WO2008152917A1 - オレフィンと芳香族ビニル化合物からなる共重合体、その製造方法、該共重合体を含む樹脂組成物及び該共重合体の延伸成形品 - Google Patents

オレフィンと芳香族ビニル化合物からなる共重合体、その製造方法、該共重合体を含む樹脂組成物及び該共重合体の延伸成形品 Download PDF

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Publication number
WO2008152917A1
WO2008152917A1 PCT/JP2008/059874 JP2008059874W WO2008152917A1 WO 2008152917 A1 WO2008152917 A1 WO 2008152917A1 JP 2008059874 W JP2008059874 W JP 2008059874W WO 2008152917 A1 WO2008152917 A1 WO 2008152917A1
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aromatic vinyl
copolymer
olefin
production
resin compositions
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Ceased
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PCT/JP2008/059874
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English (en)
French (fr)
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Nobuhide Ishihara
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Idemitsu Kosan Co Ltd
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Idemitsu Kosan Co Ltd
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Priority to CN200880024081A priority Critical patent/CN101796090A/zh
Priority to US12/663,934 priority patent/US8461270B2/en
Priority to EP08764843A priority patent/EP2157108B1/en
Publication of WO2008152917A1 publication Critical patent/WO2008152917A1/ja
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0838—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with monomers including an aromatic carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/10—Peculiar tacticity
    • C08L2207/12—Syndiotactic polypropylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

　本発明は、シンジオタクチック構造を有するブロック性が高く、分子量分布が広いオレフィンと芳香族ビニル化合物からなる共重合体である。詳しくは、芳香族ビニル化合物の含有量が１～９９モル％、分子量分布が１．７以上、共重合体の結合点である（オレフィン－芳香族ビニル化合物－オレフィン）連鎖に基づくシグナル、（芳香族ビニル化合物－芳香族ビニル化合物－オレフィン）連鎖に基づくシグナル、芳香族ビニル化合物のブロック的な連鎖（芳香族ビニル化合物－芳香族ビニル化合物－芳香族ビニル化合物）に基づくシグナル、オレフィンのブロック的な連鎖（オレフィン－オレフィン－オレフィン）に基づくシグナルが存在し、芳香族ビニル化合物成分のブロック性を示す指標が３０～１００％、芳香族ビニル化合物から構成される繰り返し単位の立体規則性が８０モル％以上であるオレフィンと芳香族ビニル化合物からなる共重合体、その製造方法、樹脂組成物及び延伸成形品である。
PCT/JP2008/059874 2007-06-13 2008-05-29 オレフィンと芳香族ビニル化合物からなる共重合体、その製造方法、該共重合体を含む樹脂組成物及び該共重合体の延伸成形品 Ceased WO2008152917A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN200880024081A CN101796090A (zh) 2007-06-13 2008-05-29 由烯烃和芳香族乙烯基化合物构成的共聚物、其制备方法、含有该共聚物的树脂组合物以及该共聚物的延伸成形品
US12/663,934 US8461270B2 (en) 2007-06-13 2008-05-29 Olefin/aromatic vinyl copolymer, process for production thereof, resin compositions containing the copolymer, and stretched products of the copolymer
EP08764843A EP2157108B1 (en) 2007-06-13 2008-05-29 Olefin/aromatic vinyl copolymer, process for production thereof, resin compositions containing the copolymer, and stretched products of the copolymer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-156742 2007-06-13
JP2007156742A JP5652688B2 (ja) 2007-06-13 2007-06-13 オレフィンと芳香族ビニル化合物からなる共重合体の製造方法

Publications (1)

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WO2008152917A1 true WO2008152917A1 (ja) 2008-12-18

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PCT/JP2008/059874 Ceased WO2008152917A1 (ja) 2007-06-13 2008-05-29 オレフィンと芳香族ビニル化合物からなる共重合体、その製造方法、該共重合体を含む樹脂組成物及び該共重合体の延伸成形品

Country Status (7)

