WO2008155755A1 - Systèmes et procédés pour le blanchissage avec recyclage - Google Patents

Systèmes et procédés pour le blanchissage avec recyclage Download PDF

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Publication number
WO2008155755A1
WO2008155755A1 PCT/IL2008/000785 IL2008000785W WO2008155755A1 WO 2008155755 A1 WO2008155755 A1 WO 2008155755A1 IL 2008000785 W IL2008000785 W IL 2008000785W WO 2008155755 A1 WO2008155755 A1 WO 2008155755A1
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solution
computer
catholyte
anolyte
waste
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WO2008155755A4 (fr
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Lev Gurevich
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F35/00—Washing machines, apparatus, or methods not otherwise provided for
    • D06F35/003—Washing machines, apparatus, or methods not otherwise provided for using electrochemical cells
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F35/00—Washing machines, apparatus, or methods not otherwise provided for
    • D06F35/005—Methods for washing, rinsing or spin-drying
    • D06F35/006—Methods for washing, rinsing or spin-drying for washing or rinsing only
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4676—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electroreduction
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/46109—Electrodes
    • C02F2001/46133—Electrodes characterised by the material
    • C02F2001/46138—Electrodes comprising a substrate and a coating
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/4619—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/308—Dyes; Colorants; Fluorescent agents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/38—Organic compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/46115—Electrolytic cell with membranes or diaphragms
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4618—Supplying or removing reactants or electrolyte
    • C02F2201/46185—Recycling the cathodic or anodic feed
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/005—Processes using a programmable logic controller [PLC]
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/04—Oxidation reduction potential [ORP]
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/05—Conductivity or salinity
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/06—Controlling or monitoring parameters in water treatment pH
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/40—Liquid flow rate
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/02—Softening water by precipitation of the hardness

Definitions

  • This invention relates to systems and methods for laundering, in particular with regard to industrial laundering employing solution mixtures produced from electrochemical processes and recycling of the solutions.
  • This invention can be implemented in the food industry, agriculture, meat industry etc. with minor modification of collection points of waste solution mixtures from electrochemical processes BACKGROUND OF THE INVENTION
  • washed fabrics contain approximately 2% of the initial detergent, which remains entrained within the fabric, as well as 2 to 5% of the original dirt, which remains in the washed fabric.
  • the detergents, softeners, bleaches and other chemicals used in the washing process are typically released into the environment. Additionally, byproducts of these chemicals may also be released into the environment.
  • ozone is a gas at room temperature.
  • an oxidizing agent is produced which enables the washing of fabrics in water without detergents.
  • maintaining the stability over time of the ozone content in the water has proven difficult and has led to increased use of electrolytically produced oxidants in washing solutions.
  • This invention relates to a method for washing and bleaching textiles.
  • the method is carried out by means of an aqueous wash bath containing a detergent substantially free of a bleaching agent.
  • the process is characterized in that the bleaching is performed by incorporating into the wash bath an aqueous alkaline oxidizing solution containing in particular hydrogen peroxide ions, which was produced electrolytically, immediately before its addition to the wash bath, by reducing oxygen at a cathode in an alkaline medium.
  • a similar invention is disclosed in Certificate of Authorship No. SU 1687684 to A. Pulavsky et al.
  • This invention relates to processes and systems for machine washing.
  • the method is carried out by passing washing solution, which has been electrolytically treated in a cathode chamber of diaphragm electrolyzer, prior to washing through a washing reservoir.
  • the washing solution is treated to attain pH level of from 10.0 to 11.5 and Oxidation Redaction Potential of from -600 to -800 mV. Additionally, oxygen is injected into the washing solution before completion of the washing process.
  • This invention has many drawbacks, such as not being able to provide fully cleaned laundry since the use of an oxidizing mixture for laundering is ineffective. This necessitates the use of many additives, such as enzymes, optical brightener, softener, deodorant etc. Furthermore, the redox potential sensor described therein cannot measure the laundering solution in real-time inside the tub where fabric or clothes are being laundered.
  • Another invention is disclosed in United States Patent No. 5,928,490, to Sweeney, which discloses an improved laundry treatment system comprising a washer which is connected to used water discharge to a tank for filtration and recirculation back to the washer, a tank containing water for making up losses in the wash cycle, and an electrolytic cell therein comprising an enclosed compartment.
  • the electrolytic cell comprises an enclosed compartment containing an anode and a cathode supported on the outside and inside respectively of an opening in the wall of the compartment open to the surrounding liquid when the compartment is immersed in the water in the tank for producing mixed oxidants dissolved in the make up water for oxidizing deleterious components, without damaging the fabric that are being washed.
  • United State Patent Application No. 2004/0172985 discloses an electric washing machine which performs a washing process with the use of electrolyzed water.
  • an electrolyzing water level which is lower than a washing water level
  • energizing of an electrolyzing device is activated.
  • air is supplied into an electrolyzing chamber by an air pump, so that water in the electrolyzing chamber is caused to flow, thereby assisting efficient electrolysis of the water.
  • the water thus electrolyzed has an enhanced cleaning capability thereby improving the washing performance of the washing machine.
  • the peroxide generating device for application in an automatic fabric washing machine comprises an electrochemical cell for the production of peroxide from tap water and air, and a pH modifying device for the production of acidic and alkaline water, thereby enabling washing of the fabric articles without the need for added chemicals and improved fabric care, due to the separate dosing of peroxide.
  • Step a) can only proceed efficiently in a highly alkaline medium/solution with above mentioned parameters of pH and ORP, such that the following saponification reaction occurs:
  • This reaction allows the soap to soften the water, decompose fatty acids, neutralize amino acids and proteins and remove decomposed substances from linen.
  • Step b) takes place in an acid medium with above mentioned parameters of pH and ORP, a chloramination reaction occurs, in accordance with following equation:
  • This reaction allows bleaching and disinfection to occur, with decomposition of amino acids, proteins, any kinds of dye-stuffs etc.
  • Step c) occurs in neutral weakly acid or weakly alkaline medium with above mentioned parameters of pH and ORP, a neutralization reaction in accordance with next equation may occur:
  • United States Patent No. 6,132,572, to Kim describes an electrolyzer apparatus including anode and cathode units that are alternately arranged in a sandwich type fashion separated from each other by ion exchange membranes.
  • Two inlet streams of water introduced into the apparatus wherein one water stream is routed through the anode sections and the other water stream is routed through the cathode sections, and resulting in two treated water outlet streams, with the anode stream being highly acidic and the cathode stream being highly alkaline that cumulates in an elevated oxidation reduction electric potential ranging from-900 to +1180 mV.
