WO2010142586A2 - Produit nettoyant cosmétique à effet désodorisant - Google Patents

Produit nettoyant cosmétique à effet désodorisant Download PDF

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Publication number
WO2010142586A2
WO2010142586A2 PCT/EP2010/057692 EP2010057692W WO2010142586A2 WO 2010142586 A2 WO2010142586 A2 WO 2010142586A2 EP 2010057692 W EP2010057692 W EP 2010057692W WO 2010142586 A2 WO2010142586 A2 WO 2010142586A2
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group
composition according
methyl
ethyl
hydrogen
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German (de)
English (en)
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WO2010142586A3 (fr
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Jutta Franklin
Qian-Yi Li
Bernhard Banowski
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Priority to EP10720306A priority Critical patent/EP2440173A2/fr
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Publication of WO2010142586A3 publication Critical patent/WO2010142586A3/fr
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants

Definitions

  • the present invention relates to a cosmetic cleaning composition which has a deodorizing effect in addition to a cleaning due to a specific combination of active ingredients. Furthermore, the present invention relates to the use of the combination of active ingredients in a cosmetic cleanser and a method for the purification, care and deodorization of human keratin fibers.
  • Detergents for example, cosmetic cleansers for the skin and hair, such as liquid soaps, shampoos, shower baths, bubble baths, shower gels and washing gels, must not only have good cleansing properties, but should continue to be well tolerated by the skin and mucous membranes and even more frequently Do not use excessive defatting or dryness.
  • the aim of the present invention was therefore to develop an agent that thoroughly cleanses, cares for and deodorizes human keratin fibers.
  • the skin and / or the scalp do not dry when it is cleansed, but at the same time they are supplied with active ingredients during the cleansing process, which moisturize the skin and leave it supple, velvety and soft.
  • the detergent should be effective against odor-causing gram-positive bacteria and thus have a deodorant effect, so that optimally can be dispensed with the use of a deodorant.
  • the subject of the present invention is therefore a cosmetic cleaning composition with a deodorizing effect, containing
  • R 1 is a methyl, ethyl, propyl, isopropyl, butyl, hydroxymethyl, hydroxyethyl, ethyl glycol, hydroxypropyl or 1, 2-dihydroxypropyl group
  • R 2 is hydrogen or a methyl, ethyl, propyl -, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, benzyl, -CH 2 -O-CH (C 2 H 5 ) - CH 2 CH 2 CH 2 CH 3 group and
  • R 3 is hydrogen or a methyl, ethyl, propyl, isopropyl, butyl, benzyl group, provided that R 2 and R 3 are not simultaneously hydrogen.
  • component c at least one compound of the formula (I) is used in which R 1 is a methyl or a hydroxymethyl group,
  • R 2 is hydrogen or an ethyl, propyl, isopropyl, butyl, pentyl, hexyl, benzyl, -CH 2 -O-CH (C 2 Hs) -CH 2 CH 2 CH 2 CH 3 -GmPPe and R 3 is hydrogen or a methyl, benzyl group, provided that when R 2 and R 3 are not simultaneously hydrogen.
  • component c) at least one compound from the group consisting of phenoxyethanol, methylbenzyl alcohol, 1,2-butylene glycol, 1,2-pentanediol, 1, 2-hexanediol, 1, 2-hepandiol, 1, 2-octanediol and / or ethylhexylglycerol.
  • ethylhexylglycerol is used as component c).
  • ethylhexylglycerol with benzoic acid or a physiologically acceptable salt of benzoic acid in a surfactant mixture according to the invention results in an effective skin and / or scalp cleansing composition which is very well tolerated by the skin and noticeably improves the skin feel after cleansing.
  • the slight burning or tightening of the skin after cleansing is reduced, and at the same time, the growth and proliferation of odor-causing Gram-positive bacteria is reliably reduced. This protects the natural skin flora.
  • Ethylhexylglycerol is commercially available - for example under the trade name "Sensiva ® SC 50" from Schülke & Mayr It is in the compositions of the invention - by weight - in amounts of 0.01 to 5 wt .-%, preferably from In a second particularly preferred embodiment of the invention, a mixture of methylbenzyl alcohol, 1, 2-hexanediol and 1 is used as component c) in a concentration of from 0.05 to 4% by weight and in particular in amounts of from 0.1 to 3% by weight
  • This active ingredient mixture in combination with benzoic acid or a physiologically tolerated salt of benzoic acid in surface-active compositions leads to cosmetic skin and / or scalp cleansing compositions according to the invention which have an excellent antifungal and antimicrobial effect in addition to an outstanding cleansing and care effect.
  • the skin moisture and thus the skin care which in turn can be prepared a cosmetic cleanser that meets the objectives of the invention (effective cleaning, care and deodorization in a 3in1 product) to a high degree.
  • the inventive compositions - based on its weight - in amounts of from 0 , 01 to 5 wt .-%, preferably from 0.05 to 4 wt .-% and in particular in amounts of 0.1 to 3 wt .-% used.
  • the cleaning agents in addition to the surfactant base, benzoic acid or a physiologically acceptable salt of benzoic acid and ethylhexylglycerol and / or the active ingredient mixture of methylbenzyl alcohol, 1, 2-hexanediol and 1, 2-octanediol additionally contain phenoxyethanol.
  • phenoxyethanol not only supports the antibacterial and antifungal properties of the detergents of the invention (and thus their action against odor-causing microorganisms), but also improves the conditioning of the skin, because it promotes the maintenance and stabilization of skin moisture during cleaning.
  • Phenoxyethanol is in the cleaning agents according to the invention - in terms of their weight - in amounts of 0.01 to 5 wt .-%, preferably from 0.05 to 3 wt .-% and in particular in amounts of 0.1 to 3 wt .-% used.
