WO2009113473A1 - Composition d'huile de laminage pour le travail des métaux - Google Patents

Composition d'huile de laminage pour le travail des métaux Download PDF

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Publication number
WO2009113473A1
WO2009113473A1 PCT/JP2009/054385 JP2009054385W WO2009113473A1 WO 2009113473 A1 WO2009113473 A1 WO 2009113473A1 JP 2009054385 W JP2009054385 W JP 2009054385W WO 2009113473 A1 WO2009113473 A1 WO 2009113473A1
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Prior art keywords
rolling
oil composition
sulfur
rolling oil
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2009/054385
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English (en)
Japanese (ja)
Inventor
秀夫 杉井
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Idemitsu Kosan Co Ltd
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Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Priority to CN200980108838XA priority Critical patent/CN101970623A/zh
Publication of WO2009113473A1 publication Critical patent/WO2009113473A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/20—Thiols; Sulfides; Polysulfides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/20—Thiols; Sulfides; Polysulfides
    • C10M135/22—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M135/26—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Definitions

  • the present invention relates to a rolling oil composition for metal working, and in particular, relates to a rolling oil composition that is suitably used when rolling iron-based materials.
  • Patent Document 1 discloses a lubricating oil for metal working formed by blending a diester that is a reaction product of a specific dicarboxylic acid and a specific alcohol.
  • Patent Documents 2 and 3 disclose a cold rolling oil for stainless steel containing a specific diester and a specific alcohol.
  • the present invention has been made under such circumstances, a rolling oil composition having excellent rolling performance, that is, no surface damage occurs even when rolling is performed at a high rolling reduction, and the rolling load is reduced.
  • An object of the present invention is to provide a rolling oil composition that contributes to the above.
  • the present inventor has found that the above problem can be solved by using a specific sulfur-containing compound as an additive. Furthermore, in general, sulfur-containing compounds have a problem of low solubility in oil, and mist is likely to be generated during rolling, and the working environment is deteriorated due to a bad odor. The inventors have found that the problem can be solved by specifying a compound, and have completed the present invention. That is, the present invention provides the following rolling oil composition. 1.
  • R 1 OOC—R 2 —S x —R 3 —COOR 4 (I) Wherein R 1 and R 4 are each independently a hydrocarbon group having 1 to 20 carbon atoms, R 2 and R 3 are each independently a hydrocarbon group having 0 to 6 carbon atoms, and x is 1 to Indicates an integer of 3.)
  • a rolling oil composition for metal working comprising 0.01 to 70% by mass of a sulfur-containing compound represented by the following formula: 2.
  • the rolling oil composition according to 1 above, wherein x of the sulfur-containing compound represented by the general formula (I) is 2; 3.
  • a rolling oil composition that does not cause surface damage even when rolling is performed at a high rolling reduction and contributes to a reduction in rolling load.
  • the rolling oil composition solves the problems related to odor while using a sulfur-based additive. Therefore, according to the rolling oil composition of the present invention, (1) the rolling reduction can be increased and productivity can be improved, (2) the rolling load can be reduced, and energy consumption can be suppressed, (3 ) The above-mentioned excellent rolling performance can be achieved without lowering the working environment.
  • the base oil used in the present invention is not particularly limited, and can be appropriately selected from mineral oil, synthetic oil and fat according to the purpose of use and use conditions.
  • Mineral oils include, for example, residual oil obtained by atmospheric distillation of paraffin-based crude oil, intermediate-based crude oil, or naphthenic-based crude oil, or distillate oil obtained by vacuum distillation of residual oil of atmospheric distillation or Examples include refined oils obtained by refining according to the method, such as solvent refined oil, hydrogenated refined oil, dewaxed oil, and clay-treated oil.
  • Synthetic oils include, for example, poly- ⁇ -olefins having 8 to 14 carbon atoms, olefin copolymers (for example, ethylene-propylene copolymers), branched olefins such as polybutene and polypropylene, hydrides thereof, and polyol esters ( Trimethylolpropane fatty acid ester, pentaerythritol fatty acid ester, and the like), alkylbenzene, and the like can be used.
  • Examples of fats and oils include beef tallow, lard, soybean oil, rapeseed oil, rice bran oil, coconut oil, palm oil, palm kernel oil, and hydrides thereof.
  • the base oil one kind of the mineral oil may be used, two or more kinds may be used in combination, one kind of the synthetic oil may be used, or two or more kinds may be used in combination,
  • the fats and oils may be used singly or in combination of two or more.
  • 2 or more types chosen from mineral oil, synthetic oil, and fats and oils can also be used together.
  • the base oil used in the present invention preferably has a kinematic viscosity at 40 ° C. in the range of 3 to 30 mm 2 / s. When this kinematic viscosity is 3 mm 2 / s or more, the flash point becomes high and the risk of fire due to ignition is small. On the other hand, when it is 30 mm 2 / s or less, there is little possibility of winding deviation. From the above points, it is more preferably 5 to 20 mm 2 / s.
