WO2010037853A1 - Enrobé bitumineux à performance acoustique importante - Google Patents
Enrobé bitumineux à performance acoustique importante Download PDFInfo
- Publication number
- WO2010037853A1 WO2010037853A1 PCT/EP2009/062834 EP2009062834W WO2010037853A1 WO 2010037853 A1 WO2010037853 A1 WO 2010037853A1 EP 2009062834 W EP2009062834 W EP 2009062834W WO 2010037853 A1 WO2010037853 A1 WO 2010037853A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- bituminous
- aggregates
- mix according
- bituminous mix
- asphalt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/18—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
- E01C7/26—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre
- E01C7/265—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre with rubber or synthetic resin, e.g. with rubber aggregate, with synthetic resin binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/18—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
- E01C7/182—Aggregate or filler materials, except those according to E01C7/26
Definitions
- the present invention relates to a bituminous mix with improved acoustic performance intended to be integrated within a wearing course or a road surface.
- the invention is therefore in the technical field of public works and more particularly in the field of pavement construction.
- An asphalt mix is a mixture of aggregates (chippings, recycled materials, sand and sand) and a binder of bituminous, synthetic or vegetable origin, with or without additives.
- the sufficient quantity of binder to obtain 1 to 15 parts by weight of residual bitumen, is kneaded with 85 to 99 parts by weight of granulate (considering their dry weight).
- Additives may be added to either the binder, granulate or asphalt.
- the term "additive” is intended to mean products of the polymer type, vegetable waxes or of petrochemical origin, adhesion dopes. These mixes can be used hot (130 0 C to 180 0 C), warm (110 0 C to 130 0 C), semi-warm (80 0 C to 110 0 C), see cold (T ⁇ 80 ° C ).
- the aggregates are heated in devices called “dryers” in order to dry them, thus allowing good adhesion of the bitumen to the granulate.
- the bitumen is also heated, at temperatures of the order of 160 0 C to lower the viscosity and allow a good coating aggregates.
- the asphalt thus formed is then applied hot (typically at more than 140 ° C.) on the pavement and then compacted hot, the initially high temperature guaranteeing its maneuverability.
- the material stiffens as it cools.
- the aggregates are not dried, and are mixed as such, that is to say with their natural moisture and at room temperature.
- bitumen then comes in various forms, the most common being that of a bitumen emulsion which thus makes it possible to have a product that is not very viscous and therefore easy to handle at ambient temperature.
- the emulsion is sometimes slightly warmed at temperatures of the order of 50 ° C.
- Another means, still in use but little developed but in growth, is to foam the hot bitumen (typically 16O 0 C) in contact with a little water injected directly into the bitumen according to suitable processes, then to mix this foam with wet aggregates.
- Additives may be added to the bitumen and / or injected water to modify the properties of the foam, including its stability and volume.
- Aggregate means materials of various origins, including aggregates from quarries or gravel pits, recycling products such as aggregates from old asphalt milling, scrap manufacturing, materials from recycling construction materials (demolition concretes, etc.), slags, shales, artificial aggregates of any origin, for example from household waste incineration slag (MIOM), and mixtures thereof in all proportions. These aggregates can be dry or wet.
- the granulometry of the aggregates is chosen in the range 0 / D max , D max being the maximum diameter of the aggregate as defined according to standard XP P 18-540 and generally ranging from 4 to 31.5 mm.
- mineral or siliceous filler any mineral or siliceous filler, having a size less than 80 .mu.m, advantageously passing through a sieve square mesh of 0.063 mm side.
- the fines can be natural or additive fines, for example fine limestone (calcium carbonate), cement or hydrated lime, or recovery.
- Binder means a hydrocarbon binder, preferably of fossil origin, or any binder of plant or synthetic origin used for the production of asphalt, asphalt, putty, membrane.
- it is a pure bitumen, any composition containing bitumen and optionally one or more additives and / or one or more emulsifiers and / or one or more viscosifiants and / or one or more fluxers and / or one or more plasticizers and / or any other additive to adjust the properties thereof, such as adhesiveness.
- bitumens bitumens modified with elastomers and plastomers, bitumen emulsions and bitumen foam.
- This bituminous binder may be in liquid form or in the form of an emulsion or a foam.
- the bituminous binder is in the form of an emulsion or a foam.
- additive any product added in the binder and / or the final product, coated, asphalts, mastics, membranes.
