WO2009043496A3 - Sinterstabiler katalysator für die hydrierung und dehydrierungen und verfahren zu dessen herstellung - Google Patents

Sinterstabiler katalysator für die hydrierung und dehydrierungen und verfahren zu dessen herstellung Download PDF

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Publication number
WO2009043496A3
WO2009043496A3 PCT/EP2008/007954 EP2008007954W WO2009043496A3 WO 2009043496 A3 WO2009043496 A3 WO 2009043496A3 EP 2008007954 W EP2008007954 W EP 2008007954W WO 2009043496 A3 WO2009043496 A3 WO 2009043496A3
Authority
WO
WIPO (PCT)
Prior art keywords
producing
same
hydrogenation
dehydrogenation reactions
resistant catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/007954
Other languages
English (en)
French (fr)
Other versions
WO2009043496A2 (de
Inventor
Aurel Wolf
Leslaw Mleczko
Jens Assmann
Frank Rauscher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer Technology Services GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US12/677,157 priority Critical patent/US20100204518A1/en
Application filed by Bayer Technology Services GmbH filed Critical Bayer Technology Services GmbH
Priority to JP2010527353A priority patent/JP5415425B2/ja
Priority to RU2010116815/04A priority patent/RU2480278C2/ru
Priority to CN200880110149A priority patent/CN101815575A/zh
Priority to EP08802454A priority patent/EP2200739A2/de
Priority to BRPI0817590-0A priority patent/BRPI0817590A2/pt
Publication of WO2009043496A2 publication Critical patent/WO2009043496A2/de
Publication of WO2009043496A3 publication Critical patent/WO2009043496A3/de
Anticipated expiration legal-status Critical
Priority to US13/625,972 priority patent/US20130035511A1/en
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/05—Metallic powder characterised by the size or surface area of the particles
    • B22F1/054—Nanosized particles
    • B22F1/056—Submicron particles having a size above 100 nm up to 300 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/16—Metallic particles coated with a non-metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10—Processes characterised by the sequence of their steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Die Erfindung betrifft einen neuartigen thermostabilen Palladium-Katalysator, ein Verfahren zu dessen Herstellung und dessen Einsatz in Hydrierungen speziell, Hydrierungen von Nitroverbindungen. Der Katalysator umfasst mindestens einen nanopartikulären Palladium-Cluster, der mit einer gas- und flüssigkeitdurchlässige Hülle enthaltend Zirkoniumoxid ummantelt wird.
PCT/EP2008/007954 2007-10-04 2008-09-20 Sinterstabiler katalysator für die hydrierung und dehydrierungen und verfahren zu dessen herstellung Ceased WO2009043496A2 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
US12/677,157 US20100204518A1 (en) 2007-10-04 2008-09-09 Sintering resistant catalyst for use in hydrogenation and dehydrogenation reactions and methods for producing the same
JP2010527353A JP5415425B2 (ja) 2007-10-04 2008-09-20 水素化および脱水素化反応において使用する焼結耐性触媒ならびにその製造方法
RU2010116815/04A RU2480278C2 (ru) 2007-10-04 2008-09-20 Не подверженный спеканию катализатор гидрирования и дегидрирования и способ его получения
CN200880110149A CN101815575A (zh) 2007-10-04 2008-09-20 用于氢化和脱氢反应的烧结稳定的催化剂及其制备方法
EP08802454A EP2200739A2 (de) 2007-10-04 2008-09-20 Sinterstabiler katalysator für die hydrierung und dehydrierungen und verfahren zu dessen herstellung
BRPI0817590-0A BRPI0817590A2 (pt) 2007-10-04 2008-09-20 Catalisador estável à sinterização para hidrogenação e desidrogenação e processo para a sua produção
US13/625,972 US20130035511A1 (en) 2007-10-04 2012-09-25 Process for hydrogenating organic compounds with hydrogen in the gas phase in the presence of a catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007047434A DE102007047434A1 (de) 2007-10-04 2007-10-04 Sinterstabiler Katalysator für die Hydrierung und Dehydrierungen und Verfahren zu dessen Herstellung
DE102007047434.4 2007-10-04

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/625,972 Division US20130035511A1 (en) 2007-10-04 2012-09-25 Process for hydrogenating organic compounds with hydrogen in the gas phase in the presence of a catalyst

Publications (2)

Publication Number Publication Date
WO2009043496A2 WO2009043496A2 (de) 2009-04-09
WO2009043496A3 true WO2009043496A3 (de) 2009-06-18