  • R 1 and R 4 are each independently a hydrocarbon group having 1 to 20 carbon atoms. If the carbon number exceeds 20, the solubility tends to be poor. Further, the larger the number of carbons within the above range, the effect of preventing evaporation is obtained, and the number of carbons is preferably 2-18, more preferably 4-18.
  • the hydrocarbon group may be linear, branched or aromatic, and may be saturated or unsaturated.
  • R 2 and R 3 are each independently a divalent hydrocarbon group having 0 to 6 carbon atoms. If the number of carbon atoms exceeds 6, the solubility tends to be poor, and the effects of the present invention are difficult to obtain.
  • the number of carbon atoms is preferably 1 to 4, more preferably 1.
  • the divalent hydrocarbon group may be linear, branched, or aromatic, and may be saturated or unsaturated. In the case of a hydrocarbon group having 0 carbon atoms, it means a state in which the carbon atom and sulfur atom of the ester group are directly bonded.
  • R 1 and R 4 or R 2 and R 3 may be the same or different, but are preferably the same for reasons of production.
  • x is any one of 1 to 3. When x is 4 or more, problems are likely to occur in terms of odor and corrosivity. Accordingly, any of the sulfur-containing compounds having x of 1 to 3 may be used alone, or a mixture thereof may be used.
  • the sulfur-containing compound represented by the general formula (I) It is preferable to use a sulfur-containing compound where x is 2 as the compound.
  • the amount of the sulfur-containing compound in which x is 2 is preferably 70% by mass or more, more preferably 90% by mass or more, and particularly preferably 95% by mass or more based on the total amount of the sulfur-containing compound represented by the general formula (I). .
  • the sulfur-containing compound represented by the general formula (I) can be produced by a conventionally known method, but the sulfur-containing compound wherein x is 2 is preferably produced by the method shown below. That is, as a raw material, general formula (II) and / or general formula (III) R 1 OOC-R 2 -SH (II) R 4 OOC—R 3 —SH (III) (In the formula, R 1 and R 4 , R 2 and R 3 are the same as described above.) Oxidative coupling is performed using a sulfur-containing carboxylic acid ester represented by: According to such a production method, the sulfur-containing compound represented by the general formula (I) where x is substantially 2 is produced.
  • R 1 OOC—R 2 —S—S—R 3 —COOR 4 R 1 OOC—R 2 —S—S—R 2 —COOR 1 , R 4 OOC—R 3 —S—S— R 3 —COOR 4 is produced.
  • a commonly used oxidizing agent can be used.
  • oxygen, hydrogen peroxide, and dimethyl sulfoxide are preferable because they are inexpensive and easy to produce the target sulfur-containing compound.
  • sulfur-containing compound represented by the general formula (I) include bis (methoxycarbonylmethyl) disulfide, bis (ethoxycarbonylmethyl) disulfide, bis (n-propoxycarbonylmethyl) disulfide, and bis (isopropoxycarbonyl).
  • Methyl) disulfide bis (n-butoxycarbonylmethyl) disulfide, bis (n-octoxycarbonylmethyl) disulfide, bis (n-dodecyloxycarbonylmethyl) disulfide, bis (cyclopropoxycarbonylmethyl) disulfide, 1,1-bis (1-methoxycarbonylethyl) disulfide, 1,1-bis (1-methoxycarbonyl-n-propyl) disulfide, 1,1-bis (1-methoxycarbonyl-n-butyl) disulfide, 1,1-bisulfide (1-methoxycarbonyl-n-hexyl) disulfide, 1,1-bis (1-methoxycarbonyl-n-octyl) disulfide, 1,1-bis (1-methoxycarbonyl-n-dodecyl) disulfide, 2,2- Bis (2-methoxycarbonyl-n-propyl) disulfide, 1,
  • one of the sulfur-containing compounds represented by the general formula (I) may be used alone, or two or more may be used in combination.
  • the blending amount is 0.01 to 70% by mass based on the total amount of the rolling oil composition. If the amount is less than 0.01% by mass, the effect of the present invention may not be obtained. If the amount exceeds 70% by mass, an effect commensurate with it cannot be obtained, and an odor is likely to be a problem. From the above viewpoint, 0.1 to 50% by mass is more preferable, and 0.5 to 30% by mass is particularly preferable.
  • the rolling oil composition of the present invention may contain an oily agent in addition to the sulfur compound.
  • oily agent include monoesters and diesters.
  • RCOOR '(IV) In the formula, R represents an alkyl group having 11 to 22 carbon atoms, R ′ represents an alkyl group having 1 to 25 carbon atoms, and the total carbon number of R and R ′ is 12 to 47.
  • the preferred total carbon number of the monoester represented by the general formula (IV) is in the range of 13 to 36.
  • Specific examples of the monoester include methyl stearate, butyl stearate, octyl stearate, octyl palmitate and the like. Among these, butyl stearate is preferred from the viewpoint of performance and availability. Is preferred.
  • the content of the monoester in the rolling oil composition is preferably in the range of 0.5 to 40% by mass. If it is the said range, the reduction effect of the gloss nonuniformity of a rolled sheet and the improvement effect of heat-scratch-proof performance will be acquired.
  • the preferable content of the monoester is in the range of 3 to 30% by mass, and more preferably in the range of 5 to 20% by mass.
  • the diester examples include a reaction product of an aliphatic dicarboxylic acid having 12 to 28 carbon atoms composed of a saturated or unsaturated branched hydrocarbon chain in the main skeleton and a linear aliphatic alcohol having 1 to 6 carbon atoms. It is preferable that the carbon number of the aliphatic dicarboxylic acid is in the above range from the viewpoint of heat scratch resistance and solubility. From the above viewpoint, the preferred carbon number is 14 to 24, and further 16 to 20.
