WO2008105212A1 - 海水排煙脱硫システム - Google Patents

海水排煙脱硫システム Download PDF

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Publication number
WO2008105212A1
WO2008105212A1 PCT/JP2008/051341 JP2008051341W WO2008105212A1 WO 2008105212 A1 WO2008105212 A1 WO 2008105212A1 JP 2008051341 W JP2008051341 W JP 2008051341W WO 2008105212 A1 WO2008105212 A1 WO 2008105212A1
Authority
WO
WIPO (PCT)
Prior art keywords
wastewater
seawater
flue
gas desulfurization
acid compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/051341
Other languages
English (en)
French (fr)
Inventor
Tomoo Akiyama
Naoyuki Kamiyama
Shintaro Honjo
Susumu Okino
Yoshio Nakayama
Motofumi Ito
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to CN200880001077.3A priority Critical patent/CN101557868B/zh
Publication of WO2008105212A1 publication Critical patent/WO2008105212A1/ja
Priority to NO20091780A priority patent/NO20091780L/no
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/74—Treatment of water, waste water, or sewage by oxidation with air
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/504—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific device
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/10—Oxidants
    • B01D2251/102—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08—Seawater, e.g. for desalination
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/06—Controlling or monitoring parameters in water treatment pH

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

 海水排煙脱硫装置から排出される排水中の亜硫酸類濃度の極端な低下や、酸化処理による排水のpHの低下を防いで、排水の酸化処理を高効率で短時間に行うことができる海水排煙脱硫システムを提供する。海水排煙脱硫システムは、吸収液として海水を用いる脱硫吸収塔17と、この脱硫吸収塔から排出される排水に含まれる亜硫酸類を酸化する排水酸化槽20とを備えており、この排水酸化槽20では、亜硫酸類を含有する排水に、空気吹込みノズル33から少なくとも2段階に分けて空気を導入して、排水中の亜硫酸類を酸化するとともに、この段階的な酸化の進行に合わせて、海水投入口26から少なくとも2段階に分けて海水を排水に投入し、排水を希釈する。
PCT/JP2008/051341 2007-02-28 2008-01-30 海水排煙脱硫システム Ceased WO2008105212A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN200880001077.3A CN101557868B (zh) 2007-02-28 2008-01-30 海水排烟脱硫系统
NO20091780A NO20091780L (no) 2007-02-28 2009-05-06 Sjovannavgassavsvovlingssystem

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007048657A JP5259964B2 (ja) 2007-02-28 2007-02-28 海水排煙脱硫システム
JP2007-048657 2007-02-28

Publications (1)

Publication Number Publication Date
WO2008105212A1 true WO2008105212A1 (ja) 2008-09-04

Family

ID=39721050

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/051341 Ceased WO2008105212A1 (ja) 2007-02-28 2008-01-30 海水排煙脱硫システム

Country Status (5)

Country Link
JP (1) JP5259964B2 (ja)
CN (1) CN101557868B (ja)
MY (1) MY157783A (ja)
NO (1) NO20091780L (ja)
WO (1) WO2008105212A1 (ja)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102557194A (zh) * 2011-12-31 2012-07-11 国家海洋局天津海水淡化与综合利用研究所 膜法曝气工业烟气脱硫海水恢复工艺
EP2578544A1 (en) 2011-10-07 2013-04-10 Alstom Technology Ltd Method and system for controlling treatment of effluent from seawater flue gas scrubber
EP2703063A1 (en) 2012-09-04 2014-03-05 Alstom Technology Ltd Desulphurization and cooling of process gas
WO2014098120A1 (ja) * 2012-12-19 2014-06-26 富士電機株式会社 排ガス浄化装置
EP2851344A1 (en) 2013-09-18 2015-03-25 Alstom Technology Ltd Method and system for seawater foam control
EP2942096A1 (en) 2014-05-08 2015-11-11 Alstom Technology Ltd Antifoam device and method of use for seawater foam control
WO2016055450A1 (de) 2014-10-09 2016-04-14 Steinmüller Babcock Environment Gmbh Oxidationsbecken und verfahren zum behandeln von ablaufwasser eines meerwasser-abgaswäschers
WO2016160682A1 (en) 2015-03-31 2016-10-06 Alstom Technology Ltd Foam intercept system
EP3132839A1 (en) 2015-08-20 2017-02-22 General Electric Technology GmbH Seawater flue gas desulfurization absorber system
EP3144281A1 (en) 2015-09-17 2017-03-22 General Electric Technology GmbH Integrated air distributor arrangement for effluent seawater treatment basin
US9630864B2 (en) 2015-06-17 2017-04-25 General Electric Technology Gmbh Seawater plant with inclined aeration and mixed auto recovery
CN116585852A (zh) * 2023-04-24 2023-08-15 中国华电科工集团有限公司 一种确定海水脱硫喷淋层投断策略的方法及系统