  • This device has several drawbacks, namely: air plugging in the chamber until it does not function properly, and b) the washing effect (washing quality) is estimated on a basis of reflection factors from dirty and clean fabrics and do not take in consideration the amount of residual dirt in the fabric.
  • This invention provides a cleansing and sterilizing apparatus for cleaning embodiments such as dishes, medical devices, clothing, etc.
  • the apparatus comprises an electrolysis chamber that uses an ion exchange membrane to separate a cathode section from an anode section of the chamber. Tap water is injected into cathode section and saltwater is injected into the anode section. Electrolysis in the anode section of the electrolysis chamber forms acidic water and HOCI, which has antibacterial and disinfectant properties. In addition, electrolysis in the cathode section of the electrolysis chamber forms alkaline water and sodium hydroxide (NaOH), which has cleansing and reducing properties.
  • NaOH sodium hydroxide
  • the alkaline water and sodium hydroxide is then pumped out of the electrolysis chamber sprayed on embodiments to be cleansed, such as medical devices (endoscopes, dialysis equipment), dishes, etc. After cleansing, the items may then be optionally sprayed with the acidic water and HOCI to sterilize or disinfect the items.
  • the ion exchange membrane includes an anion exchange membrane, a cation exchange membrane, and a neutral membrane.
  • the electrolysis chamber does not include an ion exchange membrane, thereby reducing costs of manufacturing and using the invention.
  • the current invention is directed to systems and methods for laundering soiled items without detergents and with low water consumption.
  • the method of the current invention uses 0.5 to 3.0 liters of water per 1kg of linen.
  • system and method of the present invention result in energy and fuel savings of about 85 - 90%.
  • Some embodiments of the present invention are directed to a laundering process and a method with recycling of process solutions.
  • At least one of anolyte and catholyte solutions are recycled.
  • the ratio of the fresh anolyte to recycled anolyte ranges from 1 :3 to 1 :10.
  • the ratio of the fresh catholyte to recycled catholyte ranges from 1 :3 to 1 :10.
  • the present invention has been made in consideration of the aforementioned problems of the related prior art and seeks to provide a laundering process having at least one closed-loop recycling system for separate treatment of each kind of laundry waste water.
  • the recycling system of the present invention is based upon electrochemical methods, which allow for a reduction in water consumption of 90 - 95% down to around 0.5 - 3.0 liter of water for 1 kg of laundering linen.
  • a significant saving in energy sources (such as oil, gas, electrical energy etc.), of 85-90% relative to prior art processes from 0.15 - 0.25- KW/kg linen to 0.02 - 0. 1 KW/kg linen.
  • a further saving in cycle time is around 30-90% of prior art cycle times from 30 - 90 min. to 8 - 20 min.
  • a significant saving in consumption of detergents of about 90 - 95%, down to around of 0.5 - 1.0 g. of detergent for 1 kg. very dirty linen is also provided with an average savings of about 93 - 96% of all kinds of linen, including linen for hotels, hospitals, restaurants, and domestic linen etc.
  • Such treatment of the solutions retains up to around 95% of their properties without a requirement of an external supply of energy and chemicals.
  • an improved treatment of washing solutions by multi-stage electrochemical treatment comprising the following steps:
  • Another aspect of the present invention is to provide an improved treatment of bleaching-disinfecting solutions by multi-stage electrochemical treatment comprising the following steps:
  • Yet another aspect of the present invention provides a catholyte chamber of membrane electrolyzer having two simultaneous functions- namely laundry waste washing water treatment and catholyte production.
  • a further aspect of the present invention is to provide an anolyte chamber of membrane electrolyzer having two simultaneous functions, namely laundry waste bleaching-disinfecting water treatment and anolyte production.
  • An additional aspect of the present invention provides a clean water from a reverse osmosis (RO) device to provide additional feed water for catholyte production to prevent scaling of the electrolyzer cathodes.
  • RO reverse osmosis
  • a further aspect of the present invention provides an effluent from an RO device to provide additional feed water for anolyte production.
  • a significant advance of the present invention is that the use of two electrolyzer units in series, particularly with a second unit comprising a membrane enables production of a catholyte having a higher pH than that obtainable from a comparable prior art systems.
  • the computer-controlled laundering system of the present invention includes a system, substantially as shown in the figures.
  • Fig. 1 is a simplified diagram of an industrial drum washing system with a solution recycle, in accordance with some embodiments of the present invention
  • FIG. 2 is a simplified diagram of an industrial tunnel washing system with a solution recycle in accordance with some embodiments of the present invention
  • Fig. 3 is a simplified flowchart of a method for performing a first laundering process, in accordance with some embodiments of the present invention
  • Fig. 4 is a simplified flowchart showing sub-steps of step 310 of Fig. 3;
  • Fig. 5 is a simplified flowchart of a method for catholyte recycling of a laundering step in accordance with some embodiments of the present invention
  • Fig. 6 is a simplified flowchart of a method for anolyte recycling of a laundering process, in accordance with some embodiments of the present invention.
  • Fig. 7 is a simplified flowchart of a method for rinse solution recycling of a laundering process, in accordance with some embodiments of the present invention.
  • Some embodiments of the present invention are directed to systems and methods for laundering fabrics in processes wherein the pH and ORP levels are kept substantially constant over a long period of time. More particularly, in all of the three steps: a) washing/laundering, b) disinfecting and bleaching and c) rinsing, the solution compositions are retained within strict parameter regimes by means of adding tap water, catholyte or anolyte and additives, responsive to a detected change in the solution composition in the washing machine.
  • Some embodiments of the present invention particularly relate to systems and methods for laundering fabrics in processes employing three recycling subsystems of waste solutions, namely, a) a washing/laundering (catholyte) recycle, b) a disinfecting and bleaching (anolyte) recycle and c) a rinse solution recycle.
  • waste solutions from all three laundering steps a) washing/laundering, b) disinfecting and bleaching and c) rinsing, are collected separately and recycling thereof is implemented by three separate recycles simultaneously.
  • Fig.1 is a simplified diagram of an industrial washing recycle system 100 having a drum washing machine or washer 41 or 42 in accordance with some embodiments of the present invention.
  • Fig. 2 is a simplified diagram of an industrial tunnel washing recycle system 100 comprising a tunnel washer 67, in accordance with some embodiments of the present invention.
  • the present invention provides laundering waste solution collection and recycling from drum washing machines 41 , 42 (Fig. 1) and/or from a tunnel washing machine 67 (Fig. 2) by continuous collection of the washing waste solution, bleaching - disinfection waste solution and rinsing waste solution followed by their separate and simultaneous recycling.
  • Waste washing solution from drum washer 41 or 42 is collected in reception tank 53 or 54 and by pump 55 or 58 is fed to a filter, such as a self-cleaning filter 50. Thereafter it is fed from said filter and collected in an intermediate holding tank for waste washing solution (WWS) 44.
