WO2006032189A1 - Carte en fibre de verre double face et procédé de fabrication idoine - Google Patents
Carte en fibre de verre double face et procédé de fabrication idoine Download PDFInfo
- Publication number
- WO2006032189A1 WO2006032189A1 PCT/CN2005/001476 CN2005001476W WO2006032189A1 WO 2006032189 A1 WO2006032189 A1 WO 2006032189A1 CN 2005001476 W CN2005001476 W CN 2005001476W WO 2006032189 A1 WO2006032189 A1 WO 2006032189A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mold
- glass fiber
- double
- mixture
- drier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/0423—Ornamental plaques, e.g. decorative panels, decorative veneers containing fibreglass elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/0453—Ornamental plaques, e.g. decorative panels, decorative veneers produced by processes involving moulding
Definitions
- the present invention relates to a glass fiber board which is made of a resin as a main raw material and a method for producing the same, and more particularly to a double-sided fiberglass board having certain specific functions and a method of manufacturing the same.
- a high-density fiberboard mainly in which a relatively large number of fibers are added, so that the density of the glass sheet is increased, and various properties are enhanced; and a multi-layer fiberglass sheet is disclosed in US Pat. No. 5,639,411. Doubles strength and hardness as well as other properties.
- the requirements for decoration are getting higher and higher, and the level of decoration and quality requirements are getting higher and higher.
- the above-mentioned fiberglass board can only play a decorative role at most, or The pattern on the surface of the glass plate, these single decorations can not meet the aesthetic requirements of the people, and if the specific requirements of each specific customer are to be met, the processing and transformation time is long, the technical requirements are high, and the cost is high;
- the fiberglass board cannot be made too large or too wide for strength reasons, so that it is impossible to manufacture an oversized sheet.
- the double-sided fiberglass board is mainly a panel (sheet) composed of a resin, a drier, a promoter, a glass fiber and a filler.
- the main structure and raw materials are:
- the panel includes upper and lower resin layers whose main raw material is a resin, and a filler between the resin layers;
- the raw material of the above resin layer includes a resin, a drier, and an accelerator, and the weight ratio thereof is
- Glass fibers are disposed in the resin layer.
- the resin layer is a fiber glue layer or a crystal glue layer or a top layer.
- the glass fiber is a glass fiber cloth or a glass fiber felt or a chemical fiber material.
- the filling is a luminous entry card or a signboard with Chinese and English and patterns or flowers or plants or daily necessities or building materials or clothing or jewelry, jewelry ornaments or, newspapers, magazines, book-like readable objects or photographs or clocks Or a luminous powder or a luminescent stone or a laser strip; or a combination of the above fillers.
- a reinforcing column made of a material having a uniform height and a certain hardness is disposed in the resin layer.
- the first mold has a flat and high temperature resistant bottom, a certain height border around the bottom, and an opening opposite to the bottom, and the crystal glue, the liquid accelerator and the drier are arranged according to a set ratio Mixing to form a mixture, pouring the mixture onto the first mold base, and then placing the filler in the mixture as needed, and then placing the mold in an oven at a temperature below 100 ° C for a period of time ( About 3 hours or so, the heat is shorter, the colder time is longer; the following are the same, no longer repeat) take out and cool;
- step (3) placing the glass fiber cloth or the glass fiber mat on the mixture obtained after the step (2), and then coating a small amount of crystal glue on the glass fiber cloth or the glass fiber mat, and then using the external force to the glass fiber cloth or the glass.
- the fiber mat is clamped, and then a larger amount of crystal glue is poured to fix the glass fiber cloth or the glass fiber mat, and then heated in an oven at a temperature below 100 ° C, and taken out and cooled after a period of time;
- the second mold may also be taken.
- the second mold has a flat bottom and a high temperature resistant bottom, a certain height border around the bottom, and an opening opposite to the bottom.
- the glue or crystal glue is mixed with the liquid promoter and the drier to form a mixture, and the mixture is poured into the bottom plate of the second mold, and the second mold is placed in the oven. Heating at a temperature below 100 °c, taking it out after a while and cooling it;
- Molding, edging is double-sided fiberglass board.
- the method also includes:
- the step (3) may be repeated once or more as needed.
- step (4) it can also be made according to the step (3).
