WO2007132802A1 - 冷凍装置 - Google Patents
冷凍装置 Download PDFInfo
- Publication number
- WO2007132802A1 WO2007132802A1 PCT/JP2007/059843 JP2007059843W WO2007132802A1 WO 2007132802 A1 WO2007132802 A1 WO 2007132802A1 JP 2007059843 W JP2007059843 W JP 2007059843W WO 2007132802 A1 WO2007132802 A1 WO 2007132802A1
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- WO
- WIPO (PCT)
- Prior art keywords
- heat insulating
- refrigerant
- compressor
- refrigeration apparatus
- machine room
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D19/00—Arrangement or mounting of refrigeration units with respect to devices or objects to be refrigerated, e.g. infrared detectors
- F25D19/02—Arrangement or mounting of refrigeration units with respect to devices or objects to be refrigerated, e.g. infrared detectors plug-in type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
- F25B9/006—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant containing more than one component
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D19/00—Arrangement or mounting of refrigeration units with respect to devices or objects to be refrigerated, e.g. infrared detectors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/06—Walls
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/06—Walls
- F25D23/065—Details
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D29/00—Arrangement or mounting of control or safety devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2201/00—Insulation
- F25D2201/10—Insulation with respect to heat
- F25D2201/14—Insulation with respect to heat using subatmospheric pressure
Definitions
- the present invention relates to a refrigeration apparatus that includes a refrigerant circuit including a compressor and an evaporator, and cools a storage chamber formed in a heat insulating box with an evaporator to an extremely low temperature.
- a refrigeration apparatus that keeps the inside of a refrigerator at an ultra-low temperature has a main body constituted by a heat insulating box body that is configured by filling a space formed by combining an inner box and an outer box with a foam heat insulating material.
- An ultra-low temperature space of, for example, 80 ° C. or less is formed in a storage chamber formed in the heat insulation box by, for example, a two-dimensional refrigeration system refrigeration apparatus (see Patent Document 1).
- a refrigeration apparatus that maintains a storage chamber at an ultra-low temperature such as 80 ° C or lower is composed of a heat insulating box having an opening on the upper surface and a heat insulating door that closes the upper surface opening so as to be freely opened and closed.
- a machine room in which a cooling device of a two-dimensional refrigeration system is arranged on the side of the body is formed.
- the heat insulation box is filled with a considerable thickness of heat insulating material between the inner box and the outer box in consideration of the temperature difference between the outside and the inner box. Is done.
- the refrigeration apparatus is used for the preservation of living cells in physics and chemistry laboratories and the like, and sometimes accurately measures and records the temperature at which the sample stored in the storage chamber is actually stored. is there.
- a measurement hole for introducing the sensor is required.
- FIG. 10 shows a perspective view of a conventional refrigeration apparatus 100.
- the refrigeration apparatus 100 includes a heat insulation box 101 having an opening on the upper surface and forming a storage chamber therein, and a machine room 102 formed adjacent to the side of the heat insulation box 101.
- the opening on the upper surface of the heat insulating box 101 is closed openably by a heat insulating door 103.
- a measurement hole 105 is formed in the side surface 101A located on the side opposite to the side on which the machine chamber 102 is formed of the heat insulating box 101. Yes.
- the measurement hole 105 can insert a temperature sensor into the external force storage chamber, and the wiring drawn from the temperature sensor is connected to the external recording apparatus main body via the measurement hole 105. . Then, the measurement hole 105 is closed with a plug 106 made of a spongy deformable special material in the gap with the wiring. When the temperature sensor is not attached, the measurement hole 105 is adiabatically closed by the stopper 106.
- Patent Document 1 JP-A 62-73046
- the refrigeration apparatus is often installed along the wall or along other equipment in a physics and chemistry laboratory or the like, if a measurement hole is formed in the back of the storage, the recording apparatus Therefore, it is often formed on the side surface of the heat insulation box located opposite to the side on which the machine room is formed.
- this refrigeration apparatus needs to use a heat insulating box filled with a heat insulating material having a predetermined thickness in order to maintain the storage chamber at a predetermined ultra-low temperature.
- the overall dimensions for the volume in the storage chamber increase.
- the present invention has been made to solve the conventional technical problem, and it is possible to measure the temperature and the like in the storage chamber using a measurement hole that does not affect the installation environment.
- An object of the present invention is to provide a refrigeration apparatus.
- a refrigeration apparatus includes a refrigerant circuit composed of a compressor, an evaporator, and the like, and is formed by cooling a storage chamber configured in a heat insulating box with an evaporator to an ultra-low temperature,
- the machine room is configured on the side of the heat insulation box and is equipped with a compressor.
- the measurement hole to be passed is formed on the side wall on the machine room side of the heat insulating box.
- the heat insulating box is formed by a composite structure of a vacuum heat insulating panel and a foam heat insulating material, and the vacuum heat insulating panel is attached to the front and rear walls of the heat insulating box. And it has arrange
- the refrigeration apparatus according to the invention of claim 3 is characterized in that, in each of the above inventions, an openable / closable panel for concealing the measurement hole is provided in the machine room.
- the refrigeration apparatus of the invention of claim 4 is characterized in that, in the above invention, the top panel of the machine room is configured to be openable and closable, and the measurement hole can be operated with the top panel open. To do.
- the heat insulating box in a refrigeration apparatus that includes a refrigerant circuit including a compressor, an evaporator, and the like, and cools a storage chamber configured in the heat insulating box by the evaporator to an ultra-low temperature, the heat insulating box
- the side of the machine room side of the heat insulation box has a measurement hole that communicates with the storage room.
- the heat insulating box is formed of a composite structure of a vacuum heat insulating panel and a foam heat insulating material.
