WO2011129593A3 - 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 폴리프로필렌의 제조방법 - Google Patents

티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 폴리프로필렌의 제조방법 Download PDF

Info

Publication number
WO2011129593A3
WO2011129593A3 PCT/KR2011/002584 KR2011002584W WO2011129593A3 WO 2011129593 A3 WO2011129593 A3 WO 2011129593A3 KR 2011002584 W KR2011002584 W KR 2011002584W WO 2011129593 A3 WO2011129593 A3 WO 2011129593A3
Authority
WO
WIPO (PCT)
Prior art keywords
transition metal
metal compound
preparing polypropylene
compound containing
cyclopentadienyl ligands
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2011/002584
Other languages
English (en)
French (fr)
Other versions
WO2011129593A2 (ko
Inventor
이분열
박지혜
도승현
김화규
박재영
윤승웅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honam Petrochemical Corp
Original Assignee
Honam Petrochemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020100057102A external-priority patent/KR100986301B1/ko
Priority to EP11769059.4A priority Critical patent/EP2559713B1/en
Application filed by Honam Petrochemical Corp filed Critical Honam Petrochemical Corp
Priority to KR1020110033625A priority patent/KR101384450B1/ko
Priority to ES11769059.4T priority patent/ES2596718T3/es
Priority to CN201180018695.0A priority patent/CN102834422B/zh
Priority to PCT/KR2011/002584 priority patent/WO2011129593A2/ko
Priority to KR1020110033626A priority patent/KR101384412B1/ko
Priority to US13/640,872 priority patent/US8889804B2/en
Priority to JP2013504820A priority patent/JP5546678B2/ja
Publication of WO2011129593A2 publication Critical patent/WO2011129593A2/ko
Publication of WO2011129593A3 publication Critical patent/WO2011129593A3/ko
Anticipated expiration legal-status Critical
Priority to KR1020130128127A priority patent/KR20130135802A/ko
Priority to KR1020130128150A priority patent/KR20130124273A/ko
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/06—Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

본 발명은 새로운 구조의 전이금속 화합물을 포함하는 촉매의 존재 하에 프로필렌을 중합시키는 단계를 포함하는 폴리프로필렌의 제조방법에 관한 것이다. 본 발명에 따른 폴리프로필렌의 제조방법은 새로운 구조의 전이금속 화합물을 촉매로 사용함에 따라, 중합 활성이 높아 공정 효율이 우수할 뿐만 아니라, 중합체의 미세 구조를 쉽게 제어할 수 있어, 원하는 물성을 갖는 폴리프로필렌을 용이하게 제조할 수 있다.
PCT/KR2011/002584 2010-04-12 2011-04-12 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 폴리프로필렌의 제조방법 Ceased WO2011129593A2 (ko)

Priority Applications (10)

Application Number Priority Date Filing Date Title
US13/640,872 US8889804B2 (en) 2010-04-12 2011-04-12 Method for preparing polypropylene using transition metal compound containing thiophene-fused cyclopentadienyl ligand
KR1020110033626A KR101384412B1 (ko) 2010-04-12 2011-04-12 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 폴리프로필렌의 제조방법
KR1020110033625A KR101384450B1 (ko) 2010-04-12 2011-04-12 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 올레핀-디엔 공중합체의 제조방법
ES11769059.4T ES2596718T3 (es) 2010-04-12 2011-04-12 Procedimiento de preparación de polipropileno usando un compuesto de metal de transición que contiene ligandos de ciclopentadienilo condensados con tiofeno
CN201180018695.0A CN102834422B (zh) 2010-04-12 2011-04-12 使用包含噻吩稠合的环戊二烯基配体的过渡金属化合物制备聚丙烯的方法
PCT/KR2011/002584 WO2011129593A2 (ko) 2010-04-12 2011-04-12 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 폴리프로필렌의 제조방법
JP2013504820A JP5546678B2 (ja) 2010-04-12 2011-04-12 チオフェン−縮合環シクロペンタジエニルリガンドを含む遷移金属化合物を使用したポリプロピレンの製造方法
EP11769059.4A EP2559713B1 (en) 2010-04-12 2011-04-12 Method for preparing polypropylene using a transition metal compound containing thiophene-fused cyclopentadienyl ligands
KR1020130128150A KR20130124273A (ko) 2010-04-12 2013-10-25 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 올레핀-디엔 공중합체의 제조방법
KR1020130128127A KR20130135802A (ko) 2010-04-12 2013-10-25 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 폴리프로필렌의 제조방법