- additives are used for mechanical purposes, ethylene copolymer (such as EVA, EBA, polyethylene, polypropylene), SBS, SB cross-linked or otherwise, polymers in general.
- ethylene copolymer such as EVA, EBA, polyethylene, polypropylene
- SBS cross-linked or otherwise
- tackifiers are used, for example emulsifiers derived from polyamines.
- the additives employed are, for example, natural oils that are chemically or non-chemically treated, zeolites or paraffin.
- the additives can also be used for aesthetic purposes, color change of the final products, by the use of natural or non-natural pigment, such as iron oxide for example.
- BCPC vehicle road tire contact noise
- BCPC pavement pneumatic contact noise
- Granulometry is defined as the maximum size of the aggregates used in the bituminous mix.
- An optimal particle size for the reduction of the BCPC is between 4 and 6 mm.
- void content is meant the volumetric percentage of vacuum between the asphalt elements.
- An optimal void content for the reduction of BCPC is between 18 and 25%.
- the present invention is based on these parameters, but the inventors have found that the acoustic absorption is further increased by the addition of low density materials, preferably exfoliated vermiculite or expanded perlite.
- the objective is to create a wearing course that reduces the noise pollution caused by road pneumatic contact noise (BCPC) and is resistant to road traffic as well as to climatic variations.
- BCPC road pneumatic contact noise
- bituminous mix comprising an amount of exfoliated vermiculite sufficient to improve its acoustic properties.
- the bituminous mix according to the invention makes it possible to produce a wearing course which has a great capacity for reducing noise pollution.
- exfoliated vermiculite (0.6% by weight)
- a coated base type draining 0/6 mm achieves an absorption frequency of the vibration of 90 Hz (in the impact stress test and frequency analysis used by the research center - see example 3), ie a LAmax measurement of between 69 dB (A) and 70 dB (A) (see FIG. between 2 and 3 dB (A) with respect to conventional acoustic mixes.
- this asphalt concrete has a traffic resistance meeting the standard for this type of asphalt, or 8.8% rut 3000 cycles for a specification ⁇ 20%.
- the present invention thus relates to a bituminous mix comprising a mineral and / or organic material of low bulk density of between 0.01 and 0.3 t / m 3 in an amount sufficient to improve its acoustic performance.
- the material with a low density of between 0.01 and 0.3 t / m 3 is an expanded natural rock not soluble in water, even partially.
- the expanded natural rock not soluble in water, even partially, is exfoliated vermiculite.
- Expanded perlite is excluded from the scope of the invention because it is partially soluble in water.
- Vermiculite is commercially available. Vermiculite is derived from a mineral of the micas family by heat treatment. Preferably, the expanded natural rock not soluble in water, even partially, has a particle size of between 0 and 14 mm.
- the organic material of petroleum or vegetable origin with a low bulk density of between 0.01 and 0.3 t / m 3 may preferably be an expanded organic material.
- it represents a solid expanded foam, for example a foam type Ethylene Propylene Diene Monomer (EPDM) expanded or expanded polystyrene.
- EPDM Ethylene Propylene Diene Monomer
- the aggregates according to the invention comprise aggregates of small size.
- the asphalt mix granules according to the invention have a particle size of between 2 and 8 mm, preferably between 4 and 6 mm.
- the mix according to the invention comprises from 3 to 12%, preferably from 4 to 7% by weight of binder relative to the weight of the aggregates.
- the mineral material and / or organic low apparent density of between 0.01 and 0.3 t / m 3 partially fills the voids of the granular skeleton of the bituminous mix according to the invention.
- the amount of mineral and / or organic material with a low bulk density of between 0.01 and 0.3 t / m 3 makes it possible to fill a volume of between 1 and 30% of the voids, advantageously 10% of the voids.
- the bituminous mix according to the invention thus has a voids content of between 10 and 30%, advantageously between 15 and 25%, particularly preferably between 18 and 20% of its weight. total volume.
- the amount of inorganic and / or organic material having a low bulk density of between 0.01 and 0.3 t / m 3 is between 0.2 and 5%, preferably 0.5 and 1%, so that particularly preferred 0.6 and 0.8% w / w relative to the total weight of bituminous mix.
- the bituminous mix according to the invention has a voids content of between 18 and 25%.
- the aggregates of the bituminous mix according to the invention are suitable for use in a wearing course according to the standards in force.
