WO2011069264A1 - Procédé d'extraction de gaz effectué avec de d'alcool - Google Patents

Procédé d'extraction de gaz effectué avec de d'alcool Download PDF

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Publication number
WO2011069264A1
WO2011069264A1 PCT/CA2010/001970 CA2010001970W WO2011069264A1 WO 2011069264 A1 WO2011069264 A1 WO 2011069264A1 CA 2010001970 W CA2010001970 W CA 2010001970W WO 2011069264 A1 WO2011069264 A1 WO 2011069264A1
Authority
WO
WIPO (PCT)
Prior art keywords
acid
gas
alcohol
media
stripping
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CA2010/001970
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English (en)
Inventor
Adisorn Aroonwilas
Amornvadee Veawab
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Regina
Original Assignee
University of Regina
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Regina filed Critical University of Regina
Priority to AU2010330659A priority Critical patent/AU2010330659A1/en
Priority to JP2012542325A priority patent/JP2013512772A/ja
Priority to CA2783720A priority patent/CA2783720A1/fr
Priority to CN2010800604923A priority patent/CN102695553A/zh
Priority to EP10835349.1A priority patent/EP2509703A4/fr
Priority to US13/515,264 priority patent/US20130008310A1/en
Publication of WO2011069264A1 publication Critical patent/WO2011069264A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425—Regeneration of liquid absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/96—Regeneration, reactivation or recycling of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/0005—Degasification of liquids with one or more auxiliary substances
    • B01D19/001—Degasification of liquids with one or more auxiliary substances by bubbling steam through the liquid
    • B01D19/0015—Degasification of liquids with one or more auxiliary substances by bubbling steam through the liquid in contact columns containing plates, grids or other filling elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/38—Removing components of undefined structure
    • B01D53/40—Acidic components
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B01D2252/20447—Cyclic amines containing a piperazine-ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20489—Alkanolamines with two or more hydroxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/404—Nitrogen oxides other than dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Definitions