- the storage room has a temperature of, for example, 150 ° C or less. Even when the temperature is extremely low, it is possible to improve the heat insulation performance of the heat insulation box itself, and the size can be reduced. The volume can be increased. Or, even with the same accommodation volume as the conventional one, it is possible to reduce the outer dimensions, which also makes it possible to reduce the area required for installing the refrigeration apparatus.
- the machine room is provided with an openable / closable panel for concealing the measurement hole, so that the measurement hole is not exposed to the outside. It is possible to improve the appearance.
- the top panel of the machine room is configured to be openable and closable, and the measurement hole can be operated with the top panel open. This makes it easier to operate and improves workability. In addition, it is easy to operate other equipment in the machine, and maintenance work can be improved.
- FIG. 1 is a perspective view of a refrigeration apparatus 1 to which the present invention is applied
- FIG. 2 is a front view of the refrigeration apparatus 1
- FIG. 3 is a plan view of the refrigeration apparatus 1
- FIG. 4 is a perspective view of a storage chamber 4 of the refrigeration apparatus 1.
- FIG. 5 shows a perspective view of the refrigeration apparatus 1 with the top panel 5 opened.
- the refrigeration apparatus 1 of the present embodiment is suitable for ultra-low temperature storage of, for example, a living tissue or specimen that is stored at a low temperature for a long period of time, and includes a heat insulating box 2 that opens to the upper surface, and a side of the heat insulating box 2 And the machine room 3 in which the compressor 10 and the like are installed.
- the heat insulation box 2 is composed of a steel plate outer box 6 whose upper surface is open at V, a deviation, a metal inner box 7 having good thermal conductivity, such as aluminum, and both of these boxes 6 and 7.
- Breaker 8 made of synthetic resin that connects between the upper ends, and heat insulating material 9 made of polyurethane resin filled in the space enclosed by these outer box 6, inner box 7 and breaker 8 by on-site foaming method
- the interior of the inner box 7 is a storage chamber 4 with an open top surface.
- the heat insulating box 2 that partitions the storage chamber 4 from the outside air. Compared with the low temperature where the internal temperature is set to around 0 ° C, the heat insulation capacity is required. Therefore, In order to ensure the heat insulation capacity only by using a heat insulating material 9 made of polyurethane resin
- the heat insulating box 2 in the present embodiment includes the front wall 6A, the rear wall 6B, and the machine room of the outer box 6.
- Insulating material 9 is filled in-situ foaming method.
- the vacuum heat insulation panel 12 stores glass wool having heat insulation in a container formed of a multilayer film having strength such as aluminum which does not have air permeability or synthetic resin. After that, the air in the container is discharged by a predetermined evacuation means, and the opening of the container is joined by thermal welding. Therefore, the vacuum heat insulation panel 12 can obtain the same heat insulation effect while making the thickness of the heat insulating material 9 thinner than before due to the heat insulation performance.
- an evaporator (evaporation pipe) 62 constituting a refrigerant circuit of a cooling device R, which will be described later in detail, is attached to the peripheral surface of the inner box 7 on the heat insulating material 9 side in a heat exchange manner.
- the upper surface of the breaker 8 of the heat insulating box 2 configured as described above is formed in a step shape as shown in FIG. 2 and FIG. 4, and a heat insulating door is provided there through a packing (not shown). 13 is provided at one end, and in this embodiment, is pivotally provided by pivot members 14 and 14 around the rear end. Further, the upper opening of the storage chamber 4 is provided with an inner lid 15 made of a heat insulating material so as to be freely opened and closed. In addition, a pressing portion configured to protrude downward is formed on the lower surface of the heat insulating door 13, whereby the pressing portion of the heat insulating door 13 presses the inner lid 15, thereby the storage chamber 4. The upper surface opening is closed so as to be freely opened and closed. In addition, a handle portion 16 is provided at the other end of the heat insulating door 13, that is, the front end in the present embodiment, and the heat insulating door 13 is opened and closed by operating the handle portion 16.
- a machine room 3 is provided by a side panel 3B that constitutes a side surface opposite to the side on which the front panel 3A, a rear panel (not shown) and the heat insulation box 2 are provided. It is The machine room 3 in this embodiment is provided with a partition plate 17 that divides the interior vertically. Below the partition plate 17, the compressor 10 constituting the cooling device R as described above. 20 and the like, and a ventilation slit 3C is formed in the front panel 3A and the side panel 3B located below the partition plate 17.
- an upper machine chamber 18 having an open upper surface is provided above the partition plate 17, an upper machine chamber 18 having an open upper surface is provided.
- a top panel 5 is provided at the top opening of the upper machine room 18 so as to be pivotable around the rear end in this embodiment, so that the upper machine room 18 can be opened and closed. Is blocked.
- the panel provided in front of the upper machine chamber 18 is an operation panel 21 for operating the refrigeration apparatus 1.
- a measurement hole 19 is formed on a side surface of the upper machine chamber 18 on the heat insulating box 2 side.
- the measurement hole 19 penetrates the outer box 6, the heat insulating material 9 and the inner box 7 constituting the heat insulating box 2 so as to communicate with the storage chamber 4 formed in the heat insulating box 2 provided adjacently. Formed.
- the measurement hole 19 can also insert a temperature sensor into the storage chamber 4 with an external force, and the wiring drawn from the temperature sensor is connected to the external recording apparatus main body through the measurement hole 19. Then, the measurement hole 19 is closed by a plug 19A made of a special material that can be deformed in a sponge-like manner and has a heat insulating property. When the temperature sensor is not attached, the measurement hole 19 is thermally blocked by the stopper 19A.
- the top panel 5 provided in the machine room 3 is opened and the heat insulation located in the upper machine room 18 is opened.