Family

ID=40386027

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/007954 Ceased WO2009043496A2 (de) 2007-10-04 2008-09-20 Sinterstabiler katalysator für die hydrierung und dehydrierungen und verfahren zu dessen herstellung

Country Status (8)

Country Link
US (2) US20100204518A1 (de)
EP (1) EP2200739A2 (de)
JP (1) JP5415425B2 (de)
CN (1) CN101815575A (de)
BR (1) BRPI0817590A2 (de)
DE (1) DE102007047434A1 (de)
RU (1) RU2480278C2 (de)
WO (1) WO2009043496A2 (de)

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DE102008060259A1 (de) 2008-12-03 2010-06-10 Bayer Technology Services Gmbh Katalysator für Oxidationsreaktionen in Gegenwart von Chlorwasserstoff und/oder Chlor und Verfahren zu dessen Herstellung, sowie dessen Verwendung
DE102009056700A1 (de) 2009-12-02 2011-06-16 Bayer Technology Services Gmbh Katalysator bestehend aus Silikathüllen und darin befindlichen, räumlich orientierten Nanopartikeln einer Rutheniumverbindung
CN101972651B (zh) * 2010-10-20 2012-06-13 中南民族大学 一种金属钯纳米材料催化剂及其制备和应用
US9415442B2 (en) * 2011-04-11 2016-08-16 Council Of Scientific & Industrial Research Stable oxide encapsulated metal clusters and nanoparticles
CN103480369B (zh) * 2012-06-13 2015-05-20 中国石油天然气股份有限公司 一种铂纳米复合催化剂及其制备和应用
CN103990453A (zh) * 2014-05-30 2014-08-20 南京工业大学 一种催化加氢用催化剂制备方法
US9433932B2 (en) 2014-08-29 2016-09-06 National Cheng Kung University Hydrogenation catalyst and method of manufacturing the same
US9827562B2 (en) 2015-10-05 2017-11-28 GM Global Technology Operations LLC Catalytic converters with age-suppressing catalysts
US9855547B2 (en) 2015-10-05 2018-01-02 GM Global Technology Operations LLC Low-temperature oxidation catalysts
US10046310B2 (en) 2015-10-05 2018-08-14 GM Global Technology Operations LLC Catalytic converters with age-suppressing catalysts
US10422036B2 (en) 2015-10-23 2019-09-24 GM Global Technology Operations LLC Suppressing aging of platinum group metal particles in a catalytic converter
US9901907B1 (en) 2016-08-31 2018-02-27 GM Global Technology Operations LLC Catalytic converters with age-suppressing catalysts
US10159960B2 (en) 2016-10-25 2018-12-25 GM Global Technology Operations LLC Catalysts with atomically dispersed platinum group metal complexes
US10035133B2 (en) 2016-10-25 2018-07-31 GM Global Technology Operations LLC Catalysts with atomically dispersed platinum group metal complexes and a barrier disposed between the complexes
CN109833879B (zh) * 2017-11-24 2021-08-06 中国石油化工股份有限公司 一种渣油加氢催化剂及其制备方法
CN110252272B (zh) * 2019-06-17 2022-04-22 万华化学集团股份有限公司 一种连续大规模制备烯烃环氧化催化剂的方法及装置
CN112934220B (zh) * 2021-02-05 2022-10-04 浙江工业大学上虞研究院有限公司 一种中空型钯催化剂微球的制备方法
CN112958081B (zh) * 2021-02-05 2022-10-14 浙江工业大学上虞研究院有限公司 一种中空型复合钯催化剂的制备方法
CN112958080B (zh) * 2021-02-05 2022-10-11 浙江工业大学上虞研究院有限公司 一种介孔型钯催化剂的制备方法
CN116351441B (zh) * 2023-03-21 2024-07-02 北京化工大学 具有协同位点负载型选择性加氢催化剂及其制备方法和应用
CN116060137B (zh) * 2022-11-23 2023-10-27 中国农业大学 用于液体有机储氢材料加氢与脱氢的纳米金属催化剂及其制备方法和应用

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Also Published As

Publication number Publication date
RU2480278C2 (ru) 2013-04-27
EP2200739A2 (de) 2010-06-30
RU2010116815A (ru) 2011-11-10
DE102007047434A1 (de) 2009-04-09
JP5415425B2 (ja) 2014-02-12
US20100204518A1 (en) 2010-08-12
JP2010540232A (ja) 2010-12-24
WO2009043496A2 (de) 2009-04-09
US20130035511A1 (en) 2013-02-07
BRPI0817590A2 (pt) 2015-03-31
CN101815575A (zh) 2010-08-25

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