  • WWS waste washing solution
  • Pump 47 pumps the filtered WWS from tank 44 and directs it to a conductivity meter sensor 10b and thereafter to inlet 14b of membrane-less electrolyzer 2b.
  • clean water (CW) is fed from clean water tank 3 from RO device 1 by pump 7 and salt water from tank 4 by metering pump 5 for salt water.
  • Conductivity meter sensor 10b constantly monitors the conductivity (EC) level of a replenished catholyte solution.
  • a PLC 74 and metering pump 5 are employed to retain the correct quantity and quality of the replenished catholyte solution within predetermined process limits, such that the conductivity is between 1 and 15 mS, the flow rate into the electrolytic membrane-less electrolyzer apparatus 2b is between 2 and 50 l/min.
  • Membraneless electrolyzer apparatus 2b comprises a housing, an anode 3b and a cathode 4b, an inlet nozzle 14b and an outlet nozzle 6b.
  • the anode is preferably constructed from a titanium substrate with an MMO coating from RuC> 2 and IrO 2 .
  • the cathode is preferably constructed from titanium.
  • the housing and electrodes can be round or flat, but, in any case, a distance between anode and cathode is generally from 3 to 20 mm.
  • the aqueous solution in the processing chamber of membrane-less electrolyzer 2b is subject to an electric current from anode 3b and cathode 4b, which are both connected to a DC supplier 17, and the current passes through the processing chamber such that electrochemical reactions occur at the anode and cathode.
  • Ions generated at the anode are cations and chemical agents, such as, but not limited to HOCI, HCI, Cl 2 , H + , HO 2 , H 3 O+, Na + , and K + .
  • the cathode the following types of anions are generated OH “ , HsO 2 " , NO 3 " , CO 3 2" , SO 4 2" , CIO " .
  • cations and anions may react together in one or more neutralization reactions resulting in non-treated aqueous solution and reactions products such as NaOCI, NaOH, KOH, H 2 O, HOCI etc. with pH about of from 8.0 to 9.0 at outlet nozzle 6b of membrane-less apparatus exit.
  • the resultant aqueous solution and reactions products are fed into a self-cleaning filter 16b and then through control cock 29 and flow-meter 27 to catholyte chamber of membrane electrolyzer apparatus 20 as described hereinbelow.
  • Membrane electrolyzer apparatus 20 comprises a housing, an anode 23, a cathode 24, a membrane 25, inlet nozzles 18 for anode and 19 for cathode chambers and outlet nozzles 21 for anode and 22 for cathode chambers,
  • the anode is constructed from a titanium substrate with an MMO coating of RuO 2 and IrO 2 .
  • Electrochemical reactions occur at the anode and at the cathode.
  • apparatus 20 has a membrane 25 disposed between the anode and cathode chambers.
  • the neutralization reactions occurring in apparatus 2b cannot occur herein due to their separation by the membrane.
  • electrochemical reaction products accumulate in their respective chambers and exit the chambers through outlet nozzle 21 for anode chamber and outlet nozzle 22 for cathode chamber of membrane electrolyzer 20 to catholyte tank 30 and anolyte tank 31.
  • a predetermined feed rate of catholyte from catholyte tank 30 is fed to washer 41 and 42 through electric cock 32 and 35 together with CW through electric cock 34 and 37and additives (not shown on Fig.1 and Fig.2) into an inner drum of drum washer 41 and 42.
  • a waste washing (catholyte) solution is pumped out into receptor 53 and 54 and the waste washing solution is recycled.
  • the same recycling principal is used to recycle the bleaching - disinfecting solution.
  • the waste (anolyte) bleaching-disinfecting solution is fed into receptor 53 and 54.
  • Pump 56 and 59 pumps the solution through a self-cleaning filter 49 to a tank 43 for waste bleaching - disinfecting solution (WBS) collection.
  • Pump 46 feeds the filtered solution from tank 43 to membrane-less electrolyzer 2a.
  • RO device 1 and tank 2 of effluent and pump 8 supply the effluent, in addition to filtered waste bleaching - disinfecting solution. Further additions are made via metering pump 40 for salt water from tank 4.
  • the filtered solution passes via a conductivity meter sensor 10a and then into inlet 14a of membrane-less electrolyzer 2a. Thereafter, the resultant anolyte solution from the membrane-less electrolyzer 2a is pumped into a filter, such as a self-cleaning filter 16a.
  • Control cock 28 and flow-meter 26 regulate the flow of anolyte from filter 16a to an anode chamber of membrane electrolyzer 20 via an inlet 18 to anolyte holding tank 31.
  • waste rinsing solution which includes only receptors 53 and 54 of the waste rinsing solution, a pump 57 and 60, which pumps the waste rinse solution via a self - cleaning filter 51 to a holding tank 45 for filtered waste rinsing solution (WRS). Thereafter, a pump 48 feeds the solution from tank 45 back to the drum washer as an additive solution to the washing step to the washing solution which include tap water, catholyte, filtered waste rinsing solution and additives.
  • Self - cleaning filters are released from sludge by back flash after a certain predetermined time and sludge is directed to a filter press 52, where it is filtered. The liquid phase is then directed as an additive to the waste bleaching - disinfecting solution to the inlet of membrane - less electrolyzer 2a.
  • Tap water is fed to RO device 1 and is divided into two streams: a) one to the clean water (CW) tank 3 and salt tank 4 and the other b) to the effluent (EF) tank 2.
  • CW from tank 3 fed also to inlet of membrane - less electrolyzer 2b as an addition solution to the recycled washing solution to replenish water removed with laundered linen and is also passed to the drum and tunnel washers.
  • Effluent solution (EF) is passed from tank 2 and fed to the inlet of membrane-less electrolyzer 2a as an additive to recycling bleaching-disinfecting solution in place of water, which was removed with the laundered linen.
  • a salt tank 4 is filled with CW and salt (from time to time) for saline water formation, which is further fed by metering pump 5 and 40 to inlet nozzle 14a and 14b of membrane-less electrolyzers 2a and 2b.
  • the quantity of saline water is regulated by EC meter sensors 10a and 10b.
  • Another notable improvement of the present invention over the prior art is the gathering and recycling of three main waste laundering solutions - waste washing solutions, waste bleaching - disinfecting solution and waste rinsing solution.
  • This feature is implemented simultaneously via at least one line for waste washing solution recycling and at least one line for waste bleaching - disinfecting solution recycling and at least one line for waste rinsing solution recycling.
  • the anion-containing waste washing solution cannot be in contact with the cation-containing waste bleaching - disinfecting solution and therefore neutralization reactions cannot occur.