- the measurement device can be inserted into the storage chamber 4 through the measurement hole 19 formed on the side surface of the box body 2 side. Therefore, it becomes easy to install the measuring device in the storage chamber 4 cooled to a predetermined ultra-low temperature.
- the measurement hole 19 in the present embodiment is formed on the side surface of the heat insulating box 2 on the machine room 18 side. Even when it is installed adjacent to a wall or other equipment in an installation environment such as a laboratory, it is not necessary to have a special interval for using the measurement hole 19. As a result, the area required for installing the refrigeration apparatus 1 can be reduced, which is suitable for layout in a laboratory or the like.
- the measurement hole 19 is formed in the wall surface of the heat insulating box 2 adjacent to the machine room 3.
- a vacuum insulation panel 12 can be provided on the side surfaces other than the machine room 3 adjacent to each other, that is, on the front and rear walls and side surfaces of the heat insulating box 2 configured to face the outside.
- the heat insulating performance of the heat insulating box 2 itself can be improved, and the heat insulating wall Therefore, even if the external dimensions are the same as the conventional size, the storage volume in the storage chamber 4 can be increased. Or, even with the same storage volume as before, it is possible to reduce the outer dimensions, which also makes it possible to reduce the area required for installing the refrigeration apparatus 1. .
- the measurement hole 19 in this embodiment can be concealed by the top panel 5 that can open and close the upper surface opening of the upper machine room 18, the measurement hole 19 is not exposed to the appearance. It is possible to improve the appearance. Also, by opening the top panel 5, it becomes possible to easily operate the measurement hole 19, and workability can be improved. Further, by removing the partition plate 17, it becomes easy to operate the devices constituting the other cooling devices R installed below the partition plate 17, and it becomes possible to improve the maintenance work.
- the top panel 5 can be used as a work side stand by closing the inside of the machine room 18 except when the measurement hole 19 is operated. Thus, it is suitable for the delivery work of articles such as samples into the storage chamber 4.
- the measurement hole 19 is a force concealed by the top panel 5 that closes the upper surface opening of the upper machine room 18.
- a lid member for concealing the measurement hole 19 may be provided.
- the refrigerant circuit of the refrigeration apparatus 1 in the example is a binary circuit of a high-temperature side refrigerant circuit 25 as a first refrigerant circuit and a low-temperature side refrigerant circuit 38 as a second refrigerant circuit, each as a multi-component multi-stage refrigerant circuit. It is composed of a two-stage refrigerant circuit.
- the compressor 10 constituting the high temperature side refrigerant circuit 25 is an electric compressor using a one-phase or three-phase AC power source, and the discharge side pipe 10D of the compressor 10 is connected to the auxiliary condenser 26. .
- the auxiliary condenser 26 is connected to a refrigerant pipe 27 (hereinafter referred to as a frame pipe) disposed on the back side of the opening edge in order to heat the opening edge of the storage chamber 4 and prevent dew condensation.
- the frame pipe 27 is connected to the condenser 28 after being connected to the oil cooler 29 of the compressor 10.
- the refrigerant pipe exiting the condenser 28 is connected to the oil cooler 30 of the compressor 20 constituting the low-temperature side refrigerant circuit 38, and then connected to the condenser 31.
- the refrigerant pipe exiting the condenser 31 Are connected to an evaporator 34 as an evaporator portion constituting the evaporator through a dryer 32 and a cavity tube 33 as a decompression device in order.
- An accumulator 35 serving as a refrigerant reservoir is connected to the outlet-side refrigerant pipe of the evaporator 34, and the refrigerant pipe exiting the accumulator 35 is connected to the suction-side pipe 10 S of the compressor 10.
- the auxiliary condenser 26 and the condensers 28 and 31 in this embodiment are configured as an integral condenser and are cooled by the condenser blower 36.
- the high temperature side refrigerant circuit 25 is filled with a refrigerant composed of R407D and n-pentane as a non-azeotropic refrigerant having different boiling points.
- R407D has R32 (difluoromethane: CH F) and R125 (
- Pentafluoroethane CHF CF
- R134a l, 1, 1, 2—tetrafluoroethane: C
- R32 is 15 weight 0/0
- R125 is 15 weight 0/0
- 4a is 70% by weight.
- the boiling points of each refrigerant are R32-51.8 ° C, R125 force-48.57 ° C, and R134a-26.16 ° C.
- the boiling point of n-pentane is + 36.1 ° C.
- the high-temperature gaseous refrigerant discharged from the compressor 10 is supplied to the auxiliary condenser 26, the frame pipe 27, the oil cooler 29, the condenser 28, the low-temperature side refrigerant circuit 38, the compressor 20 oil cooler 30 and the condenser 31.
- the water contained in the dryer 32 is removed after being condensed in the radiator 32, and the pressure is reduced in the capillary tube 33 and flows into the evaporator 34 one after another to evaporate the refrigerant R32, R1 25 and Rl 34a. Then, the vaporization heat is absorbed by the ambient force to cool the evaporator 34 and return to the compressor 10 through the accumulator 35 as a refrigerant liquid reservoir.
- the capacity of the compressor 10 is 1.5 HP, for example, and the final temperature reached by the evaporator 34 during operation is -27 ° C to -35 ° C.
- n-pentane in the refrigerant has a boiling point of +36. 1 ° C, so it does not evaporate in the evaporator 34 and remains in the liquid state. Due to the function of returning the lubricant to the compressor 10 in a state where water is dissolved in the lubricating oil of the machine 10 and the dryer 32, and the evaporation of the liquid refrigerant in the compressor 10, The function of reducing the temperature of the compressor 10 is achieved.