  • This disclosure relates to a method for stripping acid gases such as carbon dioxide from an absorption or adsorption medium.
  • the disclosure further relates to processes, uses, and apparatus.
  • Gas absorption, separation and recovery processes have long been provided for both industrial and environmental purposes.
  • Industrial applications typically involve the separation and removal of at least one gaseous component from a process gas stream in order to enhance the quality of gas products produced and/or to prevent undesirable downstream operational problems that might subsequently occur in downstream processes. Examples include the removal of C0 2 and/or hydrogen sulfide (H 2 S) from natural gas and synthesis gas or the removal of volatile organic compounds (VOCs) or other gases (e.g. nitrogen (N 2 ), oxygen (0 2 ), hydrogen (3 ⁇ 4)) from industrial process gas streams.
  • VOCs volatile organic compounds
  • Environmental applications typically involve the removal of at least one gaseous component such as S0 2 , C0 2 , NO x , or mercury (Hg) from combustion flue or exhaust gas streams in order to reduce emissions of pollutants.
  • Most acid gas removal methods include a step for regenerating the absorption or adsorption medium. This step is variously known as desorption, regeneration, or stripping.
  • One common method of performing the stripping step (for example, in C0 2 removal process) is to contact the C0 2 -rich scrubbing medium with steam. The steam drives off the C0 2 from the medium and the C0 2 -lean medium can be reused. The energy required to generate the steam is costly and reduces the overall efficiency of the system.
  • the present disclosure relates to a method for stripping acid gases, exemplified by carbon dioxide, from absorption media and/or adsorption media using an alcohol selected from those having a boiling point lower than the boiling point of the absorption medium and/or adsorption medium.
  • the disclosure further provides the use of gaseous alcohols and/or alcohol vapours, for stripping an acid gas from absorption media and/or adsorption media.
  • the disclosure further provides use of heat recovery apparatus and processes for regeneration and recirculation of an alcohol stripping component (or carrier). It is optional to employ exogenous low-grade heat inputs for regeneration and recirculation of an alcohol stripping component (or carrier).
  • the disclosure further provides the use of heat pumps for recovery and utilization of waste heat generated during the gas-stripping processes.
  • the disclosure further provides a process for stripping an acid gas from an absorption medium and/or adsorption medium, said process comprising:
  • the disclosure further provides an apparatus for stripping an acid gas from absorption medium and/or adsorption medium.
  • the term 'rich absorption and/or adsorption media' refers to media that has absorbed a relatively greater amount of acid gas compared to lean media.
  • the term 'lean absorption and/or adsorption media' refers to media that comprises no or low amounts of acid gas.
  • 'acid gas' refers to gases that form acidic solutions when mixed with water.
  • boiling point' refers to the boiling point at standard temperature and pressure.
  • Fig. 1 is a schematic representation of an exemplary apparatus suitable for operation therein of an exemplary process of the present disclosure for alcohol-based C0 2 stripping process from absorption media;
  • Fig. 2 is a schematic representation of an exemplary apparatus suitable for operation therein of an exemplary process of the present disclosure for alcohol-based C0 2 stripping process from adsorption media.
  • a method of stripping acid gas from absorption media and/or adsorption media using alcohols Any suitable alcohol may be used herein.
  • any suitable alcohol such as Ci-C 6 or Cj-C 4 alcohols may be used herein.
  • Exemplary alcohols include methanol, ethanol, iso-propanol, n-propanol, and combinations thereof. While not wishing to be bound by theory, it is believed that, because the stripping solvent vaporises at a lower temperature, the present disclosure allows the stripping to be performed at lower temperatures compared to the conventional stripping operation using steam. This can save energy and improve the efficiency of regeneration of media (absorbent and/or adsorbent).
  • the present disclosure allows for different materials to be used in the construction of the apparatus used for the stripping process. Such materials may, for example, be lighter and/or cheaper than those currently used. In addition, it may be possible to use low-quality heat sources such as geothermal energy for the stripping process.
  • the present method may be used to strip any suitable gas from an absorption medium and/or adsorption medium.
  • gases that may be stripped are exemplified by C0 2 , NO x , S0 2 , and the like.
  • the present disclosure provides for stripping acid gas from an absorption medium and/or adsorption medium.
  • absorption media are liquids and adsorption media are solids. Any suitable type of absorption media may be stripped using the present method.
  • absorption media include, but are not limited to, monoethanolamine (MEA), diglycolamine (DGA), diethanolamine (DEA), methyldiethanolamine (MDEA), 2-amino-2-methyl-l-propanol (AMP), piperazine (PZ), ammonia, amines, alkanolamines, derivatives and/or combinations thereof. These amines should be used as aqueous solutions.
  • the alcohol stripper preferably has a lower boiling point than the absorption media and/or adsorption media so that the alcohol is a vapour, i.e., gaseous form when it contacts the media.
  • rich absorption media is delivered to a stripping vessel.
  • the rich media may conveniently be delivered to, or near, the top of the stripping vessel.
  • the rich media may be packed in an adsorption vessel where its operation is switched to the stripping mode.
