WO2011104259A1 - Installation et procédé de carbonisation hydrothermale de biomasse et produit carboné obtenu au moyen dudit procédé - Google Patents

Installation et procédé de carbonisation hydrothermale de biomasse et produit carboné obtenu au moyen dudit procédé Download PDF

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Publication number
WO2011104259A1
WO2011104259A1 PCT/EP2011/052652 EP2011052652W WO2011104259A1 WO 2011104259 A1 WO2011104259 A1 WO 2011104259A1 EP 2011052652 W EP2011052652 W EP 2011052652W WO 2011104259 A1 WO2011104259 A1 WO 2011104259A1
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Prior art keywords
biomass
region
reactor
reaction
area
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PCT/EP2011/052652
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German (de)
English (en)
Inventor
Robert Stöcklinger
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G+R Tech Group AG
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G+R Tech Group AG
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L9/00—Treating solid fuels to improve their combustion
    • C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
    • C10L9/086—Hydrothermal carbonization
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/40—Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/447—Carbonized vegetable substances, e.g. charcoal, or produced by hydrothermal carbonization of biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/094—Char
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0969—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • the present invention relates to a plant for the production of carbonaceous products from biomass by means of hydrothermal carbonization.
  • the plant for the production of carbonaceous products from biomass comprises a first area in which the supply, crushing and mixing of at least one type of biomass is carried out. In a second area, the preparation and processing of the mixed biomass takes place. In a third area, the reaction process is carried out according to the hydrothermal carbonization. In a fourth area, the further processing of the reaction products of the reaction process takes place.
  • the invention relates to a method for the production of carbonaceous products from biomass by means of the reaction process of the hydrothermal carbonization.
  • a reaction mixture is first heated.
  • the reaction mixture comprises water, biomass and a copolymerizable substance.
  • the copolymerizable substance is supplied in the preparation of the reaction mixture.
  • the reaction mixture is transferred to a reactor.
  • the reaction takes place at a temperature of 190 ° C to 270 ° C from.
  • the biomass is transferred via a heat exchanger in another reactor in which takes place the copolymerization reaction.
  • German Offenlegungsschrift DE 10 2007 062 810 A1 relates to a plant for the production of energy from biomass, with at least one device for the treatment of the biomass.
  • the device for treating the biomass comprises at least one reactor for receiving the biomass and / or at least one device for processing the biomass and / or for working up the reaction products and / or by-products.
  • the arrangement for power generation preferably comprises a pellet stove, a fuel cell or a power plant with pulverized coal firing, in particular with a pressure-charged stationary fluidized bed firing, particularly preferably with pressurized coal firing.
  • German Offenlegungsschrift DE 10 2008 026 991 A1 relates to a process for producing coal, in particular coal sludge from biomass, in particular sewage sludge by hydrothermal carbonization.
  • the carbon structures of the biomass are added broken at least 180 ° C to 200 ° C under exclusion of air.
  • the biomass is concentrated by dewatering to more than 10% dry matter content.
  • the hydrothermal carbonization the biomass is brought to a pH of less than 4. The process waste heat produced by the hydrothermal carbonization is used for subsequent drying of the resulting product.
  • German Offenlegungsschrift DE 10 2008 028 953 A1 discloses a process for the production of coal from plants and plant residues.
  • the raw biomass wood, plant parts, eg straw, plant residues
  • the mostly still moist biomass is immersed in a water bath and filled in a pressure-resistant reaction vessel.
  • the container contents are from ambient to the desired reaction temperature, eg. B. 180 ° C, heated.
  • the tank pressure is raised to a level above the value corresponding to the evaporation pressure at the set process temperature.
  • the reaction process enters an exothermic phase where part of the energy chemically bound in biomass is converted to heat.
  • the container After the carbonation process has ended (eg 8 to 12 hours, depending on the biomass used and the pressure or reaction temperature), the container is cooled down to the point where a safe pressure reduction to ambient pressure level is possible. The container is then opened and emptied. The coal is filtered from the process water, mechanically dewatered and treated. The reaction vessel is operated intermittently.
