WO2009053972A1 - Charbon actif modifié en tant qu'adsorbant pour polluants inorganiques anioniques et cationiques - Google Patents

Charbon actif modifié en tant qu'adsorbant pour polluants inorganiques anioniques et cationiques Download PDF

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WO2009053972A1
WO2009053972A1 PCT/IL2008/001370 IL2008001370W WO2009053972A1 WO 2009053972 A1 WO2009053972 A1 WO 2009053972A1 IL 2008001370 W IL2008001370 W IL 2008001370W WO 2009053972 A1 WO2009053972 A1 WO 2009053972A1
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activated carbon
modified
gac
mmole
cationic
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Giora Rytwo
Yotam Gonen
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TOXSORB Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • B01J20/3251—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulphur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • B01J20/3253—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such comprising a cyclic structure not containing any of the heteroatoms nitrogen, oxygen or sulfur, e.g. aromatic structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • B01J20/3255—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such comprising a cyclic structure containing at least one of the heteroatoms nitrogen, oxygen or sulfur, e.g. heterocyclic or heteroaromatic structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3441—Regeneration or reactivation by electric current, ultrasound or irradiation, e.g. electromagnetic radiation such as X-rays, UV, light, microwaves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/24—Carbon, coal or tar
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/18—Carbon, coal or tar
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • C02F1/683—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of complex-forming compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/103—Arsenic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/12—Halogens or halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds
    • C02F2101/22—Chromium or chromium compounds, e.g. chromates
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/305—Endocrine disruptive agents

Definitions

  • the present invention is in the field of water treatment and purification and, more particularly, relates to modified activated carbon sorbents and to an adsorption method for removal of heavy metal complexes and anionic and cationic inorganic pollutants from water sources by the modified activated carbon sorbents.
  • Activated carbon is a natural material derived from bituminous coal, lignite, wood, coconut shell, etc., activated by several means. Carbon particles are "activated” by exposing them to an activating agent, such as steam at high temperature. This process develops a porous, three- dimensional graphite lattice structure. The size of the pores depends on the exact treatment. Longer exposure times result in larger pore sizes.
  • GAC Granular activated carbon
  • Powdered Activated Carbon is made up of crushed or ground carbon particles, 95- 100% of which will pass through a designated mesh sieve or sieves.
  • GAC Powdered Activated Carbon
  • PAC is not commonly used in filtering devices due to low hydraulic conductivity that causes high head loss.
  • PAC is generally added directly to other process units, such as raw water intakes, rapid mix basins, clarifiers, and gravity filters.
  • GAC in granular form, is designated by sizes for liquid phase extruded or vapor phase applications.
  • the most popular aqueous phase carbons are the 12X40 and 8X30 sizes because they have a good balance of size, surface area, and head loss characteristics (USEPA, 2001).
  • Activated carbon in general is considered an effective adsorbent for organic molecules but not for metals and inorganic compounds (Monser and Adhum, 2002).
  • Several works have suggested different modifications for activated carbon by various chemical treatments, and a list of such modifications is reviewed by Yin et al. (2005). Such modifications might result in different physical and chemical properties and therefore different sorption characteristics (Mien et al., 1998; Ca ⁇ êts et al., 2006; Monser and Adhum, 2002; Basar et al., 2003).
  • Acid treated activated carbon (Calgon F400, Calgon Carbon Corp., USA) was shown to have different sorption characteristics for phenol due to changes in the functional groups on the AC surface (Ca ⁇ êts et al., 2006).
  • Basar et al. (2003) studied the effect of modification of AC by surfactants on the electrostatic properties of the surface (zeta potential) and concluded that adsorption of ionic surfactants by hydrophobic interactions might lead to charged AC surface
  • US 6,881,348 describes a method for removing perchlorate or other anionic contaminants from a fluid which comprises the step of passing the fluid over activated carbon, wherein the activated carbon has been either preloaded with an organic cation functional group or organic cation polymer or cationic monomer, or tailored with ammonium or other reduced nitrogen-containing compound.
  • US 7,157,006 discloses such a method wherein the activated carbon material has been loaded with an organic cation polymer or cationic monomer having thereon functional groups; and regenerating said cation-loaded activated carbon material via thermal treatment, wherein said cation-loaded activated carbon material has a bed volume life of at least about 10% of initially treated cation-loaded activated carbon material.
