WO2008113746A3 - Verfahren zur entschwefelung von kraftstoffen und dafür geeigneter hochaktiver nickel-trägerkatalysator auf der basis von aluminiumoxid - Google Patents

Verfahren zur entschwefelung von kraftstoffen und dafür geeigneter hochaktiver nickel-trägerkatalysator auf der basis von aluminiumoxid Download PDF

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Publication number
WO2008113746A3
WO2008113746A3 PCT/EP2008/053038 EP2008053038W WO2008113746A3 WO 2008113746 A3 WO2008113746 A3 WO 2008113746A3 EP 2008053038 W EP2008053038 W EP 2008053038W WO 2008113746 A3 WO2008113746 A3 WO 2008113746A3
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WIPO (PCT)
Prior art keywords
aluminum oxide
fuels
catalyst based
highly active
nickel
Prior art date
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Ceased
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PCT/EP2008/053038
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English (en)
French (fr)
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WO2008113746A4 (de
WO2008113746A2 (de
Inventor
Juergen Ladebeck
Tiberius Regula
Klaus Wanninger
Wolfgang Gabriel
Frank Grossmann
Juergen Koy
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Sued Chemie AG
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Sued Chemie AG
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Publication date
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Priority to US12/531,540 priority Critical patent/US8992768B2/en
Priority to EP08717782A priority patent/EP2136912A2/de
Publication of WO2008113746A2 publication Critical patent/WO2008113746A2/de
Publication of WO2008113746A3 publication Critical patent/WO2008113746A3/de
Publication of WO2008113746A4 publication Critical patent/WO2008113746A4/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B01J20/28007—Sorbent size or size distribution, e.g. particle size with size in the range 1-100 nanometers, e.g. nanosized particles, nanofibers, nanotubes, nanowires or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
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    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
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    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/48—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
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    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
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    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/52—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing platinum group metals or compounds thereof
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
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Abstract

Ein hochaktiver Nickel-Trägerkatalysator auf der Basis von Aluminiumoxid weist einen Nickelgehalt von etwa 20 bis 70 Gew.-% (als Ni) auf und enthält gegebenenfalls ein Bindemittel sowie gegebenenfalls einen Promotor, ausgewählt aus Verbindungen von Mg, Ti, Pd, Pt, Ba, Ca und/oder Cu, wobei die Größe der Ni-Kristallite im reduzierten Zustand im Bereich von etwa 3,5 bis 4,5 nm liegt und der Verzerrungsfaktor der Ni-Kristallite etwa 2 bis 5% beträgt. In einem Verfahren zur Reduktion des Gehalts an Schwefelverbindungen von auf Kohlenwasserstoffen basierenden Kraftstoffen durch selektive Adsorption der Schwefelverbindungen an einen Nickel-Katalysator wird ein Nickel-Katalysator auf Basis von Aluminiumoxid, insbesondere der vorstehend beschriebene, verwendet. Ein Nickel-Katalysator auf Basis von Aluminiumoxid kann zur Verringerung des Gehalts an Schwefelverbindungen von auf Kohlenwasserstoffen basierenden Kraftstoffen durch selektive Adsorption der Schwefelverbindungen an ihn und/oder zur Hydrierung von Aromaten verwendet werden.
PCT/EP2008/053038 2007-03-16 2008-03-13 Verfahren zur entschwefelung von kraftstoffen und dafür geeigneter hochaktiver nickel-trägerkatalysator auf der basis von aluminiumoxid Ceased WO2008113746A2 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US12/531,540 US8992768B2 (en) 2007-03-16 2008-03-13 Method for the desulfurization of fuels and highly active nickel carrier catalyst based on aluminum oxide suitable for said method
EP08717782A EP2136912A2 (de) 2007-03-16 2008-03-13 Verfahren zur entschwefelung von kraftstoffen und dafür geeigneter hochaktiver nickel-trägerkatalysator auf der basis von aluminiumoxid

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007012812A DE102007012812A1 (de) 2007-03-16 2007-03-16 Verfahren zur Entschwefelung von Kraftstoffen und dafür geeigneter hochaktiver Nickel-Trägerkatalysator auf der Basis von Aluminiumoxid
DE102007012812.8 2007-03-16

Publications (3)

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WO2008113746A2 WO2008113746A2 (de) 2008-09-25
WO2008113746A3 true WO2008113746A3 (de) 2009-01-15
WO2008113746A4 WO2008113746A4 (de) 2009-03-12

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PCT/EP2008/053038 Ceased WO2008113746A2 (de) 2007-03-16 2008-03-13 Verfahren zur entschwefelung von kraftstoffen und dafür geeigneter hochaktiver nickel-trägerkatalysator auf der basis von aluminiumoxid

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Country Link
US (1) US8992768B2 (de)
EP (1) EP2136912A2 (de)
DE (1) DE102007012812A1 (de)
WO (1) WO2008113746A2 (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009022242A1 (de) 2009-05-22 2010-11-25 Süd-Chemie AG Verfahren zur adsorptiven Entschwefelung flüssiger Kohlenwasserstoffe unter Verwendung von Wasserstoffdonatoren
FR3022160B1 (fr) 2014-06-13 2021-05-07 Ifp Energies Now Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux compris entre 50 et 300 nm et son utilisation en hydrogenation
FR3068985A1 (fr) 2017-07-13 2019-01-18 IFP Energies Nouvelles Procede d’hydrogenation des aromatiques mettant en oeuvre un catalyseur obtenu par comalaxage comprenant un support specifique
FR3068982A1 (fr) 2017-07-13 2019-01-18 IFP Energies Nouvelles Procede d'hydrogenation selective mettant en œuvre un catalyseur obtenu par comalaxage comprenant un support specifique
FR3076747B1 (fr) 2018-01-15 2022-06-10 Ifp Energies Now Procede de preparation d'un catalyseur particulier d'hydrogenation selective et d'hydrogenation des aromatiques par malaxage
FR3104462B1 (fr) 2019-12-17 2022-06-10 Ifp Energies Now Catalyseur pour l’hydrogenation de composes aromatiques obtenu a partir de sels fondus et d’un additif organique
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