  • both the washing and bleaching - disinfecting solutions retain above 65 - 85% of their properties over time.
  • Yet another advantage of the present invention over the prior art is the use of two electrolytic stages (2a, 20) in both lines for recycling (waste washing solution and bleaching - disinfecting solution) by consecutively passing waste laundering solutions through first membrane-less electrolysis apparatus 2a or 2b and thereafter the two above mentioned solutions are passed simultaneously through anode and cathode chambers of the membrane electrolysis apparatus 20, having a membrane between the anode and cathode chambers.
  • membrane-less electrolyzer 2a the feed waste bleaching - disinfecting solution is processed.
  • the solution has a pH of from 3.0 to 6.0.
  • Membrane-less electrolyzer 2b is fed with waste washing solution having a pH of from 9.0 to 11.0.
  • electrolyzer 2a there prevails a reduction reaction at the cathode, in which azo- and nitro compounds are reduced to amino compounds, with further oxidation to CO 2 , NH 2 and H 2 O. Parts of the reduced products are oxidized to insoluble compounds and precipitate.
  • electrolyzer 2a there prevails an oxidation reaction at the anode and destruction of dye and organic contaminants.
  • a further advantage of the present invention over the prior art is the use of a reverse osmosis apparatus, which is configured to supply purified water back to membrane-less electrolyzer 2b from the recycle line of waste washing solution. Effluent from the RO device is recycled to the membrane-less electrolyzer 2a from the recycle line for waste bleaching - disinfecting solution. Thus, the effluent of the RO device effluent is re-used in the laundering process and is not discarded.
  • An additional advantage of the present invention over the prior art is the use of a membrane electrolyzer with an anion exchange membrane, which prevents the membrane thereof from clogging up with precipitates such as calcium and magnesium carbonates.
  • the present invention achieves pH and ORP stability within a drum washing machine 41 and 42 (Fig. 1) and/or within a tunnel washing machine 67 (Fig. 2) by providing at least periodical and preferably constant monitoring of washing, bleaching and disinfection solutions parameters and immediately correcting any of the parameters upon deviation thereof from an upper and a lower limit.
  • Tap water is fed to RO device 1 and divided into two streams: a) one to the clean water (CW) tank 3 and salt tank 4 and the other b) to effluent (EF) tank 2.
  • CW from tank 3 fed also to inlet of membrane - less electrolyzer 2b as addition to recycling washing solution in return for water, which was take off by laundered linen and also to drum and tunnel washers.
  • a salt tank 4 is filled with CW and salt (from time to time) for saline water formation, which is further fed by metering pump 5 and 40 to inlet nozzle 14a and 14b of membrane-less electrolyzers 2a and 2b. Amount of saline water is regulated by EC meter sensors 10a and 10b.
  • Membrane-less electrolysis apparatus 2a comprises a housing, an anode 3a and a cathode 4a, an inlet nozzle 14a and an outlet nozzle 6a.
  • the anode constructed from a titanium substrate with an MMO coating from RuO 2 and IrO 2 in an equal ratio (1 :1).
  • the housing and electrodes can be round or flat, but, in any case, a distance between anode and cathode is generally from 3 to 20 mm.
  • a conductivity meter sensor 10a is set at the end of an inlet nozzle 14a to the membrane-less apparatus 2a.
  • the sensor measure the quantity of saline water entering apparatus 2a and transmits this data to PLC 74.
  • the aqueous solution in the processing chamber of membrane-less apparatus 2a is subject to an electric current from anode 3a and cathode 4a, which are both connected to a DC supplier 17, and the current passes through the processing chamber such that electrochemical reactions occur at the anode and cathode.
  • Ions generated at the anode are cations and chemical agents, such as, but not limited to HOCI, HCI, Cl 2 , H + , HO 2 , H 3 O+, Na + , and K + .
  • anions are generated OH ' , H 3 O 2 " , NO 3 " , CO 3 2” , SO 4 2” , CIO " .
  • These cations and anions may react together in one or more neutralization reactions resulting in non-treated aqueous solution and reactions products such as NaOCI, NaOH, KOH, H 2 O, HOCI etc. with pH about of from 8.0 to 9.0 at outlet nozzle 6a of membrane-less apparatus exit.
  • Membrane electrolysis apparatus 20 comprises a housing, an anode 23, a cathode 24, a membrane 25, inlet nozzles 18, 19 for anode and cathode chambers and outlet nozzles 21 , 22 for anode and cathode chambers,
  • the anode is constructed from a titanium substrate with MMO coating of RuO 2 and IrO 2 in an equal ratio (1 :1) and the cathode is uncoated titanium.
  • the cross section ratio of the outlet nozzles 21 , 22 to cross-section of the inlet nozzles 18, 19 is 2:1.
  • Electrochemical reactions occur at the anode and at the cathode.
  • apparatus 20 has a membrane disposed between the anode and cathode chambers.
  • the neutralization reactions occurring in apparatus 2a 2b cannot occur herein due to their separation by the membrane.
  • electrochemical reaction products accumulate in their respective chambers and exit the chambers through outlet nozzles 21, 22 of membrane apparatus 20 to catholyte tank 30 and anolyte tank 31.
  • the pH level of the catholyte in tank 30 is typically in the range of 11.3 to 12.5 and ORP to Platinum, relative to Ag/AgCI, in the range of from -650 to -920 mV.
  • the pH level of the anolyte in tank 31 is typically in the range of from 1.7 to 2.4, and ORP to Platinum, relative to Ag/AgCI, of from +800 to +1200 mV.
  • the anolyte and catholyte produced are for use in the laundering process in drum washer 41 and 42.
  • Additives may also be added to the drum washer to improve the laundering quality, thus a solution of washing enzymes known in the art, such as lipases.
  • Another additive used in the art is a grease remover (any kind of solvent), an optical brightener, a softener, one or more fragrances or odorants (Additives holding tanks, pumps, piping etc do not shown on Fig.1 and Fig.2) .
  • the catholyte from tank 30 is used with additives such as grease remover, enzyme, optical brightener and CW by means of electrical valve 34 and 37.
  • the required pH level of the washing solution in this phase is controlled by a time control of electrical valves 32, 34 and of electrical valves for the introduction of additives (not shown in Fig.1 and Fig.2) which is based on a response to the readings from pH sensors 77 and 78.
  • anolyte is added from tank 31 , using time control of electrical valve 33 and 36 and CW is added by means of electrical valve 75 and 76, which is based on a response to the readings from pH sensors 77 and 78..
  • the required pH level of the rinsing solution is maintained in this phase by time control of electrical valves 32, 34 and 35, 37 which is established on basis of pH measurements from pH sensors 77 and 78.