  • US 2006/102562 and WO 2006/047613 describe a method for removing at least one oxyanion from a fluid comprising passing said fluid over a carbonaceous material that has been loaded with or preconditioned with at least one ionic organic species or hydroxide species and at least one metal or alkaline earth metal or halide.
  • US 5,705,269 discloses modified activated carbon material for removing bacteria from a liquid, comprising activated carbon fiber having an organic bactericidal compound selected from the group consisting of brilliant green, rivanol, benzyl alcohol and zephiran containing active bactericidal groups physically adsorbed thereon, said modified carbon material being capable of binding undesirable bacteria and thus removing same from said liquid.
  • the present invention provides a modified activated carbon sorbent for removing a heavy metal complex and anionic and/or cationic inorganic contaminants from a fluid, said sorbent comprising activated carbon modified by an agent selected from:
  • a cationic modifier or a salt thereof selected from crystal violet, berberine, methylene blue, benzalkonium, tetraphenylphosphonium, malachite green or methyl green;
  • an anionic modifier or a salt thereof selected from fast green, erythrosine
  • a chelant selected from phenanthroline, 2,2'-bipyridyl, a free-base porphyrin, histidine, malic acid, a glutathione-derived metal binding peptide (phytochelatin), EDTA (ethylenediaminetetraacetic acid) or NTA (nitrilotriacetic acid).
  • the activated carbon for use as a sorbent according to the invention may be powdered activated carbon (PAC) or granular activated carbon (GAC), and it may be virgin or regenerated.
  • PAC powdered activated carbon
  • GAC granular activated carbon
  • the activated carbon is modified by a cationic modifier as defined above and is useful for removing, for example, oxyanions such as, but not limited to, chromate, perchlorate, arsenate, phosphate, nitrate, borate or selenate.
  • oxyanion is chromate, perchlorate or arsenate.
  • the activated carbon is modified by an anionic modifier as defined above and is useful for removing, for example, cationic inorganic pollutant such as heavy metal Cd, Pb, Hg, Cu, Ni, Co, Mn, Fe, Ag or Au, or NH 4 + compounds, or mixtures thereof, preferably Cu or Ni compounds.
  • anionic modifier such as heavy metal Cd, Pb, Hg, Cu, Ni, Co, Mn, Fe, Ag or Au, or NH 4 + compounds, or mixtures thereof, preferably Cu or Ni compounds.
  • the activated carbon is modified by a chelant as defined above and is useful for removing, for example, heavy metal complexes, e.g., CdCl 2 0 , Hg(OH) 3 " , and the like, and/or heavy metal cationic inorganic pollutants as defined above.
  • a chelant as defined above and is useful for removing, for example, heavy metal complexes, e.g., CdCl 2 0 , Hg(OH) 3 " , and the like, and/or heavy metal cationic inorganic pollutants as defined above.
  • the present invention relates to a method for treating a fluid containing heavy metal complexes, anionic and/or cationic inorganic pollutants and optionally organic compounds, or mixtures thereof, comprising treating said contaminated fluid with a modified activated carbon sorbent as defined above.
  • the invention provides a method for recovery and regeneration for further use of an exhausted column comprising a modified activated carbon sorbent of the invention saturated with the adsorbed pollutant, for further use of the modified sorbent and, if desired, recovery of the pollutant, e.g., chromate from the effluent of electroplating industry, for further use.
  • the present invention provides an additional method for recovery and regeneration for extended use of a sorbing column comprising a modified activated carbon sorbent of the invention with enhanced reduction of specific pollutants on the sorbent, leading to decomposition of the hazardous pollutant to non-hazardous species, e.g., perchlorate to chlorine or nitrate to nitrogen, enabling extended use without accumulation of the pollutant
  • Fig 1 shows adsorption isotherms of chromate to unmodified PAC (triangles), PAC modified by crystal violet (PAC-CV-03, squares) and PAC modified by berberine (PAC-BER-04, circles).
  • Fig. 2 shows adsorption isotherms of 2,4,5-trichlorophenol to PAC (rhombus), PAC-CV-03 (squares) and PAC-CV-03 previously saturated with Cr (triangles).
  • Fig. 3 shows chromate adsorption versus time on PAC-CV-03 (open symbols) and PAC-BER-04 (full symbols) with initial Cr concentrations of 100 ⁇ M (triangles) and 50 ⁇ M (squares).
