WO2011091202A3 - Procédé de traitement d'une charge contenant des hydrocarbures - Google Patents

Procédé de traitement d'une charge contenant des hydrocarbures Download PDF

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Publication number
WO2011091202A3
WO2011091202A3 PCT/US2011/021967 US2011021967W WO2011091202A3 WO 2011091202 A3 WO2011091202 A3 WO 2011091202A3 US 2011021967 W US2011021967 W US 2011021967W WO 2011091202 A3 WO2011091202 A3 WO 2011091202A3
Authority
WO
WIPO (PCT)
Prior art keywords
metal
chain
hydrocarbon
containing feed
comprised
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2011/021967
Other languages
English (en)
Other versions
WO2011091202A2 (fr
Inventor
Stanley Nemec Milam
Michael Anthony Reynolds
Scott Lee Wellington
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Shell USA Inc
Original Assignee
Shell Internationale Research Maatschappij BV
Shell Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV, Shell Oil Co filed Critical Shell Internationale Research Maatschappij BV
Priority to CA2785512A priority Critical patent/CA2785512A1/fr
Priority to EP11701439A priority patent/EP2526174A2/fr
Publication of WO2011091202A2 publication Critical patent/WO2011091202A2/fr
Publication of WO2011091202A3 publication Critical patent/WO2011091202A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/24—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles
    • C10G47/26—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles suspended in the oil, e.g. slurries
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
    • B01J27/0515—Molybdenum with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/06—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention concerne un procédé de traitement d'une charge contenant des hydrocarbures, dans lequel une charge contenant des hydrocarbures comprenant au moins 20% en poids d'hydrocarbures lourds est mélangée à de l'hydrogène, du sulfure d'hydrogène et à un catalyseur pour produire un produit contenant des hydrocarbures. Le catalyseur est constitué d'un matériau composé d'un premier métal et d'un second métal, le premier métal étant sélectionné dans le groupe comprenant Cu, Fe, Ni, Co, Bi, Ag, Mn, Zn, Sn, Ru, La, Pr, Sm, Eu, Yb, Lu, Dy, Pb, et Sb et le second métal étant Mo, W, Sn et Sb, le matériau étant constitué d'au moins trois éléments de chaîne liés, les éléments de chaîne comprenant un premier élément de chaîne comportant le premier métal et présentant une structure représentée par la formule (I) et un second élément de chaîne comportant le second métal et présentant une structure représentée par la formule (II), où M1 désigne le premier métal, où M2 désigne le second métal, où le matériau contient au moins un premier élément de chaîne et au moins un second élément de chaîne et où les éléments de chaîne présents dans le matériau sont liés par des liaisons entre les deux atomes de soufre d'un élément de chaîne et le métal d'une chaîne adjacente.
PCT/US2011/021967 2010-01-21 2011-01-21 Procédé de traitement d'une charge contenant des hydrocarbures Ceased WO2011091202A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CA2785512A CA2785512A1 (fr) 2010-01-21 2011-01-21 Procede de traitement d'une charge contenant des hydrocarbures
EP11701439A EP2526174A2 (fr) 2010-01-21 2011-01-21 Procédé de craquage d'une charge contenant des hydrocarbures

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US29711810P 2010-01-21 2010-01-21
US61/297,118 2010-01-21

Publications (2)

Publication Number Publication Date
WO2011091202A2 WO2011091202A2 (fr) 2011-07-28
WO2011091202A3 true WO2011091202A3 (fr) 2012-04-19

Family

ID=44168134

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/021967 Ceased WO2011091202A2 (fr) 2010-01-21 2011-01-21 Procédé de traitement d'une charge contenant des hydrocarbures

Country Status (3)

Country Link
EP (1) EP2526174A2 (fr)
CA (1) CA2785512A1 (fr)
WO (1) WO2011091202A2 (fr)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2159511A (en) * 1934-01-11 1939-05-23 Standard Ig Co Carrying out catalytic reactions
EP0133031A1 (fr) * 1983-07-29 1985-02-13 Exxon Research And Engineering Company Catalyseurs auto-promoteurs en masse et supportés, de sulfure de molybdène et de tungstène, formés à partir de progéniteurs bis(tétrathiométallates) et leur préparation et leur usage pour l'hydrotraitement
EP0145105A2 (fr) * 1983-08-29 1985-06-19 Chevron Research And Technology Company Traitement à l'hydrogène d'huiles lourdes
US4795731A (en) * 1984-04-02 1989-01-03 Exxon Research And Engineering Company Transition metal sulfide promoted molybdenum or tungsten sulfide catalysts and their uses for hydroprocessing
US4820677A (en) * 1984-04-02 1989-04-11 Jacobson Allan J Amorphous, iron promoted Mo and W sulfide hydroprocessing catalysts and process for their preparation
WO2008141831A1 (fr) * 2007-05-23 2008-11-27 Eni S.P.A. Système et procédé d'hydroconversion des huiles lourdes
WO2008141830A1 (fr) * 2007-05-23 2008-11-27 Eni S.P.A. Procédé d'hydroconversion d'huiles lourdes
US20090011931A1 (en) * 2004-09-10 2009-01-08 Kaidong Chen Highly Active Slurry Catalyst Composition
US20090023965A1 (en) * 2008-05-01 2009-01-22 Intevep, S.A. Dispersed metal sulfide-based catalysts

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2159511A (en) * 1934-01-11 1939-05-23 Standard Ig Co Carrying out catalytic reactions
EP0133031A1 (fr) * 1983-07-29 1985-02-13 Exxon Research And Engineering Company Catalyseurs auto-promoteurs en masse et supportés, de sulfure de molybdène et de tungstène, formés à partir de progéniteurs bis(tétrathiométallates) et leur préparation et leur usage pour l'hydrotraitement
EP0145105A2 (fr) * 1983-08-29 1985-06-19 Chevron Research And Technology Company Traitement à l'hydrogène d'huiles lourdes
US4795731A (en) * 1984-04-02 1989-01-03 Exxon Research And Engineering Company Transition metal sulfide promoted molybdenum or tungsten sulfide catalysts and their uses for hydroprocessing
US4820677A (en) * 1984-04-02 1989-04-11 Jacobson Allan J Amorphous, iron promoted Mo and W sulfide hydroprocessing catalysts and process for their preparation
US20090011931A1 (en) * 2004-09-10 2009-01-08 Kaidong Chen Highly Active Slurry Catalyst Composition
WO2008141831A1 (fr) * 2007-05-23 2008-11-27 Eni S.P.A. Système et procédé d'hydroconversion des huiles lourdes
WO2008141830A1 (fr) * 2007-05-23 2008-11-27 Eni S.P.A. Procédé d'hydroconversion d'huiles lourdes
US20090023965A1 (en) * 2008-05-01 2009-01-22 Intevep, S.A. Dispersed metal sulfide-based catalysts

Also Published As

Publication number Publication date
EP2526174A2 (fr) 2012-11-28
WO2011091202A2 (fr) 2011-07-28
CA2785512A1 (fr) 2011-07-28

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