  • Another particular advantage achieved by the combination of active substances according to the invention and in particular by the addition of phenoxyethanol to the preferred active ingredient combination according to the invention is that it is undesirable for further preservatives in the compositions, such as parabens or formaldehyde donors (which due to their allergenic action on the skin are) can be waived.
  • the cleaning agent according to the invention thus contains, in addition to the aforementioned preferred components c) and optionally phenoxyethanol no further preservatives.
  • the total amount of all components c) in the detergents according to the invention is from 0.01 to 15% by weight, preferably from 0.05 to 10, more preferably from 0.1 to 7.5% by weight, and in particular based on their weight from 0.2 to 5 wt .-%.
  • the detergents according to the invention contain benzoic acid or a physiologically acceptable salt of benzoic acid.
  • Suitable salts are, for example, the alkali metal salts of benzoic acid and in particular the sodium salt.
  • Benzoic acid or sodium benzoate is in the detergents according to the invention - based on their weight - in amounts of 0.01 to 10 wt .-%, preferably 0.05 to 7.5 wt .-%, more preferably 0.1 to 5 wt .-% and in particular 0.2 to 3 wt .-% used.
  • a suitable surfactant base is the third essential component of the cleaning compositions according to the invention.
  • surfactants is understood to mean surface-active substances which carry an anionic or cationic charge in the molecule. Also, both anionic and cationic charge may be present in the molecule. These zwitterionic or amphoteric surface-active substances can also be used according to the invention. Furthermore, the surface-active substances may also be non-ionic.
  • Suitable anionic surfactants in preparations according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. Example, a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule.
  • anionic surfactants are, in each case in the form of the sodium, potassium and ammonium and the mono-, di- and trialkanol- ammonium salts having 2 to 4 carbon atoms in the alkanol group, linear and branched fatty acids having 8 to 30 C. Atoms (soaps),
  • Ethercarbon Acid the formula RO- (CH2 "CH2 ⁇ ) ⁇ -CH2-COOH, in which R is a linear
  • Alkyl group having 8 to 30 C atoms and x 0 or 1 to 16, acylsarcosides having 8 to 24 C atoms in the acyl group, acyl taurides having 8 to 24 C atoms in the acyl group, Acyl isethionates having 8 to 24 carbon atoms in the acyl group,
  • R 29 is preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms
  • R 30 is hydrogen, a radical (CH 2 CH 2 O) n R 29 or X
  • n is from 1 to 10
  • X is hydrogen, an alkali metal radical or alkaline earth metal or NR 31 R 32 R 33 R 34, with R 31 stand independently for a C 1 to R 34 to C 4 -, is hydrocarbon radical, sulfated FettTexrealkylenglykolester of the formula (TII)
  • R CO is a linear or branched acyl radical having 6 to 22 carbon atoms, x, y and z total 0 or numbers from 1 to 30, preferably 2 to 10, and X is an alkali or alkaline earth metal.
  • monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, Coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts
  • Monoglyceride sulfates of the formula (TIN) in which R 36 CO is a linear acyl radical having 8 to 18 carbon atoms are preferably used.
  • Preferred anionic surfactants in the cleaning preparations according to the invention are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids having 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule and sulfosuccinic mono- and dialkyl esters having 8 to 18 carbon atoms in the alkyl group and sulfosuccinic monoalkylpolyoxy ethyl esters having 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups.
  • the anionic surfactant (s) are in the compositions of the invention - by weight - in amounts of from 0.5 to 25 wt .-%, preferably in amounts of 1 to 20 wt .-% and in particular in amounts used from 2 to 15 wt .-%.
  • Alkylpolyglycolethersulfate having 10 to 18 carbon atoms in the alkyl group and 1 to 3 glycol ether groups in the molecule are particularly preferred anionic surfactants due to their skin milding properties.
  • Zwitterionic surfactants are those surface-active compounds which carry in the molecule at least one quaternary ammonium group and at least one -COO () or -SO 3 ⁇ group.
  • Particularly suitable zwitterionic surfactants are the so-called betaines, such as the N-alkyl-N, N-dimethylammonium glycinates, for example the cocoalkyldimethylammoniumglycinate, N-acylaminopropyl-N, N-dimethylammoniumglycinate, for example the cocoacylaminopropyldimethylammoniumglycinate, and 2-alkyl-3-carboxymethyl-3-hydroxyethyl imidazolines having in each case 8 to 18 C atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
  • particularly preferred zwitterionic surfactants are the fatty acid amide derivative known under the INCI name Cocamidopropyl Betaine and also alkyl betaines having 10 to 20 C atoms in the alkyl group.
  • Ampholytic surfactants are understood as meaning those surface-active compounds which, apart from a C 8 -C 2 ⁇ -alkyl or acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO 3 H group and which are capable of forming internal salts .
  • suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic
  • amphoteric / zwitterionic surfactant (s) are in the compositions of the invention - based on their weight - in amounts of 0.1 to 15 wt .-%, preferably in amounts of 0.5 to 10 wt .-% and in particular in amounts of 1 to 7.5 wt .-% used.
  • the surfactant base is a particularly mild surfactant mixture which is suitable for use in cosmetic skin care and / or hair-cleaning preparations.
  • a surfactant mixture it is preferred according to the invention to use a mixture of mild anionic and mild amphoteric and / or zwitterionic surfactants.
  • mild anionic and mild amphoteric and / or zwitterionic surfactants are, for example, alkyl ether sulfates, alkyl ether carboxylic acids, acyl glutamates or sulfosuccinates and also alkylbetaines, sulfobetaines, alkylamidoalkylbetaines, alkylamphoacetates and -propionates.