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
KR20100033273 2010-04-12
KR10-2010-0033273 2010-04-12
KR1020100057102A KR100986301B1 (ko) 2010-04-12 2010-06-16 테트라하이드로퀴놀린 유도체로부터 유래한 티오펜-축합고리 싸이클로펜타디에닐 4족 금속 화합물 및 이를 이용한 올레핀 중합
KR10-2010-0057102 2010-06-16
PCT/KR2011/002584 WO2011129593A2 (ko) 2010-04-12 2011-04-12 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 폴리프로필렌의 제조방법

Publications (2)

Publication Number Publication Date
WO2011129593A2 WO2011129593A2 (ko) 2011-10-20
WO2011129593A3 true WO2011129593A3 (ko) 2012-03-29

Family

ID=55442557

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2011/002584 Ceased WO2011129593A2 (ko) 2010-04-12 2011-04-12 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 폴리프로필렌의 제조방법

Country Status (7)

Country Link
US (1) US8889804B2 (ko)
EP (1) EP2559713B1 (ko)
JP (1) JP5546678B2 (ko)
KR (4) KR101384450B1 (ko)
CN (1) CN102834422B (ko)
ES (1) ES2596718T3 (ko)
WO (1) WO2011129593A2 (ko)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5567209B2 (ja) * 2010-04-12 2014-08-06 ロッテ ケミカル コーポレーション オレフィン重合用担持触媒およびこれを用いたポリオレフィンの製造方法
CN104672364A (zh) 2010-04-12 2015-06-03 湖南石油化学株式会社 使用包含噻吩稠合的环戊二烯基配体的过渡金属化合物制备烯烃-二烯共聚物的方法
JP5567208B2 (ja) 2010-04-12 2014-08-06 ロッテ ケミカル コーポレーション オレフィン重合用触媒組成物およびこれを用いたポリオレフィンの製造方法
US9683061B2 (en) 2013-09-26 2017-06-20 Lg Chem, Ltd. Catalyst composition and method of preparing polymer including the same
WO2015046705A1 (ko) 2013-09-26 2015-04-02 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 중합체의 제조방법
KR101689063B1 (ko) 2013-10-16 2016-12-22 주식회사 엘지화학 헤테로 원자를 갖는 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 중합체의 제조방법
KR101501853B1 (ko) * 2013-11-29 2015-03-12 롯데케미칼 주식회사 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 에틸렌-프로필렌-디엔 삼원중합체의 제조방법
KR101616200B1 (ko) * 2014-10-27 2016-04-27 롯데케미칼 주식회사 저온 내충격성이 우수한 폴리프로필렌 수지 조성물 및 수지 성형품
KR101617099B1 (ko) 2014-11-05 2016-04-29 롯데케미칼 주식회사 3차원 프린터 필라멘트용 열가소성 수지 조성물
KR101719064B1 (ko) 2014-11-13 2017-03-22 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR101686712B1 (ko) * 2014-11-28 2016-12-28 롯데케미칼 주식회사 에틸렌-프로필렌-비닐 노보넨 공중합체의 제조방법 및 이로부터 제조된 에틸렌-프로필렌-비닐 노보넨 공중합체
KR101731177B1 (ko) 2014-12-24 2017-04-27 주식회사 엘지화학 헤테로 원자를 갖는 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 중합체의 제조방법
KR101917911B1 (ko) 2015-07-02 2018-11-12 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR101910701B1 (ko) * 2015-07-02 2018-10-22 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR101984820B1 (ko) * 2016-09-27 2019-05-31 롯데케미칼 주식회사 연질성과 투명성이 우수한 의료용 필름
KR102753857B1 (ko) * 2018-11-15 2025-01-14 롯데케미칼 주식회사 프로필렌 중합용 담지촉매 및 이를 이용하는 폴리프로필렌 수지의 제조방법
US12421328B2 (en) 2020-08-12 2025-09-23 Lg Chem, Ltd. Method for preparing supported metallocene catalyst, supported metallocene catalyst, and method for preparing polyolefin using the same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008066266A1 (en) * 2006-12-01 2008-06-05 Lg Chem, Ltd. Supported catalysts for olefin polymerization using transition metal compound having phenylene-bridge, method for preparing the same, and method for preparing polyolefin using the same
WO2008084931A1 (en) * 2007-01-10 2008-07-17 Lg Chem, Ltd. Method for preparing transition metal complexes, transition metal complexes prepared using the method, catalysts composition containing the complexes
JP2008222635A (ja) * 2007-03-13 2008-09-25 Osaka Prefecture Univ 金属錯体化合物、色素および有機電界発光素子
KR20080101542A (ko) * 2007-05-18 2008-11-21 주식회사 엘지화학 공중합성이 뛰어난 전이금속 촉매를 이용한 올레핀중합체의 제조 방법