- the bituminous binder of the mix according to the invention is chosen from road bitumens, pure bitumens, bitumens modified with elastomers or plastomers, bitumens with additives.
- the binder of the bituminous mix according to the invention is modified or not by elastomers or plastomers and / or comprises a tackifier dopant.
- the bituminous mix according to the invention is a bituminous concrete, in particular of BBTM type (very thin asphalt concrete) class 1 or 2 in accordance with standard NF EN 13108-2.
- bituminous mix according to the invention, comprises:
- bitumen between about 4 and about 7% of bitumen, between about 0.2 and about 1% of vermiculite.
- the bituminous mix according to the invention comprises: about 82.3% of aggregates 4/6 mm, about 9.5% of granules 0/2 mm, about 2.8% of calcareous filler, about 4 , 8% modified bitumen, approximately 0.6% exfoliated vermiculite.
- the bituminous mix according to the invention comprises:
- bitumen between about 4 and about 7% of bitumen
- the bituminous mix according to the invention comprises: about 73.4% of 4/6 mm aggregates, about 18.8% of 0/2 mm aggregates, about 2% of calcareous filler, about 5.2 % of bitumen 35/50, about 0.6% of an organic additive of density ⁇ 0.3 t / m 3 .
- Another object of the invention relates to the use of a bituminous mix according to the invention for the manufacture of a wearing course with improved acoustic performance.
- Another object of the invention relates to a wearing course with improved acoustic performance characterized in that it comprises a bituminous mix according to the invention.
- Another subject of the invention relates to the use of an inorganic and / or organic material having a low bulk density of between 0.01 and 0.3 t / m 2, preferably an unsaturated natural rock which is not water, even partially, in a bituminous mix intended for the preparation of a wearing course.
- Figure 1 macrotexture of the bituminous mix according to the invention. (1) coated granules. (2) expanded natural rock. (3) empty.
- Figure 2 graph representing the LAmax (NF S 31-119-2) on site according to the frequency measured at the test carried out by the research center.
- Figure 3 Table of specifications NF EN 13108-2
- the asphalt composition tested (F1) is as follows:
- the formula is a base type draining 0/6 mm, the theoretical density of this formula is 2,234 T / m, vermiculite (0,09 T / m) significantly reduces the mix, the dosage to 0,6% is 6 kg per tonne of asphalt corresponds to a volume of 66 liters per tonne of asphalt.
- This composition corresponds to a conventional acoustic mix.
- Example 3 i Method of Measuring the Acoustic Gain of a Bituminous Mixture According to the Invention
- the inventors use, for the measurement of acoustic absorption, a test based on the shock loading of a test piece of asphalt mix and a frequency analysis of the wave after passing through the bituminous mix. After the shock, a vibratory signal is recovered which links the amplitude of the signal as a function of the vibration frequencies.
- the swept frequency range extends from 20 to 2000 Hz.
- the frequency adopted to represent the acoustic quality of the coating is that corresponding to the first maximum amplitude of the signal.
- a graph ( Figure 2) shows the relationship between this measured frequency and the performances measured at LAmax (NF S 31-119-2) on site.
- LAmax is a standardized test used by bridges and pavements, which has a national database.
- Example 4 Acoustic gain test of an asphalt mix according to the invention
- the frequency measured with the formula of Example 1 is 90 Hz, which makes it possible to obtain a measurement LAmax of between 69 dB (A) and 70 dB (A) (see FIG. 2), ie a gain of between 2 and 3. dB (A) with respect to the formula of Example 2.
- the traffic resistance measured at the CRM of the mix developed according to the invention meets the specifications of the NF EN 13108-2 standard for very hot mixes. (BBTM), at the level of all conventional mechanical tests (see table Figure 3).