  • the German patent application DE 10 2008 058 444 A1 describes a method and an apparatus for the production of fuels or fuels.
  • the raw materials or fuels are produced from a solid / liquid mixture of water and a carbon-containing component.
  • the solid / liquid mixture is at a temperature of about 100 ° C and a pressure handled by over 5bar.
  • starting materials are fed via a heat exchanger continuously to a first reactor and the reaction mixture is passed in batches from one to the next reactor and continuously removed reaction products from the last reactor.
  • the reaction space serves to receive a solid / liquid mixture, for example biomass.
  • the reactor has a brewing device with which the solid / liquid mixture can be mixed during treatment and / or processing.
  • European Patent Application EP 1 970 431 A1 also discloses a method and apparatus for the hydrothermal carbonization of biomass.
  • the starting materials are introduced through an inlet into a pressure reactor during an ongoing carbonization process.
  • the reaction products within the reactor are moved from the inlet to the outlet.
  • the biomass converted to a large extent to end products can be removed.
  • biomass, water and / or at least one catalyst can be supplied to a pressure vessel designed substantially as a pipeline with at least one controllable inlet opening and at least one controllable outlet opening via the at least one controllable inlet opening.
  • the temperature and / or pressure conditions are controlled in the pressure vessel such that the product supplied to the pressure vessel contents of biomass, water and catalyst transported in the pipeline is, with biomass, water and catalyst react with each other and at least one reaction product of the contents is removed via the at least one controllable outlet opening.
  • International Patent Application WO 2008/193309 discloses a method for converting biomass into higher energy density solids, especially coal, humus or peat.
  • organic substances from the biomass are slurried to form a suspension in water, and a part of the suspension to be converted is heated to a reaction temperature and converted at elevated pressure by hydrothermal carbonation into the higher energy density solids.
  • the method is characterized in that the conversion is carried out in a reaction volume that is below the surface of the earth.
  • European Patent Application EP 2 130 893 A2 discloses a method for producing coal, in particular coal sludge.
  • the coal slurry is made from moist biomass, in particular sewage sludge by hydrothermal carbonization, wherein the carbon structure of the biomass is preferably broken at at least 180 ° C to 200 ° C with exclusion of air.
  • the process proceeds in particular in batch mode, wherein the biomass is concentrated by dehydration to values above 10% dry matter content before the hydrothermal carbonization. Before the hydrothermal carbonization, the biomass is brought to a pH ⁇ 4.
  • the process waste heat generated during the hydrothermal carbonization is used for the subsequent drying of the resulting product.
  • Dosing devices, pumps and valves are used to feed parallel reactors. The reactors have a stirrer to improve the reaction.
  • tubular reactors can be used which ensure a good mixing of the sewage sludge.
  • biomass comprises renewable raw materials, which are available as domestic energy sources in the long term, as well as all liquid and solid organic substances and products of biological and biochemical processes and their transformation products, which have a sufficiently high carbon content for this process and otherwise in their Composition and nature of economically useful reaction, intermediate, by-products and end products can be processed by the hydrothermal carbonization to fuels.
  • the starting materials include carbohydrates, sugars and starches, agricultural and forestry products, as well as specially grown energy crops (fast-growing tree species, reed grasses, cereal crops, etc.), soybeans, sugarcane and cereal straw, as well as biogenic residues, wastes and by-products. Plants and plant remains of other origin
  • Polymeric and animal excrements including manure, horse manure and poultry droppings.
  • a device for the treatment of biogenic residual masses which comprises a cylindrical reactor, in the food waste u. ⁇ . Be subjected to a temperature-pressure hydrolysis.
  • the reactor is designed as a loop reactor with a heatable jacket surface. By means of a pump, a flow is generated within the reactor, which ensures thorough mixing of the suspension.
  • the invention has for its object to provide a plant for the production of carbonaceous products from biomass by hydrothermal carbonation, which ensures a substantially continuous operation of the plant, so that a continuous supply of biomass is possible in the system and that also a continuous decrease of end products from the plant is possible.
  • Another object of the invention is to provide a method by which products from the hydrothermal carbonization of biomass can be generated essentially by means of a continuous operation.