  • Fig. 5 shows adsorption isotherm of As to GACl (open squares), GAC l- BER-025 (full squares), GAC4-BER-033 (asterisks) and GAC4-MG-020 (triangles). Error bars represent triplicate standard deviations.
  • Fig. 6 shows breakthrough diagram of a 100 ⁇ M As solution on a GAC- BER-03 column with retention time of 18 seconds.
  • Fig. 7 shows breakthrough diagram of a 100 ⁇ M chromate solution on a GACl-BER-025 column with retention time of 18 seconds showing adsorption on a new column (rhombus) and in a regenerated column (squares) after 7 cycles of regeneration.
  • Figs. 8A-8B show removal of Cu (8A) and Ni (8B) from initial concentrations of 6750 ppb and 11400 ppb, using 10g/L or 20g/L sorbent, respectively. At such conditions, treatment with non-modified AC leaves -20% - 30% of the added pollutant in solution, whereas treatment with several activated carbons (based on GAC3) modified by a chelant achieves total removal.
  • Activated carbon in general is considered an effective adsorbent for organic molecules but not for metals and inorganic molecules.
  • a modification is performed on either powdered (PAC) or granular activated carbon (GAC) aiming to add to the sorbents the ability of removing inorganic pollutants.
  • the modification of AC according to the invention is performed by the binding of an ionic or polar aromatic molecule to the activated carbon matrix.
  • This organic modifier should consist of a hydrophobic part based on one or several separated or fused aromatic rings, which anchors the modifier to the AC, and an ionic or polar part, which interacts with the pollutant.
  • organic dyes have been selected as detailed below, but similar compounds with such characteristics would also be suitable and are encompassed by the present invention.
  • the modification is performed by using a cationic modifier, for example, a salt of an organic dye such as berberine chloride, crystal violet chloride, malachite green oxalate, methylene blue chloride or methyl green chloride, or another cationic compound such as tetraphenylphosphonium chloride or benzalkonium chloride, in order to remove anionic pollutants such as chromate, arsenate, perchlorate, phosphate, nitrate, borate, selenate, and the like.
  • a cationic modifier for example, a salt of an organic dye such as berberine chloride, crystal violet chloride, malachite green oxalate, methylene blue chloride or methyl green chloride, or another cationic compound such as tetraphenylphosphonium chloride or benzalkonium chloride, in order to remove anionic pollutants such as chromate, arsenate, perchlorate, phosphate, nitrate, borate,
  • Crystal violet or CV is a triphenylmethane dye found in gentian violet and is also called hexamethyl pararosaniline chloride.
  • Berberine a yellow dye, is an isoquinoline alkaloid found in some medicinal plants.
  • Malachite green is a synthetic dye also called aniline green, basic green 4, diamond green B, or victoria green B.
  • Benzalkonium chloride is a mixture of alkylbenzyl dimethylammonium chlorides of various alkyl chain lengths, commonly used as an antiseptic and spermicide.
  • Methylene blue is a bright greenish blue organic dye belonging to the phenothiazine family and used in biology in staining procedures.
  • Tetraphenylphosphonium can be abbreviated Ph 4 P+ or PPh 4 +.
  • the modification is performed by using an anionic modifier, for example, a salt, e.g. sodium salt, of anionic dyes such as fast green, acid yellow, or amaranth in order to remove cationic pollutants such as mercury, lead, nickel, cupper, cadmium, and the like.
  • anionic modifier for example, a salt, e.g. sodium salt, of anionic dyes such as fast green, acid yellow, or amaranth in order to remove cationic pollutants such as mercury, lead, nickel, cupper, cadmium, and the like.
  • Fast green is an acid arylmethane dye.
  • Erythrosine B or tetraiodofluorescein is a fluorescent red acid dye.
  • the Acid Yellow dye is preferably Acid Yellow 14.
  • Amaranth or 2-hydroxy-l,r-azonaphthalene-3,6,4'-trisulfonic acid trisodium salt, is also called Acid Red 27.
  • the modification is performed by using a chelant.
  • chelation refers to the binding or complexation of a bi- or multidentate ligand to metals by bonds that might be coordination bonds, ionic bonds or a combination thereof.