- the latter half of the step (3) or (4) is inserted into the viscous mixture by a reinforcing column made of a material having a certain hardness when the mixture is further viscous and not completely cooled.
- the crystal glue can be replaced by a glass fiber glue.
- the mixture of the surface glue or the crystal glue and the liquid accelerator and the drier can also be added.
- the filling is a luminous entry card or a signboard with Chinese and English and patterns or flowers or plants or daily necessities or building materials or clothing or jewelry, jewelry ornaments or, newspapers, magazines, book-like readable objects or photographs or clocks Or a luminous powder or a luminescent stone or a laser strip; or a combination of the above fillers.
- the main component of the crystal glue is resin (Polyester Resin Synolite); the main component of the surface glue is Polyester Resin Gelcoat Synolite; the main component of the accelerator is cobalt stearate (Cobalt naphthnate); the main component of the drier is peroxidation Methyl ethyl ketone (MEX-Peroxide).
- the mixture of the crystal glue and the liquid promoter and the drier is 300-500 by weight: 2. 5-10: 2. 5-10; the surface glue and the liquid accelerator and the drier The resulting mixture is ratio by weight: 10-50: 2. 5-10: 2. 5-10.
- the first mold is smaller than the second mold.
- the first mold and the second mold comprise a bottomed outer frame, the bottom of the outer frame is a wooden first bottom plate, and an inner frame is further disposed in the frame, and the bottom of the inner frame is a refractory material
- the second bottom plate is further formed to be formed inside the inner frame and extended at the four corners An angle iron to the outer frame, and a pressing member disposed on the outer frame to be rotatable to fix or disengage the inner frame from the outer frame.
- the invention can be used as building materials, furniture materials and decorative materials or decorations, and the raw materials involved are all known in the art and can be purchased on the market; the values given for the proportioning materials should include all the numerical ranges. Values, these values are all feasible, so there is no need to give an example for each value.
- Figure 1 is a schematic view showing a double-sided fiberglass board with a commemorative photograph according to a first embodiment of the present invention
- Figure 2 is a schematic view of a double-sided fiberglass board with a timepiece according to a second embodiment of the present invention.
- Figure 3 is a schematic view of a double-sided fiberglass board with a laser strip in accordance with a third embodiment of the present invention.
- Figure 4a is a schematic view of a double sided fiberglass board with reinforcing columns and luminescent stones in accordance with a fourth embodiment of the present invention.
- Figure 4b is a schematic exploded view of the assembly of Figure 4a.
- Figure 5 is a schematic view of a first mold for making a double sided fiberglass board of the present invention.
- Figure 6 is a schematic view of a second mold for making a double sided fiberglass sheet of the present invention.
- the double-sided fiberglass board comprises a glass fiber layer 2 made of a crystal glue layer 1 and a glass fiber cloth, and a top layer 3, wherein the glass fiber layer is placed on the crystal glue layer and the surface.
- a filler such as a photo 4
- the double-layer fiberglass board has a permanent commemorative value, and the fiberglass board can also be placed in any place for decoration, and can also be used as a gift to friends and relatives, because the main raw materials of the crystal glue layer and the top layer are not Saturated resin, which makes it durable and To save for a long time.
- the first mold includes a bottomed outer frame 10, the bottom of the outer frame is a wooden first bottom plate 12, and is disposed in the outer frame.
- the frame 20, the bottom of the inner frame is a second bottom plate 22 made of refractory material, and further includes an angle iron 30 which is formed to be formed inside the inner frame and extends to the outer frame at four corners, and is disposed on the outer frame
- the pressing member 40 that fixes or frees the inner frame to the outer frame can be rotated.
- the crystal glue, liquid promoter and drier are mixed and stirred according to a weight ratio of 350: 5. 0: 6. 0, wherein the main component of the crystal glue is a resin (Polyester Resin Synolite), which promotes The main component of the agent is cobalt stearate (Cobalt naphthnate), the main component of the drier is methyl ethyl ketone peroxide (MEX-Peroxide); then the resulting mixture is poured onto the second bottom plate 20 of the first mold, and then the photo 4 is placed.