  • Particularly preferred is a mixture of alkyl ether sulfates and Alkylamidoalkylbetainen.
  • Particularly preferred with respect to the dermal properties of the surfactant base is a combination of alkyl ether sulfates and Alkylamidoalkylbetainen in a ratio of 3: 1 to 1: 1. According to the invention particularly preferred cleaning formulations
  • These particularly preferred cosmetic cleansing preparations are able to gently and effectively clean the human skin and / or scalp and at the same time to care for it.
  • the skin or scalp is not dried out during and after cleansing, but moisturised, so it feels supple and soft.
  • the combination of the active substances B. and C. results in an effective control of gram-positive bacteria, which form unpleasant-smelling germs from sweat ingredients, sebum and skin cell residues, whereby an effective deodorant effect is achieved with the skin cleansers, which does not increase the additional use of deodorants makes more necessary.
  • the detergents also contain nonionic surfactants. These include as hydrophilic group z.
  • Such compounds are, for example with a methyl or C 2 - C 6 - alkyl radical end-capped addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched Fatty alcohols having 8 to 30 carbon atoms, onto fatty acids having 8 to 30 carbon atoms and onto alkylphenols having 8 to 15 carbon atoms in the alkyl group, such as those available under the trade names Dehydol ® LS, Dehydol ® LT (Cognis) available types, polyol fatty acid esters, such as the commercial product Hydagen ® HSP (Cognis) or Sovermol - types (Cognis), alkoxylated triglycerides, - alkoxylated fatty acid alkyl esters of the formula R 37 CO- (OCH 2 CHR 38 ) W OR 39 , (TIV), in R 37 CO is
  • alkyl polyglucosides Another group of nonionic surfactants which are suitable according to the invention are the alkyl polyglucosides. They correspond to the formula (I) in which R 1 is an alkyl and / or alkenyl radical having 4 to 22 carbon atoms, G is a sugar radical having 5 or 6 carbon atoms and p is a number from 1 to 10.
  • the alkyl and / or alkenyl oligoglycosides can be derived from aldoses or ketoses having 5 or 6 carbon atoms, preferably glucose.
  • the preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides.
  • alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.7 are preferred.
  • the alkyl or alkenyl radical R 1 can be derived from primary alcohols having 4 to 11, preferably 8 to 10 carbon atoms. Typical examples are butanol, caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol, and technical mixtures thereof, as obtained, for example, in the hydrogenation of technical fatty acid methyl esters or in the hydrogenation of aldehydes from Roelen's oxosynthesis.
  • the alkyl or alkenyl radical R 1 can also be derived from primary alcohols having 12 to 22, preferably 12 to 14 carbon atoms.
  • Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol and their technical mixtures, as can be obtained as described above.
  • alkyl oligoglucosides based on hydrogenated C 2 / i 4 coconut alcohol with a DP of 1-3, as are obtainable for example under the INCI name "Coco-Glucoside" in the trade.
  • the nonionic surfactants are in the compositions of the invention - based on their weight - preferably in amounts of 0.05 to 15 wt .-%, preferably from 0.1 to 10 wt .-% and in particular in amounts of 0.5 to 5 wt .-% used.
  • the pH of the cleaning compositions according to the invention is ideally in a skin-friendly range of about 2.5 to 8, preferably in a range of 3 to 7 and in particular in a range of 3.5 to 6.
  • the cleaning compositions may contain a number of other optional ingredients. Preference is given to adding to the cleaning compositions further active ingredients which have cosmetic care properties in order to support the conditioning of the skin during the cleaning process.
  • cosmetically suitable oil components, cationic polymers, plant extracts and / or humectants may be mentioned as further preferred optional components.
  • suitable oil components can be selected from mineral, natural or synthetic oil components such as petrolatum, paraffins, silicones, fatty alcohols, fatty acids, fatty acid esters and natural oils of vegetable and animal origin, and are in the cleaning compositions - based on their total weight - in an amount of 0.005 to 20 wt .-%, preferably from 0.01 to 10 wt .-%, particularly preferably from 0.05 to 5 wt .-% and in particular from 0.2 to 3 wt .-% used (wherein the amount indicated on the Total content of all oil components in the detergent according to the invention relates).
  • mineral, natural or synthetic oil components such as petrolatum, paraffins, silicones, fatty alcohols, fatty acids, fatty acid esters and natural oils of vegetable and animal origin
  • silicone oils is understood by the person skilled in the art to mean several structures of organosilicon compounds.
  • the silicones are selected from at least one member of the organosilicon compounds formed from:
  • polyalkyl siloxanes polyaryl siloxanes, polyalkylaryl siloxanes which are volatile or nonvolatile, straight chain, branched or cyclic, crosslinked or uncrosslinked;
  • grafted polysiloxane backbone silicone polymers having grafted thereto non-silicone-containing organic monomers having a polysiloxane backbone to which at least one organic macromer containing no silicone has been grafted in the chain, and optionally at least at one of its ends , such as the commercial product Abil B 8832 from Degussa marketed under the INCI name Bis-PEG / PPG-20/20 dimethicone; (vi) or mixtures thereof.
  • the fatty acids used can be linear and / or branched, saturated and / or unsaturated fatty acids having 6 to 30 carbon atoms. Preference is given to fatty acids having 10 to 22 carbon atoms. These include, for example, the isostearic acids, such as the commercial products Emersol® 871 and Emersol® 875, and isopalmitic acids such as the commercial product Edenor® IP 95, as well as all other fatty acids sold under the trade names Edenor® (Cognis).
