WO2009045744A3 - In-situ methods of generating water through the dehydration of metal salt hydrates for moisture crosslinking of polyolefins - Google Patents

In-situ methods of generating water through the dehydration of metal salt hydrates for moisture crosslinking of polyolefins Download PDF

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Publication number
WO2009045744A3
WO2009045744A3 PCT/US2008/076861 US2008076861W WO2009045744A3 WO 2009045744 A3 WO2009045744 A3 WO 2009045744A3 US 2008076861 W US2008076861 W US 2008076861W WO 2009045744 A3 WO2009045744 A3 WO 2009045744A3
Authority
WO
WIPO (PCT)
Prior art keywords
dehydration
polyolefins
metal salt
generating water
salt hydrates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2008/076861
Other languages
French (fr)
Other versions
WO2009045744A2 (en
Inventor
Eric P Wasserman
Bharat I Chaudhary
Michael B Biscoglo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Priority to EP08836737A priority Critical patent/EP2195380B1/en
Priority to AT08836737T priority patent/ATE552296T1/en
Priority to JP2010527039A priority patent/JP5395085B2/en
Priority to US12/679,539 priority patent/US8541491B2/en
Priority to CN200880117587.7A priority patent/CN101874071B/en
Publication of WO2009045744A2 publication Critical patent/WO2009045744A2/en
Publication of WO2009045744A3 publication Critical patent/WO2009045744A3/en
Anticipated expiration legal-status Critical
Priority to US13/970,900 priority patent/US8889775B2/en
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/125—Water, e.g. hydrated salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/057—Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • C08K5/57—Organo-tin compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2343/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Derivatives of such polymers
    • C08J2343/04—Homopolymers or copolymers of monomers containing silicon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Insulated Conductors (AREA)
  • Organic Insulating Materials (AREA)

Abstract

Compositions comprising a polymer resin comprising at least one copolymer with hydrolysablε groups, a water-generating meial salt hydrate, and a catalyst that comprises a metal atom and at least two ligands taken from the set alkyjoxy and carboxylate are used to form articles that moisture-cure through in-situ generation of water via dehydration of the metal hydrate. The compositions are melt mixed to promote the dehydration and start the cure process during the mixing step. The curing compositions are formed and allowed to harden.
PCT/US2008/076861 2007-09-28 2008-09-18 In-situ methods of generating water through the dehydration of metal salt hydrates for moisture crosslinking of polyolefins Ceased WO2009045744A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP08836737A EP2195380B1 (en) 2007-09-28 2008-09-18 In-situ methods of generating water through the dehydration of metal salt hydrates for moisture crosslinking of polyolefins
AT08836737T ATE552296T1 (en) 2007-09-28 2008-09-18 IN-SITU PROCESS FOR GENERATING WATER BY DEHYDRATION OF METAL HYDRATES FOR MOISTURE CROSSLINKING OF POLYOLEFINS
JP2010527039A JP5395085B2 (en) 2007-09-28 2008-09-18 In situ generation of water by dehydration of metal salt hydrates for moisture cross-linking of polyolefins
US12/679,539 US8541491B2 (en) 2007-09-28 2008-09-18 In-situ methods of generating water through the dehydration of metal salt hydrates for moisture crosslinking of polyolefins
CN200880117587.7A CN101874071B (en) 2007-09-28 2008-09-18 In-situ methods of generating water through the dehydration of metal salt hydrates for moisture crosslinking of polyolefins
US13/970,900 US8889775B2 (en) 2007-09-28 2013-08-20 In-situ methods of generating water through the dehydration of metal salt hydrates for moisture crosslinking of polyolefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US97588007P 2007-09-28 2007-09-28
US60/975,880 2007-09-28

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/679,539 A-371-Of-International US8541491B2 (en) 2007-09-28 2008-09-18 In-situ methods of generating water through the dehydration of metal salt hydrates for moisture crosslinking of polyolefins
US13/970,900 Division US8889775B2 (en) 2007-09-28 2013-08-20 In-situ methods of generating water through the dehydration of metal salt hydrates for moisture crosslinking of polyolefins

Publications (2)

Publication Number Publication Date
WO2009045744A2 WO2009045744A2 (en) 2009-04-09
WO2009045744A3 true WO2009045744A3 (en) 2009-05-22

Family

ID=40381817

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2008/076861 Ceased WO2009045744A2 (en) 2007-09-28 2008-09-18 In-situ methods of generating water through the dehydration of metal salt hydrates for moisture crosslinking of polyolefins

Country Status (7)