- the main component of the crystal glue is a resin (Polyester Resin Synolite), which promotes
- the main component of the agent is cobalt stearate (Cobalt naphthnate)
- the main component of the drier is methyl ethyl ketone peroxide (MEX-Peroxide)
- MEX-Peroxide methyl ethyl ketone peroxide
- the first mold with the functional layer raw materials and the mixture is then placed in an oven and heated at a temperature of 90 ° C for a period of time (about 3 hours or so, the heat is shorter, the day Cold for a longer time; the following are the same, no longer repeat), taken out of the oven and cooled;
- the second mold is smaller than the first mold, as shown in FIG. 6, which also has a flat bottom, a certain height border around, and An opening is provided at the opposite side of the bottom, the second mold comprises a bottomed outer frame 10', the bottom of the outer frame is a wooden first bottom plate 12', and an inner frame 20' disposed inside the outer frame, The bottom of the frame is a second bottom plate 22' made of refractory material, which also includes useful for forming An angle iron 30 disposed inside the inner frame, extending to the outer frame at the four corners, and a pressing member 40' disposed on the outer frame to rotate or fix the inner frame and the outer frame.
- the main component of the top coat is Polyester Resin Gelcoat Synolite.
- the main component of the accelerator is cobalt stearate. (Cobalt naphthnate), the main component of the drier is methyl ethyl ketone peroxide (MEX-Peroxide); the viscous mixture is poured onto the bottom plate of the second mold, and the second mold is placed in an oven at a temperature of 90 Torr. Heating down, after a period of time, taking it out of the oven and performing natural cooling;
- the glass fiber board taken out from the first mold is placed on the surface of the mixture of the second mold, pressurized, and then heated in an oven at a temperature of 52 ° C. After a period of time, from baking Removed from the furnace and cooled;
- the double-sided fiberglass board comprises a crystal glue layer 1', l'a and a glass fiber layer 2', 2a' and a top layer 3' made of glass fiber mat.
- the glass fiber layer 2a' is adhered to the top layer 3'
- the crystal glue layer la' is disposed between the glass fiber layer 2a' and the glass fiber layer 2'
- the glass fiber layer 2'-face is closely attached to the crystal glue layer 1'.
- the other side is in close contact with the crystal glue layer la'; a watch 4' is arranged between the crystal glue layer and the fiberglass layer 2'. Therefore, the double-layer fiberglass board can be used as a timepiece and decorated indoors or outdoors, while the crystal glue layer and the top layer are not saturated with resin, and are durable, and can protect the internal timepiece.
- the first mold includes a bottomed outer frame 10, the bottom of the outer frame is a wooden first bottom plate 12, and is disposed in the outer frame.
- the frame 20, the bottom of the inner frame is a second bottom plate 22 made of refractory material, and further includes an angle iron 30 which is formed to be formed inside the inner frame and extends to the outer frame at four corners, and is disposed on the outer frame
- the pressing member 40 that fixes or frees the inner frame to the outer frame can be rotated.
- the crystal glue, liquid promoter and drier are mixed according to the weight ratio of 380: 6. 0: 7. 0.
- the main component of the crystal glue is resin (Polyester Resin Synolite), and the main component of the accelerator is Cobalt naphthnate, the main component of the drier is methyl ethyl ketone peroxide (MEX-Peroxide); then the resulting mixture is poured into the second part of the first mold
- the watch is placed in the mixture, and then the first mold of the mixture with the timepiece is placed in an oven and heated at a temperature of 80 Torr. After a period of time, it is taken out of the oven and cooled. ;
- step (2) placing the glass fiber mat on the mixture obtained after the step (2), and then coating a small amount of crystal glue on the glass fiber cloth, and then clamping the glass fiber cloth with an external force, and then pouring more
- the crystal glue is fixed by a glass fiber cloth, and then heated in a baking oven at a temperature of 90 Torr, and after a period of time, it is taken out from the oven and cooled;
- the second mold is smaller than the first mold, as shown in Fig. 6, it also has a flat bottom, a certain height border around and An opening is provided at the opposite side of the bottom, the second mold comprises a bottomed outer frame 10', the bottom of the outer frame is a wooden first bottom plate 12', and an inner frame 20' disposed inside the outer frame, The bottom of the frame is a second bottom plate 22' made of refractory material, and further includes an angle iron 30' which is formed to be formed inside the inner frame and extends to the outer frame at four corners, and is disposed on the outer frame to be rotatable A press member 40' that secures or frees the inner frame to the outer frame.
- the surface glue, liquid promoter and drier are mixed according to the weight ratio of 37: 4. 5: 7. 2, the main component of the top coat is Polyester Resin Gelcoat Synolite, and the main component of the accelerator is cobalt stearate.