  • These ligands usually multifunctional organic compounds, are called chelants, chelators, chelating agents, or sequestering agent and these terms may be used interchangeable herein.
  • the chelating agent is selected from phenanthroline, 2,2'-bipyridyl, free-base porphyrin, histidine, malic acid, a glutathione-derived metal binding peptide (phytochelatins), EDTA or NTA, in order to remove heavy metal pollutants such as mercury, lead, nickel, cadmium, copper and the like, either in cationic form or as complexes based on such metals.
  • Phenanthroline particularly 1, 10-phenanthroline, acts as a bidentate ligand in coordination chemistry and forms strong complexes with most metal ions. It is used in metallocene industry in several applications including coordination of organometallic-complexes, redox mediators in biosensors, catalysts for the oxidative organic synthesis, water treatment, photolysis chemistry, etc.
  • 2,2'-Bipyridine or bipyridyl is a bidentate chelating ligand that forms complexes with many transition metals.
  • Free-base porphyrins are known chelating agents forming complexes with transition and heavy metals.
  • the term "free base” is used for porphyrin in which no metal is inserted in its cavity.
  • Examples of free base porphyrins that can be used according to the invention include, but are not limited to, corphine, corroles, porphine, coproporphyrins, etc.
  • Phytochelatins are oligopeptides of glutathione found in plants, fungi, nematodes and all groups of algae including cyanobacteria. Phytochelatins act as chelators, and are important for heavy metal detoxification.
  • the modified sorbents exhibit impressive improved sorption characteristics for the pollutants above.
  • Cr oxyanions for example, complete removal was observed at the low concentration range, with very high selectivity for Cr.
  • the modification did not hinder the original excellent adsorption properties AC poses for phenol and several other organic pollutants.
  • the modification of GAC and PAC makes them suitable for removal of metal and other inorganic molecules, without hindering the capabilities of sorption of organic pollutants.
  • the modification is based on the adsorption of an organic molecule that has strong and almost irreversible interaction and that its addition to the AC at low concentration leaves no organic molecule remaining in solution at equilibrium.
  • Such organic molecules are also not released from the AC upon washing; thus, the modifier adsorbed concentration is not depleted.
  • Such organic compounds used as modifiers are either based on an aromatic cation and a non hazardous inorganic anion (as Cl " ), or on an aromatic anion and a non hazardous inorganic cation (as Na + ), or on industrially used chelants.
  • the organic molecules comprising an aromatic cation might be used for the removal of anionic inorganic pollutants as oxyanions, by exchanging them with the CI "
  • the anionic modifiers might be used for the removal of cationic inorganic pollutants such as heavy metals or ammonium, by exchanging them with the Na + .
  • Chelant modifiers might be very effective for the removal of heavy metals.
  • the modified platforms proposed were tested for chromate, arsenate, phosphate, perchlorate, nitrate, nickel, copper, etc. presenting good to excellent capabilities as for the amount of inorganic pollutant removal, and in several cases complete removal of the pollutant was observed at least at the low concentration range.
  • the modified sorbent consists of PAC and is suitable for use in batch systems.
  • the PAC is preferably modified by about 0.1-0.6 mmole modifier per g PAC.
  • the PAC is modified by crystal violet (CV) chloride or berberine (BER) chloride. More preferably, the PAC comprises 0.3 mmole CV per g PAC (herein PAC-CV-03) or 0.4 mmole BER per g PAC (herein PAC-BER-04).
  • PAC-CV-03 crystal violet
  • PAC-BER-04 berberine
  • These sorbents are very suitable for removal of chromate (Cr(VI)) and perchlorate while maintaining its capability of sorption of organic pollutants as shown herein in the examples.
  • the modified sorbent consists of GAC and is suitable for use in both batch systems and column filters.
  • the GAC is preferably modified by about 0.2-0.6 mmole modifier per g GAC.
  • the GAC is modified by crystal violet (CV) chloride or berberine (BER) chloride, more preferably the GAC comprises 0.2 mmole CV per g GAC (herein GAC l-CV-02), 0.25 mmole BER per g GAC (herein
  • GACl-BER-025) or 0.33 mmole BER per g GAC (herein GAC l-BER-033).
  • These sorbents are very suitable for removal of chromate (Cr(VI)), perchlorate and arsenate while maintaining its capability of sorption of organic pollutants as shown herein in the examples.