  • the three zones are periodically and preferably continuously controlled by three respective pH sensors 79, 80 and 81.
  • the washing solution used is the catholyte from tank 30 by means of electrical valve 61 with the addition of additives such as grease remover, enzyme and optical brightener (tanks and electrical valves of additives are not shown on Fig.2).
  • CW water is added by means of electrical valve 62.
  • the required pH level of the washing solution to this zone is effected by time control of electrical valve 61 and pump 73, which is established by measurements from pH sensor 79.
  • anolyte is used as a bleaching and disinfecting solution, and is received from tank 31.
  • CW is added to this zone by means of electrical valve 63.
  • the required pH level of the bleaching and disinfecting solution is supplied by time control of electrical valves 64, which is established on the basis of pH measurements from pH sensor 80.
  • the required pH level of the rinsing solution is supplied to this zone by activation of electrical valves 65 and 66, which, in turn are fed signals on the basis of pH measurements from pH sensor 81.
  • All laundering operations with either the drum washer 41 or 42 or CBW - tunnel washer 67 are controlled by means of a controller, exemplified herein by, but not limited to Programmable Logic Controller (PLC) 74. Any other computer control system of the art could be used in place of PLC 74.
  • PLC Programmable Logic Controller
  • PLC 74 has inputs (1, 2, 3, 4, 10a, 10b, 30, 31, 26, 29, 45, 46, 77, 78, 79, 80, 81) and outputs (1 , 5, 6, 7, 8, 9,16a, 16b, 32, 33, 34, 353, 36, 37, 38, 39, 46, 47, 48, 51, 52, 53, 55, 56, 57, 58, 59, 60, 61 , 62, 63, 64, 65, 66, 71 , 72 and 73).
  • the PLC will have several different programs for corresponding washing programs for different types and quantities of clothes.
  • Fig. 3 is a simplified flowchart 300 of a method for performing a first laundering step, in accordance with some embodiments of the present invention.
  • a first step 310 catholyte and anolyte solutions are prepared in one or more electrolytic stages. Further details of this step are described with reference to Fig. 4 hereinbelow.
  • a washing or laundering step 320 soiled, dirty or stained clothes are placed in the washer, such as drum washer 41 or 42 (Fig. 1) or tunnel washer 67 (Fig.2).
  • CW is fed from via a water pipeline and valves 34, 37, 75, 76, 62, 63, 66 to the drum washers 41 and 42 or to the CBW 67..
  • Catholyte from tank 30 is fed and mixed with the water such that the resultant solution is a washing solution of pH from 10.8 to 11.8 and ORP to Platinum, relative to Ag/AgCI, of from - 600 to -900 mV.
  • the washing solution comprises the catholyte in combination with tap water and additives, wherein the pH of the catholyte is from 11.3 to 12.5 and the ORP of said catholyte to Platinum, relative to Ag/AgCI, is from -650 to -920 mV.
  • the additives added to the washing stage are grease remover, enzyme, optical brightener and CW
  • the required pH level of the washing solution in this phase is controlled by time control of electrical valves 32, 34, 35, 37, 61, 65, which is based on a response to the readings from pH sensor 77, 78, 79, 80 and 81.
  • the ratio of the water: catholyte is 1 : 1.
  • the washing step is performed under controlled and maintained pH and ORP. For example, if the pH of the washing solution drops from 11.5 to 10.8, pH sensor 77 measures the in situ pH of the washing solution in the washer and the PLC receives signals from the pH sensor and sends a signal back to valve 32 which allows more catholyte to feed into the washer and the pH is raised.
  • the pH and ORP are set to a set-point and the PLC adds one or more of an additive, water, catholyte and anolyte responsive to the pH change.
  • the washing stage takes 2 to 10 minutes and is performed at a temperature of 17 to 40 0 C.
  • At least one of a drain and a spin step is performed in the drum washer 41 or 42 to evacuate the spent washing solution prior to the next step.
  • the wet clothes remain in the drum washer for all steps in flowchart 300.
  • At least one drain step is performed in the tunnel washer 67 to evacuate the spent washing solution prior to the next step.
  • the wet clothes are passed from the washing zone to the next zone (disinfect and bleach zone) prior to the starting of the next step.
  • a bleaching and disinfection solution is added to the washer, having a pH of from 2.1 to 2.5 and ORP to Platinum, relative to Ag/AgCI, of from +750 to +1160 mV.
  • the bleaching and disinfection solution comprises the anolyte from tank 31 in combination with tap water.
  • the pH of the anolyte ranges from 1.7 to 2.4 and/or ORP to Platinum, relative to Ag/AgCI, of from +800 to +1200 mV.
  • the disinfecting and bleaching step takes 2 - 8 minutes and is performed at a temperature of 17 - 4O 0 C.
  • At least one of a drain and a spin step is performed in the drum washer 41 or 42 to evacuate the spent disinfect and bleach solution prior to the next step.
  • the wet clothes remain in the drum washer for all steps in flowchart 300.
  • At least one drain step is performed in the tunnel washer 67 to evacuate the spent disinfect and bleach solution prior to the next step.
  • the wet clothes are passed from the disinfect and bleach zone to the next zone (rinse zone) prior to the starting of the next step.
  • a rinsing solution is passed into the washer, wherein said rinsing solution comprises CW from tank by pump 8 and electrical valve 34, catholyte through electrical valve 32 and softener (softener tank and valve is not shown on Fig.1 and Fig.2).
  • Commercial softeners used according to this invention are 20 - 30%, which are 70% less than the requirements of prior art processes.
  • the rinsing step may include several rinse, drain and spin sub-steps as are known in the art.
  • steps 310-340 take from 8 to 18 minutes in the drum washer and from 10 to 24 minutes in the tunnel washer as function of the tunnel construction.
  • An optional drying step may be performed after step 340, which is performed at 80 -120 0 C over a time of 3 - 18 minutes. This drying step is much shorter than the drying steps of the prior art. Without being bound or limited to any theory, this may be because the surface tension of the catholyte is much less than that of tap water and thus is energetically less bound to the fabrics or clothes after the rinsing step.
  • Fig. 4 is a simplified flowchart 400 showing sub-steps of step 310 of Fig. 3.
  • a reverse osmosis step 410 tap water is fed into a reverse-osmosis module 1.
  • the function of the reverse osmosis step is to clean the tap water from Ca and Mg.
  • a first electrolysis step 420 one or more of tap water and reverse osmosis water from step 410 are fed via pumps 7 and 8 into apparatus 2a and 2b.
  • Salts added to the water from salt tank 4 such that the resultant saline solution comprises NaCI at a concentration of from 0.5 to2.5 g/l and KNO 3 at a concentration of from 0.5 to 2.5 g/l.
