WO2006102941A2 - Dispositif permettant d'eliminer l'eau d'une solution aqueuse - Google Patents

Dispositif permettant d'eliminer l'eau d'une solution aqueuse Download PDF

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Publication number
WO2006102941A2
WO2006102941A2 PCT/EP2005/051444 EP2005051444W WO2006102941A2 WO 2006102941 A2 WO2006102941 A2 WO 2006102941A2 EP 2005051444 W EP2005051444 W EP 2005051444W WO 2006102941 A2 WO2006102941 A2 WO 2006102941A2
Authority
WO
WIPO (PCT)
Prior art keywords
water
pump
solution
aqueous solution
vacuum vessel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2005/051444
Other languages
German (de)
English (en)
Other versions
WO2006102941A3 (fr
Inventor
Jürgen Ullrich
Andreas Karsdord
Heinz Dieter Bürger
Kira Bürger
Günter Heinrich
Gabriele Mitzschke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Miwe Okokalte GmbH
Original Assignee
Miwe Okokalte GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Miwe Okokalte GmbH filed Critical Miwe Okokalte GmbH
Priority to PCT/EP2005/051444 priority Critical patent/WO2006102941A2/fr
Publication of WO2006102941A2 publication Critical patent/WO2006102941A2/fr
Anticipated expiration legal-status Critical
Publication of WO2006102941A3 publication Critical patent/WO2006102941A3/fr
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/28Evaporating with vapour compression
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/04Evaporators with horizontal tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/28Evaporating with vapour compression
    • B01D1/2881Compression specifications (e.g. pressure, temperature, processes)
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/048Purification of waste water by evaporation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04CROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
    • F04C18/00Rotary-piston pumps specially adapted for elastic fluids
    • F04C18/08Rotary-piston pumps specially adapted for elastic fluids of intermeshing-engagement type, i.e. with engagement of co-operating members similar to that of toothed gearing
    • F04C18/12Rotary-piston pumps specially adapted for elastic fluids of intermeshing-engagement type, i.e. with engagement of co-operating members similar to that of toothed gearing of other than internal-axis type
    • F04C18/126Rotary-piston pumps specially adapted for elastic fluids of intermeshing-engagement type, i.e. with engagement of co-operating members similar to that of toothed gearing of other than internal-axis type with radially from the rotor body extending elements, not necessarily co-operating with corresponding recesses in the other rotor, e.g. lobes, Roots type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04CROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
    • F04C2220/00Application
    • F04C2220/10Vacuum
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B25/00Machines, plants or systems, using a combination of modes of operation covered by two or more of the groups F25B1/00 - F25B23/00
    • F25B25/02Compression-sorption machines, plants, or systems

Definitions

  • the present invention relates to a device for expelling
  • the object of the invention is to provide an expeller, the water from a
  • Water-absorbing solution expels in a vacuum boiler with low energy consumption.
  • the inventive device for expelling water from an aqueous
  • Solution in a vacuum vessel is thus characterized in that it contains a Roots pump which is connected to the suction side of the gas space above the solution in the vacuum vessel and the pressure side via a dipped into the solution condensation coil to a water outlet.
  • This device allows a very efficient expulsion of the water.
  • the Wälzkolbenpumpe may be provided with a Voreinlouksselung to improve the pump cooling.
  • a Voreinlouksselung By the Voreinlouksselung water from the water outlet of the condensation coil can be sucked into each delivery chamber of the pump just before the opening to the pressure side.
  • spray heads may be mounted in the condensation coil through which an aqueous solution of a vapor pressure reducing substance such as glycol, causticate or common salt may be injected into the condensation coil.
  • a vapor pressure reducing substance such as glycol, causticate or common salt
  • the device may comprise a heating coil in the vacuum vessel, which is immersed in the solution.
  • the Roots pump may be a Helix Roots pump, which allows operation with little energy.
  • FIG. 1 schematically shows a preferred embodiment of the expeller according to the invention.
  • FIG. 2 shows a variant of FIG. 1 according to the invention.
  • FIG. 3 shows a diagram of a cooling or heating device in which the expeller according to the invention is used.
  • a vacuum vessel 1 is shown, which is connected .An Wälzkolbenpumpe 2 so that its suction inlet 3 is connected to the gas space 4 above the aqueous solution 5 in the vacuum vessel 1, while their pressure outlet 6 opens into a condensation coil 7 , which is located in the lower part of the boiler 1 and outside the boiler via a water outlet 8 to a collection container 25 shown in Figure 2 for water.
  • a fine mesh grid 10 in the upper region of the gas space 4 prevents the suction of liquid through the Roots pump.
  • Roots piston pump is shown as a per se known Roots piston pump, but it is also possible to use another displacement pump according to the isochoric compression principle (constant volume), e.g. a three-wing Roots pump or a Helix Roots pump, the latter being characterized by a very low noise at pressures above about 100 mbar.
  • a three-wing Roots pump or a Helix Roots pump is characterized by a very low noise at pressures above about 100 mbar.
  • the pump operates as a so-called vapor compressor and generates a vacuum in the
  • FIG. 1 in the output region of the Roots pump, a precontrol laßksselung shown.
  • a coolant is sucked into each of the two delivery chambers of the pump due to the pressure difference between the suction and pressure side, just before the respective chamber opens to the outlet 6 through.
  • water is used as the coolant, which passes at the outlet 8 of the condensation coil via a line 11 to corresponding inlets into the delivery chambers. This results in effective cooling of the pump, which would otherwise be significantly heated by the very hot steam on the pressure side.
  • the required compression pressure would be only 170 mbar for a LiBr solution injected at 70 ° C. instead of 1013 mbar for pure water.
  • FIG. 3 shows a cooling or heating system in which the device according to FIG.
  • FIG. 1 can be used.
  • the vapor compression in the generator 1 of the refrigeration for a cooling chamber 21 The water-laden sorbent is pumped by a pump 22 in the expeller and there concentrated as described.
  • the concentrated sorbent passes via a (parallel to the cooling chamber 21 fed) cooler 23 in the spray head of a Sprühabsorbers 24, in the water vapor is sucked from an evaporator 25.
  • the cold water in this evaporator serves as a coolant for the cooling chamber 21 and is circulated by a pump 27.
  • the bottom of the spray absorber 23 is funnel-shaped, and its lower end is connected via a height-adjustable siphon 28 with a collecting container 29, from which the pump 22, the enriched solution for processing to the expeller 1 back.
  • the gas space 4 of the expeller 1 to be evacuated to remove permanent gases. If the solution in the generator does not already have the desired temperature of, for example, HO 0 C, it must still be heated, for example by a heating coil 9 in the generator 1. During operation, further heating can then be dispensed with since the released (caused by the energy of the pump 2) released steam energy in the generator heats the solution.
  • the invention is not limited to the exemplary embodiment described with reference to FIG. 1 and the variants mentioned above.
  • the pre-let cooling can be omitted if the temperature of the pump does not exceed a limit value during operation at the predetermined pressure ratio.
  • the concrete numerical data on the temperature, the pressure and the concentration of the solution have been given only by way of illustration and do not limit the invention.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Degasification And Air Bubble Elimination (AREA)
  • Physical Water Treatments (AREA)