- the compressor 20 is an electric compressor that uses a one-phase or three-phase AC power supply like the compressor 10, and the discharge-side piping 20D of the compressor 20 includes
- the oil separator 40 is connected through a radiator 39 composed of a wire capacitor.
- the oil separator 40 is connected to an oil return pipe 41 that returns to the compressor 20.
- the refrigerant pipe connected to the outlet side of the oil separator 40 is connected to a condensing pipe 42 as a high-pressure side pipe inserted into the evaporator 34.
- This condensing pipe 42, together with the evaporator 34, constitutes a cascade heat exchange ⁇ 43.
- the discharge pipe connected to the outlet side of the condensing pipe 42 is connected to the first gas-liquid separator 46 via the dryer 44.
- the gas-phase refrigerant separated by the gas-liquid separator 46 passes through the first intermediate heat exchanger via the gas-phase pipe 47 and flows into the second gas-liquid separator 49.
- the liquid-phase refrigerant separated by the first gas-liquid separator 46 flows into the first intermediate heat exchanger via the liquid-phase pipe 50, the dryer 51, and the capillary tube 52 as a decompression device. It cools by evaporating the phase refrigerant.
- the liquid-phase refrigerant separated by the second gas-liquid separator 49 passes through a dryer 54 through a liquid-phase pipe 53 and then a second tube 55 as a decompression device, and then a second intermediate heat exchanger 56. Flows into.
- the gas-phase refrigerant separated by the second gas-liquid separator 54 passes through the second intermediate heat exchanger 56 via the gas-phase pipe 57, and the third and fourth intermediate heat exchangers 58,
- the liquid is cooled and liquidified while passing through 59, and flows into a capillary tube 61 as a pressure reducing device via a pipe 68 through a dryer 60.
- the capillary tube 61 is connected to an evaporation pipe 62 as an evaporator, and the evaporation pipe 62 is further connected to a fourth intermediate heat exchanger 59 via a return pipe 69.
- the fourth intermediate heat exchanger 59 is connected to the third, second and first intermediate heat exchangers 58, 56, 48 one after another. After being connected, it is connected to the suction side pipe 20S of the compressor 20. Further, an expansion tank 65 for storing refrigerant when the compressor 20 is stopped is connected to the suction side pipe 20S via a capillary tube 66 as a decompression device. The expansion tube 65 is connected to the capillary tube 66. A check valve 67 with the direction as the forward direction is connected in parallel.
- the low-temperature refrigerant circuit 38 is filled with non-azeotropic refrigerant mixtures including R245fa, R600, R404A, R508, R14, R50, and R740 as seven types of mixed refrigerants having different boiling points.
- R245fa is 1, 1, 1, —3, 3 pentafluoropropane (CF CH CHF), R
- the boiling point is -0.5 ° C. Therefore, by mixing these at a predetermined ratio, it can be used as an alternative to R21, which has a boiling point of + 8.9 ° C, which has been used in the past.
- R600 Since R600 is a flammable substance, it is sealed in the refrigerant circuit 38 as nonflammable by mixing with R245fa, which is nonflammable, at a predetermined ratio, in this example, R245faZR600: 70Z30. And In this embodiment, the force that makes R245fa 70% by weight relative to the total weight of R245fa and R600 is non-flammable, so it may be more than that.
- R404A is composed of R125 (pentafluoroethane: CHF CF) and R143a (l, 1, 1-trif
- R508 is R23 (trifluoromethane: CHF) and R116 (hexafluoroethane: CF C)
- the boiling point of the mixed refrigerant is -88.64 ° C.
- R14 is tetrafluoromethane (carbon tetrafluoride: CF), and R50 is methane (CH
- R740 is argon (Ar). These boiling points are R14 force of 127.9 ° C, R50 of -161.5 ° C, and R740 of 185.86 ° C. R50 has a danger of explosion when combined with oxygen, but mixing with R14 eliminates the danger of explosion. Therefore, even if a mixed refrigerant leakage accident occurs, no explosion should occur.
- these refrigerants as described above are: R245fa and R600, and R14 and R50 are mixed in advance to form a non-combustible soot state, then a mixed refrigerant of R245fa and R600, R404A, and R508A
- the mixed refrigerant of R14 and R50 and R740 are mixed in advance and sealed in the refrigerant circuit.
- R245fa and R600, then R404A, R5080A, R14 and R50, and finally R740 are sealed in descending order.
- the composition of each refrigerant for example, mixed refrigerant force of R245fa and R600 10.
- it may be a 4% by weight of 11 pentane (range of 0.5 to 2 weight 0/0 for the total weight of the non-azeotropic refrigerant) in ⁇ Ka ⁇ in R404A Shall.
- the high-temperature and high-pressure gaseous mixed refrigerant discharged from the compressor 20 flows into the radiator 39 via the discharge-side pipe 20D, where it is radiated and oil having a high boiling point in the mixed refrigerant and high oil compatibility.
- a part of n-pentane or R600 as carrier refrigerant is condensed.
- the mixed refrigerant that has passed through the radiator 39 flows into the oil separator 40, and most of the lubricating oil of the compressor 20 mixed with the refrigerant and the refrigerant condensed in the radiator 39 are mixed.
- Part (n-pentane, part of R600) is returned to the compressor 20 through the oil return pipe 41.
- the low-boiling point refrigerant having higher purity flows through the refrigerant circuit 38 downstream from the cascade heat exchanger 43, and it is possible to efficiently obtain an ultra-low temperature.
- even the compressors 10 and 20 having the same capacity can cool the interior of the storage chamber 4 to be cooled to a predetermined ultra-low temperature, and the overall size of the refrigeration apparatus 1 is increased. It is possible to increase the storage capacity without doing so.