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010043083A1 (zh) * 2008-10-17 2010-04-22 Peng Sigan 烟气海水法同时脱硫脱硝方法及装置
WO2010095214A1 (ja) * 2009-02-17 2010-08-26 月島機械株式会社 廃水処理システム及び廃水処理方法
MY169823A (en) * 2009-04-06 2019-05-16 Mitsubishi Hitachi Power Sys Ltd Seawater desulfurization/oxidation treatment apparatus, method of treating desulfurization seawater, and power generating system employing the same
JP2010240624A (ja) * 2009-04-09 2010-10-28 Mitsubishi Heavy Ind Ltd 排煙脱硫装置及び排ガス処理方法
KR101269707B1 (ko) * 2009-05-11 2013-05-30 미츠비시 쥬고교 가부시키가이샤 해수 배연 탈황 장치 및 탈황 해수의 처리 방법
FI124473B (fi) 2009-12-15 2014-09-15 Wärtsilä Finland Oy Pesuriyksikköjärjestely ja menetelmä pakokaasun puhdistamiseksi pesuriyksikköjärjestelyssä
JP5535824B2 (ja) * 2010-08-18 2014-07-02 三菱重工業株式会社 エアレーション装置及びこれを備えた海水排煙脱硫装置
DE102010035875B9 (de) * 2010-08-30 2013-01-31 Babcock Borsig Steinmüller Gmbh System und Verfahren zur Entsalzung von Meerwasser
EP2486969B1 (en) * 2011-02-10 2016-06-15 Alstom Technology Ltd A method and a device for treating effluent seawater from a seawater scrubber
JP5773687B2 (ja) * 2011-02-28 2015-09-02 三菱日立パワーシステムズ株式会社 海水排煙脱硫システムおよび発電システム
JP2014520989A (ja) * 2011-07-01 2014-08-25 シーガン ペン, 内燃機関ガス排出背圧を最適化する方法、装置及びシステム
JP2013154330A (ja) * 2012-01-31 2013-08-15 Mitsubishi Heavy Ind Ltd 酸化槽、海水排煙脱硫システムおよび発電システム
JP2013154329A (ja) * 2012-01-31 2013-08-15 Mitsubishi Heavy Ind Ltd 海水排煙脱硫システムおよび発電システム
JP2013158720A (ja) * 2012-02-06 2013-08-19 Mitsubishi Heavy Ind Ltd 脱硫海水処理システム
JP2013208605A (ja) * 2012-03-30 2013-10-10 Mitsubishi Heavy Ind Ltd 海水脱硫酸化処理装置及び海水排煙脱硫システム
EP3189883B1 (en) * 2014-09-02 2019-09-04 Fuji Electric Co., Ltd. Exhaust gas treatment device and waste water treatment method for exhaust gas treatment device
KR101927076B1 (ko) * 2017-03-02 2018-12-10 (주)오씨아드 화력발전소 폐가스 정화장치

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59213495A (ja) * 1983-05-20 1984-12-03 Kurita Water Ind Ltd 水の処理方法
JPH09248578A (ja) * 1996-03-15 1997-09-22 Kurita Water Ind Ltd 第一鉄イオン含有水の処理装置
JPH1157396A (ja) * 1997-08-25 1999-03-02 Ebara Corp 排ガス脱硫方法及びその装置
JP2001129352A (ja) * 1999-11-02 2001-05-15 Fujikasui Engineering Co Ltd 海水による排ガス脱硫高度処理プロセス
JP2002210326A (ja) * 2000-11-17 2002-07-30 Mitsubishi Heavy Ind Ltd 湿式排煙脱硫装置、及び、湿式排煙脱硫方法
JP2004089770A (ja) * 2002-08-29 2004-03-25 Masanori Tashiro 排ガス浄化方法及びその装置
WO2006018911A1 (ja) * 2004-08-20 2006-02-23 Mitsubishi Heavy Industries, Ltd. 海水処理方法および海水処理装置
JP2006095478A (ja) * 2004-09-30 2006-04-13 Nippon Steel Corp 硫黄化合物を含む廃水の処理方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE29517697U1 (de) * 1995-07-29 1996-01-18 Gottfried Bischoff GmbH & Co. KG, 45136 Essen Rauchgasentschwefelungsanlage
CN1199712C (zh) * 2000-11-23 2005-05-04 彭斯干 动液式海水法烟气脱硫方法及设备
CN2467167Y (zh) * 2000-12-29 2001-12-26 清华大学 海水液柱喷射式烟气脱硫装置