  • the plant for the production of carbonaceous products from biomass by means of the hydrothermal carbonization comprises a first area 100, in which the provision, reduction and mixing of different types of biomass is performed.
  • a first area 100 in which the provision, reduction and mixing of different types of biomass is performed.
  • possible biomass containing some carbon can be processed.
  • a second area of the plant In a second area of the plant, the processing and preparation of the mixed biomass takes place.
  • water and a catalyst is added to adjust the required for the subsequent reaction process proportion of the dry matter in the reaction mixture.
  • the second area is followed by a third area in which the reaction process according to the hydrothermal carbonization is carried out.
  • the third area is followed by a fourth area, which serves to further process the reaction products.
  • the third area consists of at least three reactors.
  • the at least three reactors are interconnected via a first line system, a second line system and a third line system.
  • the first conduit system is guided via a first heat exchanger, so that at least one of the at least three reactors can be controlled and selectively filled with biomass from the second region.
  • the second line system is also passed through a heat exchanger.
  • a pump is provided in the second line system so that biomass in the reaction process can be controlled from the active reactor of the at least three reactors and selectively circulated during the reaction process.
  • At least one stirrer is provided in the reactor, which additionally serves for thorough mixing and circulation of the biomass. The pump thus achieves good mixing of the reaction products in the active reactor of the at least three reactors.
  • a third line system is led from the at least three reactors via a heat exchanger. About the third line system, the reaction products of the completed reaction process are withdrawn from the active reactor and fed via a relaxation device the fourth area. The reaction products are only withdrawn from the active reactor when the reaction process in the active reactor has come to
  • the at least three reactors of the third region are operable in such a way that at least one reactor is the active reactor. At least one other reactor is the reactor that is being filled with the added biomass from the second area. At least one further reactor is the reactor being emptied. This reactor was the previous active reactor in which the reaction process has come to an end, so that its content can be transferred to the fourth region for further processing of the reaction products.
  • the first line system, the second line system and the third line system are provided with a plurality of controllable two-way valves and a plurality of controllable three-way valves.
  • the entire hydrothermal carbonization plant is connected to a program control so that the specific filling, circulation and discharge of the at least three reactors in the third area can be regulated or controlled.
  • the first area for the provision, crushing and mixing of at least one type of biomass comprises a multitude of acceptance and storage positions for the unmixed provision of the different types of biomass.
  • at least one comminution unit and a mixer for the different biomasses are provided.
  • the comminution unit is necessary in order to produce the biomass to a required particle size or a range of the process-usable particle sizes of the biomass.
  • the second area has a mixing tank in which the comminuted and mixed biomass is filled.
  • the comminuted and mixed biomass is further added via a line with process water.
  • a catalyst required for the reaction process of the hydrothermal carbonization can be added to the process water.
  • the process water and the catalyst are fed together via a mixer.
  • An agitator operated by a motor is provided in the mixing vessel in order to ensure good mixing of the biomass with the process water and the catalyst. In addition, it is avoided by means of the agitator settling of the biomass at the bottom of the mixing vessel.
  • the added amount of process water to the mixed and comminuted biomass can thus adjust the proportion of dry matter in the reaction process, which takes place downstream in at least one of the reactors.
  • the mixing container If you set a dry matter content of 20% to 60%.
  • the proportion of the dry substance depends essentially on the fraction of the various types present in the comminuted and mixed biomass and the resulting reaction processes in the downstream reactors.
  • the biomass mixed with process water and catalyst reaches the third area via a third line, in which the reaction process is carried out.
  • a pump is provided so as to be able to adjust the filling rate of the at least one reactor in the third range.
  • a collecting vessel for receiving the reaction products from the at least one reactor is provided for further processing of the reaction products, from which the reaction products are removed. The reaction products are only then removed from the initially active reactor, after which the reaction process is completed in this reactor.
  • the collecting container also has a motor operated agitator. Via a pumped line, the reaction products are fed to a dehydrator and a downstream dryer.
  • a line leads to a collecting container for the process water obtained in the dewatering device.
  • the process water is returned to the second area via a line provided with a pump.
  • the process water can in turn be introduced into the reaction cycle.