- the temperature of the refrigerant entering the cascade heat exchange can be lowered. It becomes. Specifically, in the present embodiment, the refrigerant temperature flowing into the cascade heat exchanger 43 in the past can be lowered to about + 45 ° C. in this embodiment.
- the other mixed refrigerant itself is cooled by the cascade heat exchanger 43 from the evaporator 34 to about ⁇ 40 ° C. to ⁇ 30 ° C., and a part of the refrigerant having a high boiling point in the mixed refrigerant (R245fa, R600, R404A and a part of R508) are condensed. Then, the mixed refrigerant that has exited the condensation pipe 42 of the cascade heat exchange 43 flows into the first gas-liquid separator 46 through the dryer 44.
- R14, R50, and R740 in the mixed refrigerant are still not condensed because they have very low boiling points, and only a part of R245fa, R600, R404A, and R508 are condensed and liquefied.
- R14, R50, and R740 are separated into gas phase piping 47, and R245fa, R600, R404A, and R508A are separated into liquid phase piping 50.
- the refrigerant mixture flowing into the gas-phase pipe 47 is condensed by exchanging heat with the first intermediate heat exchanger 48, and then reaches the second gas-liquid separator 49.
- the low-temperature refrigerant returning from the evaporation pipe 62 flows into the first intermediate heat exchange, and the liquid refrigerant flowing into the liquid-phase pipe 50 is further depressurized by the capillary tube 52 through the dryer 51.
- a part of the uncondensed R14, R50, R740, and R508 is cooled, resulting in the first intermediate heat exchange.
- the intermediate temperature of vessel 48 is about -60 ° C.
- R508 in the mixed refrigerant that has passed through the gas-phase pipe 47 is completely condensed and liquefied, and is divided into the second gas-liquid separator 49.
- R14, R50, and R740 are still in a gas state because of their lower boiling points.
- the intermediate temperature of the second intermediate heat exchanger 56 is about -90 ° C.
- the gas phase pipe 57 passing through the second intermediate heat exchange passes through the third intermediate heat exchanger 58 and then passes through the fourth intermediate heat exchange.
- the refrigerant immediately after leaving the evaporator 62 is returned to the fourth intermediate heat exchanger.
- the fourth intermediate heat exchanger The intermediate temperature of 59 reaches a temperature as low as about 130 ° C.
- the intermediate heat exchangers 48, 56, 58, 59 condense the refrigerant still in a gas phase state one after another, In the final stage of the evaporation pipe 42, it is possible to achieve an extremely low temperature of 150 ° C or less! Therefore, the evaporation pipe 62 is configured to be heat-exchanged along the heat insulating material 9 side of the inner box 6 so that the inside temperature of the storage room 4 of the refrigeration apparatus 1 is 152 ° C. or lower. It can be realized.
- the refrigerant that has left the evaporation pipe 62 passes through the fourth intermediate heat exchanger 59, the third intermediate heat exchanger 58, the second intermediate heat exchanger 56, and the first intermediate heat exchanger 48 one after another.
- the refrigerant flows in, merges with the refrigerant evaporated in each heat exchanger, and returns to the compressor 20 from the suction pipe 20S.
- the compressor 20 constituting the low-temperature side refrigerant circuit 38 as described above is subjected to ON-OFF control by a control device (not shown) based on the internal temperature in the storage chamber 4.
- a control device not shown
- the mixed refrigerant in the low-temperature side refrigerant circuit 38 enters the expansion tank 65 via the check valve 67 whose forward direction is the expansion tank 65 direction.
- the pressure in the refrigerant circuit 38 can be quickly balanced, and the compressor 20 can be restarted.
- the compressor 20 can be restarted smoothly without applying a load to the compressor 20. This significantly improves the operating efficiency of the compressor 20 by significantly reducing the time required for the refrigerant circuit 38 to reach an equilibrium pressure when the compressor is started. For example, the time required for pull-down operation is reduced. It is possible to improve convenience.
- the evaporation pipe 62 of the low-temperature side refrigerant circuit 38 has an extremely low temperature of 166.3 ° C to 157.3 ° C, and even in the cascade heat exchanger 43- 40 ° C to -30 ° C.
- the first intermediate heat exchanger 48 is about 60 ° C
- the second intermediate heat exchanger 56 is about 90 ° C
- the third and fourth intermediate heat exchangers 58 and 59 are 130 ° C. It becomes extremely low at around ° C. Therefore, it is necessary to sufficiently insulate other heat exchangers 43 and the like other than the evaporation pipe 62 disposed in the heat insulating box 2.
- the cascade heat exchanger 43 and the first, second, third, and fourth intermediate heat exchangers have a heat insulating structure 70 that has a rectangular body surrounded by a heat insulating material.
- FIG. 7 shows a perspective view of the heat insulating structure 70
- FIG. 8 shows a perspective view of the heat insulating structure 70 with the heat insulating material removed.
- the heat insulating structure 70 that is, in addition to the heat exchangers described above, in addition to the above heat exchangers, an accumulator 35 that constitutes the high-temperature side refrigerant circuit 25, a capillary tube 33, and a dryer that constitutes the low-temperature side refrigerant circuit 38.
- the gas-liquid separators 46 and 49, the dryers 51 and 54, and the capillary tubes 52 and 55 constitute the heat insulating structure 70.
- a cascade heat exchanger 43 is provided at one end of the heat insulating structure 70, and the intermediate heat exchangers 48, 56, 5 are located on the side of the cascade heat exchanger 43. 8, 59 are arranged in layers.
- Each of the intermediate heat exchangers 48, 56, 58, and 59 superimposes a plurality of flattened outer pipes each having a relatively large diameter that are spirally wound in a plurality of stages, and the inside is spaced apart.