  • An alcohol such as methanol, ethanol, iso-propanol, and/or n-propanol, is delivered to the stripping vessel.
  • the alcohol may conveniently be delivered at, or near, the bottom of the stripping vessel or at various points in the vessel.
  • the alcohol may be delivered as a gas or a vapour. Alternatively, the alcohol may be converted to a gas or a vapour in situ.
  • the gaseous alcohol rises through the vessel and contacts the descending absorption media and/or adsorption media. This contact allows the alcohol to strip at least a portion of the acid gas from the media.
  • the lean media can be collected and, if desired, recycled.
  • the acid gas- alcohol vapour rises through the vessel, leaves the vessel and may be cooled, preferably via a heat-recovery and exchange mechanism, and condensed to separate the alcohol and acid gas.
  • the alcohol may be reused for further stripping.
  • the acid gas may be collected for storage, and then used for other industrial purposes or disposed of in another suitable manner.
  • the heat recovered in the heat-recovery and exchange mechanism may, for example, be transmitted to an alcohol vapour generator (reboiler) via a heat-pump thus improving the efficiency of the system.
  • the vessel may be of any suitable type.
  • suitable gas-liquid or gas-solid contactors For example, packed, membrane, module, spray, tray vessels may be used. Or a suitable combination thereof.
  • the vessel may be a column.
  • FIG 1 is a schematic representation of an exemplary apparatus suitable for operation therein of an exemplary process of the present disclosure for alcohol-based C0 2 stripping process from an amine absorption medium.
  • the apparatus (100) includes a heat-recovery unit (120) for generation and recirculation of alcohol vapour within C0 2 stripping process.
  • C0 2 -rich amine solution from the absorber is heated by a cross heat-exchanger (130) with C0 2 -lean solution from the stripper.
  • the heated solution is fed to the stripper (150) top, and travels downward against the upward flow of hot alcohol vapour that is introduced to the bottom and/or the sides of the stripper (150).
  • C0 2 In the presence of stripping driving force, C0 2 is released from the liquid and leaves the stripper top with alcohol vapour while C0 2 -lean solution leaves the stripper at the bottom without boiling.
  • a vapour mixture of alcohol and C0 2 from the stripper is cooled by heat recovery (122) and overhead condensers (124) to separate alcohol and C0 2 .
  • the liquid alcohol is collected in an accumulator (160) then pumped by a liquid pump (128) through the recovery condenser (122) and a reboiler (126) to evaporate into alcohol vapour before being reused in the stripper (150). Since the alcohol used is always circulated within the system, its loss and makeup rely on appropriate operating conditions of the stripper.
  • temperature of the stripper must be kept above a boiling point of alcohol but below that of absorption medium to ensure the presence of alcohol vapour and prevent a great extent of water vaporization from liquid solution.
  • the amount of alcohol vapour required and a number of alcohol injection points (152, 154, 156) along the stripper (150) height will depend on the magnitude of stripping driving force that is required.
  • a heat-pump loop (dotted lines) is applied to extract heat from overhead condenser (124) and utilize it for heating reboiler (126) at a higher temperature.
  • a heat pump with refrigerant R-134a running between 10 °C (temperature of cooling medium for condenser) and 90 °C (temperature of heating medium for reboiler) offers a heat-pump coefficient of performance (COPHP) of 2.5.
  • C0 2 stripping by alcohol vapour can be achieved at a lower temperature compared to the conventional stripping operations.
  • the lower stripping temperature may provide an opportunity to use low-quality energy drawn from power plants or low-cost heat sources, such as hot water from geothermal fields. This can lead to a significant reduction in the cost of C0 2 capture.
  • the lower stripping temperature also allows for the difference in operating temperature between absorber and stripper to be reduced, offering a potential reduction in heat- duty and size of the cross heat-exchanger used.
  • FIG. 2 is a schematic representation of an exemplary apparatus (200) suitable for operation therein of an exemplary process of the present disclosure for alcohol-based C0 stripping process from an adsorption column (210).
  • the apparatus (200) includes a heat-recovery unit (220) for generation and recirculation of alcohol vapour within C0 2 stripping process.
  • the C0 2 -rich adsorption media is one of the adsorption bed where its operation is switched to the stripping mode.
  • the CC -lean adsorption media obtained after stripping remains in the stripping column (210) where the operation is switched back to the adsorption mode.
  • an upward flow of hot alcohol vapour is introduced to the bottom (212) and at the sides (214) of the adsorption column.
  • C0 2 In the presence of stripping driving force, C0 2 is released from the adsorbent media and leaves the stripper top (216) with alcohol vapour.
  • a vapour mixture of alcohol and C0 2 from the stripper is cooled by heat recovery (222) and overhead condensers (224) to separate alcohol and C0 2 .
  • the liquid alcohol is collected in an accumulator and then pumped with a liquid pump (228) through the recovery condenser (222) and a reboiler (226) to evaporate into alcohol vapour before being reused in the stripper. Since the alcohol used is always circulated within the system, its loss and makeup rely on appropriate operating conditions of the stripper.
  • the amount of alcohol vapour required and a number of alcohol injection points along the stripper height will depend on the magnitude of stripping driving force that is required.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)