- the main component of the drier is methyl ethyl ketone peroxide (MEX-Peroxide);
- MEX-Peroxide methyl ethyl ketone peroxide
- the viscous mixture is poured onto the bottom plate of the second mold, and the second mold is placed in an oven at 85 ° ( Heating at a temperature, after a period of time, taking it out of the oven and cooling it;
- the glass fiber board taken out from the first mold is placed on the surface of the mixture of the second mold, pressurized, and then heated in an oven at a temperature of 96 ° C, after a period of time, from baking Removed from the furnace and cooled; (8) Take the mold and educe.
- the double-sided fiberglass board comprises a crystal glue layer 1", 3" and a glass fiber layer 2" made of glass fiber cloth, and the glass fiber layer 2" is disposed on the crystal glue layer.
- the laser strip itself can be illuminated, and the crystal glue is transparent, so that the double-sided fiberglass board can Beautiful light is emitted at night, which can be set on the exterior of the building to make a decorative effect, especially at night, and a special pattern can be formed by a plurality of the same double-sided glass.
- the first mold includes a bottomed outer frame 10, the bottom of the outer frame is a wooden first bottom plate 12, and is disposed in the outer frame.
- the frame 20, the bottom of the inner frame is a second bottom plate 22 made of refractory material, and further includes an angle iron 30 which is formed to be formed inside the inner frame and extends to the outer frame at four corners, and is disposed on the outer frame
- the pressing member 40 that fixes or frees the inner frame to the outer frame can be rotated.
- the crystal glue, the liquid accelerator and the drier are mixed at a weight ratio of 400: 8. 0: 9. 0.
- the main component of the crystal glue is a resin (Polyester Resin Synolite), and the main component of the accelerator is Cobalt naphthnate, the main component of the drier is methyl ethyl ketone peroxide (MEX-Peroxide); then the resulting mixture is poured onto the second bottom plate 20 of the first mold, and the laser strip 4" is placed thereon.
- the first mold of the mixture with the laser strip is then placed in an oven and heated at a temperature of 70 ° 0, after a period of time, taken out of the oven and cooled;
- the second mold is smaller than the first mold, as shown in FIG. 6, which also has a flat bottom, a certain height border around, and An opening is provided at the opposite side of the bottom, and the second mold comprises a bottomed outer frame 1 (the bottom of the outer frame is a wooden first bottom plate 12 and an inner frame 20' disposed in the outer frame, the inner frame
- the bottom portion is a second bottom plate 22' made of refractory material, and further includes an angle iron 30' which is formed to be formed inside the inner frame and extends to the outer frame at four corners, and is disposed on the outer frame to be rotatable
- the inner frame and the outer frame are fixed or free of the pressed piece 40'.
- the surface glue, the liquid promoter and the drier are mixed according to the weight ratio of 42: 7. 5: 5. 9 , and the main component of the top coat is the rubber sole (Polyester) Resin Gelcoat Synolite ), the main component of the accelerator is cobalt stearate
- the main component of the drier is methyl ethyl ketone peroxide (MEX-Peroxide);
- MEX-Peroxide methyl ethyl ketone peroxide
- the viscous mixture is poured onto the bottom plate of the second mold, and the second mold is placed in an oven at a temperature of 80 Heating, after a period of time, taking it out of the oven and cooling it;
- the glass fiber board taken out from the first mold is placed on the surface of the mixture of the second mold, pressurized, and then heated in an oven at a temperature of 98 ° 0, after a period of time, from baking Removed from the furnace and cooled;
- the double-sided glass plate comprises a glass fiber cement layer 1", a crystal glue layer la'", and a glass fiber layer 2"' made of glass fiber cloth.
- 2a'" and top layer 3"', glass fiber layer 3a'", glass fiber layer 2"' is placed between glass fiber layer 1"' and top layer 3"';
- several reinforcing columns 5"' are hooked between the glass fiber layer ⁇ " and the glass fiber layer l a'" ;
- In the crystal glue layer ⁇ " is set with luminescent stone 4,".
- the reinforcing column 5"' is made of the same raw material as the raw material of the crystal glue layer after hardening, and the height is uniform, the two ends are respectively immersed in phase
- the adjacent crystal layer is integrated with the double-sided fiberglass board, so that the strength and hardness of the double-sided fiberglass board can be increased, and it can be produced and used in large pieces, thereby reducing transportation cost and reducing the processing process.