  • fatty acids are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linoleic and erucic acid and their technical mixtures, eg in the pressure cracking of natural fats and oils, in the oxidation of aldehydes from the Roelen oxo synthesis or the dimerization of unsaturated fatty acids.
  • Particularly preferred are usually the fatty acid cuttings obtainable from coconut oil or palm oil; In particular, the use of stearic acid is usually preferred.
  • fatty alcohols it is possible to use saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C 6 -C 30 -, preferably C 10 -C 22 - and very particularly preferably C 12 -C 22 -carbon atoms.
  • Decanol, octanol, octenol, dodecenol, decenol, octadienol, dodecadienol, decadienol can be used for the purposes of the invention, for example.
  • the fatty alcohols are derived from preferably natural fatty acids, which can usually be based on recovery from the esters of fatty acids by reduction.
  • fatty alcohol cuts which are produced by reducing naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters formed from their transesterification products with corresponding alcohols, and thus represent a mixture of different fatty alcohols.
  • Such substances are, for example, under the names Stenol®, eg Stenol® 1618 or Lanette®, eg Lanette® O or Lorol®, eg Lorol® C8, Lorol® C14, Lorol® C18, Lorol® C8-18, HD-Ocenol®, Crodacol®, eg Crodacol® CS, Novol®, Eutanol® G, Guerbitol® 16, Guerbitol® 18, Guerbitol® 20, Isofol® 12, Isofol® 16, Isofol® 24, Isofol® 36, Isocarb® 12, Isocarb® 16 or Isocarb® 24 for sale.
  • wool wax alcohols such as are commercially available under the names Corona®, White Swan®, Coronet® or Fluilan®
  • the natural or synthetic waxes used according to the invention are solid paraffins or isoparaffins, carnauba waxes, beeswaxes, candelilla waxes, ozokerites, ceresin, spermaceti, sunflower wax, fruit waxes such as apple wax or citrus wax, microwaxes of PE or PP.
  • Such waxes are available, for example, from Kahl & Co., Trittau.
  • the natural and synthetic cosmetic oil bodies include, for example: liquid paraffin oils, isoparaffin oils and synthetic hydrocarbons and di-n-alkyl ethers having a total of from 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as di-n-octyl ether , Di-n-decyl ether, di-n-nonyl ether, di-n-undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n Undecyln-dodecyl ether and n-hexyl n-undecyl ether and di-tert-butyl ether, di-iso-pentyl ether, di-3-ethyldecyl ether, tert
  • Ester oils are to be understood as meaning the esters of C 6 -C 30 fatty acids with C 2 -C 30 fatty alcohols. The monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred.
  • fatty acid components used in the esters are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic Behenic acid and erucic acid and their technical mixtures which are obtained, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from Roelen's oxo synthesis or the dimerization of unsaturated fatty acids.
  • fatty alcohol components in the ester oils are isopropyl alcohol, caproic alcohol, Caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol, and technical mixtures thereof, for example, in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from the Roelen oxo synthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols incurred.
  • isopropyl myristate IPM Rilanit®
  • isononanoic acid Ci -i 6 8 -alkyl Cetiol® SN
  • 2-ethylhexyl palmitate Cegesoft® 24
  • stearic acid 2-ethylhexyl ester Cetiol 868
  • cetyl oleate Glycerol tricaprylate
  • coconut fatty alcohol caprinate / caprylate (Cetiol® LC)
  • n-butyl stearate, oleyl erucate Cetiol® J 600
  • isopropyl palmitate Rosanit® IPP
  • oleyl oleate Cetiol®
  • hexyl laurate Cetiol® A
  • di-n -butyl adipate Cetiol® B
  • myristyl myristate Cet
  • Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate
  • diol esters such as ethylene glycol dioleate, ethylene glycol di-isotricanecanoate, propylene glycol di ( 2-ethylhexanoate), propylene glycol diisostearate, propylene glycol di-pelargonat, butanediol di-isostearate, Neopentylglykoldicaprylat, symmetrical, asymmetric or cyclic esters of carbonic acid with fatty alcohols, for example described in DE-OS 197 56 454, glycerol carbonate or dicaprylyl - carbonate (Cetiol® CC),
  • Natural oils include, for example, amaranth seed oil, apricot kernel oil, argan oil, avocado oil, babassu oil, cottonseed oil, borage seed oil, camelina oil, thistle oil, peanut oil, pomegranate seed oil, grapefruit seed oil, hemp oil, rose hip kernel oil, hazelnut oil, elderflower seed oil, currant seed oil, jojoba oil, cocoa butter, linseed oil, macadamia nut oil, corn oil, almond oil , Marula oil, evening primrose oil, olive oil, palm oil, peach kernel oil, rapeseed oil, rice oil, sea buckthorn pulp oil, sea buckthorn seed oil, sesame oil, shea butter, soybean oil, sunflower oil, grapeseed oil, walnut oil or wild rose oil.
  • avocado oil apricot kernel oil, rose hip kernel oil, jojoba oil, cocoa butter, almond oil, olive oil, peach kernel oil, shea butter, sunflower oil and grapeseed oil are particularly preferred.
  • cationic polymers suitable according to the invention are meant polymers which have groups in the main and / or side chain which may be “temporary” or “permanent” cationic.
  • "permanently cationic” refers to those polymers which have a cationic group independently of the pH of the agent These are generally polymers containing a quaternary nitrogen atom, for example in the form of an ammonium group.
  • Preferred cationic groups contain quaternary ammonium groups.
  • . 4- hydrocarbon group are bonded to a constructed from acrylic acid, methacrylic acid or their derivatives polymer backbone have been found to be particularly suitable.