  • the process water is thus fed to the mixed and comminuted biomass in the mixing container provided in the second area.
  • the reaction product is removed from the dryer after the drying process and fed to a collecting container. From the collection of packaging or removal can be organized.
  • a fifth region may be provided.
  • the fifth area can be at least part of the Reaction products are fed directly from the at least one active reactor.
  • the reaction products are, as already mentioned above, only taken from the at least one active reactor, if in this the reaction process has been completely completed.
  • reaction products which are supplied to the fifth region, have a dry matter content of about 10%.
  • carbon dioxide is added to the reaction products.
  • the carbon dioxide comes z. B. from the coal combustion of a fossil power plant. Any combustion process that produces carbon dioxide can be used as a carbon dioxide source. Carbon dioxide can thus be supplied to the fifth region of the plant and is thus involved in the production of synthesis gas.
  • the plant is in the first area, in the second area, in the third area, in the fourth area and in the fifth area a variety of controllable two-way valves and three-way valves, thereby controlling a material flow within the plant via a central program control, or can be adjusted.
  • the plant can be used to produce coal and / or synthesis gas as a reaction product. It is possible by appropriate program control to adjust the reaction product to the needs of a customer so that the fuel is an optimal performance during combustion.
  • the setting and additional elements of the coal contained in the fuel can be adjusted to the reaction process by suitable selection of the starting products of the various biomass types.
  • the process for the production of carbonaceous products from biomass by means of the reaction process of the hydrothermal carbonization is characterized by the following steps: First, the biomass of different types is provided in a first region. For the provision of the biomass, various containers, silos or Storage spaces are provided. In these storage areas or silos, the biomass is stored separately by type. In the first area, the biomass is now taken from the different storage locations according to the desired composition for the reaction process. The biomass is fed to a crushing and mixing, and ultimately transferred to a second area of the plant. In the second area, the mixed and comminuted biomass is mixed with process water and a catalyst, so that a required for the reaction process content of biomass dry matter is adjusted. In a third area at least three reactors are provided.
  • the process is designed such that at least one reactor of the reactors provided in the third region is filled with the biomass, which is mixed with process water and catalyst.
  • at least one further reactor which is referred to as an active reactor, is just starting the reaction process in which the biomass is converted into a carbon-containing reaction product.
  • This reactor, which is being emptied is the reactor that was previously the active reactor and in which the reaction process is complete.
  • the reaction products which are taken from the at least one reactor are fed to a fourth region. In the fourth area, dehydration and drying of the reaction products withdrawn from the at least one reactor of the third area occur.
  • the reaction products taken from the reactor of the third range have a dry matter content of about 10%.
  • a dry matter content of about 50% is set.
  • a dry matter content of about 90% is achieved.
  • the biomass is constantly circulated via a heat exchanger. After completion of the reaction process in the at least one active reactor, the biomass is discharged from the reactor and thereby fed via a third heat exchanger and a relaxation device the fourth area.
  • a fifth region can also be provided in the system in which at least part of the reaction products can be supplied from the active reactor after completion of the reaction process. It is also possible that all of the reaction products withdrawn from the active reactor are fed to the fifth region. Synthesis gas is generated in the fifth area.
  • a program control controls the material flow within the system for carrying out the method.
  • a fuel can be produced, which is carbonaceous.
  • the fuel can be a coal.
  • the fuel may be synthesis gas.
  • FIG. 1 shows a schematic representation of the invention
  • FIG. 2 shows a schematic representation of another
  • FIG. 3 shows a further embodiment of the plant for carrying out the reaction process of the hydrothermal carbonization.
  • FIG. 4 shows a schematic representation of the first region of FIG
  • Plant for hydrothermal carbonization in which the different biomass required for the reaction process can be comminuted and mixed.
  • FIG. 5 shows a schematic representation of the second region of FIG.
  • Hydrothermal carbonation plant in which the comminuted and mixed biomass are mixed with process water and catalyst before they are sent to the reaction process.
  • Figure 6 shows a schematic representation of the third area, in which at least three reactors are provided, which are connected to each other via different lines.