  • a current is passed between the electrodes (anode and cathode) 3a, 3b, 4a, 4b such that electrochemical reactions occur.
  • Ions generated at the anode are cations and chemical agents, such as, but not limited to HOCI, HCI, Cl 2 , H + , HO 2 , H 3 O+, Na + , and K + .
  • the following types of anions are generated OH ' , H 3 O 2 " , NO 3 " , CO 3 2" , SO 4 2" , CIO " .
  • These cations and anions may react together in one or more neutralization reactions resulting in an aqueous solution, comprising reactions products such as NaOCI, NaOH, KOH, H 2 O, HOCI etc., with a pH about of from 8.0 to 9.0 at outlet nozzle 6 of membrane-less apparatus exit.
  • a membrane electrolysis step is performed.
  • the aqueous solution from nozzle 6a and 6b in step 420 is fed into apparatus 20.
  • a current is applied and an anolyte and catholyte solution form at anode 23 and cathode 24 respectively.
  • the pH level of the resultant catholyte is typically in the range of 11.3 to 12.5 and ORP to Platinum, relative to Ag/AgCI, in the range of from -650 to -920 mV.
  • the pH level of the resultant anolyte is typically in the range of from 1.7 to 2.4, and ORP to Platinum, relative to Ag/AgCI, of from +800 to +1200 mV.
  • washing cycle parameters matched to type and quantity of clothes Very dirty clothes, such as hospital blood-stained laundry may require enzymes to denature blood proteins.
  • Prior art processes for such laundry needed to be carried out at a pH of 8.6, with a working temperature to 50 0 C.
  • a chemical bleacher and an optical brightener at a pH of 9.6 and a working temperature of from 60 to 90 0 C.
  • the prior art process can be replaced by the washing/laundering step 320 with the addition of the required enzymes and optical brightener in the catholyte solution at temperature of about 30 or 35 0 C (taking into account higher catalytic ability of catholyte).
  • Mineral grease can be removed by adding any kind of solvent at a pH of 10.0 as an additive to the catholyte solution in step 320.
  • Fabric softening can be achieved in several different ways, according to some embodiments of the present invention: a) the catholyte may be added to water at ratio of from 1 :9 to 9:1 and the resultant catholyte solution may be used as a rinsing medium; b) a softener may be added to an anolyte solution at pH of 3.5 in a quantity of 3 to 5 fold less in comparison to regular washing. c) Additives may be added to the membrane electrolysis apparatus 12 in a quantity of from 7 to 10 fold less compared to regular washing.
  • any specific disinfectants e.g. as ALCOXIDINE (skin disinfectant).
  • Yet another advantage of the present invention over the prior art is the reduction in drying time of clothes washed according to the method of the present invention. This has been verified experimentally and may be due to the fact that the surface tension of the catholyte is only 36x10 "3 N/m relative to tap water 72x10 "3 N/m.
  • Yet another advantage of the present invention over the prior art is the use of two electrolytic stages (2a, 2b and 20), thus producing the anolyte and catholyte by consecutively passing saline water through first the membrane-less electrolysis apparatus 2a wherein there is precipitation of Ca and Mg carbonates. Thereafter the solution is passed through the anode and cathode chambers of the membrane electrolysis apparatus 20, having a membrane between the anode and cathode chambers.
  • This arrangement allows for a decrease in the quantity of carbonate precipitation on the cathode of membrane electrolysis apparatus 20, thus improving quality of Electrochemically Activated Water and extending the operating time of apparatus 20.
  • Another functional advantage of the two stage electrolytic cell arrangement is that the pH level of the catholyte from the membrane electrolysis apparatus is significantly higher (11.3 to 12.5) than that of a one-stage process (8-9).
  • a structural advantage of the electrolysis apparatus of the present invention is in the use of an anode coating comprising RuO 2 and IrO 2 in a ratio of approximately 1 :1.
  • This anode coating allows production of chloric oxidants, chloric - oxygen oxidants and oxygen oxidants by various reactions from NaCI and KNO 3 , the salts used in the electrolysis process.
  • membrane electrolysis apparatus 20 is constructed such that the ratio of the inlet cross-section nozzle to outlet nozzles is 1 :2, and this, in turn, provides protection to the inlet piping from hydraulic shock, due to gases generated from the electrolytic reactions. This arrangement also provides a freer exit of the catholyte and the anolyte to their respective storage tank 30, 31.
  • FIG. 5 is a simplified flowchart 500 of a method for catholyte recycling of a second laundering process in accordance with some embodiments of the present invention.
  • a second washing process 510 typically takes place in a drum washing system 100 of Fig. 1 or in a tunnel washing system 200 of Fig. 2.
  • these systems comprise at least one membrane-less and one membrane electrolytic apparatus 2a, 2b and 20 respectively.
  • the second washing process step 510 is performed on soiled linen or other soiled articles.
  • the first washing process depletes certain chemicals from the catholyte solution in which the first washing process is performed and thus a replenished catholyte solution 584 is used in step 510 to perform the second and any further washing steps.
  • the method for forming solution 584 will be explained further hereinbelow.
  • the washing step may be performed in drum washers 41 , 42 of Fig. 1 or tunnel washer 67 of Fig. 2.
  • This second washing step 510 is typically performed under conditions similar or identical to first washing step 320 of Fig. 3.
  • Replenished catholyte solution 584 is normally of a pH from 10.8 to 11.8 and an ORP to Platinum, relative to Ag/AgCI, of from - 600 to -900 mV.
  • the washing solution comprises the catholyte in combination with tap water and additives, wherein the pH of the catholyte is from 11.3 to 12.5 and the ORP of said catholyte to Platinum, relative to Ag/AgCI, is from -650 to -920 mV.
  • the additives added to the second washing stage are grease remover , enzyme, optical brightener and CW by means of electrical valve 34 or 37 or 62.
  • the required pH level of the washing solution in this phase is controlled by time control of electrical valves 32, 35, and 61, which is based on a response to the readings from pH sensor 77, 78 and 79.
  • the washing step is performed under controlled and maintained pH and ORP. For example, if the pH of the washing solution drops from 11.5 to 10.8, pH sensor 77 measures the in situ pH of the washing solution in the washer and the PLC receives signals from the pH sensor and sends a signal back to valve 32 which allows more catholyte to feed into the washer and the pH is raised.
  • this washing step 510 takes 2 to 10 minutes and is performed at a temperature of 17 to 40 0 C.
  • Other sub-steps such as draining and spinning may be performed as described hereinabove with respect to step 320 (Fig. 3).
  • waste catholyte solution may be passed into a holding tank or may be directly filtered in a filtering step 520 and solids and/or sludge 525 is removed there from.