  • the GAC is modified by methyl green (MG) chloride or benzalkonium (Benz) chloride, more preferably the GAC comprises 0.2 mmole MG per g GAC (herein GAC2-MG-02) or 0.3 mmole Benz per g GAC
  • the AC after removing the pollutant from the polluted effluent, the AC may be regenerated from the cationic-modified sorbent by elution with high NaCl concentration brine.
  • the Cl " anions exchange the pollutant anions, which might be the treated or precipitated in high pollutant concentration brine, by usual methods (generally redox treatment).
  • a similar procedure of elution may be used in cationic polluted sorbents. Simultaneous organic/inorganic pollutant experiments demonstrate that the modified PAC and
  • GAC retain their ability to adsorb non-ionic organic compounds and both pollutants were adsorbed non-competitively (see Fig. 2).
  • the GAC is modified by phenantroline (Phen) or 2,2'-bipyridine (Bipy), more preferably the GAC comprises 0.6 mmole phenantroline per g GAC (herein GAC3-Phen-06) or 0.4 mmole 2,2'-bipyridine per g GAC (herein GAC3-Bipy-04).
  • Phen phenantroline
  • Bipy 2,2'-bipyridine
  • sorbents are suitable for removal of nickel and copper both in batch and in column systems as shown hereinafter in the examples.
  • Regeneration of chelant-based modified GAC is performed by means of a solution of other chelant, usually one with lower adsorption affinity to the activated carbon such as NTA or EDTA, but high affinity to the metal in case.
  • the solution is passed or circulated through the column until the majority of the pollutant is desorbed from the modified AC (concentrations and contact times may vary according to operating conditions).
  • the filter is washed with clean water in order to remove any remaining free chelant.
  • the column is then ready for reuse, whereas the regeneration solution might be treated by redox or acidification procedures, to release the metal from the eluting chelant (which might be reused), and induce precipitation.
  • Regeneration of the exhausted modified activated carbon may be done with GAC or PAC, with different conditions for each.
  • the present invention provides a method for removing contaminants selected from heavy metal complexes, anionic or cationic inorganic contaminants or mixtures thereof and optionally organic contaminants from a fluid, comprising treating said contaminated fluid with at least one modified activated carbon of the present invention.
  • the anionic and cationic inorganic contaminants are, for example, oxyanions selected from chromate, perchlorate, arsenate, phosphate, borate and the like or cationic compounds including heavy metal (Cd, Pb, Hg, Ni, Co, Mn, Fe, Ag, Au) and NH 4 + compounds, or mixtures thereof, and the heavy metal complexes are from metals such as Cd, Pb, Hg, Ni, Co, Mn, Fe, Ag, Au.
  • the modified activated carbon may be modified virgin or regenerated powdered or granular activated carbon.
  • the present invention comprises a method for treating a fluid for removal of anionic as well as cationic inorganic pollutants possibly along with heavy metal complexes comprising treating the fluid with a combination of several modified activated carbons in order to maximize removal of all pollutants present. It should be noted that one platform does not hinder the activity of the other(s), such that they can be combined in the same filtering device
  • the fluid to be treated according to the invention may be any contaminated water such as, but not limited to, potable water, tap water, bottled water, groundwater, surface water, industrial effluent, and agricultural or municipal wastewater and reservoirs.
  • the fluid may contain also organic compound contaminants besides the inorganic contaminants.
  • the modifier is a dye having biocidal activities such as crystal violet, berberine or methylene blue
  • the method of the invention will also be useful for removal of microorganisms, e.g., viruses, bacteria and fungi, from the fluid, and particularly to hinder or to overcome problems caused by biofouling of the sorbent.
  • the present invention also provides a method for regeneration of exhausted modified activated granular carbon saturated with a pollutant selected from chromate, arsenate, perchlorate or Ni, or a mixture thereof, comprising eluting a column of the modified GAC with a solution of a salt, preferably NaCl, KCl, or CaCl 2 recovering the pollutant from the collected effluent, and washing the excess of NaCl, KCl or CaCl 2 from the column, thus recovering the modified GAC column substantially free from adsorbed pollutants for further use.
  • the regeneration of the sorbent by washing with a salt solution can also be done with PAC in batch procedures. In some cases, regeneration of the sorbent may be performed by enhanced reduction of the pollutants to non-hazardous species such as the reduction of perchlorate to chlorine.
