WO2008108398A1 - Procédé de fabrication d'un composé organique oxygéné par oxydation d'un hydrocarbure et catalyseur d'oxydation destiné à être utilisé dans ce procédé - Google Patents

Procédé de fabrication d'un composé organique oxygéné par oxydation d'un hydrocarbure et catalyseur d'oxydation destiné à être utilisé dans ce procédé Download PDF

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Publication number
WO2008108398A1
WO2008108398A1 PCT/JP2008/053934 JP2008053934W WO2008108398A1 WO 2008108398 A1 WO2008108398 A1 WO 2008108398A1 JP 2008053934 W JP2008053934 W JP 2008053934W WO 2008108398 A1 WO2008108398 A1 WO 2008108398A1
Authority
WO
WIPO (PCT)
Prior art keywords
organic compound
oxidation
hydrocarbon
producing
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/053934
Other languages
English (en)
Japanese (ja)
Inventor
Shigeo Ooyama
Xiaoming Zhang
Jiqing Lu
Juan Jose Bravo Suarez
Kyoko Bando
Zhaoxia Song
Susumu Tsubota
Tadahiro Fujitani
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
National Institute of Advanced Industrial Science and Technology AIST
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Institute of Advanced Industrial Science and Technology AIST filed Critical National Institute of Advanced Industrial Science and Technology AIST
Priority to JP2009502604A priority Critical patent/JP5017619B2/ja
Publication of WO2008108398A1 publication Critical patent/WO2008108398A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/618—Surface area more than 1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)

Abstract

L'invention porte sur un procédé de fabrication d'un composé organique oxygéné dans lequel non seulement une stabilité de catalyseur élevée mais encore une conversion élevée de la matière de départ peuvent être obtenues. Le procédé comprend l'oxydation d'un hydrocarbure par un fluide réactif comprenant une source d'oxygène et un agent réducteur pour produire un composé organique oxygéné, utilisation étant faite d'un catalyseur comprenant : un support qui est constitué d'une matière de paroi ayant une structure mésoporeuse et contenant des cristaux d'ensemencement de titanosilicate ayant une structure microporeuse, c'est-à-dire un support hybride dit micro/méso; et de fines particules d'or déposées sur le support. Le procédé permet de parvenir à la fois à une amélioration de la conversion de la matière de départ et à une amélioration de la durée de vie du catalyseur.
PCT/JP2008/053934 2007-03-05 2008-03-05 Procédé de fabrication d'un composé organique oxygéné par oxydation d'un hydrocarbure et catalyseur d'oxydation destiné à être utilisé dans ce procédé Ceased WO2008108398A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009502604A JP5017619B2 (ja) 2007-03-05 2008-03-05 炭化水素の酸化による含酸素有機化合物の製造方法及びそれに用いる酸化用触媒

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-054711 2007-03-05
JP2007054711 2007-03-05

Publications (1)

Publication Number Publication Date
WO2008108398A1 true WO2008108398A1 (fr) 2008-09-12

Family

ID=39738271

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/053934 Ceased WO2008108398A1 (fr) 2007-03-05 2008-03-05 Procédé de fabrication d'un composé organique oxygéné par oxydation d'un hydrocarbure et catalyseur d'oxydation destiné à être utilisé dans ce procédé

Country Status (2)

Country Link
JP (1) JP5017619B2 (fr)
WO (1) WO2008108398A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008230876A (ja) * 2007-03-19 2008-10-02 Toyota Central R&D Labs Inc メソ孔及びマイクロ孔を有する金属酸化物多孔体の製造方法、メソ孔及びマイクロ孔を有する金属酸化物多孔体及びそれを用いたガス浄化材料
JP2010536819A (ja) * 2007-08-20 2010-12-02 チュールム ベタイリグングスゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー パテンテ ツヴァイ コマンディートゲゼルシャフト 均質な気相中でオレフィンの酸化によりエポキシドを効率的に製造する方法
WO2011051643A1 (fr) * 2009-10-29 2011-05-05 Dow Global Technologies Inc. Oxydation catalytique sélective d'alcanes en c1-c3
CN116284724A (zh) * 2019-11-21 2023-06-23 联泓(江苏)新材料研究院有限公司 不饱和酸聚氧烯烃酯类化合物的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1176820A (ja) * 1997-09-05 1999-03-23 Agency Of Ind Science & Technol 炭化水素部分酸化用触媒及び含酸素有機化合物の製造方法
JP2002541127A (ja) * 1999-04-08 2002-12-03 ザ ダウ ケミカル カンパニー 酸化された金触媒を使用してオレフィンをオレフィンオキシドにハイドロ酸化するための方法
JP2005053808A (ja) * 2003-08-01 2005-03-03 Kansai Tlo Kk メタロシリケート光触媒を用いた有機化合物の製造方法
JP2006081988A (ja) * 2004-09-15 2006-03-30 Ne Chemcat Corp 排ガス浄化用チタニア系酸化触媒、排ガス浄化用触媒構造体および排ガス浄化方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1176820A (ja) * 1997-09-05 1999-03-23 Agency Of Ind Science & Technol 炭化水素部分酸化用触媒及び含酸素有機化合物の製造方法
JP2002541127A (ja) * 1999-04-08 2002-12-03 ザ ダウ ケミカル カンパニー 酸化された金触媒を使用してオレフィンをオレフィンオキシドにハイドロ酸化するための方法
JP2005053808A (ja) * 2003-08-01 2005-03-03 Kansai Tlo Kk メタロシリケート光触媒を用いた有機化合物の製造方法
JP2006081988A (ja) * 2004-09-15 2006-03-30 Ne Chemcat Corp 排ガス浄化用チタニア系酸化触媒、排ガス浄化用触媒構造体および排ガス浄化方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008230876A (ja) * 2007-03-19 2008-10-02 Toyota Central R&D Labs Inc メソ孔及びマイクロ孔を有する金属酸化物多孔体の製造方法、メソ孔及びマイクロ孔を有する金属酸化物多孔体及びそれを用いたガス浄化材料
JP2010536819A (ja) * 2007-08-20 2010-12-02 チュールム ベタイリグングスゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー パテンテ ツヴァイ コマンディートゲゼルシャフト 均質な気相中でオレフィンの酸化によりエポキシドを効率的に製造する方法
WO2011051643A1 (fr) * 2009-10-29 2011-05-05 Dow Global Technologies Inc. Oxydation catalytique sélective d'alcanes en c1-c3
CN116284724A (zh) * 2019-11-21 2023-06-23 联泓(江苏)新材料研究院有限公司 不饱和酸聚氧烯烃酯类化合物的制备方法

Also Published As

Publication number Publication date
JP5017619B2 (ja) 2012-09-05
JPWO2008108398A1 (ja) 2010-06-17

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