  • R 17 -H or -CH 3
  • R 18, R 19 and R 20 are independently selected from C- ⁇ - 4 -alkyl, -alkenyl or -hydroxyalkyl groups
  • m 1, 2, 3 or 4
  • n is a natural number
  • X is a physiologically acceptable organic or inorganic anion
  • copolymers consisting essentially of the monomer units listed in formula (VII) and nonionic monomer units are particularly preferred cationic polymers preferably, for which at least one of the following conditions applies:
  • R 17 is a methyl group
  • R 18 , R 19 and R 20 are methyl groups m is 2.
  • Suitable physiologically acceptable counterions X ' are, for example, halide ions, sulfate ions, phosphate ions, methosulfate ions and organic ions such as lactate, citrate, tartrate and acetate ions. Preference is given to halide ions, in particular chloride.
  • suitable homopolymers or copolymers derived from the formula (VI) for example, the Salcare ® SC 95, Salcare ® SC 96 and Salcare ® SC 92 available under the trade names commercially.
  • Other preferred cationic polymers are, for example, quaternized cellulose derivatives, such as are available under the names of Celquat ® and Polymer JR ® commercially.
  • the compounds Celquat ® H 100, Celquat ® L 200 and Polymer JR ® 400 are preferred quaternized cellulose derivatives, hydrophobically modified cellulose derivatives, for example those sold under the trade name SOFTCAT ® cationic polymers, cationic alkyl polyglycosides, cationized honey, for example the commercial product Honeyquat ® 50 , cationic guar derivatives, in particular those sold under the trade names cos media ® guar and Jaguar ® products,
  • Polysiloxanes with quaternary groups such as the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilized trimethyl silylamodimethicon), Dow Corning ® 929 Emulsion (containing a hydroxylamino-modified silicone which is also known as amodimethicone ), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ® quat 3270 and 3272 (manufacturer: Th.
  • Copolymers of vinylpyrrolidone with quaternized derivatives of Dialkylaminoalkylacry- lats and methacrylate such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers.
  • Such compounds are sold under the names Gafquat ® 734 and Gafquat ® 755 commercially,
  • Vinylpyrrolidone-Vinylimidazoliummethochlorid copolymers such as those available under the names Luviquat ® FC 370, FC 550, FC 905 and HM 552, quaternized polyvinyl alcohol, as well as those under the names Polyquaternium 2, Polyquaternium 17, Polyquaternium 18 and
  • Polyquaternium 27 known polymers with quaternary nitrogen atoms in the polymer main chain.
  • Can be used as cationic polymers are sold under the names Polyquaternium-24 (commercial product z. B. Quatrisoft ® LM 200), known polymers.
  • Gaffix ® VC 713 manufactured by ISP:
  • the copolymers of vinylpyrrolidone such as the commercial products Copolymer 845 (ISP manufacturer) are Gafquat ® ASCP 1011, Gafquat ® HS 110, Luviquat ® 8155 and Luviquat ® MS 370 available are.
  • the skin conditioning conditioning agents according to the invention comprise at least one cationic polymer which is selected from the group formed from cationic cellulose derivatives, cationic guar derivatives and / or polyquaternium-7 (Merquat 550) , Polyquaternium-6, Polyquaternium-10 and / or Polyquaternium-67 (SOFTCAT ® polymers).
  • the cationic polymer (s) is / are contained in the cleaning compositions according to the invention in amounts of from 0.1 to 5% by weight, based on their total weight. Amounts of 0.2 to 3 wt .-%, in particular from 0.5 to 2 wt .-%, are particularly preferred.
  • plant extracts suitable according to the invention are meant extracts which can be prepared from all parts of a plant.
  • extracts are produced by extraction of the whole plant. However, in individual cases it may also be preferred to prepare the extracts exclusively from flowers and / or leaves of the plant.
  • alcohols and mixtures thereof can be used.
  • the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as sole extractant and in admixture with water, are preferred.
  • Extra kte plants based on water / propylene glycol in a ratio of 1:10 to 10: 1 have proven to be particularly suitable.
  • the plant extracts can be used according to the invention both in pure and in diluted form. If they are used in diluted form, they usually contain about 2 to 80 wt .-% of active substance and as a solvent used in their extraction agent or extractant mixture.
  • compositions according to the invention may prove advantageous to add in the compositions according to the invention humectants or penetration aids and / or swelling agents (M). These excipients provide better penetration of active ingredients into the keratin fiber or help swell the keratin fiber.
  • urea and urea derivatives include, for example, urea and urea derivatives, guanidine and its derivatives, arginine and its derivatives, water glass, imidazole and its derivatives, histidine and its derivatives, benzyl alcohol, glycerol, glycol and glycol ethers, propylene glycol and propylene glycol ethers, for example propylene glycol monoethyl ether, carbonates, bicarbonates, Diols and triols, and in particular 1, 2-diols and 1, 3-diols such as 1, 2-propanediol, 1, 2-pentanediol, 1, 2-hexanediol, 1, 2-dodecanediol, 1, 3-propanediol, 1 , 6-hexanediol, 1, 5-pentanediol, 1, 4-butanediol.
  • Particularly suitable according to the invention is glycerol.
  • the humectants are in the cleaning compositions according to the invention - based on the total composition - in amounts of 0.01 to 10 wt .-%, preferably in amounts of 0.05 to 5 wt .-% and in particular in amounts of 0.1 to 3 % By weight used.
  • the use of other nourishing substances - in particular of oil components - can adversely affect the stability and the cleaning compositions according to the invention.
  • a mixture of solubilizers is added, which are selected from the group of a) ethoxylated fatty alcohols, b) ethoxylated hydrogenated castor oils and c) ethoxylated mono-, di- or triglycerol esters, the ratio of components a): b): c) being in the range of 1: (2-4) :( 3-4).