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU733813B2 (en) * 1996-11-15 2001-05-24 Montell Technology Company B.V. Heterocyclic metallocenes and polymerization catalysts
US6451938B1 (en) 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
KR100323116B1 (ko) 1997-07-18 2002-11-04 미쓰이 가가쿠 가부시키가이샤 불포화엘라스토머조성물및그의가황고무
KR100354290B1 (ko) 1999-06-22 2002-09-28 주식회사 엘지화학 담지 메탈로센 촉매 및 이를 이용한 올레핀 중합
US6444833B1 (en) 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
CA2451228A1 (en) 2001-06-29 2003-01-09 H. Lundbeck A/S Novel heteroaryl derivatives, their preparation and use
DE10145453A1 (de) 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
ATE445651T1 (de) 2002-09-06 2009-10-15 Basell Polyolefine Gmbh Verfahren zur copolymerisation von ethylen
JP4528526B2 (ja) 2003-03-03 2010-08-18 ダウ グローバル テクノロジーズ インコーポレイティド 多環状縮合複素環化合物、金属錯体及び重合方法
KR20090021399A (ko) * 2004-08-27 2009-03-03 미쓰이 가가쿠 가부시키가이샤 올레핀 중합체
EP1739103A1 (en) 2005-06-30 2007-01-03 Borealis Technology Oy Catalyst
KR100789241B1 (ko) 2005-07-08 2008-01-02 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
KR100789242B1 (ko) 2005-07-08 2008-01-02 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
KR100843603B1 (ko) 2005-12-31 2008-07-03 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
KR100820542B1 (ko) 2006-03-24 2008-04-08 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
KR101011497B1 (ko) 2007-01-29 2011-01-31 주식회사 엘지화학 초저밀도 폴리올레핀 공중합체의 제조 방법
KR100906165B1 (ko) 2008-02-12 2009-07-06 주식회사 코오롱 환상올레핀계 고분자 화합물 및 그 제조 방법
KR101130241B1 (ko) 2008-09-19 2012-03-26 김재수 포장박스 자동 공급 장치 및 방법
KR101479591B1 (ko) 2008-11-21 2015-01-08 삼성전자주식회사 이동통신 시스템의 셀 탐색 방법 및 장치
CN104672364A (zh) 2010-04-12 2015-06-03 湖南石油化学株式会社 使用包含噻吩稠合的环戊二烯基配体的过渡金属化合物制备烯烃-二烯共聚物的方法
KR100986301B1 (ko) 2010-04-12 2010-10-07 아주대학교산학협력단 테트라하이드로퀴놀린 유도체로부터 유래한 티오펜-축합고리 싸이클로펜타디에닐 4족 금속 화합물 및 이를 이용한 올레핀 중합
JP5567208B2 (ja) 2010-04-12 2014-08-06 ロッテ ケミカル コーポレーション オレフィン重合用触媒組成物およびこれを用いたポリオレフィンの製造方法
JP5567209B2 (ja) 2010-04-12 2014-08-06 ロッテ ケミカル コーポレーション オレフィン重合用担持触媒およびこれを用いたポリオレフィンの製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008066266A1 (en) * 2006-12-01 2008-06-05 Lg Chem, Ltd. Supported catalysts for olefin polymerization using transition metal compound having phenylene-bridge, method for preparing the same, and method for preparing polyolefin using the same
WO2008084931A1 (en) * 2007-01-10 2008-07-17 Lg Chem, Ltd. Method for preparing transition metal complexes, transition metal complexes prepared using the method, catalysts composition containing the complexes
JP2008222635A (ja) * 2007-03-13 2008-09-25 Osaka Prefecture Univ 金属錯体化合物、色素および有機電界発光素子
KR20080101542A (ko) * 2007-05-18 2008-11-21 주식회사 엘지화학 공중합성이 뛰어난 전이금속 촉매를 이용한 올레핀중합체의 제조 방법

