WO2004106467A1 - Procede de valorisation de produits de fischer-tropsch par deparaffinage et hydrofinissage - Google Patents

Procede de valorisation de produits de fischer-tropsch par deparaffinage et hydrofinissage Download PDF

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Publication number
WO2004106467A1
WO2004106467A1 PCT/US2003/015022 US0315022W WO2004106467A1 WO 2004106467 A1 WO2004106467 A1 WO 2004106467A1 US 0315022 W US0315022 W US 0315022W WO 2004106467 A1 WO2004106467 A1 WO 2004106467A1
Authority
WO
WIPO (PCT)
Prior art keywords
plus
dewaxing
hydrofinishing
product
sapo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2003/015022
Other languages
English (en)
Inventor
David R. Johnson
Christopher A. Simmons
Donald H. Mohr
Stephen J. Miller
Stephen K. Lee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron USA Inc
Original Assignee
Chevron USA Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron USA Inc filed Critical Chevron USA Inc
Priority to PCT/US2003/015022 priority Critical patent/WO2004106467A1/fr
Priority to AU2003229055A priority patent/AU2003229055B2/en
Priority to BRPI0318301-7A priority patent/BR0318301A/pt
Priority to JP2005500383A priority patent/JP2006526034A/ja
Priority to GB0523821A priority patent/GB2416774B/en
Publication of WO2004106467A1 publication Critical patent/WO2004106467A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/02—Multi-step carbonising or coking processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
    • C10G73/02—Recovery of petroleum waxes from hydrocarbon oils; Dewaxing of hydrocarbon oils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil

Definitions

  • diesel is considered as having a upper boiling point of about 700 degrees F (370 degrees C) and an initial boiling point of about 300 degrees F (about 150 degrees C).
  • Lubricating base oils typically will have an initial boiling point above about 600 degrees F (about 315 degrees C).
  • the syncrude fractions boiling in the range of diesel and lubricating base oils as they are initially recovered from the Fischer- Tropsch plant will usually contain a high proportion of waxy normal paraffins and unsaturated hydrocarbons, and therefore, these fractions require upgrading to meet commercial specifications for the finished products prior to their use either alone or as blending stock. During upgrading the various fractions are separated according to their respective boiling ranges.
  • the cut-point between those Fischer-Tropsch fractions boiling in the range of diesel and lubricating base oil may be adjusted to either increase the yield of diesel or the yield of lubricating base oil. For example by extending the cut-point for diesel, it is possible to not only maximize the yield of diesel but still also produce a diesel product having a very low cloud point and pour point. At the same time, the volatility of the lubricating base oil cut is minimized which is major commercial selling point for lubricants.
  • a Fischer-Tropsch derived feedstock having the specifications shown in Table 1 was dewaxed using a hydrocracking catalyst and a hydroisomerization catalyst.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Lubricants (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un procédé de production de produits d'huile de base lubrifiante et de diesel à point d'écoulement bas qui consiste à déparaffiner en vrac un pétrole synthétique F-T C5 positif (8), à soumettre l'intermédiaire déparaffiné (12) à l'hydrofinissage, et enfin, à récupérer des produits à point d'ébullition supérieur à 120 °C qui présentent des propriétés améliorés.
PCT/US2003/015022 2003-05-12 2003-05-12 Procede de valorisation de produits de fischer-tropsch par deparaffinage et hydrofinissage Ceased WO2004106467A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
PCT/US2003/015022 WO2004106467A1 (fr) 2003-05-12 2003-05-12 Procede de valorisation de produits de fischer-tropsch par deparaffinage et hydrofinissage
AU2003229055A AU2003229055B2 (en) 2003-05-12 2003-05-12 Process for upgrading fischer-tropsch products using dewaxing and hydrofinishing
BRPI0318301-7A BR0318301A (pt) 2003-05-12 2003-05-12 processos para produzir produtos de hidrocarboneto e de material bruto sintético de ponto de fluidez baixo, e produto de óleo base lubrificante de ìndice de viscosidade ultra-alto, de ponto de fluidez baixo a partir de uma instalação fischer-tropsch
JP2005500383A JP2006526034A (ja) 2003-05-12 2003-05-12 脱蝋およびハイドロフィニッシングを用いるフィッシャー−トロプシュ法生成物の改良法
GB0523821A GB2416774B (en) 2003-05-12 2003-05-12 Process for upgrading fischer-tropsch products using dewaxing and hydrofinishing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2003/015022 WO2004106467A1 (fr) 2003-05-12 2003-05-12 Procede de valorisation de produits de fischer-tropsch par deparaffinage et hydrofinissage

Publications (1)

Publication Number Publication Date
WO2004106467A1 true WO2004106467A1 (fr) 2004-12-09

Family

ID=33488752

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/015022 Ceased WO2004106467A1 (fr) 2003-05-12 2003-05-12 Procede de valorisation de produits de fischer-tropsch par deparaffinage et hydrofinissage

Country Status (5)