  • the first obligatory component a) of the emulsifier mixture is an ethoxylated fatty alcohol, which is a straight-chain or branched, saturated or unsaturated C 8 - C 22 fatty alcohol, preferably a C 10 -C 2 o-fatty alcohol, more preferably a C 12 -C 18 - fatty alcohol, and in particular a C 13 -C 15 fatty alcohol with a degree of ethoxylation of 1 to 18, preferably from 5 to 16, more preferably from 7 to 14 and especially from 8 to 12, acts.
  • ethoxylated fatty alcohol which is a straight-chain or branched, saturated or unsaturated C 8 - C 22 fatty alcohol, preferably a C 10 -C 2 o-fatty alcohol, more preferably a C 12 -C 18 - fatty alcohol, and in particular a C 13 -C 15 fatty alcohol with a degree of ethoxylation of 1 to 18, preferably from 5 to 16, more preferably from 7 to 14 and especially from 8
  • Preferred components a) according to the invention are, for example, deceth-5, deceth-7, undeceth-7, laureth-4, laureth-5, laureth-6, laureth-7, laureth-8, laureth-9, laureth-10, laureth-12 , Trideceth-5, Trideceth-7, Trideceth-8, Trideceth-9, Trideceth-10, Triedceth-12, Myreth-8, Myreth-10 and Myreth-12.
  • Particularly preferred are laureth-7, laureth-8, laureth-9, laureth-10, trideceth-5, trideceth-7, trideceth-8, trideceth-9, trideceth-10, and most preferred is trideceth-9.
  • Component b) according to the invention is ethoxylated hydrogenated castor oil having a degree of ethoxylation of from 5 to 80, preferably from 10 to 60, particularly preferably from 25 to 50 and in particular from 35 to 45.
  • PEG-10 Hydrogenated Castor OiI PEG-25 Hydrogenated Castor OiI, PEG-40 Hydrogenated Castor OiI and PEG-60 Hydrogenated Castor OiI
  • PEG-40 Hydrogenated Castor OiI is especially suitable, as for example under the trade name Cremophor ® RH 410 or Eumulgin ® HRE 455 is commercially available.
  • components a) and b). it is also possible to use components a) and b). to be used in a mixture.
  • so-called “solubilizer” mixtures are commercially available, for example under the name solubilizer ® 61 1674 or solubilizer ® 660 352 available.
  • the third essential component c) of the emulsifier mixture is a monoester and / or a mixture of monoesters and diesters of glycerol with branched, or straight-chain, saturated or unsaturated fatty acids having a C chain length of 8 to 24, preferably 10 to 18 and in particular 12 to 16, which have a degree of ethoxylation of 1 to 20, preferably from 2 to 17, particularly preferably from 4 to 13 and in particular from 6 to 10.
  • Ethoxylated glyceryl oleates and Glycerylcocoate According to the invention, and particularly preferred is PEG-7 glyceryl cocoate, such as is available commercially for example under the name Tegosoft ® GC or Cetiol ® HE.
  • the cleaning compositions according to the invention are suitable as cosmetic compositions for cleansing the skin and / or the hair, such as hair shampoos, shower gels, shower baths, washing gels, facial cleansers, hand washing agents and / or bubble baths.
  • cosmetic compositions for cleansing the skin and / or the hair
  • it may contain, in addition to the abovementioned mandatory and preferred optional components, other active ingredients, auxiliaries and additives which are described below.
  • quaternary ammonium compounds are ammonium halides, especially chlorides and bromides, such as Alkyltrimethylammoniumchloride, Dialkyldimethylammoniumchloride and trialkyl methylammonium chlorides, z.
  • cetyltrimethylammonium chloride stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as the imidazolium compounds known under the INCI names Quaternium-27 and Quaternium-83.
  • the long alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms.
  • Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element.
  • Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines.
  • Such products are marketed under the trade names Stepantex® ®, ® and Dehyquart® Armocare® ®.
  • the products Armocare ® VGH-70, a N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, as well as Dehyquart ® F-75, Dehyquart ® C-4046, Dehyquart ® L80 and Dehyquart ® AU-35 are examples of such esterquats.
  • the alkylamidoamines are usually prepared by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines.
  • the cationic surfactants are preferably used in amounts of 0.05 to 10 wt .-%, based on the detergent as a whole , Amounts of 0.1 to 5 wt .-% are particularly preferred.
  • protein hydrolysates and / or derivatives thereof can be used to increase the activity of the composition according to the invention.
  • Protein hydrolysates are product mixtures obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins). According to the invention, protein hydrolysates of both vegetable and animal origin can be used.
  • Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein protein hydrolysates, which may also be present in the form of salts.
  • Such products are, for example, under the trademarks Dehylan ® (Cognis), Promois® ® (Interorgana) Collapuron ® (Cognis), Nutrilan® ® (Cognis), Gelita-Sol ® (German Gelatinefabriken Stoess & Co), Lexein ® (Inolex) and kerasol tm ® (Croda) sold.
  • Preferred according to the invention are protein hydrolysates of plant origin, eg. Soybean, almond, rice, pea, potato and wheat protein hydrolysates.
  • Such products are, for example, under the trademarks Gluadin ® (Cognis), diamine ® (Diamalt) ® (Inolex) and Crotein ® (Croda) available.
  • protein hydrolysates are preferred as such, amino acid mixtures or individual amino acids obtained otherwise, such as, for example, arginine, lysine, histidine or pyrroglutamic acid, may also be used in their place.