  • the aliphatic dicarboxylic acid has a branched chain as the main skeleton. By having the branched chain, there is an advantage that the solubility of the diester in the base oil is improved and a rolling oil composition having desired performance can be easily obtained.
  • the aliphatic dicarboxylic acid either saturated or unsaturated can be used.
  • a compound represented by the following general formula (V) can be preferably exemplified.
  • k is an integer of 0 to 3
  • m and n are integers of 1 to 23, respectively, and the sum of k, m, and n is an integer of 8 to 24.
  • aliphatic dicarboxylic acid having 12 to 28 carbon atoms the main skeleton of which is a saturated or unsaturated branched hydrocarbon chain
  • diesters include compounds represented by the following chemical formulas. Can do.
  • aliphatic alcohols having 1 to 6 carbon atoms are used. Within this range, solubility is improved. From the above viewpoint, the preferred carbon number is 1 to 4. Further, the aliphatic alcohol needs to be linear. Those having a branched chain are inferior in heat scratch resistance. Specific examples of such a linear aliphatic alcohol include methanol, ethanol, n-propanol, and n-butanol.
  • the content of the diester in the rolling oil composition is preferably in the range of 0.5 to 30% by mass. If it is the said range, the improvement effect of heat-scratch-proof performance will be acquired.
  • the preferable content of the diester is in the range of 1 to 20% by mass, and particularly preferably in the range of 1 to 15% by mass.
  • the rolling oil composition of the present invention preferably contains a phenolic antioxidant.
  • a phenolic antioxidant By blending a phenolic antioxidant, there is an effect of suppressing oxidative deterioration of the rolling oil composition.
  • phenolic antioxidants include 2,6-di-t-butylphenol, 2,6-di-t-butyl-p-cresol, 2,4-dimethyl-6-t-butylphenol, and the like. Of these, 2,6-di-t-butyl-p-cresol is particularly preferred.
  • the blending amount of the phenol-based antioxidant is preferably in the range of 0.01 to 5% by mass, more preferably in the range of 0.1 to 1% by mass, based on the total amount of the rolling oil composition.
  • the rolling oil composition of this invention can mix
  • the rust inhibitor and corrosion inhibitor include fatty acid, alkenyl succinic acid half ester, fatty acid soap, alkyl sulfonate, fatty acid amine, oxidized paraffin, alkyl polyoxyethylene ether, and the like.
  • the antifoaming agent include dimethylpolysiloxane and polyacrylate. These additives can be used singly or in combination of two or more. The amount of these additives is usually in the range of 0.1 to 10% by mass, preferably in the range of 0.1 to 5% by mass, based on the composition.
  • the viscosity of the rolling oil composition of the present invention is not particularly limited, but the kinematic viscosity at 40 ° C. is preferably 3 to 30 mm 2 / s, and more preferably 5 to 20 mm 2 / s.
  • the rolling oil composition may be used as it is, or an emulsion may be prepared by adding an emulsifier and water.
  • the emulsifier may be appropriately selected according to the purpose. For example, an anionic emulsifier, a cationic emulsifier, a nonionic emulsifier, or a mixture thereof can be used.
  • the rolling oil composition of the present invention can be preferably used as a rolling oil composition for metal working.
  • it is preferable to use it for rolling of various iron-based materials because it can be efficiently rolled even for hard materials, and an excellent surface appearance can be obtained.
  • it is used for rolling stainless steel.
  • it is preferable to use the rolling oil composition of the present invention as it is, and priority is given to efficiency as in the rolling of steel sheets. In such a case, it is preferable to prepare and use an emulsion.
  • Examples 1-7, Comparative Examples 1-6 As shown in Table 1, a sulfur-containing compound and other additives were blended with the base oil to obtain a rolling oil composition. The following evaluation tests were conducted using these as sample oils. The evaluation results are shown in Table 2. In Table 1, the compounding amount of each component when the total amount of the rolling oil composition is 100 parts by mass is expressed in parts by mass.
  • kinematic viscosity paraffinic mineral oils chalcogenides 8mm 2 / s 1 In the general formula (I), R 1 and R 4 is n- octyl group, R 2 and R 3 are CH 2 group, X Is a sulfur-containing compound in which R 2 is a sulfur-containing compound 2: a sulfur-containing compound in which R 1 and R 4 are n-butyl groups, R 2 and R 3 are CH 2 groups, and X is 2 in the general formula (I) 3 : Dimer sulfur-based compound of thiosalicylic acid n-octyl ester 4: Contains sulfur in general formula (I), wherein R 1 and R 4 are n-octyl groups, R 2 and R 3 are CH 2 groups, and X is 4 Compound sulfur-based compound 5: Polysulfide sulfur-based compound 6: Sulfurized olefin sulfur-based compound 7: Sulfurized oil and fat oil agent 1: Buty
  • Diester compound antioxidant represented by: DBPC (2,6-di-t-butyl-p-cresol)
  • the rolling oil composition of the present invention (1) rolling at a high pressure reduction rate is possible and productivity can be improved. (2) Since rolling load is reduced, energy consumption can be reduced. 3) The above-described excellent rolling performance can be achieved without lowering the working environment, and the present invention is suitably used in rolling.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