Country Link
US (2) US8541491B2 (en)
EP (1) EP2195380B1 (en)
JP (1) JP5395085B2 (en)
CN (1) CN101874071B (en)
AT (1) ATE552296T1 (en)
TW (1) TWI476222B (en)
WO (1) WO2009045744A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102142299B (en) * 2005-09-13 2013-09-04 陶氏环球技术有限责任公司 Distannoxane catalysts for silane crosslinking and condensation reactions
WO2012005671A1 (en) * 2010-07-05 2012-01-12 Laprotech Ab Laparoscopic instrument
JP6146089B2 (en) * 2013-03-28 2017-06-14 三菱化学株式会社 Silanol condensation catalyst and silane cross-linked polyolefin
CN105722905B (en) 2013-11-25 2019-10-08 陶氏环球技术有限责任公司 Moisture and peroxide crosslinkable polymer composition
US10119015B2 (en) 2014-06-18 2018-11-06 Dow Global Technologies Llc Moisture-curable polymeric compositions having halogenated polymers and metal mercaptides
KR102396102B1 (en) 2014-06-27 2022-05-11 다우 글로벌 테크놀로지스 엘엘씨 Stabilized moisture-curable polymeric compositions
EP3383943A1 (en) 2015-11-30 2018-10-10 Dow Global Technologies, LLC Stabilized moisture-curable polymeric compositions
BR112018010300B1 (en) 2015-12-09 2022-02-01 Dow Global Technologies Llc Crosslinkable polymeric composition of silane and coated conductor
JP7461194B2 (en) * 2020-03-27 2024-04-03 株式会社オートネットワーク技術研究所 Metal crosslinked polymer composition, metal crosslinked polymer material, metal member, wire harness, and method for producing metal crosslinked polymer material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4594382A (en) * 1984-11-16 1986-06-10 The Dow Chemical Company Thermally stabilized carboxyl-containing ethylene copolymers and preparation thereof
EP1298169A1 (en) * 2000-06-28 2003-04-02 Three Bond Co., Ltd. Cold-setting composition
WO2005082989A1 (en) * 2004-02-17 2005-09-09 Clariant International Ltd Polyolefin compositions comprising hydrated inorganic or organic compounds for the prevention of discoloration

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US649662A (en) * 1899-07-10 1900-05-15 Leo Ehrlich Elevator.
US3225018A (en) 1961-12-15 1965-12-21 Union Carbide Corp Heat curing of ethylene/vinylsilane copolymers
BE794718Q (en) 1968-12-20 1973-05-16 Dow Corning Ltd OLEFINS CROSS-LINKING PROCESS
US4144202A (en) 1977-12-27 1979-03-13 Union Carbide Corporation Dielectric compositions comprising ethylene polymer stabilized against water treeing with epoxy containing organo silanes
US4591620A (en) * 1982-05-26 1986-05-27 The British Petroleum Company P.L.C. Copolymer, a film forming composition and a method of coating a surface with the composition
GB8400149D0 (en) 1984-01-05 1984-02-08 Bp Chem Int Ltd Polymer composition
JP2700265B2 (en) * 1989-01-11 1998-01-19 鐘淵化学工業株式会社 Curable resin composition
US5246783A (en) 1991-08-15 1993-09-21 Exxon Chemical Patents Inc. Electrical devices comprising polymeric insulating or semiconducting members
DE69719665T2 (en) * 1996-11-01 2004-02-05 Kaneka Corp. Crosslinkable polymer with reactive silicon-containing functional groups
JP3774559B2 (en) * 1998-01-30 2006-05-17 株式会社カネカ Curable composition
US6496629B2 (en) 1999-05-28 2002-12-17 Tycom (Us) Inc. Undersea telecommunications cable
US6331597B1 (en) 1999-08-09 2001-12-18 The Dow Chemical Company Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom
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US6714707B2 (en) 2002-01-24 2004-03-30 Alcatel Optical cable housing an optical unit surrounded by a plurality of gel layers
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Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4594382A (en) * 1984-11-16 1986-06-10 The Dow Chemical Company Thermally stabilized carboxyl-containing ethylene copolymers and preparation thereof
EP1298169A1 (en) * 2000-06-28 2003-04-02 Three Bond Co., Ltd. Cold-setting composition
WO2005082989A1 (en) * 2004-02-17 2005-09-09 Clariant International Ltd Polyolefin compositions comprising hydrated inorganic or organic compounds for the prevention of discoloration

Also Published As

Publication number Publication date
US8541491B2 (en) 2013-09-24
TW200922954A (en) 2009-06-01
US20100203276A1 (en) 2010-08-12
US20130334738A1 (en) 2013-12-19
EP2195380A2 (en) 2010-06-16
EP2195380B1 (en) 2012-04-04
CN101874071A (en) 2010-10-27
TWI476222B (en) 2015-03-11
JP2011501765A (en) 2011-01-13
JP5395085B2 (en) 2014-01-22
ATE552296T1 (en) 2012-04-15
WO2009045744A2 (en) 2009-04-09
CN101874071B (en) 2012-09-05
US8889775B2 (en) 2014-11-18

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