- the method of manufacturing the double-sided glass plate in the fourth embodiment of the present invention is as follows - Taking the first mold, as described in FIG. 5, the first mold includes a bottomed outer frame 10, the bottom of the outer frame is a wooden first bottom plate 12, and is disposed in the outer frame.
- the frame 20, the bottom of the inner frame is a second bottom plate 22 made of refractory material, and further includes an angle iron 30 which is formed to be formed inside the inner frame and extends to the outer frame at four corners, and is disposed on the outer frame
- the pressing member 40 that fixes or frees the inner frame to the outer frame can be rotated.
- the crystal glue, liquid promoter and drier are mixed according to the weight ratio of 430: 8. 6: 9. 3 , the main component of the crystal glue is resin (Polyester Resin Synolite), the main component of the accelerator is Cobalt naphthnate, the main component of the drier is methyl ethyl ketone peroxide (MEX-Peroxide); then the resulting mixture is poured onto the second bottom plate 20 of the first mold, and the luminescent stone is placed 4" In this mixture, the first mold of the mixture with feldspar is then placed in an oven and heated at a temperature of 75 ° C. After a period of time, it is taken out of the oven and cooled;
- the main component of the crystal glue is resin (Polyester Resin Synolite)
- the main component of the accelerator is Cobalt naphthnate
- the main component of the drier is methyl ethyl ketone peroxide (MEX-Peroxide)
- MEX-Peroxide methyl
- step (3) placing the glass fiber cloth on the mixture obtained after the step (2), and then coating a small amount of glass fiber glue on the glass fiber cloth, and then clamping the glass fiber cloth by external force, and then pouring the amount
- a plurality of glass fiber glues are fixed to the glass fiber cloth, and then heated in an oven at a temperature of 90 ° C, and after a period of time, are taken out from the oven and cooled;
- the second mold While performing the steps (1) and (2), taking the second mold, the second mold is smaller than the first mold, as shown in Fig. 6, it also has a flat bottom, a certain height around the border, and An opening is provided at the opposite side of the bottom, the second mold includes a bottomed outer frame 10', the bottom of the outer frame is a wooden first bottom plate 12', and an inner frame 20' disposed inside the outer frame, The bottom of the frame is a second bottom plate 22 made of refractory material, and further includes an angle iron 30' which is formed to be formed inside the inner frame and extends to the outer frame at four corners, and is disposed on the outer frame to be rotatable A press member 40' that secures or frees the inner frame to the outer frame.
- the surface glue, liquid promoter and drier are mixed according to the weight ratio of 45: 7. 5: 8. 9 , the main component of the top glue is glue Polyester Resin Gelcoat Synolite, the main component of the accelerator is cobalt stearate (Cobalt naphthnate), the main component of the drier is methyl ethyl ketone peroxide (MEX-Peroxide); the mixture of the viscosity is poured into the bottom plate of the second mold Upper, the second mold is placed in an oven and heated at a temperature of 80 ° 0, after a period of time, taken out of the oven and cooled;
- the main component of the top glue is glue Polyester Resin Gelcoat Synolite
- the main component of the accelerator is cobalt stearate (Cobalt naphthnate)
- the main component of the drier is methyl ethyl ketone peroxide (MEX-Peroxide)
- MEX-Peroxide methyl ethyl ketone peroxide
- step (3) or (4) when the mixture is still viscous and not completely cooled, a reinforcing column made of a highly uniform material of slightly hardness is stably inserted into the viscous mixture. in.
- the glass fiber board taken out from the first mold is placed on the surface of the mixture of the second mold, pressurized, and then heated in an oven at a temperature of 98 ° C. After a period of time, from baking Removed from the furnace and cooled;
- a luminous card make a sign with Chinese and English or a pattern, which can be flowers or other accessories (such as jewelry), newspapers, magazines, books, clothing, or luminous powder.
- One or more of the compositions may be used as a filler, and various toners or ABC powders and the like may be added thereto.
- anything that we can get can be used as a filler as long as it can be placed in a mold.
- This product is an environmentally friendly product that can be reused after recycling. This product can be re-created as multiple layers as needed.