  • the filter 50 (Fig. 1) used is a self- cleansing filter such as model 2"TAF-500H, Amiad Filtrarion Systems, CA, employing a 80 ⁇ m filter.
  • a filtered waste catholyte stream 524 is fed to a holding tank, such as holding tank 44 (Fig. 1).
  • the stream 524 may be held in holding step 530 for 1 to 24 hours.
  • the filtered waste catholyte 524 may be mixed with water, additives and salt solution.
  • a filtered waste catholyte stream 534 may be fed to a membrane-less electrolysis apparatus, such as apparatus 2b (Fig. 1) and water 542 and salt solution 546 may be added at the entry thereto or in the chamber thereof.
  • the waste catholyte stream is replenished with water and salt solution using pH and ORP control such that these properties of solution 534, after replenishment, fall within predetermined limits.
  • the resultant replenished mixed catholyte solution 534 may have, for example, a pH range of between 8 and 1 and its OPR may be in the range of ORP to Platinum, relative to Ag/AgCI, of from - 500 to -850 mV (verify).
  • a membrane-less electrolysis step 540 electrolysis is performed to solution 534 under conditions similar or identical to the conditions for performing step 420 of Fig. 4.
  • a catholyte solution 544 forms having the following properties: a pH range of between 8-11.5 and its ORP may be in the range of - 500 to 860 mV of Platinum, relative to Ag/AgCI.
  • Catholyte solution 544 may be filtered in a filtration step 550 employing a filter 2"TAF-500H, Amiad Filtrarion Systems, CA, employing a 80 ⁇ m filter.and waste sludge or solids 555 may be discarded. According to some embodiments, this step may not be performed.
  • a resultant filtered catholyte solution 554 is fed into a membrane electrolytic apparatus 20 for a second electrolytic step 560. This step may be performed under similar or identical conditions of step 430 of Fig. 4 hereinabove.
  • the resultant catholyte solution 564 forms.
  • Catholyte solution 564 typically has the following properties: pH level of the resultant catholyte is typically in the range of 11.3 to 12.5 and ORP to Platinum, relative to Ag/AgCI, in the range of from -650 to -920 mV.
  • Catholyte solution 564 is fed into a holding tank and when required a stream thereof 574 is mixed in a mixing step 580 with water 582 and additives 586.
  • the additives added to the washing stage may be, for example, grease remover, enzyme , optical brightener and CW by means of electrical valve 34 or 37 or 62.
  • the required pH level of the washing solution in this phase is controlled by time control of electrical valves 32, 35 and 62, which is based on a response to the readings from pH sensor 77, 78 or 79.
  • the ratio of the water: catholyte is 1 : 1.
  • the resultant replenished catholyte solution (or washing solution) 584 may then be fed into the next washing step 510.
  • Fig. 6 is a simplified flowchart 600 of a method for anolyte recycling of a second or subsequent bleaching/disinfecting process, in accordance with some embodiments of the present invention.
  • a second bleaching/disinfecting process 610 typically takes place in a drum washing system 100 of Fig. 1 or in a tunnel washing system 200 of Fig. 2.
  • these systems comprise at least one membrane-less and one membrane electrolytic apparatus 2a, 2b and 20 respectively.
  • the second bleaching/disinfecting step 510 is performed on soiled linen or other soiled articles after the second washing step.
  • the first bleaching/disinfecting process depletes certain chemicals from the anolyte solution in which the first bleaching/disinfecting process is performed and thus a replenished anolyte solution 684 is used in step 610 to perform the second and any further bleaching/disinfecting steps.
  • the method for forming solution 684 will be explained further hereinbelow.
  • Bleaching/disinfecting step 684 may be performed in drum washers 41 or 42 of Fig. 1 or tunnel washer 67 of Fig. 2.
  • This second bleaching/disinfecting step 620 is typically performed under conditions similar or identical to first washing step 330 of Fig. 3.
  • Replenished anolyte solution 684 is normally of a pH in the range of from 1.7 to 2.4, and ORP to Platinum, relative to Ag/AgCI, of from +800 to +1200 mV.
  • a bleaching and disinfection solution is added to the washer, having a pH of from 2.1 to 2.5 and ORP to Platinum, relative to Ag/AgCI, of from +750 to +1160 mV.
  • the bleaching and disinfection solution typically comprises the anolyte from tank 31 in combination with tap water.
  • the pH of the anolyte ranges from 1.7 to 2.4 and/or ORP to Platinum, relative to Ag/AgCI, of from +800 to +1200 mV.
  • the disinfecting and bleaching step takes 2 - 8 minutes and is performed at a temperature of 17 - 4O 0 C.
  • the additives added to the second washing stage are grease remover, enzyme, optical brightener and CW by means of electrical valve 75, 76 or 63.
  • the required pH level of the washing solution in this phase is controlled by time control of electrical valves 33, 36 or 64,, which is based on a response to the readings from pH sensor 77, 78 or 79.
  • waste anolyte solution 614 may be passed into a holding tank 43 or may be directly filtered in a filtering step 620 and solids and/or sludge 625 is removed therefrom.
  • a filter 49 (Fig. 1) is used is a self-cleansing filter such as model 2"TAF-500H, Amiad Filtrarion Systems, CA, employing a 80 ⁇ m filter.
  • a filtered waste anolyte stream 624 is fed to a holding tank, such as holding tank 43 (Fig. 1).
  • the stream 624 may be held in holding step 630 for 1 to 24 hours.
  • the filtered waste anolyte 624 may be mixed with water, additives and salt solution.
  • a filtered waste anolyte stream 634 may be fed to a membrane-less electrolysis apparatus, such as apparatus 2a (Fig. 1) and effluent 646 and salt solution 648 may be added at the entry thereto or in the chamber thereof.
  • the waste anolyte stream is replenished with effluent and salt solution using pH and ORP control such that these properties of solution 634 after replenishment fall within predetermined limits.
  • the resultant replenished mixed anolyte solution 634 may have, for example, a pH range of between 2.5 to 3.8 and/or ORP to Platinum, relative to Ag/AgCI, of from +600 to +850 mV.
  • a membrane-less electrolysis step 640 electrolysis is performed to solution 634 under conditions similar or identical to the conditions for performing step 420 of Fig. 4.
  • An anolyte solution 644 forms having the following properties: a pH range of between 3-5 and its ORP may be in the range of - 400 to 600 mV of Platinum, relative to Ag/AgCI.
  • Anolyte solution 644 may be filtered in a filtration step 650 employing a filter (give details) and waste sludge or solids 655 may be discarded. According to some embodiments, this step may not be performed.
  • a resultant filtered anolyte solution 654 is fed into a membrane electrolytic apparatus 20 for a second electrolytic step 660.