  • the modified activated carbon of the present invention has many uses and applications, including: (i) adsorption and complete removal of high amounts of oxyanions such as chromate, arsenate, perchlorate, nitrate, borate, selenate, and phosphate, as shown herein in the examples, while even high quality non-modified activated carbon is almost ineffective for the adsorption of those oxyanions that are severe pollutants;
  • the inorganic pollutants may be leached by eluting with a high concentration brine of a non-hazardous salt as NaCl, whereas in chelant based AC platforms the inorganic pollutants might be leached by eluting with a suitable free chelant.
  • the brine can be treated for the precipitation or removal of the inorganic pollutants, and in some cases, as with chromium, the recovered metal might be used as a resource.
  • those might be removed by the usual heating procedures of regeneration of PAC or GAC.
  • the modifying molecule is removed by heating, the remaining PAC or GAC might be re-modified and re-used. Such procedures make the sorbent more cost effective. Regeneration of the sorbent may also be performed by enhanced reduction of the pollutants to non-hazardous species.
  • each sorbent will be identified in the Examples herein by a XXX-YYY-000 notation.
  • the first group of letters (XXX) indicates the type of activated carbon used
  • the second group of letters (YYY) indicates the modifier molecule
  • the third group of algarisms (000) indicates the amount of modifier in units of mmole attached to the activated carbon in g.
  • PAC-CV-045 indicates powdered activated carbon with crystal violet adsorbed at 0.45 mmole CV per g PAC.
  • the modifiers are denoted by the following abbreviations: crystal violet (CV), berberine (Ber), methylene blue (MB), benzalkonium (Benz), tetraphenylphosphonium (TPP), malachite green (ML) and methyl green (MG), fast green (FG), Erythrosine B (EB), acid yellow (AY), amaranth (AM), phenantroline (Phen) and 2,2'-bipyridine (Bipy) (all modifiers were purchased from Sigma).
  • CV crystal violet
  • berberine Ber
  • MB methylene blue
  • Benz benzalkonium
  • TPP tetraphenylphosphonium
  • ML malachite green
  • MG malachite green
  • MG malachite green
  • MG malachite green
  • MG malachite green
  • MG malachite green
  • MG malachite green
  • MG malachite green
  • MG malachit
  • GAC granular activated carbon
  • PAC powdered activated carbon
  • the optimum loading of modifier is deduced from preliminary experiments (adsorption isotherms) of the modifier on the raw GAC as the maximum loading that did not yield "free" modifier in the equilibrium solution. Exact amounts of loadings depend on brand and type of AC and may change according to AC type, origin and particle size distribution. In addition, the influence of other parameters should be considered such as temperature, pH, ionic strength, ratio sorbent to liquid, etc. In types of AC and modifiers tested it ranged between 0.05 to 0.35 mmole modifier g "1 AC.
  • the cationic modifiers tested were: crystal violet (CV), berberine (Ber), methylene blue (MB), benzalkonium (Benz), tetraphenylphosphonium (TPP), malachite green (ML) and methyl green (MG).
  • the anionic modifiers tested (all in the sodium salt form) were: fast green (FG), Erythrosine B (EB), acid yellow (AY), and amaranth (AM).
  • the chelant modifiers tested were phenantroline (Phen) and 2,2'-bipyridine (Bipy).
  • GAC was weighed into a glass bottle to the desirable amount, the appropriate amount of modifier was added as powder, and distilled water, tap water or controlled ionic strength water was added. In our experiments we added 1 1 of water per 200 g AC, however the water to solid ratio is not critical. On the other hand, the ionic strength of the water used is an important parameter for optimization of the process. For example, tap water (EC«500 ⁇ Si/cm) instead of distilled water (DW ⁇ 10 ⁇ Si/cm) yielded higher amounts of modifier sorbed.
  • the bottle was placed on an orbital shaker and stirred until no free modifier was detected in the solution.
  • the concentration of modifier is monitored by UV- visible spectroscopy or any method that can detect the relevant molecules in solution. In our experiments the process took 12-48 h, depending on the modifier and the AC concentration.
  • the modified GAC that sorbed modifier molecules is separated from the solution.
  • the separation might be easily carried out by filtration.
  • the modified GAC is left to air dry.
