  • the antenna field 2, the electronic element HF 3 and the line 4 do not necessarily have to be all on the same surface of the glazing. It is also not necessary for the application of the invention to use a printed antenna structure.
  • the line 4 to be protected can also be connected to a coating used as an antenna arranged inside a laminated glazing unit.
  • the electronic element HF 3 can be incorporated in a composite, if its overall assembly is sufficiently flat.
  • the line itself could of course also be incorporated in a composite, its electrical passivation is not mandatory, but it is still possible.
  • a peripheral line in phantom lines indicates the inner edge line of an opaque colored frame 7, which usually surrounds as an outer limit the field of vision of the antenna glazing 1, which is otherwise transparent, and extends to outer edge thereof.
  • a colored frame also masks the electronic elements of the antenna structures described here. It is recognized that, in the planar projection of the glazing, the collector bars 2S, the electronic element HF 3, the coplanar line 4 and the interface 5 are located on this colored frame 7.
  • line 4 we provide a part to a not shown receiving device of the RF signals (amplified) provided by the electronic element HF 3 and secondly to the electronic element HF 3 active a supply voltage.
  • Line 4 is composed in the present example asymmetrically of a wide conductive strip 4G and a narrow conductive strip 4S parallel to a constant distance therefrom. It is preferably printed during the same operation as the heating field and antenna 2 and is, in the mounted state of the glazing 1, exposed to the weather.
  • the conductive strip 4G is closer to the edge of the glazing 1 than the band 4S, so that the latter respects a distance as large as possible of a metal body, in which the glazing 1 must be installed later.
  • the 4G wide conductor strip can also, if necessary, be connected directly, for example by an electrically conductive adhesive, to the chassis of the vehicle.
  • the conductive strips 4S, 4G and the heating field 2S, 2L it is possible, for example, to use a screen printing paste of the SP 1835 type of CERDEC with a silver content of 80%.
  • the opaque colored frame 7 is printed with CERDEC black enamel 14252/80860. These two materials to be printed on one another are compatible with each other, and one can with them suitably respect the desired characteristic impedance of line 4.
  • Fig. 2 shows a possible discrete embodiment of the electronic element HF 3 and elements of the active corrosion protection.
  • the connections of line 4 (4G, 4S) have been drawn, on the right side the connection 2A towards the antenna foot.
  • the 4G connection serves as a ground, while the 4S connection leads both the RF signal level to a receiving device 8 (tuner) and a supply voltage superimposed on the RF signals.
  • the RF connection of the reception apparatus 8 is not sensitive to the presence of the supply voltage.
  • such an electronic element HF can also be designed and used in an integrated form. In general, an assembly as flat as possible is interesting, which is little salient above the surface of the glazing or which can also be used incorporated in a laminated glazing.
  • the passivation voltage is an AC voltage Up with an amplitude of 1.1 V and a frequency of 3000 ⁇ 100 Hz, which is produced by a voltage source 9 shown only schematically.
  • This passivation voltage has been determined experimentally as being an optimum for active anti-corrosion protection of such lines respectively of such structures.
  • This passivation voltage is therefore used in accordance with the invention for feeding the line 4 subject to corrosion, at the place where the operating voltage was usually applied in the active components HF.
  • the voltage source 9 could also be integrated directly into the receiving apparatus 8, unlike the representation.
  • the electronic element HF 3 comprises an antenna amplifier 3A, to which the antenna signals are transmitted immediately by 2A, and which is connected by a decoupling stage 3K to the line 4S. In parallel with the 3K decoupling stage, there is a bandpass 3B for filtering the supply voltage out of the RF signals, which sends the filtered voltage to a rectifier with DC / DC converter 3W.
  • the rectifier with converter must convert the rectified voltage to the operating voltage of the electronic components possibly integrated in a module. This voltage is then sent to the amplifier 3A, by a filtering / smoothing stage 3S or alternatively directly.
  • the operating voltage UB and the ground can of course also be used for the power supply of other possible electronic elements, not shown here, for example still other amplifiers, etc.
  • the mounting of the antenna glazing 1 (for example its bonding with a flange of the bodywork) is not affected, even when the components are, in the preferred arrangement, arranged near the edge on the face of the antenna. the window located inside in the assembled state.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Details Of Aerials (AREA)
  • Support Of Aerials (AREA)
  • Prevention Of Electric Corrosion (AREA)
  • Input Circuits Of Receivers And Coupling Of Receivers And Audio Equipment (AREA)
  • Joining Of Glass To Other Materials (AREA)
PCT/FR2004/001055 2003-05-02 2004-04-30 Système de protection anti-corrosion pour vitrage d'antenne et vitrage d'antenne Ceased WO2004100307A2 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP04742619A EP1632007B1 (de) 2003-05-02 2004-04-30 Korrosionsschutzschaltung für eine scheibenantenne und scheibenantenne
KR1020057020767A KR101061935B1 (ko) 2003-05-02 2004-04-30 안테나 글레이징을 위한 부식 방지 시스템, 활성 안테나 글레이징을 사용하는 방법, 및 자동차용 안테나 글레이징
DE602004020466T DE602004020466D1 (de) 2003-05-02 2004-04-30 Korrosionsschutzschaltung für eine scheibenantenne und scheibenantenne
JP2006505826A JP4874091B2 (ja) 2003-05-02 2004-04-30 アンテナガラスのための耐食保護システム、および対応するアンテナガラス
CN2004800187510A CN1816939B (zh) 2003-05-02 2004-04-30 天线窗玻璃的腐蚀防护系统和天线窗玻璃
PL04742619T PL1632007T3 (pl) 2003-05-02 2004-04-30 Układ ochrony antykorozyjnej dla oszklenia anteny i oszklenie anteny