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
RYABOV ALEXEY N. ET AL.: "Zirconium Complexes with Cyclopentadienyl Ligands Involving Fused a Thiophene Fragment", ORGANOMETALLICS, vol. 21, 8 June 2002 (2002-06-08), pages 2842 - 2855 *

Also Published As

Publication number Publication date
EP2559713B1 (en) 2016-08-10
KR101384450B1 (ko) 2014-04-25
KR20110114476A (ko) 2011-10-19
KR20130124273A (ko) 2013-11-13
JP2013523990A (ja) 2013-06-17
CN102834422B (zh) 2015-03-18
US20130211021A1 (en) 2013-08-15
KR101384412B1 (ko) 2014-04-25
EP2559713A4 (en) 2014-01-08
KR20130135802A (ko) 2013-12-11
CN102834422A (zh) 2012-12-19
WO2011129593A2 (ko) 2011-10-20
US8889804B2 (en) 2014-11-18
JP5546678B2 (ja) 2014-07-09
KR20110114475A (ko) 2011-10-19
EP2559713A2 (en) 2013-02-20
ES2596718T3 (es) 2017-01-11

Similar Documents

Publication Publication Date Title
WO2011129590A3 (ko) 올레핀 중합용 촉매 조성물 및 이를 사용한 폴리올레핀의 제조방법
WO2011111979A3 (en) Method for preparing supported metallocene catalyst and method for preparing polyolefin using the same
MX362264B (es) Polimerizacion de composiciones que comprenden un farneseno.
WO2012006272A3 (en) Catalysts for producing broad molecular weight distribution polyolefins in the absence of added hydrogen
WO2014022010A3 (en) Non-symmetric catalysts comprising salan ligands
MX359522B (es) Metodos para controlar polimerizaciones de olefina de doble catalizador.
WO2010085631A3 (en) Polymers functionalized with polycyano compounds
WO2012134715A3 (en) Branched vinyl terminated polymers and methods for production thereof
WO2011129594A3 (ko) 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 올레핀-디엔 공중합체의 제조방법
SG11201402757UA (en) A method of preparing an olefin polymerization catalyst, the catalyst and ethylene polymers and copolymers obtained using the catalyst
WO2009069483A1 (ja) 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法
WO2011071237A3 (ko) 프로필렌 중합용 고체촉매의 제조 방법
WO2010022228A3 (en) Metal-ligand complexes and catalysts
SG11201400371UA (en) Solid catalyst component for polymerization of olefin, catalyst for polymerization of olefin, and method for producing olefin polymer
WO2011073341A3 (de) Polymerdispersionen
SG10201706412TA (en) Transition Metal Compound, Olefin Polymerization Catalyst, And Olefin Polymer Production Process
WO2013048848A3 (en) Dynamic modulation of metallocene catalysts
MY188919A (en) Catalyst composition with halo-malonate internal electron donor and polymer from same
EP2576633A4 (en) ethylene polymerization
WO2011163309A3 (en) Carbonylative polymerization methods
MX2012012073A (es) Formacion de catalizador de ziegler-natta usando componentes no mezclados.
WO2011129592A3 (ko) 올레핀 중합용 담지 촉매 및 이를 사용한 폴리올레핀의 제조방법
WO2012106695A3 (en) Metal complex catalysts and polymerization methods employing same
SG11201501885VA (en) Solid catalyst component for polymerization of olefins, catalyst for polymerization of olefins, and method for producing olefin polymer
MY148239A (en) A catalyst component for olefin polymerization and a catalyst comprising the same

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 201180018695.0

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 11769059

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 2013504820

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

REEP Request for entry into the european phase

Ref document number: 2011769059

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2011769059

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 13640872

Country of ref document: US