WO2008017781A3 - Procédé de purification d'hydrogène - Google Patents

Procédé de purification d'hydrogène Download PDF

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Publication number
WO2008017781A3
WO2008017781A3 PCT/FR2007/051775 FR2007051775W WO2008017781A3 WO 2008017781 A3 WO2008017781 A3 WO 2008017781A3 FR 2007051775 W FR2007051775 W FR 2007051775W WO 2008017781 A3 WO2008017781 A3 WO 2008017781A3
Authority
WO
WIPO (PCT)
Prior art keywords
regeneration
hydrogen
recycled
adsorption
compression
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2007/051775
Other languages
English (en)
Other versions
WO2008017781A2 (fr
Inventor
Souza Guillaume De
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to EP07823684A priority Critical patent/EP2051934A2/fr
Priority to JP2009523323A priority patent/JP2010500272A/ja
Priority to US12/376,462 priority patent/US20100322845A1/en
Priority to CA002660545A priority patent/CA2660545A1/fr
Publication of WO2008017781A2 publication Critical patent/WO2008017781A2/fr
Publication of WO2008017781A3 publication Critical patent/WO2008017781A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40001—Methods relating to additional, e.g. intermediate, treatment of process gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40028—Depressurization
    • B01D2259/4003—Depressurization with two sub-steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40077—Direction of flow
    • B01D2259/40079—Co-current
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40077—Direction of flow
    • B01D2259/40081—Counter-current
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

Procédé de purification d'hydrogène gazeux à partir d'un mélange gazeux, ledit procédé comprenant (c) une étape de purification d'hydrogène à partir du perméat gazeux enrichi en hydrogène comprimé, par un procédé d'adsorption par modulation de pression (PSA) dans lequel on utilise un ou plusieurs adsorbeurs qui suivent chacun en décalage un cycle où se succèdent une phase d'adsorption à la haute pression du cycle, essentiellement égale à P3, et une phase de régénération, produisant deux flux de régénération : un premier flux de régénération recyclé et un second flux de régénération non recyclé, caractérisé par le fait que le flux de régénération recyclé sortant du ou des adsorbeurs en phase de régénération est renvoyé, directement ou indirectement, vers le compresseur C de l'étape (b), sans compression intermédiaire de sorte qu'un seul compresseur C assure à la fois la compression du perméat enrichi en hydrogène de l'étape (a) et la compression du gaz de régénération recyclé sortant de l'étape (c) du purification d'hydrogène par adsorption par modulation de pression (PSA).
PCT/FR2007/051775 2006-08-09 2007-08-03 Procédé de purification d'hydrogène Ceased WO2008017781A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP07823684A EP2051934A2 (fr) 2006-08-09 2007-08-03 Procédé de purification d'hydrogène
JP2009523323A JP2010500272A (ja) 2006-08-09 2007-08-03 水素精製方法
US12/376,462 US20100322845A1 (en) 2006-08-09 2007-08-03 Method of Hydrogen Purification
CA002660545A CA2660545A1 (fr) 2006-08-09 2007-08-03 Procede de purification d'hydrogene

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0653329A FR2904821B1 (fr) 2006-08-09 2006-08-09 Procede de purification d'hydrogene
FR0653329 2006-08-09

Publications (2)

Publication Number Publication Date
WO2008017781A2 WO2008017781A2 (fr) 2008-02-14
WO2008017781A3 true WO2008017781A3 (fr) 2008-03-27

Family

ID=37875802

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2007/051775 Ceased WO2008017781A2 (fr) 2006-08-09 2007-08-03 Procédé de purification d'hydrogène

Country Status (7)