L'invention concerne une composition d'huile de laminage obtenue par mélange d'un composé contenant du soufre représenté par la formule générale (I) R1OOC-R2-SX-R3-COOR4 ··· (I) (dans laquelle R1 et R4 représentent indépendamment un groupe hydrocarboné contenant 1 à 20 atomes de carbone, R2 et R3 représentent indépendamment un groupe hydrocarboné contenant 0 à 6 atomes de carbone et x représente un entier de 1 à 3) dans l'huile de base en une quantité de 0,01 à 70 % en masse par rapport à la quantité totale de la composition. Lorsque la composition d'huile de laminage est utilisée, aucune détérioration de surface n'a lieu, même lorsque le laminage est réalisé avec un tirage élevé, et la charge de laminage peut être réduite.
PCT/JP2009/054385 2008-03-11 2009-03-09 Composition d'huile de laminage pour le travail des métaux Ceased WO2009113473A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200980108838XA CN101970623A (zh) 2008-03-11 2009-03-09 金属加工用压延油组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2008-061537 2008-03-11
JP2008061537A JP5529388B2 (ja) 2008-03-11 2008-03-11 金属加工用圧延油組成物

Publications (1)

Publication Number Publication Date
WO2009113473A1 true WO2009113473A1 (fr) 2009-09-17

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PCT/JP2009/054385 Ceased WO2009113473A1 (fr) 2008-03-11 2009-03-09 Composition d'huile de laminage pour le travail des métaux

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JP (1) JP5529388B2 (fr)
KR (1) KR20100122095A (fr)
CN (1) CN101970623A (fr)
WO (1) WO2009113473A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011111795A1 (fr) * 2010-03-12 2011-09-15 出光興産株式会社 Composition lubrifiante
CN115244158A (zh) * 2020-03-19 2022-10-25 出光兴产株式会社 金属加工油组合物