  • Figure 7 shows a schematic representation of the elements of the fourth
  • FIG. 8 shows a schematic representation of a reactor in FIG.
  • Figure 1 shows the schematic structure of the plant 1 for hydrothermal carbonization.
  • the plant is 1 for hydrothermal carbonization of a first region 100, a second region 200, a third region 300 and a fourth region 400 formed.
  • the first area 100, the second area 200, the third area 300 and the fourth area 400 are connected by means of a common program control 10.
  • the assembly and mixing of the different biomasses takes place.
  • the thus mixed and comminuted biomasses reach the second region 200, in which a processing and preparation of the mixed biomasses is carried out.
  • Process water PW is added to the crushed and mixed biomasses.
  • the biomass mixed with process water PW reaches the reactor region, which is referred to as the third region.
  • the reaction process of hydrothermal carbonation takes place.
  • the finished reaction product is supplied to the fourth area where processing of the reaction products of the hydrothermal carbonization process is performed.
  • process water PW is recovered, which is ultimately returned to the second area for reuse.
  • FIG. 2 shows a further embodiment of the plant 1 for the hydrothermal carbonization of biomass.
  • the fourth area is exchanged for a fifth area 500.
  • the reaction products from the third region which are taken from the reactor which was previously the active reactor and in which now the reaction process is completely completed, are fed directly to this fifth region. These reaction products have a dry matter content of about 10%.
  • a reaction process is performed in which synthesis gas is generated.
  • carbon dioxide C0 2 is supplied in the fifth area.
  • the supplied carbon dioxide may, for. B. originate from a carbon dioxide source 15.
  • a carbon dioxide source 15 is z. B. a fossil power value, o. ⁇ .
  • directly from the fossil power plant formed and formed carbon dioxide to the process for Synthesis gas extraction in the fifth region 500 of Appendix 1 are supplied.
  • FIG. 3 shows a further embodiment of the invention.
  • the fifth area 500 is provided in addition to the fourth area 400.
  • a part of the finished reaction products is thus supplied from the third region to the fourth region 400.
  • the dewatering and drying of the reaction products already mentioned in the description of FIG. 1 thus takes place.
  • the thus obtained process water is supplied from the fourth area 400 again to the second area 200.
  • Another portion of the reaction products from the third region 300 may be supplied to the fifth region 500 where synthesis gas is ultimately generated with the addition of carbon dioxide from a carbon dioxide source 15.
  • FIGS. 2 and 3 Analogous to the description of FIG. 1, the embodiments of the systems mentioned in FIGS. 2 and 3 are also assigned a program control 10 by means of which the material flow in the most varied embodiments of the system 1 can be controlled and regulated.
  • FIG. 4 shows a schematic representation of the first region 100 of the plant 1 for the hydrothermal carbonization of biomass.
  • the first area comprises a plurality of acceptance and storage locations 12 ; 12 2 , 12 n for the different types of biomass 5 ; 5 2 , 5 n .
  • the embodiment of the region 100 shown in FIG. 4 represents only one possible form of embodiment and should not be construed as a limitation. It is obvious to a person skilled in the art that the first area 100 can be designed according to the customer's requirement.
  • the number of acceptance and storage locations 12 ; 12 2 , 12 n depends on the different types of biomass that are to be processed in Appendix 1. Likewise, the number of comminution units 13 depends on the type of biomass that is to be processed with the system 1. After the appropriate comminution of the biomass these become a mixer 14 supplied, in which the mixed biomass 5N is provided for the further reaction process.
  • a first comminution unit 13 and a second comminution unit 13 2 are provided.
  • the first crushing unit 13i is designed as a crusher.
  • the second crushing unit 13 2 is designed as a hammer mill.
  • the first crushing unit 13 are thus supplied large pieces of biomass, which still require a strong crushing before they are fed to the mixer.
  • the second crushing unit 13 2 is designed as a hammer mill and thus can already shredded parts of biomass, such. B. Strohab mount, grass clippings, bark waste, wood chips, etc. continue to shred and feed them directly to the mixer 14.
  • an acceptance and storage point 12 3 for already liquid biomass is present. This liquid biomass can z. B. sewage sludge.
