WO2011120968A3 - Procédé de valorisation de l'essence - Google Patents

Procédé de valorisation de l'essence Download PDF

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Publication number
WO2011120968A3
WO2011120968A3 PCT/EP2011/054824 EP2011054824W WO2011120968A3 WO 2011120968 A3 WO2011120968 A3 WO 2011120968A3 EP 2011054824 W EP2011054824 W EP 2011054824W WO 2011120968 A3 WO2011120968 A3 WO 2011120968A3
Authority
WO
WIPO (PCT)
Prior art keywords
crystalline
catalyst
stream
olefins
aluminophosphates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2011/054824
Other languages
English (en)
Other versions
WO2011120968A2 (fr
Inventor
Delphine Minoux
Sander Van Donk
Nikolai Nesterenko
Metin BULUT
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TotalEnergies Marketing Services SA
Original Assignee
Total Raffinage Marketing SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Raffinage Marketing SA filed Critical Total Raffinage Marketing SA
Priority to CN2011800167771A priority Critical patent/CN102822320A/zh
Priority to EP11710517A priority patent/EP2553053A2/fr
Priority to US13/637,549 priority patent/US20130037446A1/en
Publication of WO2011120968A2 publication Critical patent/WO2011120968A2/fr
Publication of WO2011120968A3 publication Critical patent/WO2011120968A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/22—After treatment, characterised by the effect to be obtained to destroy the molecular sieve structure or part thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/83—Aluminophosphates [APO compounds]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La présente invention concerne un procédé permettant d'ajuster l'équilibre essence/diesel en convertissant une charge d'alimentation initiale contenant des oléfines de 4 à 20 atomes de carbone au moyen d'un catalyseur cristallin avec des limitations de diffusion réduites. Le procédé comprend : - le traitement d'un courant de charge d'alimentation contenant des oléfines de 4 à 20 atomes de carbone en présence ou en l'absence d'un courant contenant des substances aromatiques, - la mise en contact dudit ou desdits courants avec un catalyseur dans des conditions efficaces pour oligomériser au moins une partie des oléfines et finalement alkyler au moins une partie des substances aromatiques, le catalyseur étant un composé cristallin ayant une structure micro/mésoporeuse, choisi parmi les aluminosilicates cristallins, les aluminophosphates cristallins, les silico-aluminophosphates cristallins, les zéolites cristallines, ou le catalyseur étant un matériau composite comprenant au moins 20 % en poids d'au moins un des composés cristallins mentionnés ci-dessus, et le volume mésoporeux du composé cristallin étant au moins égal à 0,22 ml/g.
PCT/EP2011/054824 2010-03-30 2011-03-29 Procédé de valorisation de l'essence Ceased WO2011120968A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN2011800167771A CN102822320A (zh) 2010-03-30 2011-03-29 汽油升级方法
EP11710517A EP2553053A2 (fr) 2010-03-30 2011-03-29 Procédé de valorisation de l'essence
US13/637,549 US20130037446A1 (en) 2010-03-30 2011-03-29 Gazoline upgrading process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1052318A FR2958297B1 (fr) 2010-03-30 2010-03-30 Procede de valorisation d'essence
FR1052318 2010-03-30

Publications (2)

Publication Number Publication Date
WO2011120968A2 WO2011120968A2 (fr) 2011-10-06
WO2011120968A3 true WO2011120968A3 (fr) 2012-06-07

Family

ID=43125488

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/054824 Ceased WO2011120968A2 (fr) 2010-03-30 2011-03-29 Procédé de valorisation de l'essence

Country Status (5)