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- Laminated Bodies (AREA)
Abstract
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200580000356.4A CN1819928B (zh) | 2004-09-21 | 2005-09-15 | 双面玻璃纤维板制作方法 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410082630 CN1751881A (zh) | 2004-09-21 | 2004-09-21 | 双面各款云石玻璃纤维板的制造方法 |
| CN200410082630.4 | 2004-09-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2006032189A1 true WO2006032189A1 (fr) | 2006-03-30 |
Family
ID=34352379
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN2005/001476 Ceased WO2006032189A1 (fr) | 2004-09-21 | 2005-09-15 | Carte en fibre de verre double face et procédé de fabrication idoine |
Country Status (3)
| Country | Link |
|---|---|
| CN (2) | CN1751881A (fr) |
| HK (1) | HK1066691A2 (fr) |
| WO (1) | WO2006032189A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103982022A (zh) * | 2014-06-04 | 2014-08-13 | 广西启利新材料科技股份有限公司 | 一种玻纤毡与玻纤网叠合的砂浆底胎 |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201124578A (en) * | 2010-01-12 | 2011-07-16 | Hsu Tai Glass Fiber Co Ltd | Manufacturing method of glass fiber cotton and product thereof. |
| CN102733583A (zh) * | 2012-05-03 | 2012-10-17 | 新乡市鼎鑫机械有限公司 | 一种生产pvc地板的新方法 |
| CN103407267B (zh) * | 2013-04-16 | 2016-01-06 | 浙江未来家木业有限公司 | 一种玻璃纤维地板的加工方法 |
| CN104890258A (zh) * | 2015-05-29 | 2015-09-09 | 南通澳兰德复合材料有限公司 | 一种耐腐阻燃单孔板型材的制作工艺 |
| CN113183375B (zh) * | 2020-01-14 | 2023-09-01 | 杭州亚态农科技有限公司 | 一种内含三维内饰物的水晶生态板材的制作方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4374170A (en) * | 1981-11-09 | 1983-02-15 | Ford Motor Company | Room temperature cure polyester laminates |
| CN1476992A (zh) * | 2003-07-11 | 2004-02-25 | 宏 刘 | 仿镂空雕装饰品的制作方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2136128Y (zh) * | 1992-09-18 | 1993-06-16 | 曾小琪 | 镭射装饰塑料板 |
| CN2159892Y (zh) * | 1993-03-09 | 1994-03-30 | 王柏林 | 聚酯彩色主体花纹装饰板 |
| US5639411A (en) * | 1994-12-21 | 1997-06-17 | Holli-Nee Corporation | Process for expanding glass fiber laminates and panels formed thereby |
| CN2267152Y (zh) * | 1996-11-04 | 1997-11-12 | 尹明君 | 塑钢装饰板、画 |
| CN2461330Y (zh) * | 2001-02-13 | 2001-11-28 | 陈木财 | 通风鞋垫 |
| CN2581209Y (zh) * | 2002-05-23 | 2003-10-22 | 金坚 | 一种带浮雕效果的艺术制品 |
| CN1509904A (zh) * | 2002-12-23 | 2004-07-07 | 廉长江 | 用树脂材料仿木刻字艺术壁挂 |
-
2004
- 2004-09-21 CN CN 200410082630 patent/CN1751881A/zh active Pending
- 2004-11-04 HK HK04108693A patent/HK1066691A2/xx not_active IP Right Cessation
-
2005
- 2005-09-15 WO PCT/CN2005/001476 patent/WO2006032189A1/fr not_active Ceased
- 2005-09-15 CN CN200580000356.4A patent/CN1819928B/zh not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4374170A (en) * | 1981-11-09 | 1983-02-15 | Ford Motor Company | Room temperature cure polyester laminates |
| CN1476992A (zh) * | 2003-07-11 | 2004-02-25 | 宏 刘 | 仿镂空雕装饰品的制作方法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103982022A (zh) * | 2014-06-04 | 2014-08-13 | 广西启利新材料科技股份有限公司 | 一种玻纤毡与玻纤网叠合的砂浆底胎 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1819928A (zh) | 2006-08-16 |
| CN1751881A (zh) | 2006-03-29 |
| HK1094507A1 (zh) | 2007-03-30 |
| CN1819928B (zh) | 2010-05-12 |
| HK1066691A2 (en) | 2005-03-04 |
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