Abstract

La présente invention concerne un procédé d'extraction de gaz acides, par exemple le dioxyde de carbone, à partir d'un milieu d'absorption et/ou d'un milieu d'adsorption au moyen d'un alcool choisi parmi ceux possédant un point d'ébullition inférieur au point d'ébullition du milieu d'absorption et/ou du milieu d'adsorption.
PCT/CA2010/001970 2009-12-09 2010-12-08 Procédé d'extraction de gaz effectué avec de d'alcool Ceased WO2011069264A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
AU2010330659A AU2010330659A1 (en) 2009-12-09 2010-12-08 Alcohol-based gas stripping process
JP2012542325A JP2013512772A (ja) 2009-12-09 2010-12-08 アルコールに基づくガスのストリッピング方法
CA2783720A CA2783720A1 (fr) 2009-12-09 2010-12-08 Procede d'extraction de gaz effectue avec de d'alcool
CN2010800604923A CN102695553A (zh) 2009-12-09 2010-12-08 基于醇的气体汽提方法
EP10835349.1A EP2509703A4 (fr) 2009-12-09 2010-12-08 Procédé d'extraction de gaz effectué avec de d'alcool
US13/515,264 US20130008310A1 (en) 2009-12-09 2010-12-08 Alcohol-based gas stripping process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US26792209P 2009-12-09 2009-12-09
US61/267,922 2009-12-09

Publications (1)

Publication Number Publication Date
WO2011069264A1 true WO2011069264A1 (fr) 2011-06-16

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Family Applications (1)

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PCT/CA2010/001970 Ceased WO2011069264A1 (fr) 2009-12-09 2010-12-08 Procédé d'extraction de gaz effectué avec de d'alcool

Country Status (8)

Country Link
US (1) US20130008310A1 (fr)
EP (1) EP2509703A4 (fr)
JP (1) JP2013512772A (fr)
KR (1) KR20120116431A (fr)
CN (1) CN102695553A (fr)
AU (1) AU2010330659A1 (fr)
CA (1) CA2783720A1 (fr)
WO (1) WO2011069264A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130004406A1 (en) * 2011-06-29 2013-01-03 Kia Motors Corporation Carbon dioxide recovery system and method of exhaust gas
CN102895843A (zh) * 2012-09-24 2013-01-30 天津大学 一种采用超高温热泵回收利用mdea脱碳工艺余热的系统
FR2982169A1 (fr) * 2011-11-03 2013-05-10 IFP Energies Nouvelles Procede de captation de co2 par un solvant aux amines avec regeneration du solvant par utilisation d'une source geothermale

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Publication number Priority date Publication date Assignee Title
GB0922142D0 (en) * 2009-12-18 2010-02-03 Doosan Babcock Energy Ltd Regeneration of absorption solution
MX2013004816A (es) 2010-10-29 2013-07-02 Mecs Inc Recuperacion regenerativa de dioxido de azufre de gases efluentes.
US9492786B2 (en) * 2011-11-22 2016-11-15 Fluor Corporation Multi-purpose absorber
US10000383B2 (en) 2013-05-28 2018-06-19 The Kansai Electric Power Co., Inc. CO2 recovery apparatus and CO2 recovery method
US9533253B2 (en) * 2014-06-05 2017-01-03 Phillips 66 Company Amine solvent blends
JP6449099B2 (ja) * 2015-05-25 2019-01-09 株式会社神戸製鋼所 放出処理装置及び放出処理方法
CN106178895A (zh) * 2016-08-25 2016-12-07 中石化炼化工程（集团）股份有限公司 一种低能耗烟气脱硫工艺
CN108722118B (zh) * 2018-05-28 2020-08-04 中石化（洛阳）科技有限公司 一种低能耗脱硫剂再生方法及脱硫方法
CN110732150B (zh) * 2018-07-18 2021-10-22 中国石油化工股份有限公司 一种废甲醇的精馏吸附净化工艺
JP7524086B2 (ja) * 2021-01-15 2024-07-29 株式会社東芝 二酸化炭素回収システムおよび二酸化炭素回収システムの運転方法
EP4674509A1 (fr) * 2024-07-05 2026-01-07 Siemens Aktiengesellschaft Procédé et dispositif pour séparer le dioxyde de carbone d'un mélange gazeux