Country Link
US (1) US8461270B2 (ja)
EP (1) EP2157108B1 (ja)
JP (1) JP5652688B2 (ja)
KR (1) KR20100044168A (ja)
CN (1) CN101796090A (ja)
TW (1) TWI425013B (ja)
WO (1) WO2008152917A1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010265400A (ja) * 2009-05-15 2010-11-25 Idemitsu Kosan Co Ltd スチレン系樹脂組成物及びその成形体
JP2011084641A (ja) * 2009-10-15 2011-04-28 Mitsui Chemicals Inc 芳香族ビニル化合物と共役ポリエン化合物とのブロック共重合体の製造方法およびブロック共重合体
KR101821408B1 (ko) 2008-03-26 2018-01-23 데이진 가부시키가이샤 고체 고분자형 연료 전지의 전해질막 보강용 필름
JP2021021080A (ja) * 2017-03-31 2021-02-18 エルジー・ケム・リミテッド ポリオレフィン−ポリスチレン系多重ブロック共重合体、それを製造するための有機亜鉛化合物及びポリオレフィン−ポリスチレン系多重ブロック共重合体の製造方法

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5182877B2 (ja) * 2008-09-03 2013-04-17 独立行政法人産業技術総合研究所 マルチブロック共重合体の製造方法
JP2012057017A (ja) * 2010-09-07 2012-03-22 Idemitsu Kosan Co Ltd 芳香族ビニル化合物重合体の製造方法
JP5727736B2 (ja) * 2010-09-07 2015-06-03 出光興産株式会社 芳香族ビニル化合物重合体の製造方法
JP5727735B2 (ja) * 2010-09-07 2015-06-03 出光興産株式会社 芳香族ビニル化合物の重合用触媒の調製方法および芳香族ビニル化合物重合体の製造方法
JP6485903B2 (ja) * 2015-02-13 2019-03-20 出光興産株式会社 芳香族ビニル化合物系重合体の製造用重合触媒及び芳香族ビニル化合物系重合体の製造方法
CN107722155B (zh) * 2017-10-27 2021-01-08 中国科学院长春应用化学研究所 一种α烯烃-氟苯乙烯聚合物及其制备方法
JP2024506221A (ja) * 2020-12-18 2024-02-09 ダウ グローバル テクノロジーズ エルエルシー エチレン／ビニルアレーンマルチブロックインターポリマーのための単一反応器チェーンシャトリング反応
WO2022133143A2 (en) * 2020-12-18 2022-06-23 Dow Global Technologies Llc Dual reactor chain shuttling reactions for ethylene/vinylarene diblock and triblock interpolymers
CN112724299B (zh) * 2020-12-29 2021-10-01 中国科学院长春应用化学研究所 一种乙烯与苯乙烯多嵌段共聚物及其制备方法
CN113943315A (zh) * 2021-09-26 2022-01-18 上海大学 一种含茚基稀土金属配合物、其制备方法及其应用

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JPH01146944A (ja) * 1987-12-04 1989-06-08 Idemitsu Kosan Co Ltd 耐衝撃性ポリスチレン系樹脂組成物
JPH01182346A (ja) * 1988-01-14 1989-07-20 Idemitsu Kosan Co Ltd フィルム，シートまたはテープ、およびその製造方法
WO2000018808A1 (en) * 1998-09-30 2000-04-06 Exxon Chemical Patents Inc. Cationic group 3 catalyst system
JP2001354724A (ja) * 2000-06-16 2001-12-25 Idemitsu Petrochem Co Ltd α−オレフィン−芳香族ビニル化合物共重合体
WO2006004068A1 (ja) * 2004-07-02 2006-01-12 Riken メタロセン錯体を含む重合触媒組成物、およびそれを用いて製造される重合体