Country Link
JP (1) JP2006526034A (fr)
AU (1) AU2003229055B2 (fr)
BR (1) BR0318301A (fr)
GB (1) GB2416774B (fr)
WO (1) WO2004106467A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008005346A1 (de) 2007-08-10 2009-02-12 Indian Oil Corp. Ltd., Mumbai Neuer synthetischer Kraftstoff und Verfahren zum Herstellen desselben
CN102361960A (zh) * 2009-03-27 2012-02-22 日本石油天然气·金属矿物资源机构 液体燃料的制造方法及液体燃料的制造系统
US9492818B2 (en) 2009-06-12 2016-11-15 Albemarle Europe Sprl SAPO molecular sieve catalysts and their preparation and uses
CN106350110A (zh) * 2015-07-16 2017-01-25 中国石油化工股份有限公司 一种由费托合成油生产中间馏分油的方法
CN106554820A (zh) * 2015-09-30 2017-04-05 中国石油化工股份有限公司 一种制备润滑油基础油的方法
CN106554819A (zh) * 2015-09-30 2017-04-05 中国石油化工股份有限公司 一种由高含蜡原料油制备润滑油基础油的方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2455995B (en) * 2007-12-27 2012-09-26 Statoilhydro Asa A method of producing a lube oil from a Fischer-Tropsch wax
CN106566589A (zh) * 2016-11-13 2017-04-19 中国海洋石油总公司 一种加工高蜡含量润滑油基础油的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0323092A2 (fr) * 1987-12-18 1989-07-05 Exxon Research And Engineering Company Procédé d'hydro-isomérisation de la cire de Fischer-Tropsch en vue de la production d'une huile lubrifiante
US5135638A (en) * 1989-02-17 1992-08-04 Chevron Research And Technology Company Wax isomerization using catalyst of specific pore geometry

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS569099A (en) * 1979-07-03 1981-01-29 Toyo Tokushu Kiki Kk Abnormality detecting method of automatic press
US6605206B1 (en) * 2002-02-08 2003-08-12 Chevron U.S.A. Inc. Process for increasing the yield of lubricating base oil from a Fischer-Tropsch plant
US6703535B2 (en) * 2002-04-18 2004-03-09 Chevron U.S.A. Inc. Process for upgrading fischer-tropsch syncrude using thermal cracking and oligomerization
CA2498888A1 (fr) * 2002-10-08 2004-04-22 Exxonmobil Research And Engineering Company Rendement accru en huile de graissage par deparaffinage catalytique de cire paraffinique sous pression d'hydrogene faible ou nulle
US7344631B2 (en) * 2002-10-08 2008-03-18 Exxonmobil Research And Engineering Company Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product
CA2498904A1 (fr) * 2002-10-08 2004-04-22 Exxonmobil Research And Engineering Company Rendement ameliore d'huile de graissage par deparaffinage catalytique a pression a faible teneur en hydrogene de parafines
US20040065584A1 (en) * 2002-10-08 2004-04-08 Bishop Adeana Richelle Heavy lube oil from fischer- tropsch wax
US7201838B2 (en) * 2002-10-08 2007-04-10 Exxonmobil Research And Engineering Company Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0323092A2 (fr) * 1987-12-18 1989-07-05 Exxon Research And Engineering Company Procédé d'hydro-isomérisation de la cire de Fischer-Tropsch en vue de la production d'une huile lubrifiante
US5135638A (en) * 1989-02-17 1992-08-04 Chevron Research And Technology Company Wax isomerization using catalyst of specific pore geometry

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008005346A1 (de) 2007-08-10 2009-02-12 Indian Oil Corp. Ltd., Mumbai Neuer synthetischer Kraftstoff und Verfahren zum Herstellen desselben
US8353972B2 (en) 2007-08-10 2013-01-15 Indian Oil Corporation Limited Synthetic fuel and method of preparation thereof
CN102361960A (zh) * 2009-03-27 2012-02-22 日本石油天然气·金属矿物资源机构 液体燃料的制造方法及液体燃料的制造系统
AU2010228740B2 (en) * 2009-03-27 2013-08-01 Cosmo Oil Co., Ltd. Liquid fuel producing method and liquid fuel producing system
CN102361960B (zh) * 2009-03-27 2014-07-02 日本石油天然气·金属矿物资源机构 液体燃料的制造方法及液体燃料的制造系统
EP2412787A4 (fr) * 2009-03-27 2014-08-13 Japan Oil Gas & Metals Jogmec Procédé de production d'un combustible liquide et système pour le produire
US9492818B2 (en) 2009-06-12 2016-11-15 Albemarle Europe Sprl SAPO molecular sieve catalysts and their preparation and uses
CN106350110A (zh) * 2015-07-16 2017-01-25 中国石油化工股份有限公司 一种由费托合成油生产中间馏分油的方法
CN106350110B (zh) * 2015-07-16 2018-11-02 中国石油化工股份有限公司 一种由费托合成油生产中间馏分油的方法
CN106554820A (zh) * 2015-09-30 2017-04-05 中国石油化工股份有限公司 一种制备润滑油基础油的方法
CN106554819A (zh) * 2015-09-30 2017-04-05 中国石油化工股份有限公司 一种由高含蜡原料油制备润滑油基础油的方法

Also Published As

Publication number Publication date
JP2006526034A (ja) 2006-11-16
GB2416774B (en) 2008-08-13
AU2003229055A1 (en) 2005-01-21
GB2416774A (en) 2006-02-08
AU2003229055B2 (en) 2009-07-02
GB0523821D0 (en) 2006-01-04
BR0318301A (pt) 2006-07-11

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