  • derivatives of protein hydrolysates for example in the form of their fatty acid condensation products. Such products are for example among the Designations Lamepon® ® (Cognis), Gluadin® ® (Cognis), Lexein ® (Inolex), Crolastin ® (Croda) or crotein ® (Croda) sold.
  • Cationized protein hydrolysates can also be used according to the invention, the protein hydrolyzate on which the animal is based, for example from collagen, milk or keratin, from the plant, for example from wheat, maize, rice, potatoes, soy or almonds, from marine life forms, for example from fish collages or algae , or from biotechnologically derived protein hydrolysates, can originate.
  • the protein hydrolyzates on which the cationic derivatives according to the invention are based can be obtained from the corresponding proteins by chemical, in particular alkaline or acid hydrolysis, by enzymatic hydrolysis and / or a combination of both types of hydrolysis.
  • cationic protein hydrolyzates are to be understood as meaning quaternized amino acids and mixtures thereof.
  • the quaternization of the protein hydrolysates or amino acids is often carried out using quaternary ammonium salts such as N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halides.
  • the cationic protein hydrolysates may also be further derivatized.
  • Typical examples of the cationic protein hydrolysates and derivatives according to the invention include the products mentioned under the INCI names: Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimopnium Hydroxypropyl Hydrolyzed Casein, Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydrolyzed Hair Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl SiCl Amino Acids, Hydroxypropyl Arginine Lauryl / Myristyl Ether HCl, Hydr
  • the protein hydrolysates and their derivatives are preferably used in amounts of from 0.01 to 10% by weight, based on the total agent. Amounts of from 0.1 to 5% by weight, in particular from 0.1 to 3% by weight, are very particularly preferred.
  • composition according to the invention with vitamins, provitamins and vitamin precursors and derivatives thereof.
  • vitamins, pro-vitamins and vitamin precursors are preferred, which are usually assigned to groups A, B, C, E, F and H.
  • the group of substances called vitamin A includes retinol (vitamin A 1 ) and 3,4-didehydroretinol (vitamin A 2 ).
  • the ß-carotene is the provitamin of retinol.
  • vitamin A component according to the invention for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as the palmitate and the acetate into consideration.
  • the vitamin A component is preferably used in amounts of 0.05-1 wt .-%, based on the total preparation.
  • the vitamin B group or the vitamin B complex include, among others
  • Vitamin B 3 • Vitamin B 3 .
  • the compounds nicotinic acid and nicotinamide (niacinamide) are often performed.
  • Preferred according to the invention is the nicotinic acid amide, which is preferably used in amounts of from 0.05 to 1% by weight, based on the total agent.
  • Vitamin B 5 pantothenic acid and panthenol.
  • panthenol is preferred.
  • Derivatives of panthenol which can be used according to the invention are, in particular, the esters and ethers of panthenol and also cationically derivatized panthenols. Individual representatives are, for example, the panthenol triacetate, the panthenol monoethyl ether and its monoacetate and also the cationic panthenol derivatives disclosed in WO 92/13829.
  • the said compounds of the vitamin B 5 type are preferably used in amounts of 0.05-10% by weight, based on the total agent. Amounts of 0.1-5 wt .-% are particularly preferred.
  • Vitamin B 6 pyridoxine and pyridoxamine and pyridoxal
  • Vitamin C (ascorbic acid).
  • the usual amount used of vitamin C is 0.1 to 3 wt .-%, based on the total agent.
  • Use in the form of palmitic acid ester, glucosides or phosphates may be preferred.
  • the use in combination with tocopherols may also be preferred.
  • Vitamin E tocopherols, especially ⁇ -tocopherol.
  • Tocopherol and its derivatives which include in particular the esters such as the acetate, the nicotinate, the phosphate and the succinate, are used according to the invention preferably in amounts of 0.05-1% by weight, based on the total agent.
  • Vitamin F is usually understood as meaning essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.
  • Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] - imidazole-4-valeric acid, for which, however, meanwhile, the trivial name biotin has prevailed.
  • Biotin is preferably used in amounts of from 0.0001 to 1.0% by weight, in particular in amounts of from 0.001 to 0.01% by weight.
  • Particularly preferred according to the invention is the use of vitamins, provitamins and vitamin precursors from groups A, B, E and H. Panthenol and its derivatives as well as nicotinic acid amide and biotin are particularly preferred.
  • a UV filter (I) can additionally be used.
  • the UV filters to be used according to the invention are not subject to any general restrictions with regard to their structure and their physical properties. On the contrary, all UV filters which can be used in the cosmetics sector and whose absorption maximum lies in the UVA (315-400 nm), in the UVB (280-315 nm) or in the UVC ( ⁇ 280 nm) range are suitable. UV filters with an absorption maximum in the UVB range, in particular in the range from about 280 to about 300 nm, are particularly preferred.
  • the UV filters can be selected, for example, from substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylic acid esters, cinnamic acid esters, salicylic acid esters, benzimidazoles and o-aminobenzoic acid esters.
  • UV filters which have a cationic group, in particular a quaternary ammonium group.
  • Two preferred UV filters with cationic groups are the commercially available compounds cinnamic acid-trimethylammonium chloride (lncroquat ® UV-283) and dodecyl tosylate (Escalol ® HP 610).
  • the one or more UV filters (I) are usually used in amounts of 0.1-5 wt .-%, based on the total agent. Levels of 0.4-2.5 wt .-% are preferred.
  • cosmetic cleansing preparations there are no fundamental restrictions.
  • creams, lotions, solutions, waters emulsions such as W / O, O / W, PIT emulsions (called phase inversion emulsions, PIT), microemulsions and multiple emulsions, coarse, unstable, one or more multi-phase shaking mixtures, gels, sprays, aerosols and foam aerosols suitable.