- the asphalt composition tested (F3) is as follows:
- the frequency measured at the sound absorption test is 82 Hz, which brings us according to FIG. 2 to a LAmax measurement of 69 dB (A) .It is -3 dB (A). ) with respect to the reference composition, example 2.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Road Paving Structures (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Claims
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/122,128 US8702856B2 (en) | 2008-10-02 | 2009-10-02 | Bituminous coating with great acoustic performance |
| BRPI0920470A BRPI0920470A2 (pt) | 2008-10-02 | 2009-10-02 | revestimento betuminoso com desempenho acústico considerável |
| CA2738984A CA2738984C (fr) | 2008-10-02 | 2009-10-02 | Enrobe bitumineux a performance acoustique importante |
| PL09783695T PL2334873T3 (pl) | 2008-10-02 | 2009-10-02 | Masa bitumiczna przeznaczona do przygotowania warstwy ścieralnej nawierzchni i jej wykorzystanie, oraz wykorzystanie materiału o niewielkiej gęstości pozornej |
| EP09783695.1A EP2334873B1 (fr) | 2008-10-02 | 2009-10-02 | Enrobé bitumineux destiné à la préparation d'une couche de roulement et son utilisation, et utilisation d'un matériau de faible masse volumique apparente. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0856683 | 2008-10-02 | ||
| FR0856683A FR2936820B1 (fr) | 2008-10-02 | 2008-10-02 | Enrobe bitumineux a performance acoustique importante |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2010037853A1 true WO2010037853A1 (fr) | 2010-04-08 |
Family
ID=40626616
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2009/062834 Ceased WO2010037853A1 (fr) | 2008-10-02 | 2009-10-02 | Enrobé bitumineux à performance acoustique importante |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8702856B2 (fr) |
| EP (1) | EP2334873B1 (fr) |
| BR (1) | BRPI0920470A2 (fr) |
| CA (1) | CA2738984C (fr) |
| CL (1) | CL2011000733A1 (fr) |
| FR (1) | FR2936820B1 (fr) |
| PL (1) | PL2334873T3 (fr) |
| WO (1) | WO2010037853A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3015473B1 (fr) * | 2013-12-19 | 2017-05-12 | Eurovia | Enrobes alleges et utilisation sur ouvrages d'art |
| CN109810523B (zh) * | 2019-01-29 | 2021-05-14 | 上海同沥新材料科技有限公司 | 沥青增强剂及其在改性重交沥青中的应用 |
| CN109825098B (zh) * | 2019-01-29 | 2021-04-27 | 常德金牛通达沥青有限公司 | 改性重交沥青及其制备方法 |
| CN112094505B (zh) * | 2020-11-04 | 2021-06-11 | 佛山市交通科技有限公司 | Sbs改性沥青再生剂及其制备方法 |
| CN115260909A (zh) * | 2022-08-11 | 2022-11-01 | 广州圆肯电子科技有限公司 | 一种音箱内改善音质的涂层及制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2863841A (en) * | 1956-01-31 | 1958-12-09 | California Stucco Products Of | Paving mixture comprising vermiculite, rubber, sand, and bituminous binder |
| FR2344588A1 (fr) * | 1976-03-16 | 1977-10-14 | Rheinische Kalksteinwerke | Charge pour masses contenant du bitume et/ou du goudron pour revetements de routes |
| AT383609B (de) * | 1982-02-02 | 1987-07-27 | Asphalt Ges Richard Felsinger | Bituminoeses bindemittel fuer strassenbelagsmaterial und verfahren zu seiner herstellung |
| JPH06146204A (ja) * | 1992-11-05 | 1994-05-27 | Sekisui Plastics Co Ltd | 弾性舗装材 |
| JP2000355903A (ja) * | 1999-06-17 | 2000-12-26 | Tsukasa Kogyo Kk | 舗装材 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3533907A (en) * | 1967-03-27 | 1970-10-13 | Grace W R & Co | Method of forming water-laid vermiculite roof insulation board |
| US3782988A (en) * | 1969-11-06 | 1974-01-01 | Bank Of New York | Asphaltic coatings |
| DE2255624A1 (de) * | 1972-11-14 | 1974-05-16 | Toiturep | Schalldaemmende und waermeisolierende dichtungsmasse und verfahren zur herstellung derselben |
| JPS5353119A (en) * | 1976-10-25 | 1978-05-15 | Chiyoda Chem Eng Construct Co | Exceilent heat insulating structure |
| US4168179A (en) * | 1978-01-30 | 1979-09-18 | Gaf Corporation | Bituminous composition |