- Each of the gas-phase pipes 47 and 5 7 has a spiral double pipe structure through which it passes as an inner pipe.
- the lower force is also arranged in the order of lower temperature, that is, the fourth and third intermediate heat exchangers 58 and 59 are arranged in the lowermost layer, and the second intermediate heat exchanger 56 is arranged thereon, A first intermediate heat exchanger 48 is arranged in the uppermost layer.
- the gas-liquid separators 46 and 49 (the second gas-liquid separator 49 is not shown in Fig. 8) are dried inside the intermediate heat exchanger and around the cascade heat exchanger 43. 44, 51, 54 (not shown in Fig. 8), each non-illustrated cylindrical tube 33, 52, 55 and accumulator 35 are arranged to reduce dead space and reduce dimensions. Yes.
- the heat insulating structure 70 in the embodiment is configured such that the pipe connecting the device disposed in the heat insulating structure 70 and the device disposed outside the heat insulating structure 70 is the cascade.
- the heat exchanger 34 is disposed so as to face one end side surface opposite to the side on which the heat exchanger 34 is disposed.
- the discharge side pipe 10D after passing through the condenser 31 of the high temperature side refrigerant circuit 25 connected to the cascade heat exchanger 34, and the suction side pipe 10S connected to the compressor 10,
- the low-temperature side refrigerant circuit 38 connected to the heat exchanger 34 and the oil separator 40 of the low-temperature side refrigerant circuit 38
- the discharge-side pipe 20D, the suction-side pipe 20S connected to the suction side of the compressor 20 connected to the suction side of the compressor 20, the fourth intermediate heat exchanger Connection portion of each pipe of the pipe 68 connected to the evaporation pipe 62 from the gas-phase pipe 57 arranged in the 59 and the return pipe 69 connected to the fourth intermediate heat exchanger 59 from the evaporation pipe 62
- the portion is intensively disposed on one side surface of the heat insulating structure 70.
- the suction side pipes 10S, 20S and the discharge side pipe 20D through which the refrigerant having a relatively high temperature flows are converged outward, and in this embodiment, the heat insulating structure 70 is provided in the heat insulating box. In the state where it is attached to the body 2, it is arranged toward the machine room 3 side, and is connected to the evaporation pipe 62. In this embodiment, the heat insulation structure 70 is attached to the heat insulation box 2 and is directed to the heat insulation box 2 side outside the 10S and the like.
- the dryer 60 and the capillary tube 61 connected to the pipe 68 are arranged outside the heat insulating structure 70.
- FIG. 9 shows a rear perspective view of the refrigeration apparatus 1.
- a rectangular opening 71 extending in the front-rear direction and opening rearward is formed on the side wall of the heat insulating box 2 located on the machine room 3 side.
- a notch 72 is also formed in the rear side of the side wall on the machine room 3 side.
- the heat insulating structure 70 as described above is inserted into the opening 71 from the back of the heat insulating box 2.
- the heat insulating structure 70 is inserted into the opening 71 from the side where the cascade heat exchange 34 is disposed, and thereby each pipe extending to one side of the heat insulating structure 70 is disposed.
- 10S, 20S, 20D, 68, 69, piping 10D to which the capillary tube 33 of the high-temperature side refrigerant circuit 25 is connected 10D is a surface in the direction in which the heat insulating structure 70 is inserted and removed, in this embodiment, a heat insulating box. It will face the back of body 2.
- the heat insulating structure 70 is inserted into the opening 71, and in this state, the pipes 68 and 69 are connected to the heat insulating box 2 Connect piping to the evaporation pipe 62 provided on the side, and connect piping 10S, 10D, 20S, and 20D to equipment on the machine room 3 side. From this, the equipment constituting the heat insulation structure 70, the evaporation pipe 62 arranged in the heat insulation box 2, the compressors 10 and 20 arranged in the machine room 3, and the like, The rear surface force of the heat insulating box 2 can be easily connected to the piping, and the piping workability and the assembly workability can be improved. In addition, even if each device constituting the heat insulation structure 70 breaks down, the heat insulation structure 70 can be pulled out in the direction, not on the side where the heat insulation box 2 or the machine room 3 is formed. Therefore, it is possible to easily perform maintenance work.
- a back surface constituted by extending each pipe of the heat insulating structure 70 and a part of the side surface facing the machine room 3 side are closed by a cover member 73 bent in a substantially L-shaped cross section. Is done.
- a heat insulating plate (not shown) filled with glass wool or the like may be disposed in the gap formed between the heat insulating structure 70 and the side surface on the machine room 3 side.
- the cascade heat exchanger 43 and the intermediate heat exchangers 48, 56, 5 8, and 59 are in the state of the heat insulating structure 70 integrally formed of the heat insulating material in the heat insulating box. Since the heat insulation structure 70 is installed on the back surface of the heat insulation box 2 as in the conventional case, the entire depth of the refrigeration apparatus 1 is disposed on the side wall of the machine room 3 side of the body 2. Can be reduced It becomes possible.
- the presence of the overhang portion by the heat insulating structure 70 for surrounding the cascade heat exchanger 43 and the like can avoid the disadvantage that the overall depth dimension of the apparatus 1 becomes large.
- the overall depth dimension of the apparatus 1 becomes large.
- a refrigeration system with an internal temperature of 150 ° C or less for example, it is possible to keep the overall depth dimension to about 765 mm while securing a depth dimension of about 495 mm. Therefore, it is possible to avoid the inconvenience of changing to a normal carry-in entrance (generally about 800 mm).
- the heat insulation structure 70 can be delivered to and out of a general loading robot while attached to the apparatus 1, it is necessary to separate and connect the heat insulation structure 70 from the main body at the installation location. It becomes possible to avoid complicated work.