Country Link
US (1) US20100322845A1 (fr)
EP (1) EP2051934A2 (fr)
JP (1) JP2010500272A (fr)
KR (1) KR20090051168A (fr)
CA (1) CA2660545A1 (fr)
FR (1) FR2904821B1 (fr)
WO (1) WO2008017781A2 (fr)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2172449A3 (fr) 2005-04-06 2011-06-22 Sicor, Inc. Procédé pour la purification de l' Anastrazole
AU2011209745B2 (en) 2010-01-29 2015-05-07 Exxonmobil Research And Engineering Company Hydrogen utilization within a refinery network
US10435800B2 (en) 2012-05-28 2019-10-08 Hydrogenics Corporation Electrolyser and energy system
EP2877426A1 (fr) * 2012-07-24 2015-06-03 Nuvera Fuel Cells, Inc. Système d'extraction d'hydrogène distribué
RU2509595C1 (ru) * 2012-09-04 2014-03-20 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" Способ мембранно-адсорбционного концентрирования водорода из обедненных газовых смесей (варианты)
RU2696154C1 (ru) * 2016-03-10 2019-07-31 ДжГК Корпорейшн Новое технологическое оборудование и способ получения природного газа и водорода
CN107314242A (zh) * 2017-08-29 2017-11-03 赫普科技发展（北京）有限公司 一种氢气天然气的掺混运输和分离装置
EP3894048A1 (fr) * 2018-12-10 2021-10-20 Hydrogen Onsite, S.L. Procédé de séparation à faible teneur en hydrogène à partir d'un mélange de gaz naturel
DE102020211162A1 (de) 2020-09-04 2022-03-10 Volkswagen Aktiengesellschaft Ladesäule zum Laden eines Stromspeichers eines Elektrofahrzeugs
ES2964552T3 (es) 2020-11-11 2024-04-08 Air Liquide Procedimiento para el transporte de hidrógeno
JP7470858B2 (ja) * 2021-02-18 2024-04-18 株式会社日立製作所 水素利用管理装置、水素需給管理装置、水素需給管理運用システムおよび水素需給管理方法
EP4332426B1 (fr) * 2021-04-28 2026-05-20 Hitachi Ltd Système et procédé d'alimentation et de demande en hydrogène
WO2022230124A1 (fr) * 2021-04-28 2022-11-03 株式会社日立製作所 Procédé et dispositif de gestion de l'alimentation et de la demande en hydrogène
WO2022230121A1 (fr) * 2021-04-28 2022-11-03 株式会社日立製作所 Système d'alimentation en hydrogène
WO2022230120A1 (fr) * 2021-04-28 2022-11-03 株式会社日立製作所 Système d'alimentation en hydrogène
CN114561235B (zh) * 2022-01-11 2022-12-13 广东省氢一能源科技有限公司 一种基于压力能回收的氢气天然气混输与分离装置及方法
KR102665071B1 (ko) * 2022-07-22 2024-05-16 (주)원익머트리얼즈 고순도 황화카르보닐(cos)의 제조반응 시스템
JP2024021213A (ja) * 2022-08-03 2024-02-16 株式会社日立製作所 水素需給管理装置及び水素需給統括装置
JP2024021212A (ja) * 2022-08-03 2024-02-16 株式会社日立製作所 ガス分離装置
US12551844B2 (en) 2022-11-09 2026-02-17 Air Products And Chemicals, Inc. Hydrogen separation from natural gas
EP4445988A1 (fr) * 2023-04-11 2024-10-16 Axiom Angewandte Prozeßtechnik Ges. m.b.H. Procédé de dosage d'un gaz secondaire

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4690695A (en) * 1986-04-10 1987-09-01 Union Carbide Corporation Enhanced gas separation process
US5447559A (en) * 1989-11-14 1995-09-05 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
EP0945163A1 (fr) * 1997-10-09 1999-09-29 Gkss-Forschungszentrum Geesthacht Gmbh Un procédé de séparation/récupération des gazes
US5979178A (en) * 1997-12-16 1999-11-09 Air Liquide America Corporation Process for recovering olefins from cracked gases

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4863492A (en) * 1988-11-28 1989-09-05 Uop Integrated membrane/PSA process and system
US5006132A (en) * 1990-06-12 1991-04-09 Air Products And Chemicals, Inc. Membrane processed purified pipeline gas
US5632803A (en) * 1994-10-21 1997-05-27 Nitrotec Corporation Enhanced helium recovery
US5753010A (en) * 1996-10-28 1998-05-19 Air Products And Chemicals, Inc. Hydrogen recovery by pressure swing adsorption integrated with adsorbent membranes
US6179900B1 (en) * 1997-10-09 2001-01-30 Gkss Forschungszentrum Geesthacht Gmbh Process for the separation/recovery of gases

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4690695A (en) * 1986-04-10 1987-09-01 Union Carbide Corporation Enhanced gas separation process
US5447559A (en) * 1989-11-14 1995-09-05 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
EP0945163A1 (fr) * 1997-10-09 1999-09-29 Gkss-Forschungszentrum Geesthacht Gmbh Un procédé de séparation/récupération des gazes
US5979178A (en) * 1997-12-16 1999-11-09 Air Liquide America Corporation Process for recovering olefins from cracked gases

Also Published As

Publication number Publication date
JP2010500272A (ja) 2010-01-07
EP2051934A2 (fr) 2009-04-29
FR2904821B1 (fr) 2009-02-20
WO2008017781A2 (fr) 2008-02-14
KR20090051168A (ko) 2009-05-21
FR2904821A1 (fr) 2008-02-15
US20100322845A1 (en) 2010-12-23
CA2660545A1 (fr) 2008-02-14

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