| US4512806A (en) * | 1979-07-23 | 1985-04-23 | Minnesota Mining And Manufacturing Company | Flame resistant ashaltic compositions |
| US4332620A (en) * | 1980-09-29 | 1982-06-01 | Quinn Robert L | Colored paving composition |
| JPS57119952A (en) * | 1981-01-19 | 1982-07-26 | Hironobu Hori | Asphalt pavement mixture |
| DE3115758A1 (de) * | 1981-04-18 | 1982-11-11 | Hoechst Ag, 6000 Frankfurt | "formkoerper aus geblaehten mineralien" |
| US4548962A (en) * | 1981-12-29 | 1985-10-22 | All Seasons Surfacing Corporation | Rubberized asphaltic concrete composition |
| IT1169744B (it) * | 1983-07-12 | 1987-06-03 | Laterlite Spa | Conglomerato bituminoso a freddo specialmente per manutenzione stradale e procedimento per la sua produzione |
| GB9112035D0 (en) * | 1991-06-05 | 1991-07-24 | Causyn David W | Recycled rubber in a polymer modified asphalt & a method of making same |
| US5250578A (en) * | 1991-07-05 | 1993-10-05 | Cornwell Charles E | Foamed cementitious composition and method of making |
| ZA925701B (en) * | 1991-08-08 | 1993-04-13 | Bst Holdings Pty Ltd | Lightweight concrete. |
| GB9511162D0 (en) * | 1995-06-02 | 1995-07-26 | Spendlove Peter D | Macadam flexible pavement |
| US5652284A (en) * | 1995-11-09 | 1997-07-29 | Exxon Research & Engineering Company | Thermoplastic elastomer-asphalt nanocomposite composition |
| DE19716194C2 (de) * | 1996-05-03 | 2001-09-27 | Kieselgur Und Kalksandsteinind | Perlite enthaltender stabiliserender Zusatz für Asphaltmischungen |
| GB2340125B (en) * | 1998-07-07 | 2003-04-02 | Branko Richard Babic | Low density materials |
| JP4506530B2 (ja) * | 2005-03-24 | 2010-07-21 | 東海ゴム工業株式会社 | 多孔質弾性舗装材 |
| US7582155B2 (en) * | 2006-03-21 | 2009-09-01 | Building Materials Investment Corporation | Asphalt nanocomposite-based roofing products |
| US20100075167A1 (en) * | 2008-09-24 | 2010-03-25 | Georgia-Pacific Gypsum Llc | Compositions for the manufacture of gypsum boards, methods of manufacture thereof, and gypsum boards formed therefrom |
-
2008
- 2008-10-02 FR FR0856683A patent/FR2936820B1/fr not_active Expired - Fee Related
-
2009
- 2009-10-02 CA CA2738984A patent/CA2738984C/fr not_active Expired - Fee Related
- 2009-10-02 US US13/122,128 patent/US8702856B2/en not_active Expired - Fee Related
- 2009-10-02 BR BRPI0920470A patent/BRPI0920470A2/pt not_active Application Discontinuation
- 2009-10-02 EP EP09783695.1A patent/EP2334873B1/fr active Active
- 2009-10-02 WO PCT/EP2009/062834 patent/WO2010037853A1/fr not_active Ceased
- 2009-10-02 PL PL09783695T patent/PL2334873T3/pl unknown
-
2011
- 2011-04-01 CL CL2011000733A patent/CL2011000733A1/es unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2863841A (en) * | 1956-01-31 | 1958-12-09 | California Stucco Products Of | Paving mixture comprising vermiculite, rubber, sand, and bituminous binder |
| FR2344588A1 (fr) * | 1976-03-16 | 1977-10-14 | Rheinische Kalksteinwerke | Charge pour masses contenant du bitume et/ou du goudron pour revetements de routes |
| AT383609B (de) * | 1982-02-02 | 1987-07-27 | Asphalt Ges Richard Felsinger | Bituminoeses bindemittel fuer strassenbelagsmaterial und verfahren zu seiner herstellung |
| JPH06146204A (ja) * | 1992-11-05 | 1994-05-27 | Sekisui Plastics Co Ltd | 弾性舗装材 |
| JP2000355903A (ja) * | 1999-06-17 | 2000-12-26 | Tsukasa Kogyo Kk | 舗装材 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2738984C (fr) | 2017-01-10 |
| PL2334873T3 (pl) | 2016-05-31 |
| FR2936820B1 (fr) | 2013-04-19 |
| BRPI0920470A2 (pt) | 2015-12-22 |
| EP2334873B1 (fr) | 2015-11-25 |
| EP2334873A1 (fr) | 2011-06-22 |
| CA2738984A1 (fr) | 2010-04-08 |
| US8702856B2 (en) | 2014-04-22 |
| FR2936820A1 (fr) | 2010-04-09 |
| US20110232529A1 (en) | 2011-09-29 |
| CL2011000733A1 (es) | 2011-10-14 |
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