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10319607.2 2003-05-02
DE10319607A DE10319607B3 (de) 2003-05-02 2003-05-02 Korrosionsschutzschaltung für eine Leiterstruktur auf einer Antennenscheibe, Verfahren zum Betreiben einer aktiven Antennenscheibe und Antennenscheibe für Fahrzeuge

Publications (3)

Publication Number Publication Date
WO2004100307A2 true WO2004100307A2 (fr) 2004-11-18
WO2004100307A3 WO2004100307A3 (fr) 2005-01-20
WO2004100307A8 WO2004100307A8 (fr) 2005-12-01

Family

ID=32981186

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2004/001055 Ceased WO2004100307A2 (fr) 2003-05-02 2004-04-30 Système de protection anti-corrosion pour vitrage d'antenne et vitrage d'antenne

Country Status (9)

Country Link
EP (1) EP1632007B1 (de)
JP (1) JP4874091B2 (de)
KR (1) KR101061935B1 (de)
CN (1) CN1816939B (de)
AT (1) ATE428195T1 (de)
DE (2) DE10319607B3 (de)
ES (1) ES2325024T3 (de)
PL (1) PL1632007T3 (de)
WO (1) WO2004100307A2 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2906735B1 (de) * 2012-10-11 2022-03-30 Sembcorp Marine Repairs & Upgrades Pte. Ltd. System und verfahren zur bereitstellung eines korrosionsschutzes für eine metallstruktur mithilfe zeitveränderlicher elektromagnetischer wellen

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013091961A1 (de) 2011-12-20 2013-06-27 Saint-Gobain Glass France Verbundscheibe mit antennenstruktur und integrierter schaltfläche
CN103872465B (zh) * 2014-04-18 2016-04-20 福耀玻璃工业集团股份有限公司 一种真有源玻璃天线及其制造方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3692650A (en) * 1970-08-24 1972-09-19 Signal Oil & Gas Co Cathodic protection system
AT384626B (de) * 1985-07-12 1987-12-10 D 3 Cathodic Products Vorrichtung zur anwendung des kathodischen korrosionsschutzes an nicht erdverlegten anlagen
DE3911178A1 (de) * 1989-04-06 1990-10-11 Lindenmeier Heinz Scheibenantennensystem mit antennenverstaerker
JPH07212118A (ja) * 1994-01-18 1995-08-11 Asahi Glass Co Ltd ガラスアンテナのブースターアンプ
DE19536131C2 (de) * 1995-09-28 2002-05-02 Saint Gobain Sekurit D Gmbh Diversity-Antennenscheibe für Fahrzeuge mit Anschlußelementen
JP2000101324A (ja) * 1998-09-25 2000-04-07 Sumitomo Constr Mach Co Ltd 建設機械搭載用送受信機のアンテナ装置
DE10002777C1 (de) * 2000-01-22 2001-08-09 Saint Gobain Sekurit D Gmbh Kontaktierung einer Scheibe mit elektrischen Funktionen
US6441792B1 (en) * 2001-07-13 2002-08-27 Hrl Laboratories, Llc. Low-profile, multi-antenna module, and method of integration into a vehicle
JP2004040144A (ja) * 2002-06-28 2004-02-05 Asahi Glass Co Ltd 自動車用後部窓ガラスアンテナ

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2906735B1 (de) * 2012-10-11 2022-03-30 Sembcorp Marine Repairs & Upgrades Pte. Ltd. System und verfahren zur bereitstellung eines korrosionsschutzes für eine metallstruktur mithilfe zeitveränderlicher elektromagnetischer wellen

Also Published As

Publication number Publication date
JP4874091B2 (ja) 2012-02-08
ATE428195T1 (de) 2009-04-15
KR20060008960A (ko) 2006-01-27
WO2004100307A8 (fr) 2005-12-01
EP1632007B1 (de) 2009-04-08
PL1632007T3 (pl) 2009-08-31
CN1816939B (zh) 2010-06-16
DE10319607B3 (de) 2004-10-14
KR101061935B1 (ko) 2011-09-02
DE602004020466D1 (de) 2009-05-20
ES2325024T3 (es) 2009-08-24
CN1816939A (zh) 2006-08-09
EP1632007A2 (de) 2006-03-08
WO2004100307A3 (fr) 2005-01-20
JP2006525710A (ja) 2006-11-09

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