  • This step may be performed under similar or identical conditions of step 430 of (Fig. 4) hereinabove.
  • the resultant anolyte solution 664 forms.
  • Anolyte solution 664 typically has the following properties: pH level of the resultant anolyte is typically in the range of 1.7 to 2.4 and/or ORP to Platinum, relative to Ag/AgCI, of from +800 to +1200 mV.
  • Anolyte solution 664 is fed into a holding tank 31 and when required a stream thereof 674 is mixed in a mixing step 680 with CW 682 and additives 686.
  • the resultant replenished anolyte solution (or washing solution) 684 may then be fed into the next washing step 610.
  • Fig. 7 is a simplified flowchart 700 of a method for rinse solution recycling of a second laundering process, in accordance with some embodiments of the present invention.
  • a waste rinse solution is formed 714.
  • the rinse solution may be filtered in a filtering step 720.
  • Solids or sludge 725 may be discarded and a filtered waste rinse solution may then be mixed in a mixing step 730 with CW 732, a catholyte solution 736 and additives, such as softeners 738.
  • a resultant replenished rinse solution 734 is formed which may be used in a second and/or subsequent rinsing step(s) 710.
  • steps of flowcharts 500, 600 and 700 may be repeated for one or more consecutive laundry cycles. These cycles may be performed immediately one after the other or there may be time gaps in between the cycles, during which the solutions are held in the appropriate holding tanks.
  • Electrochemical Activation it is electrolysis of all kinds of liquids with small amount of salts for producing electrochemically activated (energetically exited) liquids such as anolyte and catholyte by applying a voltage of from 5V to 100,000V in accordance with liquids characteristics.
  • EAW Electrochemically Activated Water - electrochemically activated (energetically exited) liquids such as anolyte and catholyte
  • ECAC Electrochemical Activator - a certain type of electrolyzer for the production of anolyte and catholyte
  • Anode chamber - a half-cell of the activator wherein anolyte is produced
  • the invention further contemplates a machine- readable memory tangibly embodying a program of instructions executable by the machine for executing the method of the invention.

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Abstract

La présente invention concerne un procédé de blanchissage contrôlé par ordinateur consistant à : (i) introduire dans un appareil de lavage au moins une solution de catholyte et au moins une solution d'anolyte provenant d'au moins un appareil d'électrolyse ; (ii) laver au moins un article en effectuant un premier procédé de blanchissage dans ledit appareil de lavage, ledit premier procédé de blanchissage comprenant : d) une étape de lavage dans au moins une première solution comprenant ladite ou lesdites solutions de catholyte ce qui produit une solution de catholyte usée ; e) une étape de blanchiment/désinfection dans une deuxième solution comprenant ladite ou lesdites solutions d'anolyte ce qui produit une solution d'anolyte usée ; et f) une étape de rinçage dans une solution de rinçage ce qui produit une solution de rinçage usée ; pour produire un article pratiquement propre, au moins l'un du pH et du potentiel d'oxydoréduction (ORP) du catholyte introduit dans ladite étape de lavage ou de l'anolyte introduit dans ladite étape de blanchiment/désinfection étant suivi pratiquement en continu pour maintenir au moins l'un du pH et de l'ORP dans au moins l'une desdites étapes au moins en partie en ajustant la quantité d'au moins l'un du catholyte et de l'anolyte introduits respectivement dans chacune desdites étapes ; et (iii) recycler au moins l'une de ladite solution de catholyte usée et de ladite solution d'anolyte usée via ledit ou lesdits appareils d'électrolyse vers ledit appareil de lavage pour permettre une réutilisation au moins partielle d'au moins l'une de ladite solution de catholyte usée et de ladite solution d'anolyte usée dans un deuxième procédé de blanchissage ou dans un procédé de blanchissage subséquent.
PCT/IL2008/000785 2007-06-19 2008-06-10 Systèmes et procédés pour le blanchissage avec recyclage Ceased WO2008155755A1 (fr)

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IL184046A IL184046A (en) 2007-06-19 2007-06-19 Method and systems with cycle
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ITMI20081282A1 (it) * 2008-07-15 2010-01-16 Industrie De Nora Spa Processo di trattamento di reflui industriali
US20120266388A1 (en) * 2011-04-20 2012-10-25 General Electric Company Fabric softener sensing and reuse of grey water from the rinse cycle of a washing machine
US8496853B2 (en) 2010-12-21 2013-07-30 Ecolab Usa Inc. Corrosion inhibition of hypochlorite solutions
US8557178B2 (en) 2010-12-21 2013-10-15 Ecolab Usa Inc. Corrosion inhibition of hypochlorite solutions in saturated wipes
US8603392B2 (en) 2010-12-21 2013-12-10 Ecolab Usa Inc. Electrolyzed water system
WO2018081709A1 (fr) * 2016-10-30 2018-05-03 Skypoint Usa Llc Système de récupération d'eau
NL2025116B1 (en) * 2020-03-12 2021-10-19 Spectro B V Fluid dispenser
WO2025151663A1 (fr) * 2024-01-09 2025-07-17 Spraying Systems Co. Flux d'entrée durables pour système de production électrolytique

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CN121023789B (zh) * 2025-10-31 2025-12-30 长虹美菱股份有限公司 一种带桶自清洁功能的洗衣机

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20081282A1 (it) * 2008-07-15 2010-01-16 Industrie De Nora Spa Processo di trattamento di reflui industriali
WO2010007038A1 (fr) * 2008-07-15 2010-01-21 Industrie De Nora S.P.A. Procédé pour traiter des eaux usées industrielles
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US8557178B2 (en) 2010-12-21 2013-10-15 Ecolab Usa Inc. Corrosion inhibition of hypochlorite solutions in saturated wipes
US8603392B2 (en) 2010-12-21 2013-12-10 Ecolab Usa Inc. Electrolyzed water system
US20120266388A1 (en) * 2011-04-20 2012-10-25 General Electric Company Fabric softener sensing and reuse of grey water from the rinse cycle of a washing machine
US9334600B2 (en) * 2011-04-20 2016-05-10 General Electric Company Fabric softener sensing and reuse of grey water from the rinse cycle of a washing machine
WO2018081709A1 (fr) * 2016-10-30 2018-05-03 Skypoint Usa Llc Système de récupération d'eau
NL2025116B1 (en) * 2020-03-12 2021-10-19 Spectro B V Fluid dispenser
WO2025151663A1 (fr) * 2024-01-09 2025-07-17 Spraying Systems Co. Flux d'entrée durables pour système de production électrolytique

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WO2008155755A4 (fr) 2009-02-12
IL184046A0 (en) 2008-01-20

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