WO2010047480A2 - Procédé de production de biodiesel à partir du fruit du hevea brasiliensis - Google Patents

Procédé de production de biodiesel à partir du fruit du hevea brasiliensis Download PDF

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Publication number
WO2010047480A2
WO2010047480A2 PCT/KR2009/005674 KR2009005674W WO2010047480A2 WO 2010047480 A2 WO2010047480 A2 WO 2010047480A2 KR 2009005674 W KR2009005674 W KR 2009005674W WO 2010047480 A2 WO2010047480 A2 WO 2010047480A2
Authority
WO
WIPO (PCT)
Prior art keywords
para
rubber
fruit
alcohol
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2009/005674
Other languages
English (en)
Korean (ko)
Other versions
WO2010047480A3 (fr
Inventor
경영수
박영섭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gangneung–Wonju National University
Original Assignee
Gangneung–Wonju National University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gangneung–Wonju National University filed Critical Gangneung–Wonju National University
Publication of WO2010047480A2 publication Critical patent/WO2010047480A2/fr
Publication of WO2010047480A3 publication Critical patent/WO2010047480A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/10—Ester interchange
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C10L2200/0476—Biodiesel, i.e. defined lower alkyl esters of fatty acids first generation biodiesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

  • the present invention relates to a method for producing biodiesel using para-rubber fruit, and more particularly, refined oil obtained from para-rubber fruit; It relates to a method for producing biodiesel using para-rubber fruit comprising the step of reacting a mixture of a basic substance and alcohol.
  • Rubber producing trees include Hebraa brasiliensis, Ficus elastica, Castilla elastica growing in Latin America, Manihot glaziovli, and Taraxacum koksaghyz. have.
  • the para-rubber Hevea brasiliensis
  • the para-rubber is a tree belonging to the Euphorbiaceae, with a height of 20 to 47m and a diameter of about 60cm. Bark is smooth, ash-brown, about 200 years old.
  • the leaf is a leaf made of 3 leaflets with long and petioles. Flowers are divided into female flowers and male flowers, but they are mixed in turn and grow white. Fruits are round and contain 3 seeds.
  • Para-rubber is said to grow about 300 million trees in the Amazon River basin in South America, and once accounted for 95-98% of rubber production. After the scar on the bark, the latex ( ⁇ ) flowing out and coagulation process is used as the raw material of elastic rubber. Seeds contain 23-32% fatty oil, which is squeezed and used as dry oil, and the residue is used as feed for livestock.
  • Freshly fallen fruits of para-rubber have 30-40% moisture, dry fruits have 10-15% moisture, and the weight of the bark fruit is 45% of the total weight of para-rubber fruit.
  • Para-rubber is mainly used for producing rubber as mentioned above, but the para-rubber fruit is rarely used commercially. The reason is the specificity of the impurities contained in this fruit.
  • Ingredients contained in the oil milked from the fruit of Para-rubber include rubber components, phospholipids, high acidity free fatty acids and cyanide glucose. In addition, the oil component is highly oxidized due to the high content of unsaturated fatty acids.
  • Biodiesel is the most widely used biofuel with bioethanol. It refers to the whole pollution-free fuel made from vegetable oils such as soybean oil, rapeseed oil, waste vegetable oil, and seaweed oil. It is mainly used as a diesel fuel additive or diesel fuel in a vehicle using diesel.
  • Biodiesel is usually produced by transesterification by separating glycerol from triglycerides in which glycerol is bound to trivalent fatty acids using methanol, and then producing fatty acid esters.
  • the biodiesel produced at this time is fatty acid methyl ester (FAME). So FAME is the common biodiesel.
  • alkali as a catalyst
  • lipase lipolytic enzyme or supercritical methanol.
  • Alkaline catalysis is the most common, and as the need for biofuels increases, technologies for developing biodiesel are diversifying.
  • the present invention is to provide a method for producing biodiesel using the para-rubber fruit and the biodiesel obtained by such a method.
  • the present invention is a refined oil obtained from the fruit of the para-rubber;
  • the present invention provides a method for producing biodiesel using para-rubber fruit, characterized in that a mixture of a basic substance and an alcohol is reacted, and a biodiesel obtained by the method.
  • the biodiesel may be manufactured using the para-rubber fruit, and the raw material for producing biodiesel oil may be diversified to improve the production of biodiesel oil, and economical to the para-rubber grower. It can contribute to the improvement of phosphorus gain.
  • the present invention shows a method for producing biodiesel using para-rubber fruit.
  • the present invention is a refined oil obtained from the fruit of the para-rubber; Represents a method of preparing biodiesel using para-rubber fruit, which comprises reacting a mixture of a basic substance and an alcohol.
  • the biodiesel may be prepared using rubber tree fruit.
  • the refined oil obtained from the para-rubber fruit may be obtained by washing, drying and stripping the fruit of the para-rubber to obtain oil by pressing, and the oil obtained through the refining process of degumming, deoxidation and decolorization.
  • refined oil obtained from the fruit of the para-rubber is obtained by washing, drying and stripping the fruit of the para-rubber to obtain oil by compressing it. After filtering the precipitate can be used.
  • anhydrous magnesium sulfate (MgSO 4 ) may be used as an example of such a desiccant.
  • a mixture of 100 to 2000 parts by weight of alcohol may be used with respect to 100 parts by weight of the basic substance.
  • the basic substance may be any one or more selected from the group of potassium hydroxide (KOH) and sodium hydroxide (NaOH).
  • the alcohol may be an alcohol having 1 to 10 carbon atoms.
  • the alcohol may be an alcohol having 1 to 3 carbon atoms.
  • Alcohol in the mixture of the basic substance and the alcohol may be used methanol, ethanol or isopropanol.
  • the present invention includes biodiesel obtained by the above-mentioned method.
  • the method for producing biodiesel using the para-rubber fruit of the present invention was carried out under various conditions, in order to achieve the object of the present invention, the method for producing bio-diesel using the para-rubber fruit using the above-mentioned conditions. It is desirable to provide.
  • the fatty acid of the oil obtained above was analyzed by gas chromatography, the composition was compared with the composition of various other fatty acids (see Table 2).
  • the para-rubber fruit oil obtained above was purified by adding potassium hydroxide (KOH) aqueous solution and adding phosphoric acid to remove free fatty acids and phospholipids.
  • KOH potassium hydroxide
  • the results of the composition of the para-rubber fruit oil after purification were shown in Table 3 below. It was.
  • KOH potassium hydroxide
  • MgSO 4 anhydrous magnesium sulfate
  • biodiesel may be manufactured using the para-rubber fruit, and thus various raw materials for producing biodiesel oil may be diversified, thereby contributing to improving the production of biodiesel oil.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Fats And Perfumes (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