  • the granules obtained are used to fill columns for use as filtering devices.
  • the above procedure yielded sorbent columns that were proved as very effective for adsorption of chromate, arsenate, and phosphate, and preliminary encouraging results for adsorption of iodine and nickel.
  • Further optimization of the process might be achieved by changing temperature and or/pH conditions, increasing the salt concentration of the water to simulate different water profiles (ionic strength/EC), changing the ratio GAC/water.
  • the optimum loading is not always the maximum loading. Steric considerations of the modifier adsorbed on the granular AC may lead to a better performance at lower loadings. In the case of modification by means of benzalkonium, for example, better pollutant (chromate and phosphate) removal was obtained at 67% of the maximum loading at the relevant conditions.
  • Perchlorate is an endocrine-disrupting compound (EDC) (Wolff, 1998) that is difficult to remove from water by standard water treatment practices (Urbansky, 1998). Most of the perchlorate manufactured in the United States is used as the primary ingredient of solid rocket propellant. Wastes from the manufacture of perchlorate-containing chemicals are increasingly being discovered in soil and water. Treatment systems designed to reduce perchlorate concentrations below the recommended 4 ppb quantitation level are based on biological treatment and ion (anion) exchange systems, with additional treatment technologies under development (EPA, 2007).
  • Table 1 shows results of a preliminary experiment performed in order to test the ability of three types of modified powdered ACs (PAC-CV-03, PAC-BER-04 and PAC-BER-05) and one granular AC (GACl-BER-025) in perchlorate removal in double-distilled water (DDW) containing 1000 ppb perchlorate or tap water containing 500 ppb perchlorate, as tested at the Israel Water Commission laboratory by the ion chromatography method. Perchlorate concentration was measured by ion chromatography with a limit of detection of 4 ppb.
  • non modified PAC is not suitable for perchlorate adsorption even in batch experiments, whereas three different modified AC were very effective, lowering the amounts on solution below the limit of detection (LOD) of the instrument.
  • Additional experiments with modified AC using tap water as a matrix demonstrate that the previous results obtained for modified PAC were achieved again, even when the ionic strength is higher than for distilled water.
  • Removal of perchlorate in tap water demonstrates the feasibility of the process even when other ions are present in the water (rows 6-7).
  • Unmodified GAC 1 removes relatively large amounts of perchlorate, but it should be considered that at this experiment sorbent concentration was relatively high. At the same conditions, modified GACl removes perchlorate below LOD.
  • Table 2 shows the results of an experiment where several volatile pollutants, at concentrations of 100 ppb each, were equilibrated in batch experiments with unmodified AC (PAC or GACl) or with modified AC (PAC-BER-04, GACl-CV- 025 or GACl-BER-03). Powder sorbents (columns 2,3) were added at concentrations of 1 g/1 whereas all granular sorbents (columns 4-6) were added at concentration of 5 g/1. The table presents the amounts of pollutant remaining after adsorption, as measured by purge and trap gas chromatography.
  • Adsorption isotherms of Cr(VI) were prepared in 10 ml glass tubes with plastic screw caps by adding 1 ml of continuously stirred sorbent: unmodified PAC, PAC-CV-03 or PAC-BER-04 (10 g/L), and the appropriate amount of chromate (added as dissolved K 2 CrO 4 salt). Distilled water was added to achieve a final volume of 10 ml, thus the sorbent final concentration was 1 g/L. The tubes were agitated on an orbital shaker for 24 h and then centrifuged (2000 RPM for 30 min). Following centrifugation the supernatant was measured for Cr(VI).
  • Fig. 1 presents the adsorption isotherms of chromate to the sorbents. All adsorption experiments were conducted in triplicates at room temperature and the sorbed concentration was calculated by a mass balance. As shown in Fig. 1, whilst Cr adsorption to the unmodified PAC is weak and does not present any range of complete removal, both modified adsorbents exhibit H-type isotherms indicating strong affinity of Cr to the modified adsorbents (Sparks, 1995).
  • the breakthrough curve of As from a column filter filled with GACl-BER- 03 is presented in Fig. 6.
  • the column retained As completely for approximately 120 pore volumes before breakthrough occurred.
  • the influent solution was tap water spiked with As to a concentration of 0.1 mM and the retention time 18 seconds.