- the heat insulating box 2 is not provided with a cascade heat exchanger or a heat insulating structure for surrounding each intermediate heat exchanger on the back surface of the heat insulating box 2 as in the prior art, as described above, It is possible to dispose the vacuum heat insulation panel 12 in the front wall 6A rear wall 6B and the side wall 6C opposite to the machine room of the heat insulation box 2 configured to face the inside of the storage room 4. — It is possible to improve the heat insulation performance of the heat insulation box 2 itself even at an extremely low temperature of 150 ° C or less. Therefore, the size can be reduced, and the storage volume in the storage chamber 4 can be increased even with the same external dimensions as the conventional one. Alternatively, even with the same storage volume as in the conventional case, the outer dimensions can be reduced, and this also makes it possible to reduce the area required for installing the refrigeration apparatus 1.
- the heat insulation structure 70 can be inserted into and removed from the rear side of the refrigeration apparatus 1, that is, from the back, into the side wall of the heat insulation box 2.
- the heat insulation structure 70 is not limited to this, for example, heat insulation. It may be possible to insert / remove an upper force from the front of the box 2.
- the cascade heat exchanger 43 and the intermediate heat exchangers 48 integrated as the heat insulating structure 70 can be easily incorporated into the main body of the apparatus 1 as in this embodiment, and the assembly workability is improved. Improve be able to.
- the heat insulation structure 70 is a force that integrally constitutes the cascade heat exchange and each intermediate heat exchange that constitute the refrigeration apparatus 1, in addition to this, the cascade heat Only the exchanger 43 or only the intermediate heat exchangers 48, etc. may be integrally configured as the heat insulating structure 70, and may be detachably disposed on the side wall of the heat insulating box 2 as in this embodiment. And
- the refrigerant circuit constituting the refrigeration apparatus 1 condenses the refrigerant discharged from the compressor 10 or 20, respectively, and then evaporates to evaporate to provide an independent refrigerant closed circuit that exhibits a cooling action.
- the low-temperature side refrigerant circuit 38 is composed of the compressor 20, the condensing pipe 42, the evaporation pipe 62, and the return refrigerant from the evaporation pipe 62.
- the lowest boiling point refrigerant flows into the evaporation pipe 62 through the final stage capillary tube 61, and cascade heat exchange is performed between the evaporator 34 of the high temperature side refrigerant circuit 25 and the condensation noise 42 of the low temperature side refrigerant circuit 38.
- the force described as the two-stage multi-stage refrigeration apparatus 1 that constitutes 43 and obtains an ultra-low temperature with the evaporation pipe 42 of the low-temperature side refrigerant circuit 38 is not limited to this.
- a high-temperature side refrigerant circuit and a low-temperature side refrigerant circuit constituting an independent refrigerant closed circuit that exhibits a cooling action by condensing and evaporating the refrigerant discharged from the compressor, respectively
- This is a simple multiple (two-way) type refrigeration system that forms a cascade heat exchanger with the evaporator of the high-temperature side refrigerant circuit and the condenser of the low-temperature side refrigerant circuit, and obtains ultra-low temperature with the evaporator of the low-temperature side refrigerant circuit.
- the cascade heat exchanger 43 is insulated as in this embodiment. The same effect can be obtained by constituting the structure 70 and inserting and removing the heat insulating structure 70 on the side surface of the heat insulating box 2 on the machine room 3 side.
- the apparatus includes a compressor, a condenser, an evaporator, a plurality of intermediate heat exchangers connected in series so that a return refrigerant from the evaporator flows, and a plurality of decompression devices.
- each intermediate heat exchanger is installed by configuring the heat insulating structure 70 as in the embodiment and making the heat insulating structure 70 detachable from the side surface of the heat insulating box 2 on the machine room 3 side, the same effect can be obtained.
- FIG. 1 is a perspective view of a refrigeration apparatus to which the present invention is applied.
- FIG. 2 is a front view of the refrigeration apparatus of FIG.
- FIG. 3 is a plan view of the refrigeration apparatus of FIG.
- FIG. 4 is a side view of the refrigeration apparatus shown in FIG.
- FIG. 5 is a perspective view of the refrigeration apparatus with the top panel opened.
- FIG. 6 is a refrigerant circuit diagram of the refrigeration apparatus of FIG.
- FIG. 7 is a perspective view of a heat insulating structure.
- FIG. 8 is a perspective view of the heat insulation structure with the heat insulating material removed.
- FIG. 9 is a rear perspective view of the refrigeration apparatus showing a state in which the heat insulating structure is attached.