L'invention concerne un procédé de production de biodiesel à partir du fruit du H evea brasiliensis. Le procédé de l'invention consiste plus particulièrement à mettre à réagir de l'huile raffinée avec un mélange de substances de base et d'alcool, l'huile raffinée étant obtenue du fruit du Hevea brasiliensis.
PCT/KR2009/005674 2008-10-23 2009-10-05 Procédé de production de biodiesel à partir du fruit du hevea brasiliensis Ceased WO2010047480A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2008-0104320 2008-10-23
KR1020080104320A KR20100045231A (ko) 2008-10-23 2008-10-23 파라고무나무 열매를 이용한 바이오디젤의 제조방법

Publications (2)

Publication Number Publication Date
WO2010047480A2 true WO2010047480A2 (fr) 2010-04-29
WO2010047480A3 WO2010047480A3 (fr) 2010-07-29

Family

ID=42119799

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2009/005674 Ceased WO2010047480A2 (fr) 2008-10-23 2009-10-05 Procédé de production de biodiesel à partir du fruit du hevea brasiliensis

Country Status (2)

Country Link
KR (1) KR20100045231A (fr)
WO (1) WO2010047480A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012122826A1 (fr) * 2011-03-15 2012-09-20 清华大学 Procédé pour la préparation de biodiesel
WO2012122827A1 (fr) * 2011-03-15 2012-09-20 清华大学 Procédé pour la préparation de biodiesel utilisant une charge de départ huileuse

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102377167B1 (ko) 2022-01-17 2022-03-23 주식회사 지웨이코스메틱 파라고무나무 잎 추출물을 함유하는 화장료 조성물의 제조 방법

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070260078A1 (en) * 2006-05-05 2007-11-08 Bhat Ramanath N Integrated process for the manufacture of biodiesel
KR100790298B1 (ko) * 2006-09-18 2008-01-02 전남대학교산학협력단 고순도 지방산 알킬에스테르의 제조방법 및 이로부터 제조된 지방산 알킬에스테르
KR100811625B1 (ko) * 2007-05-25 2008-03-11 (주) 비젤 알킬 에스테르 화합물의 제조 방법

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012122826A1 (fr) * 2011-03-15 2012-09-20 清华大学 Procédé pour la préparation de biodiesel
WO2012122827A1 (fr) * 2011-03-15 2012-09-20 清华大学 Procédé pour la préparation de biodiesel utilisant une charge de départ huileuse
US10246644B2 (en) 2011-03-15 2019-04-02 Tsinghua University Method for preparing biodiesel

Also Published As

Publication number Publication date
KR20100045231A (ko) 2010-05-03
WO2010047480A3 (fr) 2010-07-29

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