Country Link
US (1) US20130037446A1 (fr)
EP (1) EP2553053A2 (fr)
CN (1) CN102822320A (fr)
FR (1) FR2958297B1 (fr)
WO (1) WO2011120968A2 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3009207B1 (fr) 2013-08-02 2021-04-30 Ifp Energies Now Modification de zeolithe de type euo et son utilisation en isomerisation des composes c8 aromatiques
KR102068312B1 (ko) 2013-10-18 2020-01-20 에스케이이노베이션 주식회사 활성화된 eu-2 제올라이트 및 이의 용도
US9670425B2 (en) 2013-12-17 2017-06-06 Uop Llc Process for oligomerizing and cracking to make propylene and aromatics
US9732285B2 (en) 2013-12-17 2017-08-15 Uop Llc Process for oligomerization of gasoline to make diesel
WO2016205878A1 (fr) * 2015-06-22 2016-12-29 Patrick James Cadenhouse-Beaty Procédé de production d'un mélange de carburant pour le transport
US11149214B2 (en) 2018-12-17 2021-10-19 Saudi Arabian Oil Company Method and process to maximize diesel yield
CN115716651B (zh) * 2021-08-25 2024-04-30 中国石油天然气股份有限公司 Zsm-35分子筛及其制备方法、异构化催化剂及其制备方法、异构化方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2931818A1 (fr) * 2008-05-28 2009-12-04 Inst Francais Du Petrole Procede d'oligomerisation des olefines legeres utilisant un catalyseur a base d'un materiau amorphe a porosite hierarchisee et organisee
FR2931708A1 (fr) * 2008-05-28 2009-12-04 Inst Francais Du Petrole Catalyseur a base d'un materiau cristallise a porosite hierarchisee et organisee et son utilisation en oligomerisation des olefines legeres

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US4150062A (en) 1976-12-20 1979-04-17 Mobil Oil Corporation Light olefin processing
US4227992A (en) 1979-05-24 1980-10-14 Mobil Oil Corporation Process for separating ethylene from light olefin mixtures while producing both gasoline and fuel oil
US4482772A (en) 1983-11-03 1984-11-13 Mobil Oil Corporation Multistage process for converting oxygenates to hydrocarbons
US4506106A (en) 1984-01-04 1985-03-19 Mobil Oil Corporation Multistage process for converting oxygenates to distillate hydrocarbons with interstage ethene recovery
US4543435A (en) 1985-01-17 1985-09-24 Mobil Oil Corporation Multistage process for converting oxygenates to liquid hydrocarbons with ethene recycle
DE3838710A1 (de) 1988-11-15 1990-05-17 Sued Chemie Ag Katalysator auf der basis von kristallinen alumosilikaten
US5601798A (en) 1993-09-07 1997-02-11 Pq Corporation Process for preparing zeolite Y with increased mesopore volume
DE102005003109B4 (de) 2005-01-22 2015-02-12 Air Liquide Global E&C Solutions Germany Gmbh Verfahren zur Herstellung von synthetischen Kraftstoffen aus Oxigenaten
US8299312B2 (en) * 2005-10-28 2012-10-30 Neste Oil Oyj Process for dimerizing olefins

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2931818A1 (fr) * 2008-05-28 2009-12-04 Inst Francais Du Petrole Procede d'oligomerisation des olefines legeres utilisant un catalyseur a base d'un materiau amorphe a porosite hierarchisee et organisee
FR2931708A1 (fr) * 2008-05-28 2009-12-04 Inst Francais Du Petrole Catalyseur a base d'un materiau cristallise a porosite hierarchisee et organisee et son utilisation en oligomerisation des olefines legeres

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Title
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OGURA M ET AL: "Alkali-treatment technique - new method for modification of structural and acid-catalytic properties of ZSM-5 zeolites", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 219, no. 1-2, 5 October 2001 (2001-10-05), pages 33 - 43, XP004303345, ISSN: 0926-860X, DOI: DOI:10.1016/S0926-860X(01)00645-7 *

Also Published As

Publication number Publication date
US20130037446A1 (en) 2013-02-14
CN102822320A (zh) 2012-12-12
FR2958297A1 (fr) 2011-10-07
WO2011120968A2 (fr) 2011-10-06
FR2958297B1 (fr) 2013-11-29
EP2553053A2 (fr) 2013-02-06

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