WO2011111994A3 - 글리세롤의 기상 탈수화 반응을 통한 아크롤레인 및 이의 제조방법 - Google Patents

글리세롤의 기상 탈수화 반응을 통한 아크롤레인 및 이의 제조방법 Download PDF

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Publication number
WO2011111994A3
WO2011111994A3 PCT/KR2011/001617 KR2011001617W WO2011111994A3 WO 2011111994 A3 WO2011111994 A3 WO 2011111994A3 KR 2011001617 W KR2011001617 W KR 2011001617W WO 2011111994 A3 WO2011111994 A3 WO 2011111994A3
Authority
WO
WIPO (PCT)
Prior art keywords
glycerol
vapor
phase dehydration
preparing same
acrolein obtained
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2011/001617
Other languages
English (en)
French (fr)
Other versions
WO2011111994A2 (ko
Inventor
박은덕
정광덕
김용태
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajou University Industry Academic Cooperation Foundation
Original Assignee
Ajou University Industry Academic Cooperation Foundation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ajou University Industry Academic Cooperation Foundation filed Critical Ajou University Industry Academic Cooperation Foundation
Publication of WO2011111994A2 publication Critical patent/WO2011111994A2/ko
Publication of WO2011111994A3 publication Critical patent/WO2011111994A3/ko
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J29/655—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

본 발명은 아크롤레인 제조 방법에 관한 것으로, 보다 구체적으로 수분이 포함된 글리세롤을 특정 구조를 갖는 제올라이트 촉매의 존재 하에서 기상 탈수화 반응시킴으로써 넓은 반응 온도 대역에 거쳐 높은 수율 및 선택도로 아크롤레인을 제조하는 방법에 관한 것이다.
PCT/KR2011/001617 2010-03-09 2011-03-09 글리세롤의 기상 탈수화 반응을 통한 아크롤레인 및 이의 제조방법 Ceased WO2011111994A2 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2010-0020694 2010-03-09
KR1020100020694A KR101148995B1 (ko) 2010-03-09 2010-03-09 글리세롤의 기상 탈수화 반응을 통한 아크롤레인 및 이의 제조방법

Publications (2)

Publication Number Publication Date
WO2011111994A2 WO2011111994A2 (ko) 2011-09-15
WO2011111994A3 true WO2011111994A3 (ko) 2011-12-15

Family

ID=44563995

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2011/001617 Ceased WO2011111994A2 (ko) 2010-03-09 2011-03-09 글리세롤의 기상 탈수화 반응을 통한 아크롤레인 및 이의 제조방법

Country Status (2)

Country Link
KR (1) KR101148995B1 (ko)
WO (1) WO2011111994A2 (ko)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102237601B1 (ko) 2013-10-31 2021-04-08 삼성전자주식회사 자석 매립형 모터 및 자석 매립형 모터를 가지는 압축기

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5387720A (en) * 1992-11-14 1995-02-07 Degussa Aktiengesellschaft Process for the production of acrolein
US7396962B1 (en) * 2005-02-15 2008-07-08 Arkema France Process for dehydrating glycerol to acrolein
US20080214880A1 (en) * 2005-02-15 2008-09-04 Arkema France Process for Dehydrating Glycerol to Acrolein
US20090177015A1 (en) * 2006-05-12 2009-07-09 Okuno Masaaki Production Method of Acrolein
EP2103590A1 (en) * 2006-12-01 2009-09-23 Nippon Shokubai Co., Ltd. Method for producing acrolein and glycerin-containing composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5387720A (en) * 1992-11-14 1995-02-07 Degussa Aktiengesellschaft Process for the production of acrolein
US7396962B1 (en) * 2005-02-15 2008-07-08 Arkema France Process for dehydrating glycerol to acrolein
US20080214880A1 (en) * 2005-02-15 2008-09-04 Arkema France Process for Dehydrating Glycerol to Acrolein
US20090177015A1 (en) * 2006-05-12 2009-07-09 Okuno Masaaki Production Method of Acrolein
EP2103590A1 (en) * 2006-12-01 2009-09-23 Nippon Shokubai Co., Ltd. Method for producing acrolein and glycerin-containing composition

Also Published As

Publication number Publication date
KR101148995B1 (ko) 2012-05-22
WO2011111994A2 (ko) 2011-09-15
KR20110101595A (ko) 2011-09-16

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