  • emulsions such as W / O, O / W, PIT emulsions (called phase inversion emulsions, PIT), microemulsions and multiple emulsions, coarse, unstable, one or more multi-phase shaking mixtures, gels, sprays, aerosols and foam aerosols suitable.
  • PIT phase inversion emulsions
  • microemulsions and multiple emulsions coarse, unstable, one or more multi-phase shaking mixtures, gels, sprays, aerosols and foam aerosols suitable.
  • auxiliaries and additives are, for example: Thickening agents such as gelatin or vegetable gums, for example agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. As methyl cellulose, hydroxyalkyl cellulose and carboxymethyl cellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays and phyllosilicates such. As bentonite or fully synthetic hydrocolloids such. Polyvinyl alcohol, Ca, Mg or Zn soaps, structurants such as maleic acid and lactic acid,
  • Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol, fiber-structure-improving active ingredients, especially mono-, di- and oligosaccharides such as glucose, galactose, fructose, fructose and lactose, dyes for staining the agent, other substances for adjusting the pH, such as ⁇ - and ß-hydroxycarboxylic acids, drugs such as allantoin and bisabolol,
  • Ceramides are understood as meaning N-acylsphingosine (fatty acid amides of sphingosine) or synthetic analogues of such lipids (so-called pseudo-ceramides), opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers, pearlescing agents such as ethylene glycol mono- and distearate and PEG-3 distearate, pigments,
  • a second subject of the invention is the use of a combination of a) a surfactant mixture b) benzoic acid or a salt of benzoic acid and c) at least one compound of the formula I,
  • R 1 is a methyl, ethyl, propyl, isopropyl, butyl, hydroxymethyl, hydroxyethyl, ethyl glycol, hydroxypropyl or 1, 2-dihydroxypropyl group
  • R 2 is hydrogen or a methyl, ethyl, propyl -, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, benzyl, -CH 2 -O-CH (C 2 H 5 ) - CH 2 CH 2 CH 2 CH 3 group and
  • R 3 is hydrogen or a methyl, ethyl, propyl, isopropyl, butyl, benzyl group, with the proviso that R 2 and R 3 are not simultaneously hydrogen, as a cleansing and deodorizing drug mixture in a shampoo, shower gel, shower bath, wash gel, facial cleanser and / or hand wash.
  • a third object of the invention is a process for the simultaneous cleaning, care and deodorization of human keratin fibers, in particular human skin, characterized in that a cleaning composition according to the invention is applied to the keratin fibers, distributed, and rinsed with water again.
  • the following examples serve to illustrate the invention.
  • the cleansing of the skin with cleansing compositions 1 or 2 resulted in effectively cleansed skin that felt soft and well-groomed. Furthermore, the cleaning compositions on the skin were deodorant. This deodorant effect lasted up to 24 hours.

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Abstract

L'invention concerne des compositions nettoyantes cosmétiques à effet désodorisant qui contiennent a) un mélange tensioactif, b) de l'acide benzoïque ou un sel de l'acide benzoïque, c) au moins un composé de formule (I) dans laquelle R1 représente un groupe méthyle, éthyle, propyle, isopropyle, butyle, hydroxyméthyle, hydroxyéthyle, éthylglycol, hydroxypropyle ou 1,2-dihydroxypropyle, R2 représente hydrogène ou un groupe méthyle, éthyle, propyle, isopropyle, butyle, pentyle, hexyle, heptyle, octyle, benzyle, -CH2-O-CH(C2H5)-CH2CH2CH2CH3 et R3 représente hydrogène ou un groupe méthyle, éthyle, propyle, isopropyle, butyle, benzyle, à condition que R2 et R3 ne représentent pas simultanément hydrogène.
PCT/EP2010/057692 2009-06-10 2010-06-02 Produit nettoyant cosmétique à effet désodorisant Ceased WO2010142586A2 (fr)

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JP2012219028A (ja) * 2011-04-05 2012-11-12 Lion Corp 粉体含有化粧料
CN110314104A (zh) * 2019-06-17 2019-10-11 重庆中妆科技有限公司 一种止汗除臭洗剂

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DE3723826A1 (de) 1987-07-18 1989-01-26 Henkel Kgaa Verfahren zur herstellung von alkylglykosiden
DE3725030A1 (de) 1987-07-29 1989-02-09 Henkel Kgaa Oberflaechenaktive hydroxysulfonate
DE3833780A1 (de) 1988-10-05 1990-04-12 Henkel Kgaa Verfahren zur direkten herstellung von alkylglykosiden
DE3926344A1 (de) 1989-08-09 1991-02-28 Henkel Kgaa Verfahren zur herstellung von hellfarbigen oelsaeuresulfonaten
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DE19736906A1 (de) 1997-08-25 1999-03-04 Henkel Kgaa Verfahren zur Herstellung von sulfatierten Fettsäurealkylenglykolestern
DE19738866A1 (de) 1997-09-05 1999-03-11 Henkel Kgaa Schaumarme Tensidmischungen mit Hydroxymischethern
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FR2869797B1 (fr) * 2004-05-10 2007-10-19 Oreal Composition cosmetique ou dermatologique a base d'un tensioactif, d'un acide monocarboxylique et d'un polyol
EP2306820B1 (fr) * 2008-07-10 2015-09-09 Symrise AG Compositions comprenant un dérivé d'alcool benzylique et d'autres composés à action antimicrobienne

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Publication number Priority date Publication date Assignee Title
JP2012219028A (ja) * 2011-04-05 2012-11-12 Lion Corp 粉体含有化粧料
CN110314104A (zh) * 2019-06-17 2019-10-11 重庆中妆科技有限公司 一种止汗除臭洗剂

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