Abstract

Dispositif permettant d'éliminer l'eau d'une solution aqueuse dans une cuve de vide. Selon la présente invention, ledit dispositif comporte une pompe Roots (2) qui est raccordée du côté de l'aspiration à la chambre de gaz (4) située au-dessus de la solution se trouvant dans la cuve de vide (1) et du côté de la pression, via un serpentin de condensation (7) immergé dans la solution, à un orifice de sortie d'eau (8). Ledit dispositif est caractérisé en ce qu'il consomme peu d'énergie pour la condensation de la vapeur d'eau éliminée.
PCT/EP2005/051444 2005-03-30 2005-03-30 Dispositif permettant d'eliminer l'eau d'une solution aqueuse Ceased WO2006102941A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/EP2005/051444 WO2006102941A2 (fr) 2005-03-30 2005-03-30 Dispositif permettant d'eliminer l'eau d'une solution aqueuse

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2005/051444 WO2006102941A2 (fr) 2005-03-30 2005-03-30 Dispositif permettant d'eliminer l'eau d'une solution aqueuse

Publications (2)

Publication Number Publication Date
WO2006102941A2 true WO2006102941A2 (fr) 2006-10-05
WO2006102941A3 WO2006102941A3 (fr) 2008-12-24

Family

ID=34963281

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2005/051444 Ceased WO2006102941A2 (fr) 2005-03-30 2005-03-30 Dispositif permettant d'eliminer l'eau d'une solution aqueuse

Country Status (1)

Country Link
WO (1) WO2006102941A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015107857A1 (fr) * 2014-01-14 2015-07-23 日本化学機械製造株式会社 Système de récupération de chaleur dans un dispositif d'évaporation utilisant un compresseur de vapeur roots
CN109404281A (zh) * 2018-12-13 2019-03-01 江阴爱尔姆真空设备有限公司 一种自动集液气冷罗茨真空机组

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US849579A (en) * 1904-04-25 1907-04-09 John E Siebel Art of distilling, concentrating, and evaporating liquids.
US3956072A (en) * 1975-08-21 1976-05-11 Atlantic Fluidics, Inc. Vapor distillation apparatus with two disparate compressors
DE2850403A1 (de) * 1978-11-21 1980-05-29 Luft U Kaeltetechnik Veb K Kompressionskaeltemaschine mit loesungskreislauf
DE3100019A1 (de) * 1981-01-02 1982-09-23 Werner Dr.-Ing. 1000 Berlin Malewski Verfahren zur durchfuehrung von kaelte- und waermepumpenprozessen nach dem kompressionsprinzip mit loesungskreislauf
HU198329B (en) * 1986-05-23 1989-09-28 Energiagazdalkodasi Intezet Method and apparatus for increasing the power factor of compression hybrid refrigerators or heat pumps operating by solution circuit
DE4230818A1 (de) * 1992-09-15 1994-03-17 Fritz Egger Gmbh Verfahren und Einrichtung zur Leistungsregelung einer Kompressions-Wärmepumpe und/oder Kältemaschine
JPH10227537A (ja) * 1997-02-13 1998-08-25 Yazaki Corp 吸収冷凍機
BE1013944A3 (nl) * 2001-03-06 2003-01-14 Atlas Copco Airpower Nv Watergeinjecteerde schroefcompressor.

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015107857A1 (fr) * 2014-01-14 2015-07-23 日本化学機械製造株式会社 Système de récupération de chaleur dans un dispositif d'évaporation utilisant un compresseur de vapeur roots
JP2015132210A (ja) * 2014-01-14 2015-07-23 日本化学機械製造株式会社 蒸気圧縮式ルーツブロワを使用した蒸発装置における熱回収システム
CN109404281A (zh) * 2018-12-13 2019-03-01 江阴爱尔姆真空设备有限公司 一种自动集液气冷罗茨真空机组

Also Published As

Publication number Publication date
WO2006102941A3 (fr) 2008-12-24

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