  • the biomass comminuted with the first comminuting unit 13 is thus supplied to a feed line of the liquid biomass from the receiving and storing point 12 3 .
  • the biomass coming from the first crushing unit 13i is already mixed with a liquid biomass before it reaches the mixer 14.
  • the biomass passes via a line 1 1 1 in the second area 200.
  • the second area 200 of the system 1 comprises a mixing container 21st In the mixing vessel 21, a stirrer 220 driven by a motor 221 is provided.
  • the mixing vessel 21 passes through the line 1 1 1, the mixed biomass 5N.
  • the process water PW is supplied to the mixing vessel 21 via a line 21 1.
  • a mixer 214 is inserted.
  • the process water PW passes via the line 21 1 in the mixer, opens into the line 21 1, a line 212 which feeds a catalyst from a tank 213 in the process water.
  • the catalyst may, for. For example, formic acid, citric acid or sulfuric acid.
  • a plurality of two-way valves 32 is provided. These two-way valves 32 are connected to the program controller 10. Thus, it is possible to selectively control the material flow through targeted control of the two-way valves and thus z. B. to set the dry matter content in the mixing container 21 targeted.
  • the size of the dry matter content depends essentially on the downstream process conditions in the third range.
  • the structure of the third region 300 is shown schematically in FIG.
  • the third region 300 comprises at least three reactors 301.
  • Each of the reactors is provided with a positive pressure line 302 which terminates in a controllable two-way valve 32.
  • the pressure inside the reactor can thus be adjusted to a predefined level. It is also possible to release the pressure if, in the interior of the at least one reactor 301, the pressure rises above a predefined level.
  • at least three reactors 301 must be present to ensure continuous production of the reaction products of the hydrothermal carbonation process.
  • At least one reactor 301 of the reactors is an active reactor 301 A.
  • active reactor means that in this reactor 301, the process of hydrothermal carbonization takes place and is not yet completed.
  • At least one other reactor 301 of the at least three reactors biomass is introduced via a line 31 1 in the reactor 301.
  • This reactor 301 is referred to as fillable reactor 301 F.
  • two fillable reactors 301 F are provided in the in Figure 6 shown schematic representation of the third area 300 of Appendix 1, two fillable reactors 301 F are provided.
  • the fillable reactors 301 F are filled via line 31 1 with the mixed with process water and catalyst biomass.
  • a first heat exchanger 310 is introduced.
  • the line 31 1 connects all the reactors 301 of the third area 300.
  • the line 31 1 can thus be disconnected in the direction of the at least one fillable reactor 300F so that the reactor 301F can be provided with biomass, process water and Catalyst can be filled.
  • a second line system 321 is provided, which likewise connects each reactor 301 of the third area 300 to one another.
  • the second line 321 is designed as a ring line and is also guided via a second heat exchanger 320.
  • a pump 30 is provided in the line 321, with which the biomass from the at least one active reactor 301 A is constantly pumped through the second heat exchanger 320. By this pumping one reaches a constant mixing of the biomass in the active reactor 301 A.
  • each reactor 301 at least one stirrer 350 is provided, which additionally serves for thorough mixing and circulation of the biomass 5-i, 5 2 , 5 n .
  • the stirrer 350 is preferably arranged in the lower region of the reactor 301.
  • a plurality of three-way valves 33 and two-way valves 32 are provided so as to circulate the material flow of just reacting in the active reactor 301 A biomass via the loop 321 and the heat exchanger.
  • the two-way valves 32 and the three-way valves 33 are controlled such that the second line 321 with the at least one active reactor 301 A forms an open ring, so that the pumping of the biomass during the reaction process in the active reactor 301 A is possible.
  • At least one further reactor 301 of the reactors in the third region 300 is a reactor 301L which is about to be emptied previously the active reactor 301 A. After the reaction process in the active reactor 301 A is completed, the reaction products can be removed from the reactor. The active reactor 301 A then becomes the empty reactor 301 L.
  • Each of the reactors 301 is connected to a third line 321, which is passed through a third heat exchanger 320. In the third conduit 331, a plurality of two-way valves 32 and three-way valves 33 are also provided, thus controlled to connect the empty reactor 301 L to the third conduit 331.