- FIG. 10 is a perspective view of a conventional refrigeration apparatus.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Devices That Are Associated With Refrigeration Equipment (AREA)
- Refrigerator Housings (AREA)
Abstract
Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07743278.9A EP2019276B1 (en) | 2006-05-15 | 2007-05-14 | A freezing apparatus |
| US12/300,707 US20090249823A1 (en) | 2006-05-15 | 2007-05-14 | Refrigeration apparatus |
| CN2007800176401A CN101443613B (zh) | 2006-05-15 | 2007-05-14 | 冷冻装置 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006135252A JP2007303791A (ja) | 2006-05-15 | 2006-05-15 | 冷凍装置 |
| JP2006-135252 | 2006-05-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2007132802A1 true WO2007132802A1 (ja) | 2007-11-22 |
Family
ID=38693893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2007/059843 Ceased WO2007132802A1 (ja) | 2006-05-15 | 2007-05-14 | 冷凍装置 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20090249823A1 (ja) |
| EP (1) | EP2019276B1 (ja) |
| JP (1) | JP2007303791A (ja) |
| KR (1) | KR20090008343A (ja) |
| CN (1) | CN101443613B (ja) |
| WO (1) | WO2007132802A1 (ja) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8011201B2 (en) * | 2009-09-30 | 2011-09-06 | Thermo Fisher Scientific (Asheville) Llc | Refrigeration system mounted within a deck |
| KR101155228B1 (ko) * | 2009-11-23 | 2012-06-13 | 엘지전자 주식회사 | 공랭식 냉각장치 |
| JP5906225B2 (ja) * | 2013-09-30 | 2016-04-20 | エスペック株式会社 | 環境試験装置 |
| KR102168586B1 (ko) | 2013-11-29 | 2020-10-22 | 삼성전자주식회사 | 냉장고 |
| WO2017033680A1 (ja) * | 2015-08-26 | 2017-03-02 | パナソニックヘルスケアホールディングス株式会社 | 超低温フリーザ |
| US10126039B2 (en) | 2015-12-29 | 2018-11-13 | Whirlpool Corporation | Refrigeration appliance having side air intake vent with sound dampening |
| EP3428559B1 (en) * | 2016-03-11 | 2019-12-25 | PHC Holdings Corporation | Ultra low-temperature freezer |
| AU2017271680A1 (en) * | 2016-05-26 | 2019-01-24 | Mohammad Ali Ahmad | Self-ice making/self heating hybrid food and beverage storage chest |
| KR102588870B1 (ko) * | 2016-06-24 | 2023-10-13 | 엘지전자 주식회사 | 초저온 냉장고 |
| JP6994419B2 (ja) * | 2018-03-29 | 2022-01-14 | 東京エレクトロン株式会社 | 冷却システム |
| JP7311483B2 (ja) * | 2019-03-04 | 2023-07-19 | 東芝ライフスタイル株式会社 | 冷蔵庫 |
| CN110305631A (zh) * | 2019-07-03 | 2019-10-08 | 上海沛芾航天科技发展有限公司 | 一种用于环境试验箱的混合工质制冷剂 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US3257820A (en) * | 1964-09-16 | 1966-06-28 | Charles B Case | Cold storage container |
| JPS6273046A (ja) | 1985-09-25 | 1987-04-03 | 三洋電機株式会社 | 冷凍装置 |
| JP2001056284A (ja) * | 1999-08-20 | 2001-02-27 | Fukushima Industries Corp | 測定孔キャップ |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE955148C (de) * | 1953-08-18 | 1956-12-27 | F & R Fischer K G | Tragbarer, elektrischer Kuehlbehaelter |
| US3055972A (en) * | 1958-07-03 | 1962-09-25 | Robert E Peterson | Fluid leakage seal for electric cables |
| US3410109A (en) * | 1967-01-09 | 1968-11-12 | Howard R. Maryland | Iceless freezer chest |
| JPS5211749Y2 (ja) * | 1973-07-27 | 1977-03-15 | ||
| DE7425284U (de) * | 1974-07-25 | 1976-07-29 | Elektrotechnik Ehmann Gmbh, 7101 Hoechstberg | Nachtraeglich an- oder einsetzbarer kaeltekreislauf |
| JPS5417549Y2 (ja) * | 1974-11-15 | 1979-07-06 | ||
| JPS573973U (ja) * | 1980-06-09 | 1982-01-09 | ||
| GB2180921B (en) * | 1985-09-25 | 1990-01-24 | Sanyo Electric Co | Refrigeration system |
| US5046328A (en) * | 1990-03-01 | 1991-09-10 | Hoshizaki Electric Co., Ltd. | Refrigeration apparatus with article preserving and displaying chamber |
| JPH06213558A (ja) * | 1993-01-19 | 1994-08-02 | Hitachi Ltd | 冷蔵庫 |
| JPH10300330A (ja) * | 1997-04-25 | 1998-11-13 | Sanyo Electric Co Ltd | 低温貯蔵庫 |
| US6628520B2 (en) * | 2002-02-06 | 2003-09-30 | Hewlett-Packard Development Company, L.P. | Method, apparatus, and system for cooling electronic components |
| JP3733079B2 (ja) * | 2002-03-29 | 2006-01-11 | 三洋電機株式会社 | 低温貯蔵庫 |
| US20040101031A1 (en) * | 2002-11-25 | 2004-05-27 | Ford Global Technologies, Inc. | Temperature sensor with improved response time |
-
2006
- 2006-05-15 JP JP2006135252A patent/JP2007303791A/ja active Pending
-
2007
- 2007-05-14 EP EP07743278.9A patent/EP2019276B1/en active Active
- 2007-05-14 KR KR1020087027848A patent/KR20090008343A/ko not_active Ceased
- 2007-05-14 WO PCT/JP2007/059843 patent/WO2007132802A1/ja not_active Ceased
- 2007-05-14 CN CN2007800176401A patent/CN101443613B/zh active Active
- 2007-05-14 US US12/300,707 patent/US20090249823A1/en not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3257820A (en) * | 1964-09-16 | 1966-06-28 | Charles B Case | Cold storage container |
| JPS6273046A (ja) | 1985-09-25 | 1987-04-03 | 三洋電機株式会社 | 冷凍装置 |
| JP2001056284A (ja) * | 1999-08-20 | 2001-02-27 | Fukushima Industries Corp | 測定孔キャップ |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101443613B (zh) | 2011-09-14 |
| KR20090008343A (ko) | 2009-01-21 |
| JP2007303791A (ja) | 2007-11-22 |
| EP2019276A1 (en) | 2009-01-28 |
| EP2019276A4 (en) | 2013-12-25 |
| EP2019276B1 (en) | 2020-01-08 |
| CN101443613A (zh) | 2009-05-27 |
| US20090249823A1 (en) | 2009-10-08 |
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