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AU610950B2 (en) 1987-12-04 1991-05-30 Idemitsu Kosan Company Limited Styrene-based resin composition
US5166238A (en) 1986-09-22 1992-11-24 Idemitsu Kosan Co., Ltd. Styrene-based resin composition
US5395890A (en) 1987-09-14 1995-03-07 Idemitsu Kosan Co., Ltd. Styrene-based resin composition
CA1326095C (en) 1987-05-18 1994-01-11 Toshikazu Ijitsu Styrene-based resin composition and moldings produced from said composition
JP2566889B2 (ja) * 1987-07-13 1996-12-25 出光興産株式会社 オレフィン系重合体またはスチレン系重合体の製造方法
JP2840605B2 (ja) 1989-03-20 1998-12-24 出光興産株式会社 スチレン系共重合体及びその製造方法
JP3210325B2 (ja) 1990-09-19 2001-09-17 出光興産株式会社 スチレン系ブロック共重合体及びその製造方法
US5446117A (en) * 1993-08-19 1995-08-29 Queen's University At Kingston Process for producing amorphous syndiotactic polystyrene
JP2000248015A (ja) 1999-02-26 2000-09-12 Idemitsu Petrochem Co Ltd オレフィン−スチレン類共重合用触媒及びオレフィン−スチレン系共重合体の製造方法
EP1211264A4 (en) 2000-04-13 2005-03-09 Idemitsu Kosan Co METHOD FOR PRODUCING ALPHA OLEFINE / AROMATIC VINYL COPOLYMER
KR100416035B1 (ko) 2001-02-23 2004-02-05 삼성종합화학주식회사 난연성 신디오탁틱 폴리스티렌 수지 조성물
KR100466201B1 (ko) * 2002-09-19 2005-01-13 금호석유화학 주식회사 스티렌계 공중합체

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* Cited by examiner, † Cited by third party
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JPH01146944A (ja) * 1987-12-04 1989-06-08 Idemitsu Kosan Co Ltd 耐衝撃性ポリスチレン系樹脂組成物
JPH01182346A (ja) * 1988-01-14 1989-07-20 Idemitsu Kosan Co Ltd フィルム，シートまたはテープ、およびその製造方法
WO2000018808A1 (en) * 1998-09-30 2000-04-06 Exxon Chemical Patents Inc. Cationic group 3 catalyst system
JP2001354724A (ja) * 2000-06-16 2001-12-25 Idemitsu Petrochem Co Ltd α−オレフィン−芳香族ビニル化合物共重合体
WO2006004068A1 (ja) * 2004-07-02 2006-01-12 Riken メタロセン錯体を含む重合触媒組成物、およびそれを用いて製造される重合体

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2157108A4 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101821408B1 (ko) 2008-03-26 2018-01-23 데이진 가부시키가이샤 고체 고분자형 연료 전지의 전해질막 보강용 필름
JP2010265400A (ja) * 2009-05-15 2010-11-25 Idemitsu Kosan Co Ltd スチレン系樹脂組成物及びその成形体
JP2011084641A (ja) * 2009-10-15 2011-04-28 Mitsui Chemicals Inc 芳香族ビニル化合物と共役ポリエン化合物とのブロック共重合体の製造方法およびブロック共重合体
JP2021021080A (ja) * 2017-03-31 2021-02-18 エルジー・ケム・リミテッド ポリオレフィン−ポリスチレン系多重ブロック共重合体、それを製造するための有機亜鉛化合物及びポリオレフィン−ポリスチレン系多重ブロック共重合体の製造方法
JP7661025B2 (ja) 2017-03-31 2025-04-14 エルジー・ケム・リミテッド ポリオレフィン－ポリスチレン系多重ブロック共重合体、それを製造するための有機亜鉛化合物及びポリオレフィン－ポリスチレン系多重ブロック共重合体の製造方法

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Publication number Publication date
EP2157108A4 (en) 2010-10-06
EP2157108A1 (en) 2010-02-24
EP2157108B1 (en) 2013-02-20
JP2008308557A (ja) 2008-12-25
TWI425013B (zh) 2014-02-01
CN101796090A (zh) 2010-08-04
KR20100044168A (ko) 2010-04-29
JP5652688B2 (ja) 2015-01-14
TW200914477A (en) 2009-04-01
US20110172366A1 (en) 2011-07-14
US8461270B2 (en) 2013-06-11

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