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US3324627A (en) * 1961-03-18 1967-06-13 Metallgesellschaft Ag Process for the purification of gases
US3846536A (en) * 1972-09-07 1974-11-05 Exxon Research Engineering Co Regeneration process for flue gas sorbent
US4302220A (en) * 1979-06-07 1981-11-24 Basf Aktiengesellschaft Simultaneous removal of water and hydrogen sulfide from gases
US4670027A (en) * 1985-02-06 1987-06-02 Linde Aktiengesellschaft Process for regeneration of a loaded scrubbing medium

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FR2482979A1 (fr) * 1980-05-22 1981-11-27 Commissariat Energie Atomique Procede de distillation de l'alcool comportant l'utilisation d'une pompe a chaleur, et dispositif de mise en oeuvre de ce procede
MXPA05010713A (es) * 2003-04-04 2006-05-19 Univ Texas Mezclas de sal alcali/poliamina para la eliminacion de dioxido de carbono de flujos de gas.
FR2863910B1 (fr) * 2003-12-23 2006-01-27 Inst Francais Du Petrole Procede de capture du dioxyde de carbone contenu dans des fumees
WO2007012143A1 (fr) * 2005-07-29 2007-02-01 Commonwealth Scientific And Industrial Research Organisation Recuperation de dioxyde de carbone a partir de gaz de combustion

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3324627A (en) * 1961-03-18 1967-06-13 Metallgesellschaft Ag Process for the purification of gases
US3846536A (en) * 1972-09-07 1974-11-05 Exxon Research Engineering Co Regeneration process for flue gas sorbent
US4302220A (en) * 1979-06-07 1981-11-24 Basf Aktiengesellschaft Simultaneous removal of water and hydrogen sulfide from gases
US4670027A (en) * 1985-02-06 1987-06-02 Linde Aktiengesellschaft Process for regeneration of a loaded scrubbing medium

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2509703A4 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130004406A1 (en) * 2011-06-29 2013-01-03 Kia Motors Corporation Carbon dioxide recovery system and method of exhaust gas
US8894953B2 (en) * 2011-06-29 2014-11-25 Hyundai Motor Company Carbon dioxide recovery system and method of exhaust gas
US20150037238A1 (en) * 2011-06-29 2015-02-05 Hyundai Motor Company Carbon dioxide recovery system and method of exhaust gas
FR2982169A1 (fr) * 2011-11-03 2013-05-10 IFP Energies Nouvelles Procede de captation de co2 par un solvant aux amines avec regeneration du solvant par utilisation d'une source geothermale
CN102895843A (zh) * 2012-09-24 2013-01-30 天津大学 一种采用超高温热泵回收利用mdea脱碳工艺余热的系统

Also Published As

Publication number Publication date
AU2010330659A1 (en) 2012-07-26
JP2013512772A (ja) 2013-04-18
EP2509703A1 (fr) 2012-10-17
CA2783720A1 (fr) 2011-06-16
EP2509703A4 (fr) 2014-01-22
CN102695553A (zh) 2012-09-26
KR20120116431A (ko) 2012-10-22
US20130008310A1 (en) 2013-01-10

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