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59213495A (ja) * 1983-05-20 1984-12-03 Kurita Water Ind Ltd 水の処理方法
JPH09248578A (ja) * 1996-03-15 1997-09-22 Kurita Water Ind Ltd 第一鉄イオン含有水の処理装置
JPH1157396A (ja) * 1997-08-25 1999-03-02 Ebara Corp 排ガス脱硫方法及びその装置
JP2001129352A (ja) * 1999-11-02 2001-05-15 Fujikasui Engineering Co Ltd 海水による排ガス脱硫高度処理プロセス
JP2002210326A (ja) * 2000-11-17 2002-07-30 Mitsubishi Heavy Ind Ltd 湿式排煙脱硫装置、及び、湿式排煙脱硫方法
JP2004089770A (ja) * 2002-08-29 2004-03-25 Masanori Tashiro 排ガス浄化方法及びその装置
WO2006018911A1 (ja) * 2004-08-20 2006-02-23 Mitsubishi Heavy Industries, Ltd. 海水処理方法および海水処理装置
JP2006095478A (ja) * 2004-09-30 2006-04-13 Nippon Steel Corp 硫黄化合物を含む廃水の処理方法

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2578544A1 (en) 2011-10-07 2013-04-10 Alstom Technology Ltd Method and system for controlling treatment of effluent from seawater flue gas scrubber
WO2013050988A1 (en) 2011-10-07 2013-04-11 Alstom Technology Ltd Method and system for controlling treatment of effluent from seawater flue gas scrubber
CN102557194A (zh) * 2011-12-31 2012-07-11 国家海洋局天津海水淡化与综合利用研究所 膜法曝气工业烟气脱硫海水恢复工艺
EP2703063A1 (en) 2012-09-04 2014-03-05 Alstom Technology Ltd Desulphurization and cooling of process gas
US10363523B2 (en) 2012-12-19 2019-07-30 Fuji Electric Co., Ltd. Exhaust gas purifying apparatus
WO2014098120A1 (ja) * 2012-12-19 2014-06-26 富士電機株式会社 排ガス浄化装置
EP2851344A1 (en) 2013-09-18 2015-03-25 Alstom Technology Ltd Method and system for seawater foam control
EP2942096A1 (en) 2014-05-08 2015-11-11 Alstom Technology Ltd Antifoam device and method of use for seawater foam control
JP2015213904A (ja) * 2014-05-08 2015-12-03 アルストム テクノロジー リミテッドALSTOM Technology Ltd 消泡装置および海水泡制御のための使用方法
WO2016055450A1 (de) 2014-10-09 2016-04-14 Steinmüller Babcock Environment Gmbh Oxidationsbecken und verfahren zum behandeln von ablaufwasser eines meerwasser-abgaswäschers
DE102014015036A1 (de) 2014-10-09 2016-04-28 Steinmüller Babcock Environment Gmbh Oxidationsbecken und Verfahren zum Behandeln von Ablaufwasser eines Meerwasser-Abgaswäschers
WO2016160682A1 (en) 2015-03-31 2016-10-06 Alstom Technology Ltd Foam intercept system
US9771279B2 (en) 2015-03-31 2017-09-26 General Electric Technology Gmbh Foam intercept system
US9630864B2 (en) 2015-06-17 2017-04-25 General Electric Technology Gmbh Seawater plant with inclined aeration and mixed auto recovery
EP3132839A1 (en) 2015-08-20 2017-02-22 General Electric Technology GmbH Seawater flue gas desulfurization absorber system
EP3144281A1 (en) 2015-09-17 2017-03-22 General Electric Technology GmbH Integrated air distributor arrangement for effluent seawater treatment basin
CN116585852A (zh) * 2023-04-24 2023-08-15 中国华电科工集团有限公司 一种确定海水脱硫喷淋层投断策略的方法及系统

Also Published As

Publication number Publication date
JP2008207149A (ja) 2008-09-11
CN101557868A (zh) 2009-10-14
MY157783A (en) 2016-07-29
NO20091780L (no) 2009-05-06
CN101557868B (zh) 2013-04-10
JP5259964B2 (ja) 2013-08-07

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