  • the reaction product withdrawn from the emptying reactor 301 L is passed via the third line 331 via an expansion device 340, so that the reaction products are brought substantially to an ambient pressure level. From the expansion device 340, the reaction products reach the fourth region 400 and / or the fifth region 500, in which, as already mentioned, synthesis gas can be produced. For the further description of the invention, the fifth region 500 is omitted, in which synthesis gas can be prepared from the reaction products in conjunction with carbon dioxide.
  • the reaction product now passes via the line 331 in the fourth area and is spent there in a collecting container 41. In the collecting container 41, a stirrer 420, which is driven by a motor 421, is arranged.
  • the reaction product is placed in a dewatering device.
  • the reaction products fed in via line 331 have a dry matter content of about 10%.
  • the dry matter content is increased to about 50%.
  • the process water PW obtained from the reaction products passes into a collecting container 436. Should the level in the collecting container 436 become too high, the excess process water PW is discharged via an overflow 437 to the environment.
  • the line 31 which is provided with a pump 30 and a two-way valve 32, the Process water PW returned to the second area 200 of Appendix 1. From the dehydrator 430, the reaction product passes into a dryer 432.
  • the dryer is driven by a motor 433.
  • the dry matter content of the reaction products is increased to about 90%.
  • the dried reaction product passes into a collecting container 434. From the collecting container 434, the distribution to the consumers of the reaction products prepared with the plant 1 can finally take place.
  • FIG. 8 shows a simplified schematic representation of the active reactor 301 A in conjunction with the ring line 321 and the second heat exchanger 320.
  • the biomass which is currently reacting is constantly transferred via the pump 30 and the ring line 321 second heat exchanger 320 recirculated.
  • the filled biomass is brought to a certain temperature and a certain pressure.
  • the temperature and the pressure prevailing in the active reactor 301 A pressure is maintained substantially.
  • reactors 301 are shown. These reactors 301 may take on different functions depending on the end of the production process. Thus, at least one reactor 301 may be the active reactor 301 A. Is the If the at least one reactor 301 a that can be emptied is completely emptied, the reactor 301 becomes the fillable reactor 301 F. How many reactors 301 are active reactors 301 A or emptying reactors 301 L or refillable reactors are 301 F depending on the process conditions to ensure a continuous output of reaction products.

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  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Physics & Mathematics (AREA)
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Abstract

L'invention concerne une installation (1) et un procédé de préparation de produits carbonés à partir de biomasse (51, 52,..., 5n) par carbonisation hydrothermale. Au moins un type de biomasse (51, 52,..., 5n) est préparé dans une première zone (100). La biomasse mélangée (5M) est traitée et préparée dans une deuxième zone (200). Le processus réactionnel de carbonisation hydrothermale se déroule dans une troisième zone (300). La transformation ultérieure des produits de la réaction a lieu dans une quatrième zone (400). Au moins trois réacteurs (301) sont placés dans la troisième zone (300), au moins un réacteur (301) étant toujours le réacteur actif (301A). La recirculation de la biomasse soumise au processus réactionnel peut être assurée de manière commandée et sélective au moyen d'une pompe par l'intermédiaire d'un deuxième échangeur de chaleur (320), avec l'aide d'un agitateur (350) placé dans chacun des réacteurs (301).
PCT/EP2011/052652 2010-02-26 2011-02-23 Installation et procédé de carbonisation hydrothermale de biomasse et produit carboné obtenu au moyen dudit procédé Ceased WO2011104259A1 (fr)

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DE102010000576A DE102010000576B4 (de) 2010-02-26 2010-02-26 Anlage und Verfahren zur hydrothermalen Karbonisierung von Biomasse
DE102010000576.2 2010-02-26

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CN111111590B (zh) * 2019-12-27 2022-04-22 苏州清陶新能源科技有限公司 一种正极浆料搅拌方法
CN111676036B (zh) * 2020-05-29 2024-07-30 华电电力科学研究院有限公司 一种生物质热解反应器及其工作方法

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