  • a column filter filled with GAC4-MG-02 achieved complete removal of more than 250 pore volumes.
  • the adsorbent shown in Fig. 6 is the same as in Figs. 4 and 7, thus the same adsorbent may be useful for the removal of several oxyanions.
  • Example 5 Batch Ni and Cu removal with anionic modifier or chelant
  • chelant modifiers such as phenantroline (Phen) and 2,2'-bipyridine (Bipy).
  • Figs. 8A-B show almost complete to complete removal of very high concentration solutions of Cu and Ni, respectively, by several chelant-based modified activated carbon: AC-Phen- 03, AC-Phen-05, AC-Phen-08, AC-Bipy-02, AC-Bipy-04 and AC-Bipy-06 (Fig. 8A) and AC-Phen-03, AC-Phen-05, AC-Phen-08, AC-Phen-09, AC-Bipy-02 and AC-Bipy-04 (Fig. 8B). All ACs used here were prepared based on GAC3. Treatment with non-modified activated carbon at the same conditions left about 20- 30% of the heavy metals in solution.
  • the regeneration process of an exhausted modified GAC column after use and saturated with pollutant depends on the type of modification. In cases where modification was performed with cationic or anionic compounds as CV, BER,
  • Reuse of the pollutant is possible according to usual recycling processes. For example, recycle of chromate from the eluted solution was made by reducing it in an alkaline environment and collecting the Cr(OH) 3 precipitate. Experiments show that the procedure leads to a precipitate that might be easily separated from the NaCl washing solution and reused.
  • the electroplating industry generates effluent with high chromate concentrations from the process, and the Cr in this case is both a pollutant and a needed product.
  • the washing solution might be reused several times and the separated metal, in this case chromium, is thus reintroduced to the process.
  • Regenerated columns of this type were used in our laboratory at least for seven cycles, with a small decrease in performance between the first two cycles (see Fig. 7) and no further decrease afterwards.
  • the method was tested also for different pollutants (first cycle chromate, second arsenate, etc.).
  • Regeneration of chelant-based GAC or PAC was performed by a similar process, but the eluent was a solution of a chelant with relatively low adsorption affinity to the activated carbon such as NTA or EDTA.
  • the solution was circulated through the column for three to five pore volumes, until the majority of the pollutant was desorbed from the modified AC (concentrations and contact times vary according to operating conditions).
  • the filter was washed with clean water in order to remove any remaining of free chelant.
  • the column was then ready for the next cycle.
  • the chelant may be reclaimed from the regeneration solution by changing redox or acidity conditions of the regeneration solution.
  • NTA-based regeneration solution lowering the pH by concentrated HCl releases the bound metal, leading to precipitation of NTA, which might be recollected. Suitable redox process might lead to precipitation of the metal, and removal by appropriate means.
  • Fig. 7 shows a breakthrough diagram of a 100 ⁇ M chromate solution on a
  • GACl-BER-03 column with retention time of 18 seconds, showing adsorption on a new column (rhombus) and in a regenerated column (squares) after 7 cycles of regeneration.

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Abstract

La présente invention a pour objet un charbon actif modifié par un modificateur cationique ou anionique ou par un chélatant, qui est utilisé en tant que sorbant pour éliminer d'un fluide des complexes de métaux lourds et des contaminants inorganiques anioniques et/ou cationiques et facultativement des contaminants organiques.
PCT/IL2008/001370 2007-10-22 2008-10-22 Charbon actif modifié en tant qu'adsorbant pour polluants inorganiques anioniques et cationiques Ceased WO2009053972A1 (fr)

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WO2011018514A1 (fr) * 2009-08-14 2011-02-17 Hansgrohe Ag Procédé pour traiter des déchets ou des eaux usées contenant des agents tensio-actifs
EP2298441A3 (fr) * 2009-08-21 2012-05-30 Samsung Electronics Co., Ltd. Système de filtre d'eau potable, son procédé de régénération et dispositif de purification de l'eau incluant le système de filtre d'eau potable
EP2478956A1 (fr) * 2011-01-21 2012-07-25 Samsung Electronics Co., Ltd. Dispositif d'absorption régénérable et son procédé de commande
WO2014128702A1 (fr) 2013-02-21 2014-08-28 Toxsorb Ltd. Enlèvement de perchlorate contenu dans des liquides industriels aqueux
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