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58109597A (ja) * 1981-12-24 1983-06-29 Kawasaki Steel Corp 冷延鋼板用圧延油
JPS58109595A (ja) * 1981-12-24 1983-06-29 Kawasaki Steel Corp 冷延鋼板用圧延油
JPS6060193A (ja) * 1983-09-12 1985-04-06 Kawasaki Steel Corp 冷間圧延油
JPS61213294A (ja) * 1985-03-20 1986-09-22 Kao Corp 金属材料の冷間圧延用潤滑油
JPS61213296A (ja) * 1985-03-19 1986-09-22 Kao Corp 金属材料の冷間圧延用潤滑油
JPS61246293A (ja) * 1985-04-03 1986-11-01 Kao Corp 鉄鋼用冷間圧延油
JPS6213495A (ja) * 1985-07-12 1987-01-22 Kao Corp 金属材料の冷間圧延用潤滑油
WO2000056845A1 (fr) * 1999-03-19 2000-09-28 Yoshitomi Fine Chemicals, Ltd. Composition d'aide au travail du metal, contenant du thiodipropionate de dialkyle, et procede de travail du metal
JP2001152173A (ja) * 1999-11-30 2001-06-05 Sumitomo Metal Ind Ltd 冷間加工用潤滑剤
JP2001181665A (ja) * 1999-12-24 2001-07-03 Sumitomo Metal Ind Ltd 冷間加工用潤滑剤
JP2001288490A (ja) * 2000-04-05 2001-10-16 Yushiro Chem Ind Co Ltd 金属加工用潤滑油

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL75960C (fr) * 1951-04-23
JP3738643B2 (ja) * 2000-03-02 2006-01-25 住友金属工業株式会社 鋼材の冷間塑性加工用潤滑剤組成物
JP4981240B2 (ja) * 2003-02-05 2012-07-18 出光興産株式会社 潤滑油用及び燃料油用添加剤、並びに潤滑油組成物及び燃料油組成物

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58109597A (ja) * 1981-12-24 1983-06-29 Kawasaki Steel Corp 冷延鋼板用圧延油
JPS58109595A (ja) * 1981-12-24 1983-06-29 Kawasaki Steel Corp 冷延鋼板用圧延油
JPS6060193A (ja) * 1983-09-12 1985-04-06 Kawasaki Steel Corp 冷間圧延油
JPS61213296A (ja) * 1985-03-19 1986-09-22 Kao Corp 金属材料の冷間圧延用潤滑油
JPS61213294A (ja) * 1985-03-20 1986-09-22 Kao Corp 金属材料の冷間圧延用潤滑油
JPS61246293A (ja) * 1985-04-03 1986-11-01 Kao Corp 鉄鋼用冷間圧延油
JPS6213495A (ja) * 1985-07-12 1987-01-22 Kao Corp 金属材料の冷間圧延用潤滑油
WO2000056845A1 (fr) * 1999-03-19 2000-09-28 Yoshitomi Fine Chemicals, Ltd. Composition d'aide au travail du metal, contenant du thiodipropionate de dialkyle, et procede de travail du metal
JP2001152173A (ja) * 1999-11-30 2001-06-05 Sumitomo Metal Ind Ltd 冷間加工用潤滑剤
JP2001181665A (ja) * 1999-12-24 2001-07-03 Sumitomo Metal Ind Ltd 冷間加工用潤滑剤
JP2001288490A (ja) * 2000-04-05 2001-10-16 Yushiro Chem Ind Co Ltd 金属加工用潤滑油

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011111795A1 (fr) * 2010-03-12 2011-09-15 出光興産株式会社 Composition lubrifiante
JP2011190331A (ja) * 2010-03-12 2011-09-29 Idemitsu Kosan Co Ltd 潤滑油組成物
US9309481B2 (en) 2010-03-12 2016-04-12 Idemitsu Kosan Co., Ltd. Lubricant composition
CN115244158A (zh) * 2020-03-19 2022-10-25 出光兴产株式会社 金属加工油组合物

Also Published As

Publication number Publication date
JP5529388B2 (ja) 2014-06-25
CN101970623A (zh) 2011-02-09
JP2009215459A (ja) 2009-09-24
KR20100122095A (ko) 2010-11-19

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